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By H. Sato, I. Matsuoka, T. Kawai, S. Hasebe

In a limestone mine, a large amount of slime is washed off in order to remove impurities such as clay minerals. A fine sized calcite is, consequently, wasted and freight for carring the slime to reclaim land is expensive. The separation of calcite from the slime has been investigated by the flotation process, using sodium oleate as a collector. A satisfactory flotation of calcite from the slime requires great amounts of sodium oleate, because sodium oleate is consumed by clay minerals. But, the amounts of sodium oleate required are reduced to half by adding suitable amounts of sodium silicate. After rougher and cleaner flotation, the concentrate containing more than 97% calcite is obtained with 70% recovery; thereby the amount of slime to be reclaimed is reduced to 40%.

Jan 1, 1976

By Paul Billingsley

The Asientos-Tepezala district is in the north of the State of Aguasca-lientes, about 30 miles north of the city of Aguascalientes, the capital. The district is reached by a standard-gage railway on the west side through the junction, Rincon de Romos, which is on the main line of the National Railways of Mexico from El Paso to Aguscalientes. The terminal is Tepezala. On the east side a narrow gage connects Asientos with the junction, San Gil, on the main line, Asientos to San Luis Potosi. Tepezala on the west side of the Asientos hills is about 2 miles from Asientos on the east side. The area between the two mining centers is separated by a low subdued divide which forms the central part of the hills. The district is in a group of isolated hills surrounded by characteristic bolsón plains. The hills rise above the surrounding plains about 6500 to 10,000 ft.; the highest peak is Alta Mira. The two mining districts lie somewhat upon the flanks of the hills at about the same elevation, 7200 ft. The district is an old one and has been known since early in the 17th Century when the mines were worked by the Franciscan Monks. Their mining operations, which were limited to the oxidized ore above the water level, consisted chiefly in extracting silver from the Santa Francisca vein. To judge from the old workings and the remains of surface plant, the operations were on a large scale. By modern mining operations since about 1900, the various mines of the district have been one of the principal sourees of ore for the smelter located at Aguascalientes. Topography The topographic features of the Asientos hills are largely controlled by the character of the underlying rocks. During the Tertiary period, the entire group of hills was probably covered by extrusive volcanic material in the form of cones and lava flows. The central part of these have since been carried away by erosion, so that remnants have been left along the borders of the hills. These remnants form rather conspicuous peaks,

Jan 1, 1927

Jan 1, 1941

By John M. Pitt

Shear strength assessment and the associated variability in rock masses historically have been hindered by high costs and biases in laboratory testing programs. An in situ direct shear device was developed on the principle of the previous borehole shear device for soils. Using wedge action to simultaneously apply normal and shear stress to an envelope of material on the periphery of a borehole, the device develops a complete Mohr-Coulomb failure envelope. Tests performed in homogeneous materials show expected strengths and their variability equivalent to laboratory tests. However, tests in a structurally non- homogeneous coal did not display significant variability. A 38 mm diam borehole was used in this work; however, larger or smaller bore- holes may also be used within the size limits of the device. The device is employed in holes commonly drilled for rock bolt placement, at 1 to 2 minutes per test.

Jan 1, 1984

By N. H. Cone

It is somewhat surprising that among the many mechanical devices that were brought into the State of Colorado, that the Brückner cylinders alone have stood the test for roasting ores. The brick walls of the Arey and Stetefeld furnaces have been remodelled into reverberatories and compound reverberatories, their binding and anchor irons have been forged into hoes and shovels, while the Crosby and Thompson cylinders have been rent by the ruthless hand of the foundryman searching for a tough piece of boiler plate. Two only of these furnaces remain in operation, of the large stock that came into Colorado by car-loads several years ago, and they occupy only a subordinate position to some reverberatories on the North Boulder Creek. But to-day there are in Colorado, in active operation, ten Brückner cylinders, and two or three more running part of the time. Dur-

By B. L. Dunic, Terkel Rosenqvist

rr has long been suspected that sulphur has a small but finite solid solubility in iron, but up to the present more accurate data have been lacking. The survey given by Hansen' illustrates the divergence of data and opinions. Solubilities between 0.01 and 1.5 pct have been suggested, and opinions vary regarding the effects of temperature and phase transformations in iron on the sulphur solubility. The extent of solid solution and its variation with temperature might be expected to be an important factor in the occurrence of hot shortness in steel. Therefore, the object of the present investigation was to study this problem more systematically. It was furthermore hoped that solubility data for sulphur might contribute to an understanding of the factors which determine solid solubilities in general. Experimental Procedure The present work was based on the measurement of the chemical activity of sulphur in the solid solution by means of equilibrium with a mixture of hydrogen and hydrogen sulphide. When the solid solubility limit is reached, the sulphur activity in the iron becomes equal to that in the coexisting sulphide phase. A gas mixture of a controlled H,S/H, ratio was passed over pure metallic iron heated to a temperature in the range 900" to 1500". The amount of sulphur absorbed by the iron was determined by analysis, and from a plot of percentage of sulphur vs. gas composition the sulphur activity and the solubility limit were determined. As the rate of diffusion of sulphur in solid iron is very small, often several days were needed to be sure that equilibrium conditions had been established. To produce a gas flow with less than 1 pct H,S of constant composition for several days, was in itself a problem. The most satisfactory arrangement was obtained by a continuous synthesis of hydrogen sulphide from the elements. This was done in the part of the apparatus shown to the left in Fig. 1. The hydrogen used was first purified in tank batches by passage through activated charcoal cooled in liquid nitrogen under a pressure of 150

Jan 1, 1953

By Walter L. Rice

It is a pleasure to report that the light metals industries are running well ahead of the growth schedule projected by the President's Materials Policy Commission. In the compilation of this survey on the five-year growth of our light metals industries, some gratifying facts come to light. By 1956, for instance, light metals consumption had increased more than 20 pct beyond Paley report expectations-a growth not anticipated by the study until the year 1960.

Jan 9, 1959

By E. L. Larison

DURING the early years of the present century a notable interest appeared in American industry in the matter of recovering and render-ing profitable byproducts of manufacturing operations. Among the byproducts of reduction of sulfide ores in many plants large amounts of sulfur dioxide gas were available. In certain instances the concentration of S02 in the gases evolved was, or could be made, sufficient to make them suitable for manufacturing sulfuric acid. At the Anaconda Reduction works such a condition existed. Large tonnages of copper concentrate were being roasted and the roaster gases were available and suitable as a source of sulfuric acid. Earlier work on a large scale at Martinez, Calif., and in the Ducktown region, Tennessee, had shown the feasibility of manufacturing sulfuric acid from the S02 contained in gases arising from the reduction of copper sulfide ores. In California and Tennessee the acid found a ready market in manufacture of fertilizers, while the situation regarding disposal of the sulfuric acid was quite different at Anaconda. No local use for acid existed, and a commodity of such low value could not stand freight charges to consuming centers. There was a very large accumulation of sand tailings from the gravity concentration mill below the plant at Anaconda. This material, made by the comparatively crude methods in use up to about 1915, contained about 13 lb. of copper per ton, largely as sulfide minerals. In 1912 serious research work toward recovery of this copper was instituted and after about two years of laboratory and pilot-plant development, a process for accomplishing it was perfected. This process involved roast-ing the sand tailings, leaching the roasted tailings with sulfuric acid, and throwing out the copper by passing the solutions over scrap iron. Under this plan each ton of sand required the introduction of about 70 lb. of 60° Be. sulfuric acid.

Jan 1, 1934

By J. A. M. van Liempt

Since the discovery of von Laue, that a crystal forms a natural grating for X-rays, our knowledge of the structure of solids has gone forward with rapid strides. This progress is not only of purely scientific interest, but has also yielded direct technological results. One of the most valuable results is the broadening of our knowledge of the structure of pure metals and alloys. To promote these studies it is often desirable to have at our disposal pieces of metal consisting of one single crystal. As is so often the case in the natural sciences, we obtain the best results by making our earliest experiments on pure, simple materials and avoiding unnecessary complications. The Cryogen Laboratory at Leyden followed this method with much success, because the work was done at such low temperatures that the heat movement of the atoms was almost absent. Similarly we can simplify the studies of metals by leaving out of consideration the influence of the grain boundaries and the mutual influence of the crystals by using unicrystalline instead of polycrystal-line metal. Methods of making single crystals have been scientifically studied during the past few years. Some methods were already known in the arts, but these have been improved and new methods have been developed. The methods for making metallic single crystals may be divided into the following groups: A. From the liquid state B. From the gaseous state C. Electrolytically D. By recrystallization in the solid state Method A 1. Tamwmnn's Method1—Tammann succeeded in making bismuth single crystals of a maximum length of 20 cm. by undercooling the molten metal 0.1 to 0.3' G. below its melting point in glass tubes of a maximum

By James E. Lawver

Efficiency of industrial research and development depends on the ability of engineers and scientists to collect and present data to top management for decisions. In many cases, the data presented are so deceptive that management makes costly wrong decisions. Since management personnel often are selected on the basis of higher administrative quality than technical ability, it is the responsibility of the industrial scientist or research engineer to make certain that the data presented tell a completely ac- curate story of each industrial problem. It is rare that misleading data are deliberately presented, but when this is done, it is? of course, dishonest. The rise of deceptive data usually stems from the lack of knowledge of experimental design and statistical methods of analysis. Most of the better chemical engineering schools have recognized the need for courses in industrial experimentation and many of them offer complete courses at both graduate and un- dergrarluate levels. By contrast, many of the mining and metallurgical schools have not recognized the importance of industrial experimentation courses and some of them, in fact, do not allow credit toward a mining or metallurgical engineering degree for statistical courses even when taken as an elective. The sole purpose of this paper is to make a plea for mining and metallurgical schools to present required industrial. statistical courses for their graduates. It is true that fine industrial research has been accomplished in the past without the assistance of any statistical techniques. Industrial problems have also been solved without the use of digital or analog computers, electron microscopes or other modern conveniences. The fact remains, however, that the correct use of these modern tools tends to reduce the cost of research and to eliminate costly errors. A working knowledge of experimental design and statistical data analysis must simply be viewed as a valuable tool whose proper use will greatly reduce the cost of experimentation and minimize the cost of false conclusions. These statistical methods, however, simply cannot replace fundamental knowledge or, for that matter, "good horse sense". Nevertheless. an experimenter armed with fundamental knowledge and good horse sense but completely ignorant of elementary statistical techniques, may easily present his data in such a deceptive form to cause management to make incorrect decisions.

Jan 6, 1962

By Eugene A. Stephenson

In most instances the fluids produced from underground reservoirs have been described as they appear at the surface, and usually it has not been necessary to distinguish between surface and reservoir phases. More recently it has become imperative to recognize the fact that changes in phase may occur between the reservoir and the receiving unit. The simple terminology of "wet" and "dry" gases and "crude petroleum oil" served our needs fairly well in the shallow, low-temperature and low-pressure fields. It has been left to the legislatures, regulatory commissions, and courts to decide whether a field is or was a gas field, an oil field, or both. This they have done by direct definition and also by implication. For example, in Texas:' (d) The term "gas well" is any well (a) which produces natural gas not associated or blended with crude petroleum oil at the time of production, or (b) which produces more than one hundred thousand (100,000) cubic feet of natural gas to each barrel of crude petroleum oil from the same producing horizon, or (c) which produces natural gas from a formation or producing horizon productive of gas only encountered in a well bore through which crude petroleum oil is also produced through the inside of another string of casing. (e) The term "oil well" is any well which produces one (1) barrel or more of crude petroleum oil to each one hundred thousand (100,000) cubic feet of natural gas. In the state of Louisiana, the same general result is achieved largely by the following paragraph :* Wells producing both oil and gas shall not waste or blow into the air an amount of gas of more value at three cents per thousand cubic feet, than the market value of the oil recovered. The Commissioner of Conservation shall allow a reasonable time to determine the status of any well. This means that for wells making both oil and gas, if n represents the price of oil in dollars, and x the allowable gas waste expressed in M cu. ft. Per day,

Jan 1, 1938

By V. Rajaram, H. W. Earnest, A. W. Jenike

Mine backfilling is a desirable method for the disposal of retorted oil shale. Hydraulic, mechanical and pneumatic transport and stowing methods were investigated, and the mechanical transport and stowing method using conveyors was selected as the most promising system. Transport of retorted oil shale at the rate of 2700 t/h (3000 stph) to the backfill level, situated about 610 m (2000 ft) below surface, with skips or conveyors is uneconomic. Hence, borehole transport utilizing gravity flow was investigated. This Paper describes the theory of flow, flow properties of retorted oil shale, and the design of a borehole and hopper system.

Jan 1, 1980

By Ernest O. Kartinen

This report is the accumulation of eight years of experience on only one small phase in the business of oil production. It is not intended as a final report but rather as a progress report dealing with the internal corrosion of oil field dehydrating tanks. The corrosion of dehydrating tanks continues to be a problem in the production of crude oil. The deterioration hy corrosion of these tanks falls into three general classifications: (1) Atmospheric corrosion of exterior areas, (2) corrosion of the underside of deck and the rafters and top area of the upper row of staves in that part of the tank which is known as the vapor space, and (3) corrosion of the bottom and shell areas, and the steam coils which are normally immersed in water and thus exposed to the corrosive action of the water. Atmospheric corrosion is primarily a paint problem, and has been omitted in this discussion. The corrosion in the vapor space, in this company's experience, which has been of great concern only in one area. has also been omitted in this discussion. The third, and most troublesome type of corrosion, and the one with which this report deals, is that which occurs in the water-exposed areas of dehydrating tanks, and, to a lesser degree. in some stock tanks. The operating temperature of these waters varies from 80°F to 160°F and the salt counts run from a few thousand to as high as 25.000 parts per million. Corrosion in these tanks occurs in three forms: (1) pits, (2) ringworm type of attack along the vertical and horizontal bolt seams, and (3) as a general attack, spread over a wide area. Steam Coils In dehydrating tanks, our experience has been that the steam coils are the first to show signs of corrosion, and then the shell and bottom areas. This action is not uniform throughout this company's operations. Some installations have coil troubles with very little tank trouble, and some show just the opposite. But in the majority of cases the coils are the more seriously corroded areas. This may be partly due to the fact that we have tried by periodic application to keep a protective coating on the interior areas of the tanks, and some protection has been afforded by these coatings. Through the years several types of hot and cold coatings have been tried with many various methods of cleaning the steel, ranging from use of cleaning solvents to hot and cold Oakite washes, as well as sandblasting. Although experience has shown that a longer life expectancy of a coating is possible after a very thorough steel cleaning job, it has still been necessary to recoat these tanks at least every two or three years. Until a few years ago, vertical spiral steam coil bundles were installed when the tanks were originally erected. When these coils needed replacement, in some cases within 18 months, it was necessary to remove a couple of shell staves to accomplish this task. This required a down time period of several days and was often very inconvenient to the production operations of the leases. This problem was considered on the basis that the coils were expendable, and thus. to eliminate any unnecessary down time when changing coils, the vertical spiral coils were discarded in favor of horizontal flat coils which could be taken in and out of the tanks by way of the cleanout openings, and put together with unions. This made a fairly easily replaceable and repairable coil. But it was still very much of a nuisance when repairs were necessary. Efforts to increase the useful life of the dehydrating tanks led to the adoption of galvanized tanks at an increased initial cost. The zinc coating was depended upon for protection and no other protective coatings were applied. In July, 1944. during the development of a new lease, a 3-ring 1,500 bbl, black iron water tank was converted into a dehydrating tank with steam coils to handle the new production. This tank was coated inside with a cold, brushed-on coating, for protection against corrosion. After approximately 18 months of service, holes developed in the tank and the steam coils. The tank was emptied and cleaned for repairs. The coils were so badly pitted that it was felt advisable to replace them. Coating Becomes Loose Inspection of the tank showed the protective coating to be still in place but loose, and numerous blisters were in evidence. A closer inspection showed that the interior of this tank was so badly pitted under the coating that any further attempt to use the tank was inadvisable. This tank was therefore discarded and a new galvanized tank ordered and set up at considerable expense and inconvenience. In April, 1946, another dehydrating tank installation was made on an adjoining lease. This installation consisted of a 1,500 bbl. 3-ring galvanized tank with two sets of flat steam coils 12 in. and 24 in. up from the bottom. In September, 1947. seventeen months after installation. salt showed up in the boiler feed water. When the dehydrating tank was opened and cleaned, the steam coils were found to be badly pitted — several holes having penetrated through the wall of the pipe. New coils were installed.

Jan 1, 1950

By R. J. Sweigard, R. V. Ramani

Demands on available lands will continue to increase due to the projected population increase and industrial expansion. Though there is an upper limit on available lands, the multi-use nature of the lands will make it possible to meet these demands. However, this will not happen without adequate planning. Land uses can be broadly categorized as nonrenewable and renewable. Lands with minable resources can be dedicated at some Point to the extraction of resources. Such a dedication, however longterm, is only temporary because of the nonrenewable nature of the minable resources. The land will be available before and after mining for other uses. Planning for such lands must have the objective that, as far as practicable, no nonrenewable uses are preempted and no renewable uses are permanently destroyed. This paper addresses primary aspects of this planning process. These aspects include a discussion of planning responsibility, data needs and availability, the integration of mine planning and post-mining land use planning, and a long-term plan for resource conservation and utilization. Minerals, with agriculture and forest products, are the primary sources of wealth. Therefore, to amid land development that may preempt future mineral resource utilization, local planning groups must be aware of the mineralization and mining potential. Much work needs to be done to identify and characterize the mineral resources. Even more land use planning is needed for lands with mineral deposits.

Jan 1, 1985

By John H. Puffer, Andreas H. Vassiliou

The Bemco mine area is within the Precambrian igneous and metamorphic rock terrain of the New Jersey Highlands province. Rocks In the area include a pyroxene granite, a hornblende granite, a quartz-oligoclase gneiss and a pegmatite and its host rock, a lens of amphibolite which becomes a sulfide-rich pyroxenite near the ore zone. The ore-bearing zone occurs along the hanging wall and foot-wall contact of the pegmatite which was emplaced discordantly into the amphibolite-pyroxenite.

Jan 1, 1985

By T. C. Atchison, W. I. Duvall, D. E. Fogelson

Dr. Clark has given an excellent resum6 of the recent theoretical re- search work that has been done on the generation and propagation of stress waves in various types of media.1 Unfortunately the dynamic properties of rock do not fit the assumed properties of the idealized media. As a result, none of the theoretical solutions for the generation of stress waves by applied pressures to interior boundaries of the spherical or cylindrical cavity appear to be completely satisfactory to explain experimental data. This fact does not mean that the theoretical work is in error. It simply means that the appropriate dynamic properties of rock have not been taken into account in the present theoretical derivations. Because of the difficulty of theoretically accounting for the crushing and cracking that takes place when explosives are detonated in spherical or cylindrical cavities, it seems advisable that future theoretical studies should attempt to separate the generation of stress waves from the propagation of stress waves. Perhaps if these two problems are separated, we may be able to solve one of them satisfactorily so that theory and experimental data agree. Dr. Clark's resumé of the research work on scaling and crater formation by point charges is aimed at obtaining a basic understanding of the physical theory of rock breakage, wave generation, and wave propagation. A cursory reading of Dr. Clark's paper shows that there is very little information summarized that can be used by the practicing engineer in the field of blasting. When problems become too difficult to solve theoretically it is always helpful to take the empirical approach and collect experi-

Jan 1, 1967

By Irving Fatt, Robert J. S. Brown

INTRODUCTION The wettability of reservoir rocks is recognized as one of the major factors that determines their multiphase flow properties. Multiphase flow properties in turn govern reservoir performance. For this reason, the reservoir engineer is vitally interested in the wettability of reservoir rock. The production research scientist is interested in wettability because the solution of the problem of improving waterflood recovery by use of surface-active additives may hinge on a detailed understanding of the wettability of reservoir rock. Early workers believed that all reservoir rocks were preferentially water wet. Continued study soon uncovered certain rocks which had flow properties that indicated that they were preferentially oil wet. Recent studies show that there is a spectrum of wettability. Some reservoir rocks have multiphase flow properties which indicate that they have an intermediate wettability. The differences in recovery observed among different reservoirs may, in part be the result of small differences in wettability. Differences in wettability amcng reservoir rocks may be the result of differences in the fraction of the total surface area that is preferentially oil wet and preferentially water wet. Nuclear magnetic relaxation measurements may provide a method for determining the fraction of preferentially oil wet and preferentially water wet area in porous media. Measurements to be reported here were made on water-saturated unconsolidated sand packs which were mixtures of preferentially oil wet and preferentially water wet sands. The resulting data show definitely that the fraction of each wettability in these sand packs can be determined by this nondestructive method of measurement. THEORY OF NUCLEAR MAGNETIC RELAXATION The details of the theory of nuclear magnetic relaxation have been presented previously1. In this paper, only a very brief review of the theory will be given to show its application to the measurement of fractional wettability. Nuclear magnetic relaxation is a process of adjustment undergone by certain atomic nuclei when their magnetic environment is changed. They adjust, or relax, to be in equilibrium with a new magnetic field. The reason that some atomic nuclei are affected by a magnetic field is that they themselves behave in some respects like tiny magnets. In particular the proton, the nucleus of the hydrogen atom, behaves as a magnet. The proton spins, somewhat as the earth spins on its axis. The spinning charge produces a magnetic field just as current traveling in a loop of wire produces a magnetic field. No net charge is required, however; for instance, the neutron has spin and magnetic moment. When the spinning proton is subjected to an externally applied magnetic field, its axis tends to line up with the magnetic field, somewhat as a compass needle tends to line up, but the spinning proton cannot do this as easily as the needle can. The proton also has mass, and its spinning mass makes the proton behave somewhat like a gyroscope. As is well known, a force which tends to change the axial direction of a gyroscope merely causes the gyroscope to precess: lhat is, the axis begins to trace out a conical surface. The gyroscope cannot actually assume the position suggested

Jan 1, 1957

Meeting of Nov. 20, 1914.-Charles F. Rand was unanimously elected as the representative of the Institute on the John Fritz Medal Board of Award. E. Gybbon. Spilsbury was unanimously elected to succeed himself in January, 1915, on the Library Board of the United Engineering Society. . The President appointed Messrs. Walter Douglas, Charles E. Mills, and L. D. Ricketts as delegates to the seventeenth National Convention of the American Mining Congress, Phoenix, Ariz., Dec. 7 to 11, 1914. It was voted that the sum of $857.61, or so much of it as may be necessary, be advanced to the Land Fund from the general funds of the Institute, in anticipation of the collection of unpaid installments of subscriptions to the Land Fund; and that the Treasurer be instructed to pay to Andrew Carnegie at the present. time the sum of $2,500 on account of the Land Fund indebtedness.

Jan 1, 1915

By E. V. Howard

During the recent expansion of precipitate copper production at the Chino Mines Division of Kennecott Copper Corp., Santa Rita, N. Mex., local studies of the dump leaching process were intensified. As these studies progressed, it became apparent that a reliable method for locating leach solutions within the dump was required, since the contact between the leach solutions and the copper-bearing ma.teria1 determines recovery. In the past, the problem of determining leach solution contact has been attacked by various methods, including destructive testing (dump dissection), indirect observation (such as chloride or dye tracers) and mathematical or laboratory model studies, but they have not proved completely satisfactory. The investigation of methods for in situ observation of leach solutions led to consideration of radiation logging in drillholes, which are subsurface techniques used in petroleum exploration and development for locating fluids and measuring porosity. A significant advantage of radiation logging is that, unlike other types of logging, measurements may be made in cased holes, since gamma rays and neutrons will penetrate steel and cement. Three techniques are currently used at Chino: Natural gamma ray logging; neutron-neutron, or moisture logging; and gamma-gamma, or bulk density logging.

Jan 4, 1968

By M. D. Hassialis, Arthur F. Taggart

WARK1 observed some years ago that collector-coating reactions with xanthates and with fatty acids clearly follow paths parallel to those prescribed by the familiar mass-action law for reactions in dilute solutions. He proposed, therefore, the logical hypothesis that they are governed by the solubility=product principle. However, he went astray in the application of his proposal to collector coating by overlooking the fact that coating involves a heterogeneous reaction. A mistaken concept of the meaning of the word adsorption also entered. Wark thought that the concentration of metallic ion that must be used in setting up the solubility-product equation for the coating reaction was that which could be obtained by solution of the mineral. Since this is very low for sulphide ores, and since the amount of the collector ion necessary for coating produces an extremely low concentration, the resulting ion-concentration product, under conditions when coating occurs, is much lower than that which would indicate a saturated solution of the collector-coating compound. Hence he was forced to the position that the solubility product governing the coating is much smaller than the standard solubility product. To justify this position it was necessary to postulate a coating mechanism that did not obey the ordinary laws of chemical reaction. This Wark did by adopting the concept that adsorption is a property of matter, rather than merely a more or less ephemeral local concentration thereof. Thus he says (p. 142 of ref. I): "Adsorption is not a purely physical property of the solid surface, for the specific nature of the adsorbed molecule or ion is important." The result was that he destroyed the great potential utility of his postulate by tying it to this erroneous concept in the words (pp. 142, 143): "It will be obvious that the adsorption solubility product is less than the normal solubility product." The writers have found quantitatively in the case of galena and potassium ethyl xanthate, and semiquantitatively in the case of covellite and the same collector, that the coating reaction does follow the mass-action law to the extent that coating occurs when the ordinary solubility product of the coating compound is exceeded, and that coating does not take place under the reverse conditions. In the course of the investigation leading to the establishment of this fact it was necessary to work with xanthate concentrations so low (down to 0.0004 mg. per liter), that very long conditioning times, and bubble-contact times of as much as 16 hr. were necessary sometimes to follow the reactions. The results have led to some illuminating conclusions as to necessary collector concentrations in normal flotation operations, and the action of the frothing agent in connection therewith. The experimental work comprised. accurate determination of the standard solubility product of lead ethyl xanthate, development of a much less laborious

Jan 1, 1946