Search Documents

By J. M. Whiting

"North America has entered a period when greatly increased attention must be given to energy .supply and demand by government, industry and individuals. Such increasing concern about energy will be a long-term phenomenon, accompanied by continuing examination of future resource development and utilization. Those engaged in or associated with mining, a major energy consumer, are likely to experience a variety of problems which are associated with the end of an era of low-cost, virtually unlimited energy supply. Their efforts, furthermore, may be subjected to escalating public and government scrutiny, involvement and control. However, ever-growing recognition of the real and urgent necessity to systematically develop new energy supplies within Canada and the United States will provide unusual challenges and opportunities for those companies and individuals with mining expertise. The vast deposits of coal, tar sands and oil shale provide a relative certainty of supply which only stands to gain in attractive ness with time. In order to benefit from this aspect of certain supply, nevertheless, synthetic fuels will have to be produced at a tolerable cost. This will always require excellent process design and engineering. As synfuels development expands to any significant production level, however, and Jess than ideal reserves are scheduled, the usual geologic-productivity complexities encountered in making ore out of low-value rock will tend to become of prime concern. It is for this reason that the services of experienced mining personnel will be in growing demand in energy production."

Jan 1, 1973

"The outlook for Eastern Canada is decreasing coal production over the next few years; however, a reappraisal of the long-term requirements and increased prices of coal could lead to a revitalizing of the industry. The market for Western coal is expanding and is expected to exceed 50 million tons per year in the metallurgical and thermal power fields. Western coal reserves are currently estimated at 119 billion tons. Technical developments in Eastern Canada include a shearer and gate-end support system to mechanically cut the stall and brushing at the tail-end of a longwall. In Western Canada, the most modern equipment is used in mining, beneficiating and shipping coal. Results to date on the underground hydraulic experiments exceed expectations. The importance of reclamation is recognized and plans have been made to restore and re-vegetate disturbed areas and mine dumps. In Eastern Canada, experiments were started to determine the feasibility of coal reclamation from mine dumps, including one dump that is on fire. The Mining Research Centre, Mines Branch, continued to conduct research work oriented toward solving Canadian mining problems The Western office of the Centre, opened in 1970, was set up primarily to study problems associated with a resurgent coal industry."

Jan 1, 1971

By Cedric E. Gregory

"A study of model rectangular mine shafts has been made in the wind tunnel, with the aim of reducing air-flow resistance elements to a practicable minimum. An analysis of Table 7 shows an indicated average decrease in resistance of 28 per cent by adopting the over-all modifications involved in the configurations actually tested. Much greater reductions (up to 68 per cent) are indicated by extrapolating beyond the test results directly achieved. Intermediate partial reductions in aerodynamic resistance are shown for individual modifications, such as: (1) about 3 per cent for locating the lagging in the No. 4 (inside flush) position as against the No. 1 position - 8 per cent as against the No. 2 position - and 23 per cent as compared with position No. 3; (2) about 12 per cent for using lagging instead of steel meshwork along the divider separating the skipway from the service compartment; (3) about 14 per cent for using steel gridwork ladder stagings at 3-set intervals instead of similarly spaced wooden stagings; (4) about 12 per cent for using steel gridwork ladder stagings at 3-set instead of at 1-set intervals; (5) about 13 per cent for fitting a streamlined fairing (see Fig. 5) to the upstream face of the skipway divider. Contrary to expectations, an advantage of only 3 per cent is indicated for lagging in the inside flush (No. 4) position over the outside position (No. 1). This slight gain does not appear to warrant the cost of moving the lagging. However, if the lagging is already in the No. 2 or No. 3 position, there is an 8 and 23 per cent advantage respectively."

Jan 1, 1973

By I. Dymov, W. Phillips

A process has been evaluated, on a continuous pilot plant scale, to treat refractory gold arsenopyrite/pyrite concentrates. The process consisted of biological leaching to partially oxidise sulphides, followed by pressure leaching for complete sulphide oxidation and arsenic precipitation, followed by liquor neutralisation and cyanidation of the autoclave residue for gold recovery. This paper provides a brief description of the treatment flowsheet and discusses some of the main parameters and results of the process. During integrated pilot plant campaigns, it was confirmed that acceptable sulphide oxidation and gold extraction of 96-98% could be achieved by a two-stage oxidation with BIOX® (4 days total retention time) followed by PDX (40 minutes retention time at 220°C). Only partial arsenic precipitation was achieved in the autoclave, followed by complete precipitation by neutralization under atmospheric conditions. The overall process could be significantly simplified, and capital and operating costs reduced, with a flowsheet modification allowing all of the BIOX® liquor to bypass the autoclave directly to the neutralization circuit.

Jan 1, 2004

By A. E. Hilder

Introductory The following pages present the results of field investigations, laboratory and commercial tests, drilling, surveying, and preliminary development of the refractory clays which have been discovered recently in the township of Kipling, at the foot of Long rapids on the west side of the Mattagami river about 57 miles north of Kapuskasing and approximately 7 miles north of Smoky Falls, the terminus of the privately owned railway operated by the Spruce Falls Power and Paper Company, Kapuskasing (see Figure 1). Investigations on the clays of northern Ontario have been carried on over a period of seven years by officers of the Ontario Department of Mines, and I am indebted to the information published by that Department in reports by W. S. Dyer and A. R. Crozier, as well as?by Professor R. J. Montgomery, of the Ceramic Department, University of Toronto. It was, in large measure, the data given in the 37th, 38th, and 42nd Annual Reports of the Ontario Department of Mines that led me to make a personal investigation of the Mattagami River clays, with the result that we now have a commercial undertaking that will develop eventually into an industry of considerable importance in supplying the central manufacturing districts of Canada with refractories that heretofore have been largely imported from the United States. An extract from the 42nd Annual Report of the Department, Part III, 1933, page 75, reads as follows: "As for the refractory clay, the deposits are undoubtedly very large, but what is urgently needed is a deposit near the railway under sufficiently shallow overburden for recovery by stripping'. Having previously made an investigation of the clays adjacent to the Temiskaming and Northern Ontario railway, and these clays proving unsuitable, I turned my attention to the outcrops of refractory clays on the Mattagami river, first reported by Keele in 1919. This area offered possibilities within the economically permissible distance from rail transportation.

Jan 1, 1935

By Mathieu Dubé

Good mechanical strength of green iron ore pellets is required to avoid breakage and excessive deformation during their handling and further processing. However, green balls with good resistance to handling are often too plastic, which impacts the bed permeability in induration furnaces. Measurements of plasticity, bed void fraction and green ball sphericity as well as bed permeability were carried out on various samples of green iron ore pellets having different mechanical strength. Results show that bed void fraction, sphericity and permeability all depend, to some extent, upon green ball mechanical strength (plasticity). Understanding and controlling the mechanical strength of green iron ore pellets would then help to maximize both the productivity of the induration process as well as the quality of fired pellets through a more stable firing process. Results of research work carried out at COREM, with the objective of improving green ball characterization methods, are presented in this paper.

May 1, 2007

By J. Forster, C. A. Pickles, Mackowiak. K.

The future development of nickel laterite deposits is crucial with regards to satisfying impending nickel demands. The commercial implementation of new hydro/pyrometallurgical processes in recent years has led to significant improvements in the extraction of nickel from the laterite ores. One potential alternative pyrometallurgical processing route would be to selectively reduce the nickel and produce a concentrate with nickel contents similar to those attainable in the conventional flotation of sulphide ores. However, even bench scale studies have not yet been able to produce a high grade (>15% nickel) concentrate from a low grade laterite ore. The present research involved the microwave vacuum reduction roasting of a nickel laterite ore to yield a high grade concentrate, rich in nickel. Firstly, the effects of temperature and pressure on the nickel grade and recovery were investigated using a thermodynamic model. Secondly, briquettes containing a mixture of charcoal and a low grade silicate nickel laterite ore were reacted in a microwave vacuum system. The experimental variables studied were the input microwave energy, pressure and absorbed microwave power. Thirdly, the ferronickel in the reacted briquette was concentrated by magnetic separation and nickel grades of up to 21% could be achieved.

Jan 1, 2015

By John Convey

"IRON ORE was first smelted in Canada about the year 1736 at Les Forges, Quebec -a most appropriate name for such a historic locale. During these early years of the 18th, 19th, and first quarter of this century, about six million tons of ore were mined and employed in the manufacture of items ranging all the way from kettles, stoves, and cannon for the early settlers to weapons of war for the allied armies of World War I.But this symposium on iron ore is not concerned with this early period. Instead, it is concerned with the iron ore industry of today -an industry which will soon be-come one of the two most valuable mineral industries in Canada.The subject in its broad geographic and economic aspects will be introduced by Mr. Buck; Dr. Harrison will describe the geology and origin of the principal iron ore deposits; Dr. Downes will go into beneficiation as it applies to iron ores; and Mr. Gertsman will discuss primary processing. The symposium will not deal with the steel end of the industry, because that phase itself could well form the subject of a symposium."

Jan 1, 1955

By J. W. Merkley, K. B. Hustwick

"The authors describe the use of a computer system for the control oj warehouse inventory at Cominco's Canadian operations. The challenge presented by the company's diverse products and various locations necessitated a practical approach to operational and manpower requirements. The utilization of modern forecasting techniques, manual intervention and exception reporting provides system flexibility. The system also provides both operational and management control to set required service goals at the lowest inventory levels for inventory management.IntroductionCominco Ltd. is a Canadian company, with international operations, the principal business of which is zinc, lead and chemical fertilizer s. Its involvement is fully integrated and range s from mineral exploration through mining, smelting, refining and by-product production to international marketing. It also embraces related services, including trade, wharfarge and power. With head office in Vancouver, it is involved, directly or through subsidiary or associated companies, in Canada and in the United States, Greenland, Europe, Australia, India and Japan.Cominco has over 12,000 employees and 26,000 shareholders, with 91% of all shares held in Canada.Cominco's Inventory Control System is one of the most extensively used computer systems employed by the company. Also, inventory control is regarded as one of the most economically successful computer applications to be undertaken by the Data Processing Services (D.P.S) Group that was responsible for the development of the Inventory Control System.The main use of automatic inventory control has been at operating plants in Western Canada and the Northwest Territories, which are separated by large distances. Each location has equipment-intensive mining and processing operations and it is essential to maintain control of parts and supplies inventories. Some of these locations are remote from urban and industrial centres and it is important to avoid the adverse effects of high personnel costs and re-training due to turnover."

Jan 1, 1982

By H. V. Kinsey

"IntroductionTITANIUM is probably the most widely publicized metal today. Much has been written, both in the lay press and the technical press, about its properties and potentialities. In view of the fact that Canada possesses large quantities of titanium-bearing ore, and could conceivably become a major producer of metallic titanium, it was felt that a paper dealing mainly with the physical metallurgy of titanium would be of interest to this Institute. This paper is concerned chiefly with the useful properties of titanium and its alloys and the fundamentals governing the modification of its properties by alloying.Physical Properties of TitaniumTitanium belongs to a family of metals that have been termed 'gas sensitive' (I), because their mechanical properties are altered by certain gases which they readily absorb and retain. Other metals of this group are zirconium, hafnium, vanadium, columbium, tantalum, and chromium. Titanium has a strong affinity for oxygen and nitrogen and once it has absorbed these gases they cannot be removed either by melting in vacuum or by any degassing agent. These gases, when present in excess of about half a per cent oxygen plus nitrogen, render the metal brittle and useless as a structural material.Some of the typical physical properties of titanium are listed in Table I along with those of common structural metals for comparison."

Jan 1, 1953

By J. E. Dutrizac, Alba Sunyer

The factors affecting the precipitation of arsenic-free alunite (KAl3(SO4)2(OH)6) were investigated in a series of laboratory experiments. Although the amount of alunite precipitated increased with increasing retention time, temperature, solution pH and the concentrations of Al(SO4)1.5 or K2SO4, the composition of the products remained nearly constant. The preferred conditions identified for the precipitation of arsenic-free alunite were then used to assess the behaviour As(III) and As(V) during alunite precipitation at 98°C. Increasing additions of As(III), as NaAsO2 or As2O3, resulted in a slight increase in the amount of precipitate formed at pH 2.80. However, X-ray diffraction analysis showed all the precipitates to be alunite, and <0.2% As(III) was detected in the products. In contrast, increasing additions of As(V), as KH2AsO4 or As2O5, resulted in significant increases in the amount of precipitate formed at pH 2.80 or 3.00. Furthermore, the arsenate (AsO43-) contents of the precipitates increased up to 15%, and the sulphate contents decreased, as the As(V) concentration of the synthesis solution increased from 0 to 9 g/L. X-ray diffraction analysis of the products detected only alunite, but there was a progressive expansion of the alunite cell with increasing arsenate content. The implication is that arsenate substitutes for sulphate in the alunite structure. Preliminary observations on the environmental stability of the arsenate-bearing alunite using the TCLP protocol gave solubilities <0.4 mg/L from a precipitate containing 8.5% AsO4 and 7.8 mg/L from a product containing 19.5% AsO4. Thus, it appears that alunites containing less than -10% AsO4 would be an acceptable vehicle for the disposal of arsenic from hydrometallurgical processing solutions.

Jan 1, 2011

"IntroductionThe Chairman, in his speech to this body last year in Montreal, stated that the Dominion Coal Board looked to and depended upon the Bureau of Statistics for statistical material, and the Bureau does collect and publish monthly and annual data on coal. It may therefore be asked why an officer of the Dominion Coal Board should prepare and give a talk on statistics.I would explain that it has been our experience in the Board that, since the supply and consumption of coal in Canada is subject to a seasonal ebb and flow, it can be more profitably studied on the basis of a twelve-month period ending on March 31st than of a calendar year, since the end of March does represent a fairly stable end point in this ebb and flow. The figures are not prepared or published by the Bureau on that basis and it has therefore been thought that a presentation on this fiscal-year period would be of interest. The Bureau of Statistics has agreed that this may be valuable and all the data here presented are based on the reports secured from various sources by the Mining, Metallurgical and Chemical Division, Dominion Bureau of Statistics. The only contribution by either myself or the staff of the Dominion Coal Board has been the tabulation in a different twelve month period, and the comments upon the picture presented.It should be noted that the data for the month of March, 1950, are not available in all cases and consequently the figures for that year contain an estimate for this month."

Jan 1, 1950

By J. A. Russell

AS THE LOCAL electric generating plants increased in size and capacity and costs of producing electricity came down, it became apparent that it was no longer good economy to operate individual boiler plants at the Company&apos;s various collieries to power steam hoists and compressors. Great economies could be made by burning the Coal at central power plants and using electric power at the collieries. During the period after the end of the war, a steady and continuing programme of replacing first the smaller steam-driven units, and later the steam-driven compressors, was undertaken, and finally the larger hoists, those at No. 12 Colliery in New Waterford and No. 20 Colliery in Glace Bay, were the last units operated by steam.

Jan 1, 1958

By H. L. Cheng, C. H. B. Leitch, C. T. Hood, A. J. Sinclair

"Epithermal Zn-Pb-Cu-Ag-Au quartz-carbonate-barite veins at the Silver Queen mine near Owen Lake, west-central British Columbia, are hosted by Late Cretaceous Tip Top Hill andesitic volcanic rocks. The veins form a rectilinear northwest-northeast pattern that differs slightly from regional structural trends. The main northwest-trending veins are oriented very close to the trend of regional northwest faults, but the crossing veins tend to be more east-north-easterly (070 degrees)compared to a regional north-easterly trend (040 degrees). The character of the veins suggests they are extensional features formed by dextral slip related to Paleogene oblique subduction, or intrusion of magma at depth, or both.In detailed exploration at the mine, the veins cannot be modelled as simple tabular sheet-like bodies. Instead, they are complex structures that divide and rejoin, forming multiple veins or stringers, or are found in shear zones as replacement features with quartzsericite- clay-carbonate-pyrite alteration haloes of variable width that make definition of vein margins and correlation from hole to hole ambiguous. In addition, individual veins within each of the main structures have en echelon characterboth along strike and down dip.Geological and assay data must be carefully studied to define the margins of these complex veins before any estimation of ore reserves may be made. Where multiple veins occur in a section, ore/gangue mineralogy, assays, character of wallrock alteration, and thickness of vein and mineralized hangingwall, median and footwall zones must be used to evaluate continuity of mineralized structures. Well-defined sections are projected into areas of increasing complexity. Once the vein boundaries are defined, metal concentrations, important metal ratios(Au/Ag, Pb/Zn, Cu/Zn), and true thicknesses of the vein provide the basic data for reliable ore reserve estimation."

Jan 1, 1991

By Sangjian Zhang, Zhu Xiao, Lairong Xiao, Rushi Chen, Mei Fang, Zhou Li

The copper-graphite metal matrix composites were fabricated by two different production methods: directly sintering with copper and graphite (Cu-Gr composite), and in-situ sintering with cuprous copper and graphite (Cu2O-Gr composite). During the in-situ reaction sintering, a redox reaction occurs at the interface of the Cu2O particles and Gr particles, resulting in the improved physical and mechanical properties of Cu2O-Gr composites. Compared with Cu-Gr composite, Cu2O-Gr composite has a higher compression strength at any given graphite content due to the improved interface bonding and uniformly distributed fine graphite particles in the matrix. Increasing graphite content decreases the mechanical properties of the copper-graphite composites. The compression strength of Cu2O-Gr composite is 50-100 MPa higher than that of Cu-Gr composite. INTRODUCTION Copper-graphite composites have been widely used in industry due to their low density, relatively high strength and hardness, good thermal and electrical conductivity, arc ablation resistance and self- lubrication ability (Grandin & Wiklund, 2018; Han & Xu, 1999; Huang et al., 2017). Electric sliding contact friction pair in the high-speed railway system and motor brush in electric contact components have a very high demand on electrical conductivity and self-lubrication ability of materials. The electric devices need to bear both mechanical load and high electric current. Copper-graphite composites with good mechanical, electric and self-lubrication properties are the best candidates for application in multifunctional electric sliding contact frication components. The relative sliding speed of friction pair is developing towards 100 m/s or even faster, which can withstand the electric flow of more than 800 A, and it is often accompanied with vibration and impact (Guo & Ding, 2008). Conventional wear-resistant materials can no longer meet the current requirements and this promotes the development of copper- graphite composites with excellent comprehensive properties (Ding, Chen, Zhu, Zhang, & Zhou, 2009; Yasar, Canakci, & Arslan, 2007). There are many ways to fabricate copper-graphite composites, mainly including powder metallurgy method, liquid immersion infiltration method, rapid sintering method and electrodeposition method (Kalin & Poljanec, 2018; Kim, Lee, & Han, 2014; Liu et al., 2018; Wang et al., 2018). Each method has its own advantages and disadvantages, and the powder metallurgy method is the most commonly used one due to its simple process, high economic benefit, and industrial production applicability. The common steps of the powder metallurgy method are as follows (Samal, Parihar, & Chaira, 2013): firstly mixing the copper (copper alloy) powders and graphite with a certain ratio, following by die-forming, and then sintering at the high temperature with or without pressure. The advantage of copper-graphite composites is that the graphite distributed in the copper matrix uniformly and it can form a carbon diaphragm preventing the wear of the composite (Fu & He, 2010). However, the bonding strength of the interface between the copper matrix and the graphite is relative low as the combination between them is mechanical interlocking but not metallurgical bonding (Ma et al., 2008). It is meaningful to develop new fabrication technology of copper-graphite composites with better interface bonding, which could provide guidance for the design of copper-graphite composites with excellent comprehensive properties.

Jan 1, 2019

By P. Mundell, R. Torbin

"There are many physical and operational obstacles in pipelines that make the passage of inspection robots impossible including:•,Small radius bends•,Low operating pressure•,Plug valves•,Large changes in pipe size•,No permanent access to the pipeline.The inspection of unpiggable pipelines requires the marriage of a highly agile robotic platform with NDE sensor technology operating as an integrated system. Foster-Miller and GE/PII are developing a robot that is essentially a battery powered, train-like platform. Both front and rear tractors propel the train in either the downstream or upstream direction. Like a train, the platform includes additional ""cars"" to carry the required payloads. The cars are used for various purposes including the NDE sensor module(s), the power supply, and data acquisition/storage components. The robot is designed with a slender aspect ratio and the ability to change shape as required by the physical obstacle presenting itself. The MFL sensor module must also morph itself through the physical obstacles, and thus, will require some level of segmentation. The segmented MFL magnetizers and transformable sensor module represent a major advance in the science of sensor technology and pipeline inspection."

Jan 1, 2005

By Herbert D. Drechsler, James B. Stephenson

"AbstractThe paper identifies the major components of price change which affect the determination of the internal rate of return of a mining project. It illustrates several price indexes which may be used to measure general price increases, identifying techniques which might incorporate them into mine valuation procedures. The ""hurdle rate"" for new investment is discussed.IntroductionDECISIONS regarding the value of an orebody and whether or when to mine an orebody are based on an estimate of the cash flows which would be associated with its exploitation. These pro-forma cash flows represent cash in or out of a possible mineable deposit and include exploration and construction costs, sales revenues, operating expenses, taxes, debt borrowings, interest and debt repayment. It has long been recognized that when combining the cash flows occurring over the life of the mine, dollars received or paid out early have greater value than those received or paid out later. This time value of money has been incorporated into mine evaluation calculations through the use of present-value or discounting techniques. Another factor affecting mine valuation, inflation, is not accounted for by valuation techniques now in use. In recent years, price changes have become more volatile. In the past, price change could easily be ignored when evaluating potential mines. Today, the combination of larger investments and greater price volatility leads to great concern about the effects of price change on mine valuation."

Jan 1, 1977

By Sergio Cattalanl, Francis Chartrand

"The geology and origins of volcanogenic massive sulfide (VMS) deposits in the Abitibi belt of northwestern Quebec have been the subject of discussion since the discovery of the Horne orebodies in Noranda in 1923.The present Noranda version of the VMS model characterizes the ideal deposit as a stratabound, base-metal accumulation that is in close spatial relationship with hydrothermal alteration and stockwork zones, felsic lava domes, coarse phreatic-pyroclastic breccias, and subvolcanic intrusions that characterize vent- and proximal{acies submarine volcanic environments. Deposits tend to occur in a favorable stratigraphic interval within a mining camp, and this is well-documented in the Rouyn-Noranda and Matagami camps.However, in recent years many VMS deposits have been shown to deviate from the ideal Noranda-type. For example, the Ansi/ deposit is characterized by sulphide-bearing alteration zones that extend far above the massive sulfide lenses, and by abundant magnetite immediately underlying massive sulfide. The Horne deposit appears to lack the typical chloritic alteration pipe underlying the massive sulfide lenses, as well as laterally-equivalent exhalite horizons. The Horne and Quemont deposits, besides being the two giants of the camp, are particularly rich in gold, whereas others, such as WaiteAmulet and Millenbach, have low gold values. Finally, some deposits in the Noranda camp, such as the Ansil, Corbet and Mobrun mines, are outside the favorable stratigraphic interval. Therefore, it would appear that part of the key to renewing base metal reserves in northwestern Quebec is the use of evolving descriptive-genetic models that incorporate geological variations like those cited above."

Jan 1, 1990

By Wayne D. Goodfellow, William M. Luff, Steven J. Juras

Abstract-Brunswick No. 12 is a vent-proximal massive sulfide deposit that formed above a feeder pipe with associated hydrothermal alteration. Because of the replacement of bedded sulfides deposited above the hydrothermal vent, individual sulfide lenses show the following vertical and lateral zoning outward from the vent complex: massive pyrite-pyrrhotite-chalcopyrite core - interlayered pyrite-sphalerite-galena (Pb-Zn ore zone) - bedded pyrite. The feeder zone which underlies the Cu-rich core consists of an anastomosing network of pyrite-pyrrhotite-chalcopyrite­ quartz veins with variable and generally minor contents of ferroan carbonate, Fe-rich chlorite, sphalerite, galena and arsenopyrite. Hydrothermal alteration of felsic igneous rocks hosting and adjacent to the feeder pipe is represented by an inner zone (zone 1) characterized by sulfide stringers, Fe-rich chlorite, muscovite, quartz, and ferroan carbonate that formed at the expense of feldspars and what was probably glass; outer zones (Il and III) are represented by Mg-rich chlorite and muscovite formation, and the albitization and silicification of K-feldspar. Accompanying these alteration trends is a marked decrease of Na + Ca, and an increase in Fe + Mg + C03 in zone 1, and increases in Mg + Na in the outer zones. The classic zoning of metals within the sulfide lenses, the formation of a feeder pipe below the vent-proximal sulfide core, and the hydrothermal alteration of felsic volcanic rocks cut by the feeder pipe all support a vent-proximal origin for the Brunswick No. 12 deposit. Furthermore, restriction of sulfide stringer mineralization to the footwall sequence, the folding of the stringer zone by an F1 fold, and the difficulty of long distance mass transfer of metals from the sulfides into the host rocks all argue against a tectonic origin for the stringer zone. All of the evidence indicates that the feeder pipe formed during the ore forming hydrothermal event, but has been distorted and in some areas detached from the overlying massive sulfides during subsequent deformation.

Jan 1, 1992

By J. E. Dutrizac

"The end of an era in zinc metallurgy took place on July 31, 1976 when the horizontal retort furnaces of the National Zinc Company in Bartlesville, Oklahoma were permanently shut down (1) . For more than a century, horizontal retorting had been the most common method of producing zinc in the United States; it was a thriving industry in many parts of that country, especially in the natural gas belts of Oklahoma and Texas. With the Bartlesville closure, yet another metallurgical process has become an object of historical interest for North American metallurgists. Although shrouded in controversy, the origins of zinc metallurgy seem to date back at least 2000 years. Pyrometallurgical methods with carbon reductants are capable of producing zinc from oxidic zinc ores, but only above the boiling point of the metal. Although slow cooling results in re-oxidation of the zinc vapour by air or carbon monoxide, quenching yields liquid zinc; some form of rapid cooling, either accidental or intentional, was likely used by ancient metallurgists to liquify the metal. Zinc metal found in Athenian objects of the Roman era was likely of accidental origin. The Romans employed brass extensively for coins and ornaments(2) , and this was intentionally produced by the calamine process whereby oxidic zinc ores were added to molten copper under strongly reducing conditions. Zinc appears to have been known in China and India as early as 1000-1300 A.D., and was probably smelted commercially in those countries from the 14th century. Although the early metallurgical procedures were probably inefficient, they were able to produce zinc metal in significant amounts. The large heaps of zinc residues with clay retorts bear testimony to an early smelting industry of impressive magnitude. It is estimated that the heaps at Zawar, India alone represent the extraction of 100 000 tons of metallic zinc(2) In the 1730s the smelting of oxidic zinc ores was developed in England using a vertical retort method. In 1788 a British patent was granted for making zinc from zinc blends (ZnS) by roasting the ore in a coalfired reverberatory furnace, mixing the calcine with charcoal and smelting the mixture with suitable zinc condensation. The English process was very energy intensive, however, and early in the 19th century the Belgians developed a horizontal retort process for the reductiondistillation of zinc that was more fuel efficient. This technique was gradually developed into what came to be known as the Belgian process, the forerunner of the ""modern"" horizontal retort furnace."

Jan 1, 1999