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By R. H. Moore

The data for diffusion in dilute binary alloys with the Solvents Ag, Cu, Ni, Fe. Al. and Pb hare been correlated as a function of atomic volume. Linear equations of the form: Q = b - a log V are obtained with constants "a" and "b" ciuirac-teristic of each solvent metal. In most cases. 3-d In recent years measurements of diffusion coefficients in solid binary alloys. using small concentrations of radioactive isotopes. have resulted in accumulation of highly reproducible data. Such and 4-d transition elements correlate on separate straight lines from those which serve to correlate the non/ransition elements. The data for the uon-transilion elements diffusing in silver and copper liave been fitted by least-squares analysis. It is concluded that the size and charge effects which determine the magnitude of the activation energy for diffusion are a function of atomic volume. systems represent the simplest possible examples of chemical diffusion since solute interaction effects can be neglected and Kirkendall-like phenomena do not occur. Generally it is found that thc diffusion rate of the solute is within an order of magnitude of the diffusion rate of the solvent. The differences have been attributed to the effect of size and to electrostatic interactions between the solute and solvent atoms.

Jan 1, 1965

By R. F. Mehl, M. Gensamer

THE stresses which initiate deformation processes in metals are fundamentally important in the study of the mechanical properties of metals. A point of inflection in the load-elongation curves obtained for single crystals1 has been rather too readily interpreted as a true yield point, and the critical resolved shearing stress on the plane of slip taken as a material constant. Even early work showed that the stress at this point varies with rate of loading, but it has not been generally appreciated that creep tests under static loads alone are suited for determining the existence or nonexistence of a yield point.2 It has now been shown by Miller that single crystals of zinc3 when loaded statically begin to yield at loads too small to measure; as a result there is no case now known, apart from that cited in the present paper, in which a true critical stress for yielding has been demonstrated for single crystals of metals. The case of iron has especial interest: the existence of an upper and lower yield point and of an elongation at the yield point in ordinary iron and steel marks this substance as unusual, though the effects have been found to a very minor degree in other metals and alloys. ‡ Most alloys do not show such marked phenomena when appreciable yielding begins, and accordingly modern practice is to speak of the yield strength of such materials, a stress read from the load-elongation curve after elongation has begun, rather than yield point. The special behavior of iron suggests that it is more likely that single crystals of iron should have a true yield point than other metals. The study of the mechanical properties of metals and alloys requires a determination of the crystallographic mechanism of deformation, whether deformation proceeds by slip, twinning, or cleavage, or a combination of these, and a determination of the stresses that induce these modes of

Jan 1, 1938

Jan 1, 1943

By Charles Weaver

DURING the past few years there has been considerable activity in prospecting for oil and gas in several parts of western Washington. From time to time seepages of oil or emanations of gas have been reported from various places. Several companies have been organized for the purpose of drilling, but only a part of these have actually begun operations. In certain localities very small seepages of oil occur, but up to the present time no oil or gas in commercial quantities has been obtained. In order to determine the conditions which may be favorable or unfavorable 'to the occurrence of petroleum it becomes necessary to know the character and extent of the geological formations in which such deposits might occur. In other regions where producing wells have been developed it is possible to know what formations contain the oil mind what structural conditions influence its concentration in reservoirs or zones. It is usually possible to determine those strata which contained the a materials from which the petroleum may have been derived and also the position and distribution of the more porous sandstone belts into which it may have collected. Detailed stratigraphic surveys, may even determine the depth at, which a certain known oil-bearing zone may be tapped at any particular place. It is also possible to recognize those formations which are presumably barren of oil, as well as those which are absolutely so.

Jan 7, 1915

By Roger B. Alke

INTRODUCTION Request to Mine Beneath Bridge The Jakes Run Bridge is a reinforced Portland concrete arch filled bridge located on WV Route 7 near Pentress, WV. The bridge has a span of 22.9 m (meters) and a height of 4 m above normal pool elevation to the underside of the center of the arch (See Fig 1). The bridge is a two lane structure with a width of 6.86 m. The structure is over 50 years old having been built in 1929 and is owned by the Department (WV Department of Highways). [ ]

Jan 1, 1984

Here, published for the first time, is the group of Anaconda officials (New York office) concerned with the planning and operations of the company's copper properties in Chile.

Jan 1, 1952

By J. A. Marton, N. Brown, M. Herman

AT high temperatures a deformed polycrystalline metal shows grain-boundary displacement in preference to slip lines.' This has led to the conclusion that overall strain at high temperatures is produced chiefly by grain-boundary displacement. Detailed microscopic examinations of individual grain boundaries have shown many interesting ways by which their displacement occurs; sometimes no grain deformation was observed except possibly in the immediate neighborhood of the boundary. However, X-ray examinations show that at high temperatures subgrain formation occurs;Y he process, generally called polygonization, results from lattice bending and the subsequent climb of dislocations to form low-angle boundaries. Quantitative measures of the grain-boundary displacements show that they make a minor geometrical contribution to the overall strain; the major contribution is made by grain deformation."'" A relationship between grain-boundary displacement and grain deformation was suggested by McLean, who showed how the degree of polygonization would determine the amount of grain boundary displacement: and by Dorn, who showed that for a given creep stress, the amount of grain-boundary shear was related to the overall strain and was independent of temperature.' Although the grain-boundary displacement may make a small geometrical contribution to overall strain, it may still be the rate-controlling factor in high-temperature creep. If in general grain-boundary displacement and grain deformation are dependent quantities, then the designer of a creep-resistant metal would like to know whether it is more desirable to strengthen the matrix of the grain or to increase the strength of its boundary. The widespread interest in the relationship between temperature and grain-boundary displacement makes it desirable to test the generality of Dorn's result6 that the ratio of grain-boundary displacement to overall strain is independent of the temperature for a given creep stress. In this investigation p-brass was used because it produces sharp grain-boundary displacements above 400°C. Since B-brass undergoes an order-disorder transformation which abruptly strengthens the grain, it is an excellent metal for determining whether grain-boundary displacement or grain deformation is the rate-controlling factor in creep. The problem will be confined to the temperature range where

Jan 1, 1958

By O. Hyvärinen

The treatment of anode slimes at Outokumpu Pori Copper Refinery comprises the following process stages: copper leaching by air oxidation, nickel removal by digesting slimes in concentrated sulphuric acid at 200 °C, and dissolving of the formed nickel sulphate into water, roasting of the slimes in controlled gas atmosphere at 600 °C for selenium removal, smelting of slimes in a Doré furnace, electrolytic refining of silver, sulphuric acid and aqua regia leaching of slimes from the silver cells followed by the reduction of gold and platinum metals. The paper discusses operational experiences and recent developments of the process.

Jan 1, 1984

By Charles W. Schwartz, Subash Kolluru

INTRODUCTION Creep of rock in situ, like most rock mass behavior, will be largely governed by the behavior of the natural discontinuities -- bedding planes, faults, and joints, in particular, Several past studies have investigated various aspects of the time-dependent deformation of rock discontinuities; examples include Amadei and Curran (1980), Engelder and Scholz (1976), Johnson (1975), Kaiser and Morgenstern (1979), Solberg et al. (1978), and Wawersik (1974). These studies have provided much insight into the general phenomenon, but they have also produced some inconsistent conclusions and left many unanswered questions. This paper will attempt to shed some light on one of these questions: What is the influence of stress level on the creep of unfilled rock joints? The discussion will follow a two-part approach to the problem: (1) laboratory creep experiments on small scale jointed specimens, (2) a simple theoretical mechanism to explain, at least in qualitative terms, some of the results from the experimental program. EXPERIMENTAL PROGRAM Uniaxial creep tests were conducted on intact and jointed samples of a specially formulated gypsum plaster "synthetic rock." Synthetic rock materials have several advantages over natural rock for long-term creep testing: (a) higher creep rates, (b) lower strength and therefore lower loading requirements, (c) simpler specimen preparation, and (d) more controlled and consistent properties. Gypsum based plasters have been used previously in studies of short-term strength and deformability of jointed samples (Patton, 1966; Einstein and Hirschfeld, 1973). Furthermore, Williams and Elizzi (1977) demonstrated that natural gypsum, at least, creeps in a manner similar to that of most other creep-susceptible natural rocks.

Jan 1, 1982

By P. Somasundaran, D. R. Nagaraj

This study initiated to explore the potential of commercial chelating extractant for beneficiation of minerals revealed "LIX "65N to be an excellent collector for cuprite and chrysocolla. The collector action of the LIX is proposed to result from its chelation with copper species on the surface of the minerals. Thus, the syn-isomer of LIX65N, which is unable to form a chelate with copper ions, failed also to act as a collector. The proposed mechanism takes into account partitioning of LIX between the mineral surface (to form a surface chelate) and the copper chelate dispersed in the bulk aqueous phase (either due to formation of the chelate with dissolved copper, or due to detachment of chelate formed at surface). The efficiency of the collection is dependent upon this partitioning since the bulk chelate is found unable to collect. The marked decrease in flotation obtained when copper was added to the system supports this mechanism. The dependence of flotation of chrysocolla and cuprite on pH and reagentizing time is discussed on the basis of the proposed mechanism. Batch laboratory flotation tests using synthetic mixtures of oxide, sulfide and mixed oxide-sulfide copper minerals with quartz demonstrated the ability of LIX to separate the copper minerals from quartz.

Jan 1, 1980

By W. M. Courtis

This district commences near Pigeon River, the northeastern boundary between Minnesota and Province of Ontario, and extends entirely around the north shore of Lake Superior, terminating for the present at the Bruce Mines on Lake Huron. The discoveries of mineral-bearing veins have been confined for the most part to the lake shore, or to the country opened up by the Dawson Red River road. As yet the country back from the lake has been but little explored, on account of its roughness, being intersected by steep, rocky trap bluffs, 1000 or more feet high, and alternating white cedar and tamarack swamps. The forests are exceedingly difficult for prospectors. In many places Titanic piles of rocks, protected by chevaux-de-frise of dead cedars, with their hooked, tough, sharp branches, and a covering of spongy moss, sometimes several feet thick, successively guard against the discovery of hidden treasure. The Hudson's Bay Company for nearly a century have maintained trading-posts at Fort William and other points, which probably opened the way to the first discoveries that were made at Prince's Bay, near the western limit of the district. At this point a large vein was worked by Colonel Prince, the owner, as early as 1846. The richest part of the vein seems to have been on Spar Island, but work was stopped on account of excess of water. Sir William Logan states that a mass of ore weighing several hundred pounds and carrying 3 per cent. of silver was taken out. On the mainland small quantities of native and sulphide of silver were found, together with iron and copper pyrites, zinc blende, and galena, in a large spar vein. On the main shore a drift 165 feet long and 90 feet in depth

By K. R. Van Horn

RESIDUAL stresses in metals operate under a cloak of mystery, as they have neither been seen in the laboratory nor detected by means of the microscope. In spite of their phantom-like nature, they frequently exert metallurgical effects that cannot be ignored. In some cases the results have been detrimental, causing rejections or premature failures, but frequently the effects have been highly beneficial to the producer or consumer of metal products. First, however, what is a residual stress? When a metal is plastically deformed by bending, rolling, pressing, or by a phase transformation or precipitation from solid solution, or by a sharp temperature gradient resulting from nonuniform cooling, quenching, or welding, it remains in a state of strain. The strains or strain gradients produced by such operations and retained after all external forces are released are known as residual strains, and the accompanying stresses as internal or residual stresses. Many defects or failures in metal products have been ascribed to residual stresses, sometimes erroneously, because there was no other apparent explanation after the usual metallurgical tools of diagnosis had been applied. For example, during World War 11, the forged aluminum alloy aircraft cylinder head in the reciprocating engine began to replace the cast head with the familiar cooling fins. The fins were machined in the solid forged head by an ingenious milling operation. One plant reported an epidemic of excessive distortion during the delicate high-speed milling. A thorough examination revealed that the composition, heat treatment, mechanical properties, and metallurgical quality of these heads were comparable to those of forgings that machined satisfactorily. It was then claimed that the cause of the machining difficulties was connected with residual stresses resulting from the quenching during the solution heat treatment. An elaborate stress analysis actually demonstrated, however, that the magnitude of residual cooling stresses was lower in the cylinder heads which machined poorly than in those which were satisfactory in this respect. Subsequent tests proved that the machining problems in this case originated from variations in the tools and tool design. Sources of Residual Stresses in Metals Residual stresses are of two origins—mechanical and thermal. Thus, stresses may be produced in a metal by any cold-working process. The distribution and magnitude of these mechanically produced stresses can be calculated in a satisfactory, although approximate, manner for such simple cases as bending, torsion, and expanding of tubes. However, most manufacturing processes are too complex, and the original stress-strain relations in the products are not sufficiently known to permit calculation of the resulting residual stresses. Also, a specific process, such as wire drawing, may vary in complexity or uniformity of working, and large or small residual stresses may result, depending on the conformation of the dies and other features of the working process. Neither substantially unidirectional deformation, such as can be imparted by stretching a metal product having essentially the same mechanical properties throughout the cross section, nor deformation

Jan 1, 1954

By C. S. Desai

INTRODUCTION Behavior of joints in rock and interfaces in structures and geological media subjected to static and cyclic loading play an important role in analysis and design of structures founded on rock and soil foundations. The objectives of this paper are (1) to describe a device that can permit laboratory testing of joints and interfaces under translational and torsional motions, (2) to present procedures for constitutive modelling of joints and interfaces with a typical example of modelling of a concrete-sand interface, and (3) to give brief details of the proposed research plans for cyclic testing and modelling of joints in concrete as a simulation of joints in rock. The subject of testing and modelling of interfaces and joints is wide in scope, and in view of space limitations, it is not possible to provide a comprehensive review herein. Hence, only a few references, particularly relevant to the ongoing research by the authors and co-workers are included; a review of the subject can be found in (Desai, 1981) and (Heuze and Barbour, 1982). Although there can be (minor) differences in modelling for the behavior of joints and interfaces, the basic procedures can be considered to be essentially similar. Now onwards in this paper, the term joints will be used to imply both joints and interfaces. TESTING DEVICE Appropriate laboratory (or field) testing is an important and indispensable ingredient for constitutive modelling of joints. A new device has been developed for static and cyclic testing of

Jan 1, 1984

By M. Weinstein, J. F. Elliott

IN conjunction with a study on the solubility of hydrogen in liquid pure iron and iron alloys, new and

Jan 1, 1963

Jan 1, 1929

By James H. Neisz, Gregory P. White

This paper discusses the development of surface coal mine planning programs for a microcomputer. A set of seven programs which were originally written for a large mainframe computer are described. The problems encountered in converting these programs to a micro with 52K of available core storage are discussed. A program for economic evaluation which is currently running on the micro is described and plans to convert other programs to the micro are detailed. In addition, we explain the microcornputer system we have assembled and give the rationale for each component. Problems we have encountered with this system are described for the benefit of others who may follow our path.

Jan 1, 1983

By L. F. Mondolfo, F. A. Crossley

SURFACE effects in the brittle fracture of materials such as glass and in the plastic slip of zinc and cadmium crystals are well known.' Recently, another surface effect has been found for zinc monocrystals. It has been observed that certain normally ductile zinc monocrystals become ex- tremely brittle when their surface is coated with a layer of oxide or copper plate.

Jan 1, 1952

By Hans S. Carlsson

Like most industrial processes, nuclear power production creates wastes, which have to be handled and ultimately disposed of in a safe manner. Some of the wastes contain very long-lived radioactive substances and have to be isolated for very long periods of time before they have decayed to harmless levels. Sweden, like many other countries with similar geology, intends to use crystalline rock for isolating the high-level nuclear waste from the biosphere. The suitability of a rock mass for a repository needs to be investigated extensively. Apart from the political and practical considerations for a site selection, a detailed study has to be performed in terms of geology, hydrogeology, geophysics, geochemistry and rock mechanics. The responsibility of the site selection studies in Sweden is entrusted to the Swedish Nuclear Fuel Supply Company, Division KBS (SKBF/KBS) . The paper gives a brief presentation of the "Standard Program" for the studies that will be carried out during 1980-1990. Modifications of the program are justified on the basis of gained experience or specific circumstances for each site. The program is compiled by the Geological Survey of Sweden (SGU) in cooperation with KBS.

Jan 1, 1982

By A. J. W. Headlee

RECENT interest in germanium centers around its use as a semi-conductor of electricity in electronic devices. It is generally believed that germanium transistors, diodes, triodes, photocells, and rectifiers will largely replace the present-day vacuum tubes. The germanium electronic devices are much smaller, lighter, and more resistant to shock, and they require only a small fraction of current required for conventional devices. Hence only a small amount of heat is given off by the equipment. This development will require many times the quantity of germanium now being produced, which in 1948 was approximately 1000 lb1 and was obtained almost entirely from zinc ores in Missouri, Kansas, and Oklahoma. No one knows with certainty what the demand will be for germanium by 1956. It may be 40,000 lb.1 Known concentrations in zinc ores are not sufficient to

Jan 10, 1953

By Anna H. Connard

SUMMARY The discussion focusses on developments in the debt/equity swap market since the Marte project was negotiated in early 1988. It emphasises carrying forward the recent market trends to anticipate the breadth and scope of debt/equity conversions for mine development in the 1990s. Secondary market prices of LDC paper, conversion values and political influences in the host countries and the use of near debt and commodity-based instruments as components of mine financing in debt/equity deals will be placed in the perspective of recent trends and expectations for the future. THE MARTE PROJECT The Marte mine is a gold porphyry deposit in Chile's high Atacama, for which financing was put together at the beginning of 1988. The Marte project was financed by a combination of common equity and loans. It was unusual that the equity infusions were made under different programs. Some of the international equity was infused with fresh funds via DL 600. Other common foreign equity was provided through the conversion of Chilean bank debt under Chapter XIX. On the loan side,. export credits for the import component of machinery and equipment were sought. Local bank financing was negotiated for the remainder of ' the project's anticipated cost. The debt conversion market in Chile was at its apex in terms of interest, activity and government support when the mine financing was arranged. The price of Chilean paper in the secondary market hovered about 62 to 66 cents per U.S. dollar of face value. Meanwhile, the Chilean government was negotiating conversion redemptions significantly closer to full face value. The government differentiated between debt paper exchanged for corporate investors who had sourced that paper in the secondary market, and debt paper held by bank investors who would incur a transaction loss in the conversion. The use of a combined DL 600lChapter XIX equity financing created different yield calculation bases for the various investors. Chapter XIX prevents remittance of profits before year 5 and capital repatriation before year 11. Investors choosing this vehicle have either for a corporate policy in the target project not to declare dividends until repatriation is allowed, or they have to seek uses for the peso liquidity that would be generated through dividend declarations in the early years. However, DL 600 investors face no such waiting period on dividends, nor do they have restrictions imposed on cashing out of the investment before the 11th year. Therefore, any equity structure with components of both investment mechanisms will have inherent differences in cost basis and future income flows for the various participants. This equity imbalance is defensible if the investment motivations of the parties are analyzed: a mining investor using fresh funds looks for a hurdle return on equity calculated at conservative commodity prices, with as much flexibility to reap upside benefits as possible; a mining investor choosing to invest through a debt conversion mechanism will realize a modest short term gain on the conversion, reducing his effective cost basis, but sacrificing some return because of the waiting period on repatriation of dividends. INVESTMENT OBJECTIVES A bank investor exchanging his own paper for an equity participation in a mining project realizes a conversion loss on the transaction. He seeks a risk adjusted acceptable hurdle rate of return to recoup that loss over time. Motivation for the bank investor to take that loss may be derived partly from a strategy to diversify its existing portfolio by internal policy and externally regulated guidelines. The bank will compare yields on its loan portfolio to that country with anticipated dividend flows discounted back at a risk adjusted rate. It will analyze the project with return objectives of yield enhancement over time and with

Jan 1, 1990