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By Weng Fu, James Vaughan, Stefan Lakemond

Uranium bearing copper sulphide flotation concentrates produced from iron oxide copper gold uranium (IOCG–U) ore contains radionuclides such as 238U, 230Th, 210Pb, 226Ra, 210Po, which have the potential to reduce their marketability, thus posing a challenge to the industry. Thus, a two–stage leach process has been proposed in this study. In first stage, a sulphuric acid leach process effectively dissolve most of the 238U and 230Th into solution, but other radionulclides (mainly 210Pb, 226Ra and 210Po) remain associated with copper sulphide minerals owing to their low solubilities in sulphuric acid solution. In the second leaching stage, the use of methanesulfonic acid (MSA, CH3SO3H) is investigated to selectively dissolve the 210Pb, 226Ra and 210Po from the residue of the first stage. The results indicate that 96% of 238U, 87% of 230Th, 90% of 210Pb, 86% of 226Ra and 17% of 210Po are dissolved using 3 mol/L MSA solution at 90°C for 3 hours, which represents a dramatic decrease in the radioactivity of the copper concentrate. INTRODUCTION Australia is host to one of the largest iron oxide copper–gold–uranium (IOCG–U) deposits in the world. Most of the value in these deposits is associated with copper. In mineral processing, the gangue minerals are separated from copper sulphide minerals that report to a copper flotation concentrate. However, due to the strong association of uranium with copper minerals and hematite, even clean copper concentrates can contain significant amounts of uranium (238U) and its radioactive decay elements, of which thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) are the long life radionuclides. These hazardous radionuclides negatively affect the marketability of the copper concentrates. Customer copper smelters in China, Japan and Europe may consider the radionuclides penalty elements or may not be able to process the feed. Therefore, there is a strong motivation to remove radionuclides from copper concentrates at the mine site before shipping to custom smelters in global market. Hydrometallurgical leaching has been widely employed to remove radionuclides from different kinds of minerals such as copper concentrates (Ragozzini & Sparrow, 1987), zircon concentrates (Aral, Sparrow, McDonald, & Norgate, 2007), and coal ash (Lei, Qi, Sun, Xu, & Wang, 2014). Leaching using sulphuric acid (H2SO4) solutions is the most widely used process for the extraction of uranium from uranium ores due to the relatively low cost and wide availability of the acid (Bhargava et al., 2015; Gilligan & Nikoloski, 2015). The leach process involves treating ground ore slurry with sulphuric acid at elevated temperatures (typically 60–90 °C) under oxidising conditions in order to convert the uranium in the minerals 2+ from the relatively insoluble tetravalent form (UO2) into water–soluble hexavalent state (UO2), which then complexes with SO42- and forms UO2(SO4)22- in solution. The uranium oxidation is generally carried out in the presence of ferric ion (Fe3+), regardless of the reagent and oxidant used. The most commonly used oxidants for uranium include sodium chlorate, pyrolusite and oxygen (Ring, 1980). These oxidants act indirectly by converting ferrous sulphate, formed by the oxidation reaction of UO2 in slurries, into ferric sulphate. The presence of Fe–containing gangue minerals such as hematite in the ore usually provides sufficient Fe required for the oxidation of UO2. After sulphuric acid leaching, the locked thorium (230Th), radium (226Ra), lead (210Pb), and polonium (210Po) elements are chemically liberated from hematite and uranium mineral grains (Ciobanu, Wade, Cook, Schmidt Mumm, & Giles, 2013). However, the extraction rate of radium (226Ra), lead (210Pb), and polonium (210Po) in sulphate solution is very low due to the limited solubilities of (Ra, Pb, Po)SO4 (Bagnall & Freeman, 1956; Liu & Papangelakis, 2006; Nikitin & Tolmachev, 1933).

Jan 1, 2019

By M. Arvola, A. Mäkinen, N. Isomäki

Arsenic is a compound that has no significant market value. However, it needs to be removed from ores, concentrates and other process streams because of environmental or technical processing concerns. A wide range of arsenic containing minerals exists in nature, and in many instances these minerals are also associated with the ones that have commercial value. For example, sulfide copper ores are normally closely associated with minerals like enargite, Cu3AsS4 and tennantite Cu12As4S13. After mineral processing these arsenic sources can report to the waste waters and these effluents need to be treated before discharge or recycling. Ferric arsenate precipitation is a well-established method for stabilizing arsenic in effluents. Electrochemical arsenic removal utilizes the same adsorption/precipitation ideology as ferric arsenate precipitation. Electrochemical arsenic removal, even though it is a simple process in terms of equipment, is a complex system involving chemical and physical mechanisms taking place simultaneously to remove dissolved and/or solid arsenic components from wastewaters. The whole process can be described by the following three steps: 1) electrolytic oxidation at a sacrificial anode (dissolving electrode metal, iron for example), 2) chemical reaction between dissolved iron and arsenic to form a solid precipitate and 3) aggregation of the particles to form flocs, which can be removed by known solid/liquid separation methods. Electrochemical arsenic removal is a very efficient way to remove arsenic from different waters to very low residual concentrations.

Jan 1, 2016

By Kerry Gee, Gary Colgan, James Fricke

Introduction Elevated zinc concentrations are observed in groundwater within alluvium adjacent to Silver Creek east of Park City, Utah. The study area is located in a small valley one and one-half miles northeast of Park City, Utah in Summit County, Utah (Figure 1). Although surface water concentrations in Silver Creek are typically less than 1 mg/l, groundwater concentrations have been measured as high as 85 mg/l in a near neutral pH environment. The elevated zinc concentrations in groundwater result from several factors including: (1) dissolution of zinc from tailings exposed at the surface and within the alluvium, (2) oxidizing conditions created by surface/ground-water exchange, and (3) ideal geochemical conditions for the dissolution of zinc-containing minerals. These ideal conditions include readily soluble minerals, available anions for complexation, and lack of available surface adsorption sites.

Jan 1, 2005

By Fulton Flick

THE micrography and macrography of aluminum and its alloys present certain difficulties. Many of the difficulties attendant on the micrography have been removed by methods developed during the past few years, notably those of E. H. Dix, Jr.1 The development of grain size in aluminum and its alloys may be equally troublesome, yet comparatively little detailed attention appears to have been given to it. Satisfactory reagents. are available for the development of such structures in ferrous and most non-ferrous metals, but those applied to aluminum and its alloys, i. e., alcoholic or aqueous solutions of sodium hydroxide or hydrofluoric acid are not entirely satisfactory. Hanson and Archbutt,2 in speaking of these two reagents, state that "These two reagents give fairly satisfactory results, but they sometimes produce badly tarnished surfaces from which the surface deposit is difficult to remove." It has been our experience that neither of these reagents is to be entirely relied on for developing structures suitable for study or photography. This means that when the etch fails to produce satisfactory results the, specimen must be repolished, through the 000-paper at least, and then etched with another reagent. This procedure entails a con¬siderable loss of time, and the final results may not be all that might be desired. However, the reagent to be described, although not a panacea for all etching troubles, has improved results so markedly that it is felt that it is worth offering as a grain-size etch generally applicable to aluminum and aluminum alloys. Czochralski3 in 1915 mentioned the application of a solution of 10 to 20 c. c. concentrated hydrofluoric acid in 100 c.c. absolute alcohol, etching in this reagent being followed by dipping in concentrated hydrochloric-acid solution.

Jan 2, 1925

By David F. Gearhart

The Burrell Can1 is a thin, steel, tubular shell filled with aerated concrete that is used as a roof support in coal mines. The Can height is always shorter than the mining entry, so it is capped with wooden timbers and wedges when it is installed. This combination of the Can and the wooden header is a standing support system that is designed to yield in a controlled manner and exhibit a constant yield, or elastic-plastic behavior. The Burrell Can is capable of withstanding 20 in or more of vertical convergence and 15 in or more of horizontal displacement. Because of this exceptional ability to sustain load through extended convergence and displacement, it is one of the most robust standing supports in use today. The National Institute for Occupational Safety and Health (NIOSH) conducted testing on seventeen Burrell Cans in 1995, during development of the support where the ratio of the height to the diameter, or the aspect ratio, was between 2:1 and 4:1. Based on the results of that testing, it was suggested that the standard aspect ratio of the Can be less than 5:1. This suggestion is intended to preserve the overall stability of the Can, which will help to maintain the initial stiffness and prevent load shedding. Recently, the necessity of the aspect ratio has been questioned, and this issue will be addressed in this paper. Since the initial development and introduction, more than 130 tests of the Can have been conducted at the NIOSH Mine Roof Simulator (MRS), and 25 of those specimens had aspect ratios greater than 5:1. The 18-in-diameter by 10-ft-tall specimens had the largest aspect ratio, 6.67:1.However, the aspect ratio is not the only parameter that affects the performance characteristics of the Can. Multiple factors, such as the use of different wood species, the use of different header or footer configurations, and the use of pedestals, as well as biaxial loading conditions can also decrease the stiffness and capacity of the Can. Data from full-scale tests that include these other factors are analyzed to show that the initial stiffness is primarily affected by the roof and floor contact configurations. Furthermore, load shedding is more likely to occur or begin earlier when the aspect ratio is greater than 5:1 and one or more of the other factors are present.

Jan 1, 2012

By G. R. Peterson

To determine the availability of lead and zinc from demonstrated resources, the Bureau of Mines evaluated 235 mines and deposits in 31 market economy countries. Of the 235 mines and deposits evaluated for this study, 186 were evaluated as zinc operations, 30 as lead operations, and 19 as copper operations. Demonstrated lead-zinc resources of market economy countries in 1981 were approximately 4.3 billion metric tons (t) of ore containing 221 million t of zinc and 97 million t of lead. Of these amounts, approximately 154 million t of zinc and 70 million t of lead are estimated to be recoverable. The analyses indicate that demonstrated resources in market economy countries should be sufficient to satisfy projected demand for primary lead and zinc through the balance of the century. The U.S. lead industry will continue to have a comparative advantage over the rest of the world industry, barring any drastic increase in the cost of compliance with pollution control regulations. It appears that the comparative disadvantage faced by the U.S. zinc industry will probably intensify owing to the relative quantity of lower cost zinc resources in other countries, especially Canada, Australia, Mexico, and Peru.

Jan 1, 1985

By R. C. Bryce

"Selbaie is located northwest of Joutel, in what is known as the fourth east-west volcanic sediment group in northwestern Quebec. The main metals produced are copper and zinc, with important contents of both silver and gold. Production comes from an open pit mine on the A-I zone and from two underground mines on the B zone and the A-2 zone. Each mine gave rise to important capital investment programs for construction and mine development, all of which were managed and staffed with company-hired, non-union personnel. Production from all sources now exceeds 7000 tonnes per day, with a workforce of540 regular employees. Of particular interest technically is the high recovery of B zone reserves underneath 40 m of overburden cover, the low-cost capital development of the A-2 zone, the computerized control of open pit mining, and the successful copper-zinc separation of the A-1 zone ore. Due to the low grades of the mineral deposits, efficiency in all aspects of the production process, is essential to the success of the operation.LocationThe Selbaie Mine is located 82 km northwest of the locality of Joutel in northwestern Quebec (Fig. 1). Access to the mine is by an all-weather road, 32 km of which is paved. A second road access to the site is via La Sarre, 134km to the southwest. Employee access, materials transport and haulage of copper and zinc concentrates take place over both of these roads."

Jan 1, 1990

By Peter Ryan

A patented process for agglomeration of Smelter ESP dusts is described. Addition of suitable binders followed by compaction, transforms fine, difficult to handle material into a dry, flowable agglomerate suitable for plant reentry. Details for the agglomeration process metallurgy and laboratory pilot plant testing are discussed. An example of full scale plant operations is described.

Jan 1, 1999

By W. E. Roscoe, H. Agnerian

The contour method can be used to estimate the mineral resources of a mineralized body. It relies on geological interpretation and allows the geologist to determine the plunge of a mineralized ore shoot along the dipping plane of the mineralized body. The technique is best applied to estimate tonnage and average grade of relatively planar bodies, i.e., where the two dimensions of the mineralized body are much greater than the third dimension, such as Archean lode gold vein deposits or mantos of massive sulphide mineralization, based on exploration drilling. For these types of deposits, the contour method can provide a clear view of the “mineralization landscape” with “peaks” and “valleys” along the plane of the mineralized vein. The technique also reduces the “nugget effect” of local high values commonly present in gold deposits. With sufficient drill hole information, the contour method may be used to estimate the tonnage and average grade of individual blocks within a mineral deposit. General procedures for the contour method are described in this paper, along with examples and explanatory notes.

Jan 1, 2002

By John K. Owens, Wayne L. Howie

Mobile roof support (MRS) machines are used as roof support during pillar recovery in retreat operations in lieu of wooden posts, cribs, or hydraulic props. A Mine Safety and Health Administration-permissible load rate monitoring system was developed for the MRS by researchers at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health. The system uses a dedicated embedded processor to monitor changes in pressure inside the hydraulic cylinders of the MRS through multiplexed data acquisition channels and converts these pressure changes to load rates that sequentially activate three load-rate-indicator lights mounted on the machine. Each light represents a different loading rate to alert mine personnel to dangerous conditions during pillar extraction.

By M. W. Grabinsky, M. S. Diederichs, E. Hoek

Provided that they are used correctly, numerical models can be of considerable assistance to mining engineers in designing underground excavations. Guidance is given to the engineer or geologist who is not a specialist in numerical analysis but who is interested in using numerical modelling tools or in employing someone to analyse the stresses, displacements and failure in the rock surrounding underground excavations. A description of the theoretical background to a number of these numerical models and discussion of the advantages and disadvantages of each are followed by guidelines on the selection of appropriate models for each stage in the development of a mine, from exploration to the completion of mining

Jan 1, 1991

By L Olivier, R J. Lowther, J L. Lett, I Brunton

Hydraulic fracturing to precondition the orebody to enhance rock mass cavability is gaining acceptance in underground cave mining applications. Assisting cavability is becoming important as an increasing number of cave mines are being implemented in hard, deep and competent rock masses where clamping stresses are higher and cave column heights may be in excess of 1000 m. Propagating large caves to surface in such conditions can be challenging as risks such as slowed propagation and air gaps can develop during the process.Underground-based hydraulic fracturing is routinely used at Cadia East as a means of preconditioning the orebody to assist in cave propagation, fragmentation and seismicity reduction. This paper presents a summary of a surface-based hydraulic fracture program that was successfully implemented to assist in the propagation of the Cadia East Panel Cave 1 (CE-PC1) cave to surface through competent overlying rock masses. In this case study, the propagation of the CE-PC1 cave slowed as the cave grew past 750 m in height, initiating a Trigger Action Response Plan regarding the cave propagation rate. Surface-based hydraulic fracturing was subsequently used to stimulate the cave to propagate through the final 450 m to surface. The paper details the equipment, strategy, implementation and risk management involved in the program as well as the key learnings.CITATION:Lowther, R J, Olivier, L, Lett, J L and Brunton, I, 2016. Implementation of a surface-based hydraulic fracturing program to successfully propagate a large cave through hard, competent near-surface rock masses to achieve breakthrough, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 83–96 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By Gordon M. Matheson, Douglas A. Anderson, David K. Miller

"Traditionally, analysis of vibrations from blasting has been focused on peak particle velocity fordetermining the likelihood of both annoyance and damage. The US Bureau of Mines, in RI 8507,indicated the importance of frequency in vibration. Methods of controlling the vibration by reducingthe vibration concentrated in certain frequency bands using delays have been successful over the past decade."

Jan 1, 1997

By Glenn Norris, Tyler Buckingham

"Gold recovery gains in the order of one to two percent have been realized in 2009 due to changes in the operation of the grinding circuits at Barrick Gold Corporation’s Hemlo - Williams Mill. The initiative known as “split milling” involves milling low grade open pit ore in one grinding circuit and higher grade underground ore in the other grinding circuit under different conditions.The philosophy of split milling involves processing higher grade underground ore at a lower throughput rate and a finer grind while milling lower grade open pit ore at a higher throughput rate and a coarser grind. Bench scale tests showed that the recovery relationship for underground ore sources was much more grind sensitive than that of open pit ore. This relationship proved to hold in the plant. The gold recovery gain due to finer grinding of the higher grade ore is much greater than the recovery loss due to coarser grinding on the lower grade ore. Since the majority of gold is being recovered at a higher rate, this results in higher overall plant gold recovery when compared to the traditional operation philosophy of blending the ore sources.The challenges for achieving the maximum benefits of split milling were two fold; the need to increase throughput on the open pit ore milling circuit and a means of grinding finer on the underground circuit. The former was met with an increase in SAG (Semi-Autogenous Grinding) mill ball charge, a basic “drill to mill” blasting campaign and changes to the primary gyratory crusher. The latter was met with a reduced SAG mill ball charge and a higher milling density. The resulting benefits in additional gold recovered are in the order of $3-5 million per annum.INTRODUCTIONThe Williams Mill processes ore from three different ore sources, the David Bell Mine (DB), the Williams Underground Mine (WUG) and the Williams Open Pit (OP). All three ore sources are located within the Hemlo camp in Northwestern Ontario adjacent to the Trans-Canada Highway. The Williams Mill was built in the mid 1980’s at which time it was designed to process 3,000 dry metric tonnes per day through a 22’ SAG mill in series with a 16’ ball mill. In 1988 a Mill expansion doubled the mill capacity by adding a second identical grinding circuit. A photo of the current grinding circuit can be seen in Figure 1. Today the Williams Mill processes an average of 8,000 tonnes per day of which approximately 60% is from the Williams Open Pit."

Jan 1, 2010

Copper, zinc, lead, and silver in the discordant magmatic-hydrothermal orebody of the Conrad Mine, N.S.W., all have a relatively high mean abundance. Any single concordant sulphide orebody containing the same metals has a similar order of mean abundance of only one or two of these, particularly copper, copper and zinc, or zinc and lead.The relative abundances of the metals in the Conrad orebody vary more widely than in concordant orebodies, and the lead-zinc-silver and copper-zinc-lead relationships are significantly different.INTRODUCTIONIn previous investigations of metal abundances in sulphide ores, the basis of selection of the orebodies was their form, and to some extent their geological setting, rather than hypotheses concerning their origin. In all cases they were generally concordant with the bedding of the sedimentary or meta-sedimentary rocks enclosing them, and most occurred in volcanic-sedimentary sequences. Their mineralogies were simple, and they were copper, copper-zinc, zinc or lead-zinc rich in composition. Most were of the type ascribed by several authors to exhalative-sedimentary processes.In one of these investigations (Stanton, 1958), it was pointed out that since the metals in ores of this type showed similar abundance patterns and behaviour, it would clearly be of interest to examine, and to compare with them, orthomagmatic and vein types, unquestionably derived from their igneous rock associates.The present investigation is concerned with a single orebody, of clearly discordant type, and of indisputable hydrothermal origin. The abundance and behaviour of copper, zinc, lead, and silver have been determined and compared to similar data fOl!' the concordant type. Such a comparison tests the possibility that metal abundance patterns of base metal ores may be indicative of the mode of ore deposition.

Jan 1, 1963

In the minerals industry allocating capital for setting up a new project or for upgrading an existing facility usually requires that a compromise be found between the initial cost of equipment, its operating performance and on-going operating costs. To maximise the return on the investment usually requires that various possible combinations and layouts of equipment be assessed. This task is both difficult and time consuming. Computer simulation can be used as a means of determining the expected operating performance of a range of alternate equipment configurations. Simulation is a particularly important technique for analysis as it is one of the few approaches that allows the analyst to take into account the variability inherent in a mining process. While computer simulation is a well established technique its use, until recent years, has been limited to large organisations with access to substantial computing facilities. However, with the current availability of low cost computing platforms combined with easily understood animated displays, simulation is now becoming more widely used across the industry.

Jan 1, 1990

By M. C. Bhulose

Paper written on project work carried out in partial fulfilment of B. Eng (Mining Engineering) degree The purpose of this project was to identify constraints that could occur in the current sub-decline shaft at Turffontein Shaft should an increase in production take place. Particular attention was to be paid to the transportation of men and materials and to the broken rock and ventilation capacity of the shaft. This project is an in-depth evaluation of the logistic capacity of the sub-decline system at Turffontein Shaft in order to determine by how much production can be increased in this area to replace tonnages from the vertical shaft area, where ore reserves are rapidly becoming depleted.

Jan 1, 2004

By D Craw, C E. Martin, C Smith, C Rufaut

Wangaloa Coal Mine opened in 1945, and by the time of its closure in 1989, had produced 750 000 tonnes of coal and disturbed an area of 75 ha. The original mining licence required land rehabilitation to exotic forestry, however the current owner, Solid Energy, has worked with Crown Minerals and local councils to write a new rehabilitation objective. The site is now being stabilised and replanted with native species, and may be available for public use before the coal mining licence expires in 2007. Site discharge permits expire in 2017, and by that time, it is anticipated that discharge water chemistry will be similar to background levels. MWH are currently contracted for management of the mine rehabilitation project. The Kaitangata coal unit mined at Wangaloa is sulfurous lignite with associated pyrite. Kaitangata coal contains 3.2 wt per cent sulfur, which is higher than most New Zealand coals. Initial analyses at Wangaloa indicate low pH (2.56.2) values in soil, groundwater and surface waters as a result of acid rock drainage (ARD) processes, leading to increased metal mobility and challenging conditions for vegetation. Pilot studies indicate pinus radiata needles contain up to 67 mg/kg boron, and elevated As, Cu and Zn concentrations in surface waters. The main lake at the site has a pH of approximately 4.9, despite lime dosage in 2002. There is a real need for a complete geochemical model of the Wangaloa coal mine. Such a model could be applied to similar restoration projects, and would assist by pinpointing geochemical processes and toxic metal relationships most harmful to the receiving environments. Using this model, rehabilitation in the future will be targeted and more efficient. This project is part of a larger scheme to characterise and model the Wangaloa mine site restoration, including waters, soil, vegetation, geology and invertebrates.

Jan 1, 2003

By G. Onal, E. Gock, H. Dincer

"During the conventional chromite dissolution process; chromite ore concentrates were ground to at least <90 µm using the ball mill and after adding Na2CO3 and leaning material (instead of CaCO3 also residues from the leaching process) at a ratio of e.g. 1:0.75:1.2, depending on the specific formulation, follows the digestion e.g. in a rotary kiln, heated in countercurrent. The reaction time is 3 to 8 h. The calcine is comminuted and leached with water or a thin chromate solution. Depending on the type of ore used, the yield is 75-85 %. The disadvantage of the above-described process is that it is impossible, using current technology, to achieve a complete digestion of the chromite ores and that the chromium-containing residues have to be disposed of as special waste, involving a large financial effort.The subject of this study was the investigation of the effect of vibratory milling on chromite dissolution. The impact stress in the vibratory mill causes the mechanical activation of chromite, which is characterised by lattice defects. The degree of mechanical activation can be quantified by measuring the relative X-ray diffraction intensities at the parent lattice planes of chromite. Each relative X-ray diffraction ratio correlates with a certain degree of digestion. As opposed to vibratory milling, a complete digestion of chromite using a ball mill is impossible, even at extremely long grinding times.In this investigation a chromite concentrate from Pulpinar/Kayseri with content of 44 % Cr2O3 and the Eccentric Vibratory Mill was used. In order to verify the effect of the vibrating grinding on chromite dissolution, reaction kinetic investigations on digestion and leaching were carried out."

Jan 1, 2003

By Steve Kral

The mining industry has had three difficult years. Commodity prices have remained low and investor confidence in the industry has been shaken. And even though the Asian economy appears to be improving, it will be some time before this improvement will translate into better commodity price conditions for mining. In addition, increased environmental and social restrictions that have been placed on the industry in developed and developing countries have made mining a more difficult proposition. And, if that is not enough, the global mining industry has found itself in fierce competition with Internet businesses for investor capital. Despite that gloomy picture, more than 10,500 mining industry professionals from about 70 countries gathered in Toronto, Ontario March 5-10, 2000 for the Mining Millennium 2000 conference. This meeting was a joint effort between the Canadian Institute of Mining, Metallurgy and Petroleum(CIM) and the Prospectors and Developers Association of Canada (PDAC).The joint meeting also featured two trade exhibitions and more than 150speakers. PDAC’s trade show attracted about 400 exhibitors and an additional 200 in the concurrent Investors’ Exchange. CIM’s exhibition attracted about 600 equipment and service companies.

Jan 1, 2000