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By M. B. Standing, D. L. Katz

Density data are reported on 15 saturated hydrocarbon liquids in the range of 35° to 250°F. and 1000 to 8220 lb. per sq. in. The apparent liquid densities of methane and ethane are shown to vary with the density of the system in which they are present. A method is proposed whereby the densities of liquid hydro- carbon mixtures containing both methane and ethane in solution may be computed at elevated temperature and pressures within the accuracy of usual engineering computations. A method of computing the shrinkage of crude oils based upon the gas-oil ratio, gas analysis, and crude gravity is outlined. Introduction The densities of naturally occurring liquid hydrocarbon mixtures are important in many petroleum engineering computations. Calculation of the shrinkage of a subsurface sample of crude oil as the natural gas is evolved is one example of the use of liquid-density data. Sage, Hicks, and Lacey5 have presented a method of computing the density of hydrocarbon liquid mixtures based on partial molal volumes. Katzl has indicated a method based on the principle of additive

Jan 1, 1942

By M. B. Standing, D. L. Katz

Density data are reported on 15 saturated hydrocarbon liquids in the range of 35° to 250°F. and 1000 to 8220 lb. per sq. in. The apparent liquid densities of methane and ethane are shown to vary with the density of the system in which they are present. A method is proposed whereby the densities of liquid hydro- carbon mixtures containing both methane and ethane in solution may be computed at elevated temperature and pressures within the accuracy of usual engineering computations. A method of computing the shrinkage of crude oils based upon the gas-oil ratio, gas analysis, and crude gravity is outlined. Introduction The densities of naturally occurring liquid hydrocarbon mixtures are important in many petroleum engineering computations. Calculation of the shrinkage of a subsurface sample of crude oil as the natural gas is evolved is one example of the use of liquid-density data. Sage, Hicks, and Lacey5 have presented a method of computing the density of hydrocarbon liquid mixtures based on partial molal volumes. Katzl has indicated a method based on the principle of additive

Jan 1, 1942

By Arthur Knapp

The economics of fuel oil must be considered in two aspects; viz., fuel oil as one of a number of competitive fuels and fuel oil as a refined product of petroleum. "Fuel oil" is usually defined as that product of petroleum which is used in furnaces for the generation of heat by simple combustion. It is true that any product of petroleum used in an internal combustion engine is essentially a fuel oil, but such oils are not included in the class known as "fuel oil." Fuel Oil as One of Several Fuels For a number of years, the petroleum industry has believed that the petroleum reserves were very limited and that petroleum products would begin to become scarce within a few years. The industry has believed that there would be a gradual but continual rise in prices as a result of this impending scarcity. The industry, therefore, has informed the users of fuel oil thai., once they were eliminated by price, they were eliminated for all time. The petroleum industry believed and made the consumer believe that there would never be any appreciable recession in price which would make it

Jan 1, 1928

By W. O. Philbrook, C. W. McCoy

The reduction of chromous oxide from lime silica alumina slags by carbon-saturated iron behaves as a first-order process having a rate of 0.001 grams Cr min 1 cm 2 (pct Cr ) , substantially independent of slag composition and temperature over an important range for iron smelting. The equilibrium ratio (pct Cr)/[pct Crl is below 0.04 for slags having lime-silica ratios above 0.6. MANY studies have been conducted on chromium in slag-metal systems under oxidized conditions. The Purpose of these investigations has been twofold; namely, (1) to determine those conditions which lead to greater chromium recovery in electric-furnace and open-hearth practice, and (2) to determine the nature of oxide inclusions and de-

Jan 1, 1959

By R. G. Knickerbocker

A most important research and development item on ferroalloys in the calendar year of 1949 was the increase of interest in the recovery of secondary manganese. Owing to the importance of manganese to the nation's welfare, it is Ferroalloys most necessary that all possible avenues of research and development on the recovery of this vital metal be investigated. The principal objective of this new development is to recover manganese from steel furnace slags. Steel furnace slags contain a total of approximately 772,000 tons of metallic manganese which is compared to the 680,000 tons of metallic manganese as ferromanganese that is estimated to be used by the steel industry, annually, at this time.

Jan 6, 1950

By S. Y. Han

INTRODUCTION More than 97% of the total uranium production of the United States comes from sedimentary deposits (1). These sandstone deposits were formed by reduction of migrating uranium-bearing solutions from volcanic silicate rock sources. Such deposits occur in two major forms, either as relatively flat, lens-like deposits or as crescent- shaped roll front deposits. The lens-like deposits are found as discrete masses enclosed in reduced sandstone which is generally surrounded by oxidized sandstone. The roll front deposits are found along crescent-shaped interfaces between reduced and oxidized sands tone (2). In-situ mining of selected sedimentary deposits has proven to be a viable method of extraction and competitive with conventional mining for relatively deep low-grade ores (2). In in-situ leaching, uranium is recovered by drilling injection and collection wells in the ore body, pumping a suitable lixiviant to dissolve the mineral, extracting uranium from the pregnant solution by ion exchange, and finally regenerating and recycling the lixiviant. Even though there is increasing interest and practice in developing the in-situ technique for obtaining uranium values from deeper, lower-grade reserves, there is a lack of knowledge of the basic leaching kinetics and combined transport processes. In-situ leaching operations, in general, appear attractive for the following three general types of deposits (2): (1) low-grade surface dumps or deposits which lie above the natural water table,

Jan 1, 1983

By M. E. Lombardi

The cost of maintaining the production of an operating oil company is one of the most important, as well as one of the most difficult to estimate, of the various items which go to make up the total cost of producing oil. In the opinion of many operators the cost of drilling and developing new wells, whose, production takes the place of the loss in production through decreased yield of the old wells, is considered an operating expense, for the reason that the total income-producing power of the property is not increased. The cost of these new wells may be added directly to production expense, or it may be charged to capital account, and this account depreciated to the same extent. In either case, after an oil company is on a satisfactory income-producing basis, the money for drilling new wells to maintain production must be taken from the income of the company. Three factors determine the cost of maintaining production: First, the rate of decline in yield of the wells; second, the cost of drilling and equipping new wells in terms of their production; third, the decrease in initial production of new wells as the property is drilled and gas pressure taken off the sands, etc. In order to check theoretical figures for the cost of maintaining production the writer, with the assistance of Reed Bush and Fred Tough, has compiled the following figures. It is necessary first of all to choose a' period of time during which production for the field or territory studied remains fairly constant. The longer the period of time over which this condition prevails, the better. It is also necessary to eliminate or allow for any extraneous condition which may have affected the production returns, such as the shutting down of a large number of wells, the bringing in of a well of exceptionally large yield, the opening up of virgin territory where the flush yield is greater than will be had from new wells in after years, etc. All these conditions are exemplified most simply in the case of the Coalinga field, and perhaps these figures are more truly prophetic than the two other cases given. In applying these figures to the future it is well to assume that the average yield of new wells will constantly de-

Jan 1, 1916

EUGENE WESLEY SHAW,* Washington, D. C. (written discussion ?).-Studies of the probable future production of oil wells and fields-particularly those in the nature of the recent work by Lewis and Beal, having the object of increasing the percentage of recovery-rank, in both practical and theoretic value, very high, if indeed they do not outrank all other petroleum investigations except structural surveys. Even such surveys, although saving untold millions that might have been spent in prospecting unpromising territory, may have less ultimate value than generally supposed, for it may perhaps be argued that much if not most of the condemned territory will sooner or later be tested-some is already productive-and the most that can be rightly claimed is the recovery of cream first; also that the consumption of the richest portions first cannot be extenuated, as it might with some resources, on the ground that if the best is not taken now it will deteriorate.

Jan 5, 1918

During the year 1915 the Committee received 161 manuscripts, which were treated as follows: 3 accepted for. New York Meeting (110th) . 64 accepted for San Francisco Meeting (111th) 49 accepted for New York Meeting (112th) 3 accepted for Arizona Meeting (113th) 29 rejected 4 returned to authors for revision and not yet accepted 9 in committee. 161 Every paper which was presented at the San Francisco Meeting was published in advance in the Bulletin with one exception. The work of the Committee has been systematized and. the Executive Committee of the Committee on Papers and Publications has given prompt attention to all manuscripts, with the result that every paper received by the Committee on Papers and Publications is in the hands of the, printer within 30 days thereafter, unless delays occur owing to questions as to acceptability, in obtaining from the author permission for revision, or other like causes.

Jan 2, 1916

By Gordon C. Rausser, Michael D. Boehlje, Richard A. Levins, John A. Otte

Changes in SO2 emission standards will not only influence the cost of supplying energy demands from coal, but also the competitive position of various production regions and the method of mining (surface vs. underground). A multiperiod interregional competition model was utilized to evaluate the interactions between mining capacity, new mine development, coal reserves, mining, processing and transportation costs and equipment availability and SO2 emission standards. The empirical results indicate that not only will costs increase dramatically, but production in eastern as well as western regions that have low sulfur reserves will also increase as sulfur standards become increasingly more strict. Implications of the adjustments in the location of coal mining activity for the processing, transportation, and capital goods markets are also presented.

Jan 1, 1978

By Walter Renton Ingalls

The ores of zinc which are important as sources of that metal are of two classes, viz., the sulphide and the oxidized. The latter includes six varieties: zincite (the red oxide) and franklinite (the oxide of zinc, iron, and manganese), which are found abundantly only in New Jersey; and the hydrous and anhydrous carbonates, the hydrous and anhydrous silicates, which are of widespread occurrence. The hydrous carbonate is known mineralogically as hydrozincite, zinconise, or zinc-bloom; the anhydrous silicate is recognized as willemite. With respect to the anhydrous carbonate and the hydrous silicate, however, there is a confusion of name which is of old standing. Attempts to clear it away were long ago made by the mineralogists with the result that there is now a more or less national uniformity of nomenclature; but there is still an international disagreement, sometimes very perplexing and always leading to inexactness in expression, which may be considered an adequate excuse for this return to a time-worn subject. The name calamine, together with Galmei of the Germans, is commonly supposed to be derived from xadµela, which was used by the Greeks to designate the peculiar kind of ore employed with copper in their brass-making, and also the accretions which formed in the brass-founder's furnaces. Agricola, however, says that it is from calamm, a reed, in allusion to the appearance of the material, cadmia fornacum, which collected 011 the furnace-walls. But whatever the derivation of the word, it was used until within one hundred years to include all the oxidized

Jan 1, 1896

Joseph Hartshorne was born in Philadelphia in 1852. He died Aug. 23, 1918. After graduating from Haverford College, he took a special course in chemistry at the Massachusetts Institute of Technology, and later at the University of Pennsylvania. He started with The Pennsy!vania Steel Co. as an apprentice in 1873, working in the laboratory and mills for two years, and then one year as foreman in the Bessemer Department. Next, he was assistant chemist in the second Geological Survey of Pennsylvania. In 1878, he went to Prance to investigate the Pernot open-hearth furnace for the Cambria Iron Co. Upon his return, he assisted in designing and erecting the plant in Johnstown and was foreman of a turn for one year, and superintendent for the next. In 1881, he became superintendent of the Bessemer and rolling-mill departments. In 1884, he went to Pottstown and also made a trip to Europe to investigate the Bessemer basic process. Upon his return he dcsigned and erected the basic Bessemer plant for the Pottstown Iron Co., and was superintendent there until 1893, when the company failed. Since then he has been a consulting metallurgical engineer, and expert in patent cases. The !most important of the latter was that of Krupp versus Midvsle on the armor-plate patent case, in which he was leading cxpert for Midvale. He was a good linguist, having command of French and German, and a fair knowledge of Italian and Spanish. In all, he made eight professional trips to Europe.

Jan 1, 1920

By Leon O. Hart

The nickel-chromium alloys of importance are those containing iron and those free from iron. The most important alloys containing iron, with regard to high tonnage, are the nickel-chromium steels. Straight nickel steel was introduced about the year 1889, but it was not until 1895, when it was found that the addition of chromium greatly increased the strength and resistance to shock, that nickel-chromium steels came into use. The three types of nickel-chromium steels developed at this time were: Type 1, containing 3.,50 per cent. nickel and 1.50 per cent. chromium; type 2, containing 2.00 per cent. nickel and 1.00 per cent. chromium; and type 3, containing 1.50 per cent. nickel and 0.50 per cent. chromium.

Jan 1, 1921

By Orville R. Lyons

CENTRIFUGAL force has been utilized for the dewatering of fine coal for over 50 years by means of machines commonly called centrifugal dryers. In any centrifuge the coal and water are subjected to a spinning action which usually inctedtocreases in intensity as the coal progresses through the machine. This spinning action, or the centrifugal force that it induces, tears water away from coal particles and produces a dewatered coal. The effectiveness of the dewatering action for any particular machine is governed by the size-consist of the coal and the centrifugal force imparted to the water on the coal. Four makes of centrifuge are currently being used to dewater fine bituminous coal in the United States. These include the vertical, basket-screen C.M.I. (Centrifugal and Mechanical Industries) Carpenter, Reineveld, and the horizontal solid-bowl Bird. The C.M.I. and Reineveld centrifuges are similar in construction and are variations of the Elmore centrifuge, varying principally in the slope of the basket, operating speed, size of perforations in the basket, and diameter of the basket. The same operating description suffices for both. These centrifuges are made up of two rotating elements, an outside conical screen frame and an inside solid cone which carries spiral pusher blades. The screen frame is supported by a hollow shaft, and the solid cone by a spindle shaft passing through the hollow shaft. Both the screen frame and the solid cone rotate at high speeds; the solid cone, with its scraping flights, rotating somewhat more slowly than the screen. The wet coal enters the machine at the top, falls on the cone, and is thrown against the screen by centrifugal force. The coal slides down the screen until it meets the upper end of the flights, where it is moved slowly along the flights until discharged at the bottom. The elfluent passes through the sieve basket or screen and discharges into a launder. The Carpenter centrifuge consists of a conical rotating element with a vertical axis, built up of three rows of perforated stainless-steel plates or stainless-steel wedge-wire or round-wire sections cut and rolled to conform to the surface of the cone. Wet material is delivered to a conical hopper inside the centrifuge casing and is distributed in a thin, even layer over the inner surface of the cone by a disk mounted on the rotor shaft. Impacting of the coal against the screen and the centrifugal force exerted as the material moves downwards creates a dewatering effect. The moisture is forced through the coal bed and then through the perforated plates of the basket, collecting in a circular trough built into the centrifuge. The effluent is conducted from the trough through the centrifuge casing by outlet pipes. The dewatered coal is discharged over the inside bottom edge of the rotor. The Bird centrifuge consists of a tank or truncated conical shell, which is revolved at the desired speed by means of a drive sheave. A screw conveyor rotates inside the cone or bowl at a slightly lower speed in the same direction of rotation. The feed entrance, in the center of the large end of the truncated cone, is high enough to allow formation of a pool of slurry. Adjustable effluent-discharge ports are located in the large end of the bowl so the level of the liquid can be regulated. The solids are moved forward by the screw conveyor as fast as deposited and carried above the level of the pool for an interval before leaving the bowl. In the past these four makes of centrifuge could be compared only by indirect means. The author published a rough comparison method in 1949' but

Jan 1, 1952

The following resolution was passed by the Military Engineering Committee of New York on April 12, 1917. Copies are being sent to each member of Congress and to each of the five members in every State forming the committee representing, the five National engineering societies which carried on the industrial census under the direction of Howard Coffin. The Committee is urging every man to wire his Congressman and his Senator, asking him to do everything in his power to obtain favorable action by Congress on this resolution: Whereas in any large army to be created for the war, engineer troops will be needed in large numbers, and Whereas they should be officered by skilled engineers only, and Whereas the composition and training of such troops differ so much from the composition and training of non-technical troops that they should be organized under one central authority rather than under many scattered authorities. Now, therefore, be it resolved: That the members of the Senate and House of Representatives be requested to insist that all new units of engineer troops be organized and maintained by the War Department and not by the individual States.

Jan 6, 1917

By H. M. St. John

LIKE every present-day manufacturer, the brass foundryman is faced with the necessity of reducing the cost of his finished product without impairing its appearance or quality. He must use every economy that the progress of art and science puts at his disposal and should also be alert to profit by any peculiarity in his own situation or the nature of his product that may give him an exceptional advantage. Much can be accomplished by the adoption of labor-saving equipment and improved methods of melting, molding and handling. Control of pouring temperature, study of defective castings and their causes, laboratory control of molding sand and core mixtures, the use of less expensive alloys, all contribute to the desired end. Assuming that the composition of the alloy is already as inexpensive as the character of the casting will permit, still further savings can be made by the intelligent purchase and utilization of the metals needed to produce the desired analysis.

Jan 1, 1929

By Nicholas J. Grant, H. C. Chang

EMPHASIS on the importance of grain boundary sliding as a mode of deformation at elevated temperatures has been presented elsewhere.' The extent to which boundary sliding occurs under certain creep conditions has been determined for high purity aluminum2,3 and aluminum alloys.' In general, boundary deformation extends quite far into the adjoining grains, resulting in a rather wide band of deformation along the grain boundaries. This has led some investigators to doubt that grain boundary sliding consists of shearing along the boundary surface; it has been contended instead that boundary sliding is a result of concentrated slip in the neighborhood of the deformed grain boundaries."' The purpose of this note is to present evidence that grain boundary sliding takes place by a bulk shear process. gh purity polycrystalline aluminum, wherever and whenever there is grain boundary sliding, boundary migration and concentrated deformation along both sides of the deformed boundary are associated with it. Therefore, it has been rather difficult to obtain unambiguous evidence of boundary sliding. On the other hand, it would be expected in certain alloys of aluminum, when tested under particular conditions. that the severity of the interfering effects of boundary migration and concentrated deformation along the deformed boundary might be reduced. Current research in this laboratory' shows that a 20 pct Zn-A1 solid solution alloy fractures in an intercrystalline manner during creep at 500°F with a small total elongation of not more than about 14 pct, and that it does so with extremely limited grain boundary migration. Accordingly, this alloy was chosen for the present study. The experimental procedure was similar to that used in previous work and has been presented elsewhere.' Two parallel flat surfaces were milled from a round specimen. The gage portion of the specimen was 1 in. x .09 in. x .17 in. The specimens, which were annealed at 1030°F for 24 hr, showed two to four grains across the width of the test bar. The specimens were subjected to creep at 500°F at stresses of 2000 to 5000 psi. The rupture times were from 10 sec to 3 hr. Appreciable boundary sliding occurred in all the tests. A typical example of boundary sliding is shown in Fig. 1. (The tension axis is vertical in the micrographs.) Sliding has taken place along the boundary between grains A and B unaccompanied by important boundary migration. The sharpness of the offset at the triple point can be clearly seen in grain C. As a result of sliding along the boundary between grains A and B, a new boundary surface between grains A and C was created. The offset at the triple point is about 0.07 mm. This boundary sliding is accompanied by the formation of rather sharp kinking bands and, of course, slip on several slip systems in grain C. This type of deformation has been referred to as fold formation' in previous work with high purity aluminum.

Jan 1, 1957

Man is born on Mother Earth without knowledge or skills. Soon he finds physical needs for food, clothing, shelter, exercise, and relaxation. His personal needs are self-expression, new experiences, and amusements, while his social needs have been classified as work, status, security, friendship, companionship, and love. He finds himself infinitesimal in comparison to the whole. Often- times when he feels smug, he is actually riding for a fall. And nothing is much worse than frustrated man. The postwar world does not provide the Utopia of peace and prosperity of which man had dreamed. In fact, it seems that the sacrifices and waste of that great struggle are being lost in the morass of stupidity, selfishness, and cupidity which unfortunately are still the most conspicuous traits of the human race. Perhaps it is too soon to expect the blessiilgs which are supposed to appear in a peaceful world, and man's thought is clouded with a pessimism engendered by the conflict itself, in which all activities tend to enhance his pessimistic nature. Must man submit that it is a law of nature for nations to go to war? The war has demonstrated that when faced with a common danger, peoples differing in antecedents, language, forms of government, and resources can unite for a time, pool their skills and abilities, and emerge victorious from a contest unparalleled in magnitude, ruthlessness, carnage, waste, and cost. This has been accomplished by great individual and national sacrifices, the

Jan 1, 1950

By R. R. Brandenthaler

Petroleum producers in the Mid-Continent field, up to the present time, have been more concerned with the mechanical operation and efficiency of the gas-lift than with its possible effects on the physical properties of the oil. As a result few specific data are available on the subject and contradictory opinions exist. Some operators are positive that the gravity of the oil is decreased, while others present data which definitely show that the gravity of the oil is increased. In other localities, some operators have given careful attention to the effect of the gas-lift on the gravity of the oil. When the emulsions formed have given much trouble, the problem has usually been dodged by placing the well on the pump. Certain Fundamentals Certain fundamental results may be expected under ordinary conditions and with all types of crude oil, when gas is the prime mover of oil in producing formations. For example, the gravity of oil will decrease as the rock pressure in the producing formation declines, the change being greater in the higher gravity oils. Furthermore, the character of emulsion formed is primarily dependent on the kind of oil, thus more refractory emulsions are formed from asphaltic-base oils, less refractory from mixcd-base oils, and the least refractory from paraffin-base oils. However, refractory emulsions are sometimes formed from paraffin or mixed-base oils that are difficult to treat by ordinary methods, especially by electrolytic processes. With oils having the same base, those of lighter gravity are less subject to the formation of emulsions, especially of refractory emulsions. There are two types of emulsions formed; namely, water-in-oil emulsions and oil-in-water emulsions. The former are the more common; in fact, very few examples of oil-in-water emulsions have been noted in the oil fields. The amount of water produced with the oil influences the percentage of emulsion formed. Agitation and velocity of flow play an important part in the forming of emulsions.

Jan 1, 1928

By C. H. Wilson, J. J. Jakosky

In recent years geophysical prospecting methods have become well established as important steps in economically initiating new mining ventures in the field of base-metal exploration, placer mining and water-supply problems. The value of these methods as applied to these problems has been greatly increased by new and improved instruments, and a greater degree of skill in laboratory and interpretative technique. Considerable success has been attained, with subsequent drilling checking the predicted depths within 1 to 5 per cent, on problems requiring information on thickness of fill material, depth to and contour of bedrock, extent and yardage of gravels to be mined, and location of hydrostatic water table. In these applications the geophysical work gives data comparable to drilling, and at a cost of about one-fiftieth that of drilling. Discussion of several surveys with accompanying illustrations showing geophysical methods applicable to both simple and complicated placer problems are contained in the paper. The electrical instruments for measuring electromagnetic field strength and surface potentials are described, and their use, coupled with that of other geophysical instruments in modern field procedure, is noted.:

Jan 1, 1934