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By M. Nagamori, A. J. Plumpton

"Commercial HCl-leaching of magnesite and serpentine yields highly concentrated aqueous solutions containing 25 mass % to 33 mass % MgCl2. The partial molar enthalpies and heat capacities, the ionic activities of Mg2+ and Cl–, and the Raoultian activity of H2O have been assessed for the concentrated MgCl2-H2O solutions at temperatures of 348 to 373 K. These thermodynamic data are used to calculate the pH of aqueous MgCl2 solutions saturated with a Mg-bearing mineral such as magnesite, serpentine, brucite, forsterite, enstatite or talc. On the basis of these thermodynamic data, technico-economic aspects are discussed as to neutralization with pulverized MgCO3, water evaporation from the MgCl2 solutions, and ore composition including such minor constituents as CaCO3, FeCO3 and Fe3O4. IntroductionA major magnesium electrolytic reduction plant operates in Quebec, where another will begin its production in the year 2000. One uses imported magnesite ore as raw material, while the other will utilize local asbestos tailings (serpentine). Both processes produce a concentrated salt solution of 25 mass % to 33 mass % MgCl2 by leaching the ore with concentrated hydrochloric acid. Thus, the two processes differ mainly in the HCl-leach and related operations. After the HCl-leach of the ore, the serpentine process yields about 25 times more wet cake to filter and wash than the magnesite counterpart. A comparative cost-engineering study with respect to slurry filtration and cake washing has been published elsewhere (Blackburn and Nagamori, 1994). By contrast, the present study considers the thermodynamics and technicoeconomics of the HCl-leach itself for both ores."

Jan 1, 1999

By G. E. Viens, R. A. Campbell, G. N. Banks

A survey of the literature reveals wide differences in the procedures used in making iron ore pellets and in the properties of the pellets obtained. In this paper, the methods of production and the properties of pellets, as reported in the literature, are examined in an effort to determine what correlations exist between them. An attempt is also made to determine the levels of the properties of pellets which are considered acceptable and desirable in modern practice. M UCH has been written regarding the important changes which have been taking place recently in the iron ore industry. As the demand for ore has increased and the supply of direct-shipping ore has dwindled, tl1e problems associated with the utilization of lower grade ores ha\•e been intensely investigated and important advances in both beneficiation and agglomeration techniques have taken place. In particular, there has been a great deal of activity in connection with the pelletizing method of agglomeration. The superiority of pellets over raw ore has been demonstrated in blast furnace tests

Jan 1, 1962

By Ron Light, Doug Applett

"HistoryThe Nanisivik mine began operation in October 1976 as the world's most northerly metal mine and the first permanent industrial project in the Canadian High Arctic. Located 700 km north of the Arctic Circle on Baffin Island's Strathcona Sound, exploration by Texasgulf Inc. between 1957 and 1970 had outlined the ore deposit. In 1974, Nanisivik Mines Ltd. was formed with Mineral Resources International, the Government of Canada, Metallgesellschaft and Billiton being shareholders, and Strathcona Mineral Services Ltd. providing project management. In 1996, Breakwater Resources purchased the mine from Alberta Energy Corporation Limited which had recently acquired the assets of then owners Conwest Exploration Ltd.Ore DepositThe main ore deposit is very flat, approximately 80 m in width and varying in thickness from 3 m to 16 m. The length of the deposit is approximately 3000 m with satellite zones located on the perimeter of the main zone. The economic mineralization is sphalerite with minor galena and silver. The sphalerite and galena are coarse grained and associated with pyrite as the main gangue component with minor inclusions pf dolomite and calcite within the deposit. The deposit being hosted in a permafi·ost environment creates a number of challenges. Dry drilling is employed in room and pillar production drilling. The permafrost aids in the stability of both the pillars and the back."

Jan 1, 2000

By Güney

"An investigation carried out to determine the tendency of coals to heat spontaneously in terms of time-temperature curves coupled with the resulting oxidation products in an adiabatically controlled laboratory setup is described. Tests were made at differing moisture conditions, including oxidation and also oxidation with either adsorption or desorption of water vapour on coal.From the experimental evidence, there is reason to believe that the oxidation of coal, although an important factor, is not the predominant one in the development of spontaneous heating. In addition to the temperature increase in coal and the gaseous products evolved due to auto-oxidation, the process is accelerated by adsorption and retarded by desorption of water vapour on coal."

Jan 1, 1971

By John Dasher

The analyses reported on in this paper indicate that there are hydrometallurgical routes from sulphide concentrates to copper that are potentially competitive with smelters which are not permitted to emit sulphur oxides. The various hydrometallurgical processes, and their economics, are discussed.

Jan 1, 1973

By T. Iwasaki

This paper points out two key elements in resource trade in general and the Canada-Japan relationship in particular. The first is that the advanced countries have a more important role than one would expect in the supply of resources in world trade. Canada 's dual role as a major resource supplier in conjunction with an advanced economy will continue to increase. The second point is the heavy reliance on foreign resource supplies in some advanced economies, particularly in Japan. Finally, as regard the future of the Canada-Japan economic relationship, particularly .in resource development, it is suggested that trade could be enhanced by an accelerated exchange of various types of resources between the two countries. These include natural resource commodities as well as the more abstract capital, technological and human resources.

Jan 1, 1978

By G. S. Hume

In the transformation of carbonaceous materials, such as peat, to coals of various grades, the changes are known to be both physical and chemical and the grade of coal finally produced depends on the stage to which alteration proceeded. Those changes, which are frequently spoken of as the results of metamorphism, are due to pressure with accompanying heat and, according to the amount of metamorphism to which the sediments with the included carbonaceous beds have been subjected, there is a gradation from peat to anthracite coal, and even to graphite. The improvement in the quality of the coal as a result of metamorphism is due to an increase of the carbon content of the coal and a corresponding loss of the volatile materials. This rise in the quality of the coal according to the degree of metamorphism is well illustrated by the coals of western Canada. In the Plains area, where the deformation and the attendant metamorphism of the sediments is comparatively small, the coals are lignites, whereas in the mountains, where deformation has been severe, the coals are semi-anthracites. Sub-bituminous and bituminous coals occur in the intervening areas. The same general relationship between the quality of the coal and the degree of metamorphism holds true for the Appalachian basin of the United States, where there is a progressive improvement in the quality of the coals from west to east, that is, from an area of comparatively slight metamorphism to an area of marked deformation in the Appalachian Mountain region. But while it is true that this relationship holds in a general way, it has been found that the improvement in the quality of the coal is not always uniformly progressive, and there may be local variations such that an area containing coal with a carbon content indicating low or medium metamorphism may be surrounded by areas in which the coals are of higher grade. These local variations in many cases can be explained, and they in no way detract from the general rule that, in a region exhibiting a progressive betterment in the quality of the coal from an area of low metamorphism to one of more marked deformation, the quality of the coal, i.e., the amount of fixed carbon in the coal, may be taken as an index of the degree of metamorphism of the coal as well as of the sediments in which it occurs, It has been pointed out (') that certain coals, such as cannels, are unreliable indicators of the varying degree of metamorphism because of the nature of the material from which such coal was derived. Such coals, however, are not known in western Canada and their behaviour need not here be discussed.

Jan 1, 1927

By E. M. Cameron

Reconnaissance radiometric and geochemical data have been obtained for an area on the western shore of Wollaston Lake that includes the Rabbit Lake uranium deposit. The study area is extensively drift cover ed. The geochemical data were obtained by analysis of center-lake sediments and surface waters for a variety of elements and other constituents. The airborne radiometric data comprise measurements of eU, eTh and K obtained with a .50,000-cc NaI (Tl) detector at a mean terrain clearance of 120 m and 5-km flight-line spacing. Uranium in lake sediments and uranium in waters are the most effective geochemical indicators of uranium mineralization; the other elements measured are not notably anomalous. A sample site density of one per 1 8 km 2 is more than adequate for identification of the mineralized area. Because many water samples contain close to or below the current analytical detection limit of 0.05 ppb U, the use of sediments is generally favoured. for broad-scale reconnaissance in the region. Uranium in these lake sediments appears to be little influenced by variations in the organic or iron and manganese content. The most effective radiometric indicator of the mineralization is the eU/eTh ratio. This parameter is less influenced by environmental variation on the ground beneath the flight line than eU alone . The eTh/K ratio is anomalous under the Athabasca Formation unconformity where, in places, the uranium mineralization is localized.

Jan 1, 1977

By Loris S. Russell

THE plains of southern Alberta constitute one of the classic areas of geological investigation in Canada, for it was here in 1874, and in 1881 to 1883, that George Mercer Dawson (1, 2, 3) made the pioneer observations that are basic to all subsequent work on the interior plains of Canada. Dawson's work was extended eastward by R. G. McConnell ( 4) and northward by J. B. Tyrrell( 5) , but it remained. for D. B. Dowling to re-examine Dawson's Bow and Belly River Area and to make certain necessary revisions in the stratigraphical system of his predecessor. In 1917, Dowling published his memoir, The Southern Plains of Alberta( 6) , which remained for over ten years the last word on the stratigraphy and structure of the area described. It is generally conceded that Dowling's work made known the existence of a great artesian basin beneath the semi-arid plains of southeastern Alberta. In addition, his structural studies greatly stimulated the search for natural gas and petroleum. The most recent general publications on this area by the Geological Survey are based on the field work of M. Y. Williams, E. J. Whittaker, W. S. Dyer, and P. S. Warren, between the years 1923 and 1926. Their results were embodied in the Calgary Sheet (7) and the memoir, Geology of Southern Alberta and Southwestern Saskatchewan (8). By this time, the number of geologists working in Alberta in the development of the petroleum and natural gas industries had become large, and in 1931 the Alberta Association of Petroleum Geologist~ offered the Donaldson Bogart Dowling Memorial Symposium on Stratigraphy of Southern Alberta( 9) , a most valuable series of papers descriptive both of the ,surface stratigraphy and that observed in the well records.

Jan 1, 1937

By K. N. Subramanian

Previously reported work on total oxidative leaching of chalcopyrite concentrates ha s shown that high copper extractions are obtained at 210°C and 0.4 MPa oxygen pressure. A simple integrated flow sheet using pressure leaching, solution treatment involving precipitation with a calcium base, and electrowinning to produce wire-bar-quality copper is described. Reagent and energy requirements developed from this work indicate that the process could be attractive for small operations where a smelting-refining complex cannot be justified.

Jan 1, 1978

By Daniel E. Walsh, P. D. Rao

"A four-inch compound water cyclone (CWC) was tested to evaluate its gold recovery characteristics when processing -4.8 mm run-or-pit, placer material. Neutron activated placer gold particles (840 to 37 microns) were used as radiotracers (/98Au) in a closed circuit ewe test loop to determine concentrator recovery; a procedure believed unique to this study. The effect on gold recovery of gold size and shape, feed pulp density, feed pressure, vortex finder clearance (VFC), ewe cone type, top-size of the feed solids, presence or absence of heavy minerals in the feed, and the quantity of-37 micron slimes in the feed was investigated in over 300 tests.CWC concentration ratio and the top-size of the underflow solids were both affected by cone type, VFC, and feed pressure. Gold recovery was significantly affected by gold size, gold shape, and concentration ratio. These effects are complex, because significant size-concentration ratio and size-shape interactions exist. Radiotracer techniques showed gold particles had a residence time within the ewe of approximately one second. This study suggests ewe gold recovery is a concentration. This work suggests ewe gold recovery is a function of particle size and shape, and the flow rate through the cyclone. CWC cone ""bed density"" is considered important only as a thin, protective layer, which shields coarser gold particles from the entraining currents and facilitates their movement through the CWC.IntroductionCompound water cyclones (CWC), or automedium cyclones, are enhanced gravity concentrators for the beneficiation for slurries of sand, coal, and ground ore (Fig. 1). They are called compound water cyclones because of the compound slopes of their basal cones (Fig. 2) and are operated to suppress classification phenomena in favour of gravity concentration effects. The compound water cyclone is not a new wet concentrator. It was developed in the late 1950s by Dr. Jan Visman through research sponsored by Canada's Department of Energy, Mines, and Resources. Since that time, it has become a common unit in coal washeries for cleaning fine coal. CWCs and other versions of concentrating cyclones have also shown promise for heavy minerals and precious metals recovery."

Jan 1, 1988

By J. Visman

"The Compound Water Cyclone is a concentrator for the wet processing, in bulk, of finely divided materials such as slack coal, fine ores and mineral sands. It was originally developed by the Fuels and Mining Practice Division of the Mines Branch, Department of Mmes and Technical Surveys, Ottawa, for the cleaning of friable slack coals and slurries.Since its introduction in the coal industry in 1962, its application to other materials has also been studied, with special emphasis on simplicity of operation and low over-all cost per ton of finished product .In this paper, a description is given of commercial two-stage units presently available for the processing of granular materials, including wastes a1:1d other low-grade products. A pneumatic control system is used for operating the cyclone under back pressure .and for automatic cut-point adjustment. An account is given of results obtained on coal mineral sands and ores in the Wes tern Regional Laboratory of the Department of Mines and Technical Surveys. Results of several industrial applications are discussed."

Jan 1, 1966

By L. Kilburn

A survey of 281 mineral exploration agreements examines the ratios among three ways that may be used to purchase an interest in a mineral property, viz: pay cash, pay shams and make future expenditures on the property. The dollar value of the future expenditures exceeds that of cash or shams by about nine times in most of the 110 agreements that contain cash-expenditure or share-expenditure components. Results suggest that cash and shams are treated about the same in terms of value. Buyers and sellers haw opposing priorities for the way that they prefer to purchase a mineral property. These opposing priorities should give rise to a perceived 50:50 balance between cash/share payment and future expenditures to satisfy the idealized situation described by most definitions of fair market value (FMV). This balance between cash/share payments and future expenditures appears to be rationalized in negotiations to a FMV when expenditures are nine times greater than cash and/or payments. On this basis, it is proposed that the FMV of a property may be determined by aggregating the dollar amount of the cash/share payments plus one-ninth the dollar value of future expenditures, as set forth in the respective purchase agreement, and proportionately applying such aggregate to full property value.

Nov 1, 2005

By K. C. Grogan

"GeneralGIANT ORE is complex, with the gold values for the most part occurring in extremely close association with arsenopyrite, stibnite, jamesonite, and a wide group of antimonial minerals locally termed 'the grey minerals'. Pyrite is the most abundant of the sulphide minerals• and minor quantities of chalcopyrite, galena, and sphalerite also occur. Pyrrhotite has been found in some sections of the mine, but to date none of it has been nickeliferous. Native gold occurs in varying amounts throughout the ore bodies.In 1944, ore dressing investigations were commenced on diamond-drill core rejects and samples of surface outcrop ore. Results soon indicated that treatment to produce satisfactory recovery of the gold values would involve fine grinding to 80-85 per cent minus 200 mesh, recovery of free gold by jigs, followed by flotation, roasting of the flotation concentrate, and subsequent cyanidation of the calcine. Proceeding from this information, the flow-sheet was prepared, plant design worked out, equipment purchased, and construction of the treatment plant commenced in May, 1947.The crushing, grinding, and flotation units of the plant were rushed to completion and commenced operation on May 12th, l.948, at 225 tons of ore per day. This rate was maintained until January 27th, 1949, when the Allis-Chalmers roaster and cyanide plants were completed and commenced operation. During the period May 12th, 1948, to January 27th, 1949, gold recovered by amalgamation was the sole source of revenue. Flotation concentrate was stockpiled pending the completion of the Allis~Chalmers roaster and cyanide plants."

Jan 1, 1953

By C. Tan, A. Putz, P. Lacombe, R. Kemp, M. Kaya, B. J. Huls, A. R. Laplante

"This paper concentrates on the four recent plant trials/ applications of froth washing. Results showed that improved metallurgical performance can be achieved with wash water. Increased froth cleaning yielded better upgrading, and some cases slightly improved recovery. Froth sampling and salt tracer tests supported the findings of froth washing tests.At Falconbridge, Ni grade increased from l.47% to 2.15% and recovery from 85% to 87%. At Eastmaque, final Au grade increased from 2.3 to 2.7 oz/st at a slightly higher recovery. At Les Mines Selbaie, Cu grade increased from 24.5% to 25.S% and Zn grade from 54.5% to 56.l%. At Zinc Corp. of America, average Zn grade increased from 55% to 56. 8% at the same recovery for a 45-day period. A number of plants in Canada and the United States have evaluated and/or now practicing froth washing. Wash water has now proved itself in some plants over several months of operation.INTRODUCTIONFroth washing in mechanical flotation cells offers a number of metallurgical (i. e. increased grades and/or recoveries) and economical (i.e. decreased transportation and smelting & refining costs) benefits. Fundamental development work in laboratory and pilot scales performed at McGill yielded encouraging results. (Kaya and Laplante, 1988a and 1989a). Since laboratory and pilot flotation performance can differ from full-scale due to differences in hydrodynamics, kinetics, and froth characteristics (e.g. stability, loading etc.), plant trials were essential to prove the viability of this technology."

Jan 1, 1990

By A. E. Boone

"The paper presents critical areas in which improved coordination of effort by industry, government and sup-pliers will be essential to continue the growth record of the Canadian mining industry into the 'seventies'. The analysis includes: exploration, production, mining methods, research and development, markets, management and industrial relations. Performance objectives are suggested where tangible results can be measured. The author suggests the methods by which the 'seventies' can be the greatest decade in the history of Canadian mining. It is indicated that a national mineral policy is essential to the Canadian mineral industry."

Jan 1, 1970

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966

By R. M. BUCHANAN

The segment of Canadian industry based on smelting of alum in um and manufacture of consumer products is based entirely on imported alumina and bauxite. In the absence of Canadian bauxite deposits, consideration of anorthosite, a less desirable aluminous rock, is being undertaken as one alternative in maintaining assurance of supply. Anorthosites in Canada cover many thousands of square kilometres of the Precambrian Shield. Although compositions vary widely among Canadian anorthosites, many appear to exceed the specified minimum of 25% A I 20 3 in bodies containing more than the required JOO million tonnes. A lthough most Canadian anorthosites are of Precambrian age, one located in British Columbia has been identified as being Middle _Cretaceous.

Jan 1, 1984

By Wm Petruk

"The tungsten-bismuth-molybdenum deposit in southwestern New Brunswick occurs in greisenized and silicified tuffite * and feldspar porphyry in and adjacent to volcanic necks. The ore minerals occur as veins and veinlets and as disseminated grains in gangue. These minerals can be grouped into three assemblages. Assemblage 1 consists of oxides and phosphates of W, Ti, Fe, Nb, Sn, Ta and rare-earth elements, with the main minerals being deposited in the sequence wolframite, rutile, cassiterite. Assemblage 2 consists of arsenopyrite, molybdenite and bismuth, and assemblage 3 of sulphides with minor cassiterite and arsenopyrite. Sphalerite is the main sulphide mineral, but it contains minute inclusions of copper-tin- and indium-bearing minerals. Textural relations suggest that most of the elements can be recovered from this ore by conventional mineral beneficiation and extraction methods, but a variety of techniques must be employed. It is expected that the wolframite and molybdenite can be recovered satisfactorily, but poor recoveries are expected for bismuth and cassiterite. A sphalerite concentrate can be readily obtained by flotation, but it would contain a wide variety of elements. It is suggested that leaching be used to recover the bismuth and the elements in the sphalerite concentrate."

Jan 1, 1973

By John Ramsay, Frederick A. Edwards, J. Eric Belford, Clarence V. Amyotte

"DEVELOPMENT of the underground mine is carried out from a main ramp driven from surface to the 800 and 1200 levels and from a shaft sunk to 3050 ft. Sub-levels at approximately 100-ft vertical intervals, starting 300 ft above the 800 level, were collared from the ramp as it advanced and a considerable amount of development work was pursued. The lateral and ramp work provided an opportunity to train drift crews, test equipment and methods, assess ground conditions and advance the initial stope development. The development of an exhaust ventilation raise system closely followed the extension of the level development to the south end of the orebody (Fig. 26) . On completion of the shaft, temporary lip pockets were installed at the shaft stations on the 800, 12.00, 1600, 2000 and 2400 levels. The permanent loading pocket had been installed on the 2860 level as part of the shaft-sinking contract and the level had been connected to the 2800-level station by a small muck transfer raise. Development of the 2800-level area was given top priority at this stage. This included a 1000-ft cross-cut to the crusher location, the crusher excavation, storage bins, conveyor ways and a ramp to connect the 2800 level to the loading pocket, the rope changing station and the shaft sump. The development and installation of the rock handling system between the 2400 level and the shaft bottom was contracted to Macisaac Mining and Tunnelling Company, of Sudbury, Ontario."

Jan 1, 1974