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By P. den Hoed, R. I. Rambiyana

"Four sulphide minerals - pyrite (FeS2), pyrrhotite (Fe1-xS), pentlandite ([Ni,Fe]9S8), and chalcopyrite (CuFeS2) - contain the base metals and most of the iron in concentrates of platinum group metals (PGMs). In the pyrometallurgical processing of PGM concentrates these sulphides form a matte during smelting, and iron and sulphur are removed from the matte during the converting process. This paper discusses the roasting of Merensky concentrate in air before smelting, with the purpose of reducing the matte load to the converter.Roasting tests were conducted in a bench-scale rotary kiln at temperatures from 350°C to 700°C. The concentrate tested contained 17.4% sulphur and consisted of 23% pyrrhotite, 16% pentlandite, 11% chalcopyrite, and 2% pyrite. The particles were fine (d50 = 22 µm), and all the sulphide particles were liberated. Roasting in air at 550°C and 650°C for 20 minutes removed respectively 60% and 70% of the sulphur. The iron in the sulphides was oxidized to Fe3O4 (magnetite) at temperatures below 500°C and to Fe2O3 (haematite) at temperatures above 550°C. At 700°C the bed sintered and copper oxides formed. At temperatures below 450°C oxidation was incomplete: pyrrhotite remained and only 30% of the sulphur was removed. Smelting tests were conducted to assess matte fall and the deportment of copper and nickel to matte. It was evident that roasting resulted in lower matte falls (a drop of approximately 60%) compared with matte falls from unroasted concentrate. The iron and sulphur levels in the matte were reduced to below 3.5% and 22% respectively.This paper also briefly describes the mechanisms by which pyrrhotite, chalcopyrite, and pentlandite are oxidized during roasting. For chalcopyrite, the mechanism proceeds through an intermediate solid solution phase, which extends from Cu1.02Fe1.04S2 to Cu2.04Fe0.72S2 to a copper-rich solid solution of bornite (Cu4Fe1.4S4-Cu2S). The oxidation of pentlandite proceeds through a monosulphide solid solution (Ni0.39Fe0.53S-Ni0.74Fe0.15S) to a solid solution of heazlewoodite ([Ni,Fe]3}xS2). These mechanisms are explored in relation to chemical thermodynamics and microstructures."

Jan 1, 2015

By Met B. E

During the operation of the Parkes process of desilverising, and in the earlier days of the continuous process, gold and silver were removed separately from softened lead bullion. Gold was removed in the Parkes process by a selective zincing, and -in the continuous process by treatment with zinc in a special de-golding kettle, in each case a crust being obtained carrying the gold and a small portion of the silver. Actually the process could have been more correctly termed a de-copperising process, on accountof the relatively large amount of this metal present, and its affinity for zinc, which caused it to enter the crusts produced.The crust was treated in reverberatory furnaces, where the bulk of the copper and zinc was removed in by-products, and the resulting "gold bullion" cupelled to give adore bullion containing approximately 2,000 ounces gold per ton.For the purpose of parting this dore, a small Balbach-Thum plant of 11 cells was used, and once each six months a short campaign was conducted on the accumulated metal.With the development of the process of de-copperising smelter bullion by means of sulphur, when a bullion averaging about .004% copper was constantly available for refining, the need for a separate de-golding process disappeared.The de-golding kettle of the Continuous Process...

Jan 1, 1937

Standards And Laboratory Monitoring In Gold Assay Key Components Of Best Practice

Jan 1, 2005

By Woodcock J. T, Sparrow G. J, MacRae C. M

The external urfaces and interiors (as polished sections) of particles of coconut hell and extruded peat activated carbons taken from everal Australian carbon-in-pulp operations were examined with an optical micro cope, a scanning electron microscope, and an electron microprobe.Calcium carbonate (calcite) precipitated from the pulp was the major inorganic material on the external surfaces of the carbon particle, but several ore minerals, including quartz, hematite, pyrite, arsenopyrite, and clay minerals were also identified, along with trona, gypsum, a nickel cyanide, and a magnesium salt. Sections of carbon particles showed that calcite was virtually the only introduced inorganic material inside the carbons.It was distributed in the pores and cracks throughout the coconut shell carbon particles but tended to be concentrated in the outer layers of the extruded peat carbon particles. The mechanism of calcite formation and deposition is uncertain. Gold X-ray dot maps showed that gold was distributed through to the centre of coconut shell carbons and to a depth of at least 500 µm in extruded peat carbons. The distribution of gold within the carbon particles was similar to that of calcite.

Jan 1, 1988

By J. Dienenthal

Automatic Charging and Stoking Machines for use at ferroalloy furnaces are in operation for more than 20years. Dango & Dienenthal Maschinenbau GmbH (short: DDS) has developed several machine generations. Today advanced solutions help to achieve better charging and stoking results to minimize cost and to improve the working environment around the furnaces. Three different alternatives can be considered: Rail-mounted solution The machine(s) travel(s) on an overhead monorail to one or several furnaces and is locked in the desired working position from where charging and stoking is performed. Mobile solution This machine travels on the charging platform and is also locked at the respective working position to perform charging and stoking. Automation of a standard mobile charging and stoking machine A standard charging and stoking machine can be adapted for automation. A reliable navigation system is included. Charging and stoking is performed with the moving machine. Advantage versus other solutions: considerable lower investment cost and possibility to upgrade the mobile charging and stoking machine for later automation. Overall, automatic charging and stoking can save up to 10 per cent of the specific smelting energy. A better and more consistent furnace operation can be achieved. Different programs are used to cope with different furnace conditions and changing raw materials. All machine movements can be recorded and correlated to other furnace parameters. Working environment on the charging platform is greatly improved.

Jan 1, 2007

By Anne Lemnitzer

Full-Scale cyclic field testing was performed on a 3x3 pile group consisting of nine cast-in-drilled-hole (CIDH) reinforced concrete shafts and a comparable single-shaft in order to investigate group interaction effects. Both specimens were constructed with pile diameters of d = 0.61m (2 ft), fixed head boundary conditions, and placed in stiff clayey soil at a test site near the LAX Airport in Southern California. Internal instrumentation was installed in the single pile as well as in three piles within the pile group to obtain pile curvatures. External instrumentation controlled the lateral displacement of the specimens. A combination of experimentally and analytically obtained p-y curves for the single pile was used to simulate results for piles located in the group when field data were not available. All test specimens were tested to structural failure and excavated after test completion to investigate pile damage and plastic hinge formations. Calculated group interaction factors ranged between 1.0 at very small displacement levels of <2.5 mm (0.1 in), 0.8 at the initiation of the pile-soil-pile interaction, i.e. between 4 mm - 15 mm (0.16-0.6 in), and increased towards 0.9 near structural failure (displacement >25 mm or 1 in). A literature set of p-multipliers was found to reproduce an accurate fit to the available load displacement test data from the group.

Jan 1, 2010

By B. Y. Park

This paper develops a series of three-dimensional simulations for the Bayou Choctaw Strategic Petroleum Reserve. The U.S. Department of Energy plans to leach two new caverns and convert of one of the existing caverns within the Bayou Choctaw salt dome to expand its petroleum reserve storage capacity. An existing finite element mesh from previous analyses is modified by adding two caverns and increasing the size of existing Cavern 102. The structural integrity of the three expansion caverns and the interaction between all the caverns in the dome are investigated. The impacts of the expansion on underground creep closure, surface subsidence, infrastructure stability, and well integrity are quantified. The results show that from a structural viewpoint, the locations of the two newly proposed expansion caverns are acceptable, and all three expansion caverns can be safely constructed and operated.

May 1, 2009

By Curtis Wilson

FROM the results of his investigation of the hardenable copper-nickel-silicon and copper-cobalt-silicon alloys, M. G. Corson1 explained the dispersion-hardening effect by assuming the precipitation of the inter-metallic compounds nickel silicide and cobalt silicide, and on this basis he constructed diagrams for the pseudobinary systems copper-nickel silicide and copper-cobalt silicide. A consideration of these diagrams and of the factors that exert such an important influence upon the rate of precipitation, such as degree of supersaturation, nucleus number and rate of diffusion, leads to the expectation that the rate of precipitation of the silicides on reheating the quenched solid solutions at temperatures below the alpha-phase boundary should increase continuously as the reheating temperature is raised. The present investigation shows that while this rate does increase with the reheating temperature in a general way, it does not do so continuously. Supplements to Corson&apos;s diagrams are offered, showing the discontinuities, and slight modifications in the solubility curves are suggested.

Jan 1, 1933

Sulfidisation Promotion Effect of Ammonium Sulfate on the Flotation of Copper Oxide Ores

Sep 13, 2010

By Michael Amick

Over the last few years as the coal industry has seen an increase in the price of coal, a renewed interest in the additional mining of pre-law highwall sites has occurred. Much premium coal and property remains behind these pre-law highwalls but access to mining is limited because prior mining used auger machines to remove coal from under the highwall. Older augers seldom reached more than 200 feet and often no more than 100 feet but this zone of auger holes destabilizes the highwall to where additional mining is often unsafe. If the reserve is large enough, the highwall can be stabilized with common flyash and cement grouts to form a face-up for an underground mine but this expensive method is usually not practical for continuous use with a highwall mining machine. It is estimated there are hundreds of miles of highwall riddled with auger holes where the coal reserve available is ill-suited for deep mining for a variety of reasons. However, these same properties are ideal for additional mining with state-of-the-art highwall mining machines that have a reach up to 1200 feet, except to the relatively thin auger mined de-stabilized zone. The renewed interest in highwall mining these properties has driven research into finding an economical way to stabilize the highwall so the highwall mining machine can recover additional coal. This research discovered and fine-tuned a process that is economical and is successfully supporting the highwall at a highwall mining operation. This paper discusses the research involved in determining the strengths need, the methodology used to place any grouts, the effect on mining plans and the increased recoveries. ARMPS-HWM is used extensively in this research. The failure of the highwall, when not grouting, and the success, when grouting using the new materials and equipment utilized, confirmed the ARMPS-HWM method.

Jan 1, 2007

By Oscar Concha

El presente texto describe la exploración, geología, controles estructurales, mineralización y los tipos de alteración hidrotermal del yacimiento minero Cuajone, situado al sur de la Cordillera Occidental de los Andes y en el flanco Andino de Moquegua. En 1937, se inicia su exploración a través de una campaña exploratorla de la empresa Cerro de Pasco, donde se determina la zona como un proyecto potencial de cobre porfirítico de baja ley. Posteriormente en 1942, se inicia la primera campaña de perforación diamantina exploratoria y en 1969, se inicia la etapa de construcción y desbroce de material para preparar la mina. De otro lado, se ha desarrollado un modelo de la evolución del yacimiento desde las rocas preminerales del Grupo Toquepala, de las cuales la andesita basáltica fue una gran receptora de la mineralización de cobre originada por la intrusión de un primer pulso de latita porfirítica.

Apr 26, 1999

By M. Mikolás, L. Pomothy, K. Špakovská, M. Vanek

"Enterprises are faced with increasing economic competition and managers are obliged to look for methods that will ensure a competitive edge in their companies’ markets. These methods include managerial concepts that employ common sense and are low cost. One of these approaches is the KAIZEN methodology, of Japanese origin; kaizen means continuous improvement (CI) when translated. A mining company, despite some of its idiosyncrasies, is just an enterprise where the application of KAIZEN can be advantageous. The company investigated, OKD, is the only domestic producer of hard coal in the Czech Republic and operates four mines that produce 11 Mt of coal annually. The OKD management team opted for KAIZEN as their principal method of continuous quality improvement. This paper suggests ideas for development and application of processes that provide for continuing improvement of production and management. The authors have taken the OKD Company to be their benchmark in the field of mining activities. The paper also focuses on possible difficulties accompanying the introduction of CI sustainable methods. Three years of application of CI methods has increased the income of the company by almost US$38.1 million, which provides a strong argument for continued application."

Jan 1, 2015

By R. L. Guerguerian

Nowadays, most grinding mills driven by a wrap-around ring motor are operating successfully. Some of the earlier problems could be attributed to the lateral stiffness and stability of their bearings. As a result, modifications to the bearings included the rearrangement of the shoes, or the addition of more shoes, closer to the horizontal centerline. This technical paper reports a study of the effects of bearings on the lateral stiffness of grinding mills driven by a wrap-around ring motor. The discussions cover the design of the four shoe trunnion bearings and examine the effects of the angular location of the shoes.

Jan 1, 2000

Surface subsidence caused by coal mining operations was the subject of a very successful symposium organised by the Illawarra Branch of The Australasian Institute of Mining and Metallurgy in February, 1973. This symposium dealt with the principles of subsidence and overseas experiences arising out of underground mining. Since that time the New South Wales Department of Mineral Resources and Development (formerly the Department of Mines) has incorporated in the approval for pillar extraction certain conditions related to the monitoring of surface movement. Surveys and plans are required to be kept at mines where total or partial extraction of coal takes place. This paper traces the monitoring of surface movement in the Northern Coalfields of New South Wales over the past ten years. Reference is made to the National Coal Board&apos;s Subsidence Engineers&apos; Handbook (1975) and how the guidelines expressed therein have been beneficial. Mining engineers in Australia are able to plan underground workings where minimum subsidence is allowable and are in a position to foreshadow the surface effects where total pillar extraction is carried out. In certain cases such surface effects can be minimised by structural design in buildings or pipelines.

Jan 1, 1980

By Neil Westoll

But First, An Overview of the Selwyn Basin and Its Resources ?World-renowned sedimentary-exhalative (SEDEX) deposits of zinc, lead, silver +/-barite ?Significant reserves/resources remain and vast tracts of prospective stratigraphyremain under-explored and untested. ?More details are at the Yukon Geological Survey?s Selwyn Basin Metallogenysite:http://www.geology.gov.yk.ca/metallogeny/selwyn/ Overview of Metal Price and Demand Trends ?The pace of economic change in China has been extremely rapid since the start of economic reforms just over 25 years ago. According to official statistics, economic growth has averaged 9.5% over the past two decades and seems likely to continue at that pace for some time. National income has been doubling every eight years. Such an increase in output represents one of the most sustained and rapid economic transformations seen in the world economy in the past 50 years.? Organization for Economic Co-operation and Development 16-Dec-2005

May 1, 2006

By Jean R. Garcia, Paulo J. R. Albuquerque, Renato P. Cunha, Osvaldo Freitas Neto

"Abstract Results obtained from in-situ load tests carried out on drilled displacement piles sunk in a porous, lateritic and unsaturated soil deposit, are analyzed in this paper. Three slow-maintained load tests were performed on deep instrumented piles with a diameter of 0.37 m and around 12 m long. The soil deposit consists of a superficial, silty clay “porous” layer 6 m thick, with an average standard penetration blow count (NSPT) of 4 and cone tip resistance and sleeve friction (qc and fs) of 1.5 MPa and 48 kPa, respectively. Under this layer there is a residual stratum 10 m thick, geotechnically consisting of a “porous” clayey silt with an average NSPT of 7 and qc and fs of 2.4 MPa and 202 kPa, respectively. The water table was reached at a depth of 17 m below ground level. The results of the field load tests yielded a maximum pile load (average for the tests) of 1428 kN, which is twice as high as corresponding experimental values from standard bored piles with similar geometric conditions. Exhumation of one of the tested piles was carried out after the test, in order to check integrity and shaft conditions. Numerical finite element analyses, using the commercially available French Code LCPC Cesar®, were performed in order to back-analyze the geotechnical soil parameters for a post execution pile condition. The results permitted a better understanding of the improvement of the subsoil given the intrinsic execution characteristics of this particular pile. It was also possible to note that drilled displacement piles have great potential to become an economically viable solution in tropical soils, given the enhanced behavior of such piles when compared to alternative (cheaper) techniques. In fact, it has several advantages which should make it a key foundation type in the Brazilian market in the future.IntroductionMost buildings in tropical soils use, as the main type of foundation, deep bored or auger type piles. These types of foundations can be performed in various ways, for example with or without soil extraction, with or without bentonite mud and so on. Two main processes maybe formulated: the first execution process is typified by bored pile types, continuous flight auger piles etc., which do not cause excessive soil displacement during excavation. With respect to the second process, one could mention, amongst others, driven piles (precast concrete or steel), Franki piles and drilled displacement piles, which do displace the soil during excavation by pushing the soil laterally around the hole in order to allow either the penetration of the pile or the excavator auger."

Jan 1, 2014

Performance of Dry Separation Processes in Cenospheres Recovery from Coal Fly Ash

Sep 13, 2010

By N. Sutcliffe

Refractories and slags play a vital role in the production of stainless steel. They are in intimate contact with the steel at temperature, and chemical reactions between the three can and do occur. These interactions can be beneficial, in the case of active tundish and ladle slags, and negative in the case of refractory erosion and slag entrapment. This paper presents the results of both plant trials and laboratory investigations of steel/refractory and slag/refractory interactions. The interaction mechanisms observed are described leading to selection criteria for new refractory products. Keywords: slags, steels, refractories, reaction mechanisms.

Jan 1, 2004

By Axel Nitschke, Josef Arnold

Bochum’s Underground Lot 306 was characterised by a confined site and unique tunnelling methods. A highly mechanized construction concept was developed to achieve high progress rates. Bespoke backup systems for muck disposal and material supply were used. For the first time in suburban tunnelling, wet shotcrete, batched onsite, was applied. A three-storey underground car park had to be undermined with only1.5 m of overburden and had to be lifted several times by “compensation grout in.” An existing operational two-lane metro tunnel was enlarged without any major impact on train operation.

Jan 1, 2005

By Robert Martin, Brian W. Stump, David P. Anderson, W Scott Philips

Since 1994, various mines in the US have cooperated with research scientists at the Los Alamos and Lawrence Livermore National Laboratories to address issues related to verification of the Comprehensive Test Ban Treaty (CTBT). The .CTBT requires that no country may conduct any nuclear explosion in the future. While the CTBT is a significant step toward reducing the global nuclear danger, verifying compliance with the treaty requires that the monitoring system be able to detect, locate and identify much larger numbers of smaller amplitude seismic events than had been required previously. Large mining blasts conducted world-wide will be of sufficient amplitude to trigger the monitoring system at the lower threshold. It is therefore imperative that research into the range various blasting practices employed, the relationship of yield to seismic magnitude, and identification of anomalous blasting results be performed. This paper will describe a suite of experiments funded by the Department of Energy and conducted by the Los Alamos and Lawrence Livermore National Laboratories in cooperation with the US mining industry. Observations of cast blasting, underground long wall generated coal bumps, stoping, and explosively induced collapse of room and pillar panels will be presented. Results of these dual use experiments which are of interest to the mining community will be discussed. These include 1) variation of amplitude of seismic energy at various azimuths from cast blasts, 2) identification of the extent of back failure following explosive removal of pillars, and 3) the use of single fired shots for calibration of the monitoring system. The wealth of information and discovery described in this paper is a direct result of mutual cooperation between the US Government and the US Mining Industry.

Jan 1, 1997