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By H. R. Shell, John L. Miller, M. V. Denny

In the mica research program conducted by the Bureau of Mines at Norris , Tenn . , many micas other than silicon fluorphlogopite have been synthesized . It has been well established since the initiation of the program that synthetic micas are important materials useful for their superior or unique properties as well as substitutes for natural micas . The possibility of controlling the physical properties of synthetic mica by isomorphic substitution of other ions in the fluorphlogopite lattice further emphasizes the importance of these materials . Accurate measurement and reporting of their properties constitute an essential part of the research program . The study of germanium fluorphlogopite is in keeping with the requirements of a comprehensive study on isomorphic substitution , specifically to identify precisely the material -- chemically , structurally , and optically . The X- ray measurements , including indexed powder and single crystal data , with a description of the methods used to obtain these data , are provided . 5 Earlier work on germanium mica by R. A. Hatch et al . (5) gave an estimate of the cell parameters from X - ray powder data , but no attempt was made to index the diffraction pattern or to determine the space group symmetry . Later work by E. A. Schatz and J. C. Withers (9) listed X- ray and optical measurements , but no attempt was made to index the mica or determine its symmetry . Roth (7) found that germanium dioxide having the a - quartz structure , when heated with equimolar percentages of MgO , CaO , Sr0 , or Ba0 at 1,235 ° C , formed ABO3 -type compounds , e.g. MgGe03 isostructural with enstatite (MgSiO3 ) . Geo₂ also has a rutile - type polymorph with Ge ++ ions in octahedral coordination . Germanium was substituted for silicon in the serpentine structure by Roy and Roy (8 ) using hydrothermal techniques . These authors wrote as follows : "The substitution of Ge + for Si + yielded a magnesia - germania serpentine , formed easily in euhedral hexagonal plates which in some instances were visible in the light microscope . Electron micrographs and the sharp X - ray diffraction patterns confirm a plate - like rather than tubular habit . " It has been shown in this investigation that substitution of germanium for silicon in the mica structure is readily accomplished without radically changing the characteristics of the mica . Substitutions in the mica structure take place in three locations : Tetrahedral , octahedral , and interlayer positions . The tetrahedral positions are normally occupied by Sit or by a combination of Sit with Al +3 the most common combination being 2A1 +3 and 6Si +4 · , The octahedral position , which has six - fold coordination in phlogopite , contains a larger cation such as magnesium . In muscovite it contains only 2A1 ions ; therefore , this mica is considered a dioctahedral mica , whereas phlogopite is considered trioctahedral . +3 The interlayer position has twelve - fold coordination with six oxygen ions from each of two adjacent tetrahedral silica layers . This is the cleavage plane of the mica and commonly contains the largest cation in the mica structure (e.g. potassium) .

Jan 1, 1964

By Charles C. Myers, Robert M. Doerr

The apparatus described was developed for determining the kinetics of gas - solid reactions at high temperatures by measuring the volume of gas consumed with respect to time . This apparatus consists essentially of a horizontal precision- bore glass tube connecting a small reaction chamber in a furnace to a large constant - temperature reservoir . A drop of mercury in the tube separates the two sides of the system and serves as an indicator that moves at a speed proportional to the rate of gas consumption . The sensitivity of the apparatus depends inversely on both the density of the gas in the system and the cross - sectional area of the tube ; with a tube having an area of 0.079 cm² , the sensitivity for oxygen at 308 ° K and 0.5 atm is 20 cm/mg . The reproducibility of data with the volumetric apparatus is good .

Jan 1, 1964

By M. H. Kersten, G. A. Brady, Jerry W. Ramsey

Anthracite samples were oxidized with nitric acid to prepare products representing intermediate stages of oxidation . Similar oxidizing conditions affected different anthracites to varying degrees as characterized by peptization behavior with 0.1 N NaOH . Techniques used in attempts to separate and characterize the products included esterification , absorption spectrophotometry , sublimation , chromatography , electrophoresis , metal salt formation , and solvent extraction . Mellitic acid , either free or in the form of metallic salts , was identified in the acid- soluble products from 10 tests in which the anthracite was treated with nitric acid for periods varying from 24 to 1,000 hours . pentacarboxylic acid was also found in some products . Other benzene carboxylic acids were not present in amounts detectable by the methods used in this study . The acid- insoluble residue from nitric acid treatment varied significantly in solubility behavior toward different classes of solvents . The most effective ones tried included polar oxygenated solvents and pyridine . Infrared spectra of the extracted material indicated that similar compounds were extracted by the different solvents . Aliphatic amines and aniline peptized the residue and o- toluidine reacted with it . Organic material separated from the residue by peptization with dimethylformamide contained 1 percent ash , consisting of more than 50 percent zirconium .

Jan 1, 1964

By W. H. Ode, W. A. Selvig

Briefly, this swelling test consists in heating 1 gram of pulverized coal in a silica crucible over a gas flame under prescribed conditions to form a coke button which is compared in size and shape with a series of standard profiles numbered 1 to 9. These profiles are intended to cover the size and shape of buttons obtained from coals covering a wide range in plastic properties. The number of the standard profile with which the maximum cross-sectional area of the button most nearly corresponds is recorded as the swelling index. Although the swelling test showed poor relationships with the various tests that were used for measuring expansion or contraction of coal during carbonization, it gave indications of having value in measuring free-swelling and coking properties of coals when burned on fuel tests. An opportunity to investigate this occurred when an engineering company reported pronounced differences in burning characteristics on grates of various shipments of Pocahontas coal. Some of these coals gave trouble by swelling excessively and clogging the grate. Samples were obtained, and it was found that the troublesome coals gave radically higher free-swelling numbers than did the coals that performed satisfactorily. Also, it was found that the free-swelling index test gave better differentiation between coals than could be obtained from the coke buttons from the standard volatile-matter test or iron agglutination-value results. The results of the free-swelling test were confirmed by the Subcommittee on Plasticity and Swelling, Coal, a special group of the Subcommittee, under the chairmanship of R.A. Shuman, worked along with the test method. Estberg, Limacher, and Shuman of the Battelle Memorial Institute investigated the various factors affecting the test and found that the swelling index was a good indication of the suitability of coal for performance on residential-type stokers from the swelling characteristics of the coal. Data were presented that also showed that the index was helpful in the selection of coal for industrial underfeed stokers.

Feb 1, 1948

By M. Vanpée, H. G. Wolfhard

Jets of hot gases issuing into explosive gaseous mixtures are efficient agents of ignition . The ignition temperature is defined as the temperature of the jet as it enters the cold explosive mixture which is just high enough to produce ignition . Such data have been published recently.5/ The investigators note especially that no correlation seems to exist between hot - gas ignition temperatures and spontaneous ignition temperatures , although there is a rather loose relation with limit flame temperatures . Before a more quantitative theory of the hot - gas ignition process can be attempted effectively , several questions must be answered : ( 1 ) Can the reactions leading to ignition be described by an Arrhenius type activation energy? ( 2 ) Is ignition preceded by an induction period ? ( 3 ) What is the rate - determining process of the ignition ? (4) And how does turbulence affect this type of ignition ?

Jul 1, 1960

By Gilbert Chuah, Peter Middendorp, Joost Bakker, Soon-Hoe Chew

"The Rapid Load Testing (RLT) of foundation piles has been applied worldwide since 1984. Several International and national codes are available, such as the Japanese Code of Practice (2002), ASTM D7383-2010, German recommendation on Piling (2012) and Eurocode (2015). RLT methods like Statnamic and StatRapid are gaining popularity in Asia, Europe and North America. For checking the performance of piles, they are more economical, faster and environmentally friendly than Static Load Testing (SLT), while yielding good correlations with SLT results through an objective analysis method. To date (October 2016) hundreds of piles have been successfully tested by RLT method in Singapore. A number of these RLT tests were coupled with static load testing correlation tests, some of them with instrumentation for shaft load transferred. Examples of some correlation results for foundations installed in various geological formations in Singapore are presented in the paper. The findings from these results indicate that loading rate effects are negligible for Rapid Load Test results when foundations are socketed in competent non-cohesive soil layers and derive most of their capacity from these soil layers.INTRODUCTIONRapid Load Testing (RLT), by which a quasi-static load is applied to a foundation pile, is used increasingly as an alternative to Static Load Testing (SLT) for cast in-situ piles, such as drilled shafts or bored piles. It is recognized nowadays that the determination of the pile capacity with Dynamic Load Testing (DLT) through signal matching techniques such as CAPWAP, TNOWAVE and AllWave-DLT, yield a wide spread of results for cast in-situ piles (Stahlmann et. al, 2012), making it practically very difficult, if not impossible to calibrate the DLT results with SLT results. This spread is due to the empirical and subjective assumptions that are used to interpret the test data, especially for cast insitu piles (Holeyman et al. 2001, Viana da Fonseca in 2008, Herten et al, 2013). This is further complicated by the inhomogeneity of the concrete and variable cross-sections over the pile length for the cast in-situ piles."

Jan 1, 1900

By Jan Luca Grunow, Ansgar Bendiek, Klaus Böde

According to the Markowitz portfolio theory the value of a diversified portfolio is higher than the sum of the parts of a portfolio, which is an important consideration for the correct valuation. This is valid for real estate portfolios as well as for mining assets (or enterprises). This paper analyses the application of the portfolio theory to a diversified portfolio of assets in the real estate industry and draws conclusions on further research work to be done in the minerals industry. The volume of real estate transactions is increasing over recent years. As such, the nature of those transactions is constantly changing and in some cases portfolios become more heterogeneous as they are composed of different property categories, e.g. locations and types of use. This makes their economic evaluation more difficult. This paper focuses on the acquisition of a fairly heterogeneous real estate property portfolio purchased by “Commerz Real” in Germany in Q4 2019. For economic evaluation the widely used Markowitz portfolio theory (Markowitz, 1952) was applied. It was investigated whether diversification effects could achieve added value in the form of a reduction in risk compared to the sum of their individual components. As a result the findings of this research could be applied to other heterogeneous real estate transactions and even to mine property portfolio or PPP1 project portfolio transactions.

Jun 25, 2023

By Pancho J. Garza, Keith H. Dahlen, Chris A. Labye

"Design for reconstruction of the East Flagstaff traffic interchange project located in Flagstaff, Arizona posed particular challenges. The proposed design included construction of a nearly 50-foot tall mechanically stabilized earth (MSE) wall given rightof- way constraints and soft subgrade soils. The tight right-of-way, approximately 15 feet in certain locations, adjacent to existing structures limited the number of viable remedial alternatives to provide grade separation at the proposed bridge abutment without significant settlement. Preliminary analyses indicated the existing subgrade soils - consisting primarily of relatively soft silts and clays with decomposed pumice - would settle approximately 12 to 14 inches resulting in unacceptable wall deformation. Stone columns placed via vibratory methods (vibro-replacement) consisting of circular excavations which penetrate to firm bearing soils and which are filled with crushed stone were selected to densify the existing subgrade soils. The implemented mitigation measures helped limit settlement to less than one inch and allow for successful construction of the project. The project history - including site constraints, subsurface conditions, evaluation of remedial alternatives, stone columns methodology, and effectiveness of ground improvements - will be discussed.IntroductionThis paper describes the subsurface investigation performed for the reconstruction of the Business Route 40 (B-40) (Country Club Drive) and United States (US) 89 Traffic Interchange (TI) located within the city limits of Flagstaff, Arizona. This project is currently referred to as the East Flagstaff TI. The Project Site Vicinity Map is shown below.The former B-40/US 89 TI was considered ineffective in handling the current and projected volumes of traffic which transition from northbound (NB) B-40 to US 89 (both directions), as well as from southbound (SB) US 89 to SB B-40. The intent of the project was to reconstruct the TI to better accommodate projected traffic volumes. The project eliminated the existing ramps from both NB B-40 to SB and NB US 89. The new interchange includes a Tee intersection from B-40 to US 89. In order to accommodate this alignment, the profile of US 89 was raised several feet (on nearly the same as existing horizontal alignment) to match the elevated profile of B-40. B-40 was shifted just west of its current alignment to accommodate construction of a new, wider bridge structure which spans over Industrial Drive, the Burlington Northern Santa Fe (BNSF) railway, and old Route 66. South of the new bridge, B-40 transitioned back to the existing alignment just north of the I-40/B-40 TI. Within the project limits, both US 89 and B-40 were widened to three travel lanes in each direction."

Jan 1, 2015

By Gerald Verbeek, Erick Baziw

Dynamic soil analysis (DSA) in geotechnical practice is intimately related to the capability of measuring the necessary soil properties of shear modulus and absorption. In DSA the methods of analysis are based upon the stress-deformation response of soils due to imposed shear strains. Typically the soil profile is numerically modeled as linear visco-elastic system. This technique is referred to as the Equivalent Linear (EL) method, and it requires the specification of the input parameters of low-strain (<10-5) shear modulus, modulus reduction, and the equivalent viscous damping ratio, which is directly related to the soil absorption value. Downhole seismic testing (DST) has proven to be a very accurate tool for estimating low strain shear modulus values as long as source wave raypaths are taken into account, especially for near-surface investigations. DST has also been utilized to estimate low-strain interval absorption values. In these cases standard frequency domain absorption estimation algorithms (such as the spectral ratio technique) are utilized where it is assumed that the source waves are traveling along the same travel path, which is obviously not the case for near surface DST investigations. This paper outlines a unique DST absorption estimation methodology, which is carried out in the time domain and takes into account source wave travel paths. 1. INTRODUCTION There is considerable interest in methods of geotechnical in-situ engineering that provide accurate estimates of the shear wave velocity and the associated absorption values in the ground, since these parameters form the core of mathematical theorems to describe the elasticity/plasticity of soils and they are used to predict the soil response (settlement, liquefaction or failure) to imposed loads (whether from foundations, heavy equipment, earthquakes or explosions).

Jan 1, 2019

By Steven R. Ahlfield, Ali Ghandeharioon

A wastewater treatment plant commissioned in 1978 is undergoing a major expansion. Planning various phases of the 8-hectare expansion at this site requires an understanding of the site response during and after construction, and the potential impact on adjacent properties and infrastructure. The expansion project requires nominally 5 m of site grading fill for flood protection. The site is underlain by loose to compact fine sand over firm to very stiff clay stratum that extends to great depths. Ground improvement is required to mitigate the liquefaction hazard in the fine sand stratum, and preloading is proposed to reduce post- construction settlements in the deep clay. Site development and foundation systems for the plant expansion project were evaluated by conducting settlement analyses which accounted for the historic and future site loading and 3-D modeling of soil layers with interpolation between borehole and cone penetration test (CPT) locations. The numerical model was calibrated to match short-term and long-term settlements measured at the plant site. The analyses were carried out to assess the effects of past loading, proposed preload and surcharge heights, lateral extents and durations as well as vibro-replacement ground improvement on post-construction settlements. Two design options were considered for the preload footprint across the site and foundation system for proposed facilities. It is shown that limiting the preload extent and founding some of the proposed structures on deep friction piles reduce the predicted settlements of adjacent infrastructure and result in reasonable performance for the proposed facilities. INTRODUCTION A wastewater treatment plant commissioned in 1978 will be replaced with a new plant on an undeveloped portion of the site to provide wastewater treatment for an expanded service area. The existing facilities must remain in operation until completion of the new plant. The site grade will be raised nominally 5 m for flood protection. The large areal extent of the site grading fill and plant structures will cause stress changes extending to great depths in the underlying soils and result in settlement of the existing and new structures. Historic settlement of the existing facilities has been tolerable for plant operations, but no settlement performance data was recorded during site development and post-construction from 1978 to 2007. Development of the 8-hectare expansion at this site is planned in three phases to reduce the overall construction schedule. Planning for each phase requires evaluating the effects of various site development activities from start to completion of expansion and during the design life (i.e. post-construction period), and the potential impact on existing wastewater treatment facilities and adjacent properties and infrastructure including an adjacent viaduct structure. Figure 1 presents the site plan and three distinct site development phases considered for the plant expansion.

Jan 1, 2019

By John J. Sammarco

Light-emitting diodes (LEDs) are emerging as viable replacements for incandescent (INC)-based cap lamps used in mining. The photometric and energy characteristics of these light sources differ in important ways. This paper describes the performance of LED and INC sources in cap lamps in terms of correlated color temperature, color rendering, light output, electric power, ambient temperature and air flow, and light source aging. Importantly, these characteristics can influence a miner?s ability to spot mining hazards thus impacting safety. Second, some of these characteristics interact with the operating life of the cap lamp?s battery power, such that differences between LED and INC sources can be magnified toward the end of a 10-h battery discharge cycle. Empirically, we have determined that after 8 h at an ambient temperature of 25 ?C, the average light output of an INC cap lamp can decrease to about 69% of its initial value when powered by a lead-acid battery, and it can decrease to about 65% of its initial value when powered by a nickel-hydride battery. An LED-based cap lamp using a constant current drive circuit can maintain about 96% of its initial value when powered by a nickel-hydride battery. Real-world tests addressing the effects of ambient temperature and air flow on the light output of an LED and INC cap lamp were conducted in the National Institute for Occupational Safety and Health Safety Research Coal Mine. The LED cap lamp yielded a vertical average illuminance improve­ment of approximately 9.5%, and the INC cap lamp yielded a vertical average illuminance degradation of approximately 4%. The differences between LED and INC cap lamps were further quantified by the calculation of ?mesopic luminance? data that indicated for the same photopic luminance (i.e., as measured using a conventional light meter) the LED cap lamp could be up to 38% more efficient than the INC cap lamp with a lead-acid battery at the end of the 10-h driving cycle. Lastly, accelerated life tests were used to empirically determine light output depreciation as the INC light source age approached its useful life. There was about a 35% decrease in light output. This is quite considerable, particularly given that the light output will decrease an additional 30% to 45% over the period of a 10-h shift. The implications of the differences between LED and INC sources are discussed. This information is crucial in determining how visual performance could be affected for real-world conditions where batteries discharge during the work shift and as the light source ages. To date, only idealized conditions have been used for LED and INC cap lamp visual performance research.

Jan 1, 2009

By T. Wajima

Recovery of precious metals from hydrochloric solution using sulfur-impregnated carbonaceous adsorbent was examined. Sulfur-impregnated adsorbent with adsorption abilities of precious metals can be prepared from activated carbon using pyrolysis at 600 oC under 10 % H2S gas flow, and the adsorbed Au and Pd were precipitated as metal phase on the surface of the adsorbent. The adsorbents after precious metals adsorption were burned at 700 oC to obtain the residue mainly containing precious metals. The adsorbent was found to be highly efficient and selective for the uptake of precious metals, especially Au, in the presence of excess base metal ions from simulated spent automotive catalyst eluted solution using a column pack test. Keywords: Gold, platinum, palladium, reduction precipitation

Jan 1, 2020

By J. D. T. Steyl, G. B. Grobbelaar

Two examples are presented to show how first-principles – physical-dynamic, here termed behavioural modelling, is used to build digital twins of unit processes or plant sections. A digital twin equips the metallurgist, engineer, or manager with a powerful tool to conduct model-based design, solve process problems and improve operations. It is particularly relevant in the metallurgical industry where plant behaviour is highly integrated, rates respond to particle dynamics in complicated ways and mineral flows across flowsheet boundaries are variable. The two examples used to illustrate the behavioural modelling methodology are 1) a flotation column unit block and 2) a multi-compartment pressure oxidation (POX) autoclave. It simultaneously accounts for the causality of material and heat flow, takes care of mineral particle dynamics, physical and chemical reaction rates, the plant control system behaviour and operating heuristics. The basic modelling building blocks are briefly reviewed to show how the behavioural modelling attributes constrain the mass and heat flow dynamics to physically realistic values. This is the key aspect that allows project value to be created with minimal input data. Behavioural modelling is especially valuable where the process dynamics are poorly understood or controlled, where data-driven models fail to cope with complex and highly integrated plant behaviour, where quality data is lacking or limited funds are available to generate the data required to fill all the knowledge gaps. The paper uses the flotation column example to show how behavioural modelling and simulation can be used to optimise plant performance, while the multi-compartment POX autoclave model shows how it can be used to diagnose process problems. It also provides a solid basis to add a data-driven component – in other words, it makes a strong case for a hybrid first-principle– data-driven approach to solve process problems, especially where microscopic-level understanding is poor. Keywords: Digital twin, behavioural modelling, simulation, flotation column, pressure oxidation

Jan 1, 2020

By D. F. Caicedo, I. A. Brum, L. A. Betancourt

Ferricyanide ()()*is one of the most stable cyanometallic complexes present in the gold mining effluents. This cyanocomplex is hard to degrade by natural attenuation and generates a negative impact on aquatic environments. Although free cyanide (CN-) can be obtained by acidifying the solution, the CN- is lethal for all forms of life. The oxidation of ()()* in a typical photocatalitic system was evaluated with the addition of H2O2. To verify the degradation, chemical parameters, such as free cyanide, the formation of ammonia, nitrate, and total iron were analysed at the end of the process. The degradations obtained were up to 70% in a heterogeneous photocatalysis system with TiO2, and a low rate of dissociation was observed by photolysis. The best result was achieved with the H2O2 and TiO2 photocatalytic system, and the stoichiometric concentration was about 2.5 times less than the peroxide used in the real gold mining industry, reaching 83% degradation. The photocatalytic process obtained less toxic byproducts than the original synthetic ferricyanide used as mining wastewater. Keywords: Cyanide, heterogeneous photocatalysis, titanium dioxide, UV radiation, gold wastewater

Jan 1, 2020

By B. k. Kenzhaliyev, M. A. Naimanbayev, Zh. A. Baltabekova, N. G. Lokhova

In research various desorbents were used to desorb the following rare-earth metals from Purosorb 140 cation exchanger, i.e. ammonium chloride; ammonium sulfate; a mixture of nitric acid and ammonium nitrate; a mixture of hydrochloric acid and ammonium chloride; a mixture of sulfuric acid and ammonium sulfate. It was established that a solution containing 30 g/dm3 of H2SO4 + 300 g/dm3 of (NH4) 2SO4 is the most optimal desorbing solution to desorb REMs from macroporous Purosorb 140 cation exchanger impregnated with rare-earth metals from industrial dihydrate wet-process phosphoric acid. It was established that the residual REM content in the cation exchanger decreased from 0.89 to 0.10 wt. % with an increase in the ammonium sulfate concentration from 10 to 400 g/dm3. Technological desorption regimes for rare-earth metals from cation exchanger were developed. The optimal conditions were determined to desorb rare-earth metals from the Purosorb 140 cation exchanger, particularly temperature 25°C; L:S ratio = (0.8 ÷ 1.1):1; duration = 1.0-1.5 hours. Keywords: Rare elements, sorption, cation exchangers, wet-process phosphoric acid, desorption

Jan 1, 2020

By L. Rojas Mendoza, F. J. Hrach, A. Gupta, K. P. Flynn

ST Equipment & Technology (STET)’s tribo-electrostatic belt separator technology allows for the beneficiation of fine mineral powders by means of an entirely water-free technology with high throughput and low energy consumption. The STET separator is suited for separation of very fine (<1 μm) to moderately coarse (500 μm) particles, in contrast to other electrostatic processes that are typically limited to particles >75 μm in size. STET has performed exploratory studies with several iron ores including tailings and experimental results to date have demonstrated that low-grade iron fines can be upgraded by means of STET tribo-electrostatic separator to commercial grades (58-65%Fe). Experimental results together with high-level economic evaluations indicate that scavenging processes involving low drying costs, DSO operations and tailings beneficiation offer a commercially viable processing method to recover fine iron that would otherwise be lost by traditional processing. Dry electrostatic processing of iron ore presents a clean, low-energy opportunity for iron producers to reduce costs and wet tailings generation associated with traditional gravimetric, flotation and wet magnetic separation circuits. Moreover, STET technology allows for mining waste utilisation and resource recovery from iron ore fines and tailings, therefore offering processors a novel method to recover fines that would otherwise be difficult to process to sellable grades with existing technologies. Keywords: Iron fines, industrial minerals, dry separation, calcium carbonate, talc, barite, quartz, tribo-electrostatic charging, belt separator, fly ash

Jan 1, 2020

By G. Akdogan, C. Dorfling, L. Bumhira

Hydrometallurgical recovery of rare earth elements from phosphors obtained from end-of-life fluorescent lamps involve leaching followed by extraction of dissolved metals from solution. The similar properties of rare earth elements make selective recovery of individual elements challenging. The aim of the paper was to investigate the extraction of primarily Ce and Tb from a hydrochloric acid leach solution also containing other REEs (Y and Eu) as well as impurity metals (Ca and Al). Batch solvent extraction tests were performed with di-(2-ethylhexyl) phosphoric acid (DEHPA) at various extractant concentrations, pH conditions and organic-to-aqueous ratios. Extraction isotherms and separation factors for the range of conditions tested in the project are presented in the paper. Separation of individual REEs was not possible at the conditions investigated, but a mixed REE product can be obtained in a single extraction stage operated at a pH of 0.5 using 1 M extractant at an O/A ratio of 1; these conditions resulted in complete Y and Eu, 95 % Ce and 99 % Tb extraction with Ca and Al coextraction below 7 %. A better quality mixed REE product can be produced by operating at lower pH and extractant concentration conditions, but this would require a larger number of extraction stages. Keywords: Cerium, fluorescent lamps, phosphors, rare earth elements, solvent extraction, terbium

Jan 1, 2020

By Milka Madahana, John Ekoru

Particulate matter is one of the leading pollutants in the mines and in the communities in the areas near or surrounding the mines. The availability of large Clinical and environmental data sets obtained from the mines has brought about the need to use better approaches to analyze the collected data. Prediction and control of particulate matter concentration in the mining environment is essential in minimizing air pollution and protecting the respiratory health of mine workers. The main objective of this research work is to analyze datasets obtained from a mining area using machine learning techniques which will then be followed by the real-time estimation of dust particulate in the mines. Datasets collected over 8 years in an hourly sampling rate from an open cast mine is cleaned and analyzed for trends and patterns. Artificial Neural Networks (ANNs), Support Vector Machines and decision trees techniques are applied to analyze and predict the particulate concentrate. The estimation of particulate concentration using Artificial Intelligence will significantly contribute toward the development of quantitative tools to be used in correlating of cause and effect of dust concentration in mines. The results obtained in this work will form a sub-unit of a respiratory health monitoring system for mine workers. The system is essential in the collection, analysis, and tracking of mine workers’ respiratory health, thus it forms part of an early intervention system for mine workers. From the existing theory, we expect the Artificial Neural Network will perform much better than previously used classical models.

Jun 25, 2023

By Josiah Pohl, Christopher Utter, Kyle Everly, Akshay Chowdu

Battery Electric Vehicles offer increased energy efficiency for open-pit load & haul operations at a potentially lower overall carbon cost. Electrifying a mine’s fleet, however, presents a unique set of operational challenges. In this study, we explore the effects of electrification on productivity at real operations using a Discrete Event Simulator. The model can simulate multiple shifts, a mixed fleet of diesel and electric trucks, charging and refueling stations, trolley systems, and accurate shovel-truck loading cycles. This study helps determine the trade-offs of adopting electric fleets and how they interact with the layout of today's mines.

Jun 25, 2023

By Augusto Andres Torres Toledo, João Felipe Coimbra Leite Costa, Luciano Nunes Capponi, Diego Machado Marques

Short-term mine planning to open pit requires defining diglines to orientate the excavation geometry. In deposits with multiple chemical variables, it is necessary to have more rigorous control over the feeding of the processing plant. This study analyzes the impact of incorporating multiple chemical variables, the risks generated by geological uncertainty, and the number and starting point locations of shovels in the sequential design of diglines. The objective is to maintain and preserve the low-grade variability, required tonnage, and continuity in sequentially selecting blocks. To achieve this, the probability distribution function of each chemical variable is used while attempting to maintain the ore grades as constant as possible. As it is difficult to maintain multiple elements with low variability simultaneously, the relevance of each chemical variable in the economic benefit is identified. Weights are assigned to signal the importance of each element based on its significance in the recovery process. Several diglines, consisting of sequential blocks, were generated on the same seed point to meet the weekly ore demand. Optimizing the stationarity of multiple chemical variables, accessing and reducing the geological uncertainty performed through geostatistical simulation of grades and transfers functions, considering the number and location of shovels, while meeting the operational restrictions of the selected blocks. The optimized digline with the multiple grades as stationary as possible is retained. The process is illustrated in a phosphate mine. The results show that the proposed method is viable and allows for a quick solution.

Jun 25, 2023