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By J. B. Littlefield

[At B. meeting of the Subcommi ttce on Chemica.l _ et.lOds of Air Ant:..1ysis of-the American Public Health Ascociation in October 1937, the llse of the impinger for collectinG lcs.d fu.l1e wa:., discussed. The Bureau of \~nes de-cided to obtain infornw.tion on the efficiency of the lerge and midget im-pingers for this purpose y using the electric recipitator as a r?ference ]

Jan 1, 1938

By Fabiola Alvarez, Ana E. Bote, Daniel Pasquevich

"The oxidation of aluminum and its alloys was extensively studied for improving the corrosion resistance in structural materials having high specific strengths. But this reaction involves the formation of a very thin barrier layer on the metallic pieces. Furthermore, the ·recent development of the directed melt oxidation process for producing metal-ceramic; composites has renewed the interest in the study of interaction between gases and metals. Oxidation experiments in the presence of different chlorine partial pressures and at different temperatures were performed in ·a thermogravimetric balance, and microstructures were analyzed by electronic microscopy and X-ray diffraction. The oxy-chlorination kinetics was determined and the oxide formed W(IS amorphous at temperatures below 600 °C and crystalline .at higher temperatures. The appropriate experimental conditions for the fastest completed oxidation was further determined.IntroductionThe use of fine powders for the manufacture of ceramic components has significant advantages. They include excellent sinterability; low sintering temperature and better microstructure leading to improved mechanical properties. The conventional method of producing fine oxide powders involves controlled precipitation and pirolysis of suitable salts. The main limitation of the high temperature decomposition route is the evolution of environmentally unacceptable and corrosive gases. Controlled precipitation of hydroxides from solutions of salts, followed by thermal treatment involves large volumes of solutions and the calcination step that can induce grain growth (1).Direct oxidation of aluminum metal for producing alumina powder requires high temperatures for the direct oxidation of molten Al alloys by a vapor phase oxidant process (2, 3) or high technological process like thermal plasma reactor ( 4).Oxidation of high purity aluminum (5, 6) below the melting temperature· is initially characterized by a nearly linear reaction rate, followed by a rate which decreases rapidly with further weight gain. However, the oxidation rate of an aluminummagnesium alloy is much faster and it does not conform to any common oxidation law, but it is nearly parabolic at temperatures between 200 and 400 °C, an nearly linear· above 400 °C."

Jan 1, 2000

"Energy efficiency in mining and minerals processing has attracted considerable public and industry attention because of the significant quantities of energy consumption involved. In this context the question of what are worthwhile targets for energy efficiency improvements ought to be of the highest priority. It is however worth taking a step back to avoid falling in the trap of taking preconceived ideas that have been reiterated repeatedly before as gospel. The aim of this paper is to highlight areas where new or alternative approaches could potentially be the better way forward. Some may come as a surprise to conventional industry thinking. Ultimately any such solutions are attractive to practitioners not just in an environmental but also in an economic sense, and hence should be targeted through applied research and development efforts. This paper highlights key aspects of each group of opportunities and some of the individual approaches to provide an overview of the current status quo.MINING INDUSTRY POWER UTILISATION – WHERE IS THE BIGGEST BANG FOR THE BUCK?The question of where is the biggest bang for the buck when trying to determine worthwhile targets for energy efficiency improvements has not always been reported on broadly enough, typically because industry practitioners operate in specific areas of expertise and comfort zone. Looking beyond the familiar doesn’t always come easy. Any technology or methodology consideration to address energy efficiency needs to take into account the context of alternative opportunities of superior value or risks not achieving desired uptake. The following sub-chapters have been ordered by magnitude of improvement potential as best as is possible, starting with the biggest first, and the smallest last. Some may be a surprise relative to conventional mining industry thinking."

Jan 1, 2016

By Takahiko Okura

Most non-ferrous raw materials are associated with sulphur. To extract the metals, the sulphur is recovered typically as Sulphuric acid or liquid S02. On the other hand, natural gas may contain over 20% of hydrogen sulphide (H2S) and a huge quantity of elemental sulphur is produced through oil and gas refining processes in the world. A large fraction of the sulphur mined from natural sources is eventually returned to the earth as fertilizers, by-products of desulphurisation and neutralisation processes, or as fugitives to the atmosphere. However, the supply and demand for sulphur are in imbalance. Such situation urges to develop a new smelting process without sulphuric acid production. This paper briefly reviews the global sulphur balance and the technologies for recovering elemental sulphur. The core of this paper is a proposal to convert S02 gas to elemental sulphur by using organic materials. Some results of thermodynamic calculations and experiments are presented.

Jan 1, 2003

By Brad Gunn

Our program has been dictated by the necessity of broadening our markets through converting potash chemicals to fertilizers more in demand than potassium chloride. To this end, we have undertaken studies on methods of preparing potassium sulphate or potassium magnesium sulphate by rather simple conversion. When mixtures of sodium and magnesium sulphates are reacted with potassium chloride, the ratio of sodium to magnesium is quite pertinent. A range of ratios has been selected and the conversions of potassium chloride to sulphate have been assessed by cyclic operations. Results from experimental procedures for producing potassium nitrate are also avail-able. The influence on recovery for systems including organic solvents is assessed for a variety of situations.

Jan 1, 1971

By Langtry E. Lynd

The titanium dioxide pigment industry in the United States has always relied to varying degrees on imported titanium concentrates. Dependence on foreign ilmenite was especially high (generally over 85% of consumption) until 1942, when large-scale U.S. production of ilmenite began, and has since ranged from 12% to 47%. Rutile import reliance was generally in the 45% to 80% range until the early 1960's, when increased use in the chloride pigment process raised dependence on imported rutile to over 90% in most years since 1963. Import reliance of zircon, obtained almost entirely as a byproduct of titanium mineral production, has generally ranged from about 30% to 65% of consumption. This paper will examine the history of U.S. sources of these heavy mineral commodities, and will discuss the potential U.S. future supply in view of changing industrial uses and processes and the anticipated development of new heavy-mineral-sand processing operations, such as those at Richards Bay in the Republic of South Africa and in Sierra Leone.

Jan 1, 1978

By James B. Fletcher

The Miami mine is located near the town of Miami, Gila County, Arizona. The Miami mine started mining in 1910 and finished in July, 1959. The orebody was divided and mined as follows: Tons High Grade 24,400,000 - Top slicing, sub-level caving, etc. Low Grade 105,100,000 - Block caving Mixed ore 9,800,000 - " Low Grade #2 13,100,000 - " Total Mining 152,400,000 GEOLOGY Ore minerals are largely in pre-Cambrian Pinal schist intruded by tertiary Schultz granite porphyry and covered to some extent by Quarternary Gila conglomerate. The structures are highly faulted and shattered. The Miami fault on the east cuts off the ore and the Pinto fault on the southwest caused re-oxidation of enriched sulphides producing mixed ore. MINERALOGY The chief mineral is chalcocite, with chalcopyrite, bornite, covellite, malachite, azurite, chrysocola, cuprite, native copper, and molybdenite as minor minerals. The ore minerals occur in seams, veinlets and disseminated particles. In block caving there is always some dilution, and drawing of ore stops when the grade drops past an economical point. This results in a small amount of copper left in the stopes below the capping. There is some copper in the capping, probably below 0.03% or less than 0.6 lbs. per ton. Over the low grade #2 orebody and portions of the high grade there was an oxide capping which was not mined. The crushed pilars are another source of copper. The leaching at Miami is an attempt to recover this last remaining copper of a worked-out mine. The enrichment at the Miami mine had gone more nearly to completion than most ore bodies in the southwest. There is practically no pyrite in the capping and very little in the ore.

Jan 1, 1971

By J. W. Rogers, S. K. Schwartz

"The Cape Breton Development Corporation (CBDC) is a federal Crown corporation which operates two coal mines (Phalen and Prince Collieries), a coal preparation plant, a railway, a central workshop and a deep water shipping facility.The Sydney coal field consists of 11 major seams, which range from 0.8 m to over 3.7 m in thickness. Of the 2.4 billion tonnes of known coal resources in the field, approximately 550 million tonnes can be mined with present mining technology. These parameters define reserves which extend more than 8 km beneath the ocean to a depth of 1200 m. With today’s design and present high production faces, the colliery life is projected at approximately 20 years."

Jan 1, 1996

By A. A. Terchick

It has been reported in the literature that there is a substantial economic incentive for removing sulfur from coal. Therefore, U. s. Steel initiated an investigation to determine the feasibility of lowering the sulfur content of its Pittsburgh-seam coal. Preliminary crushing and washability studies on a representa-tive sample indicated that substantial sulfur reductions could be attained. Figure 1 shows the effect of the top size of a given coal sample on the sulfur content of the float-l.45 specific-gravity fraction of coal. At a top size of 3 inches, the raw-coal sulfur content of 2.32 percent was reduced to 1.64 percent. Crushing to a top size of 20 mesh reduced the raw-coal sulfur to 1.25 percent. Below a top size of one inch, the sulfur content decreased rapidly as top size was decreased. Figure 2 shows the effect of specific gravity of separation on pyritic sulfur. Normally this coal has an organic-sulfur content of approximately 1 percent. As expected, pyritic sulfur was reduced as the separating gravity was lowered for all the various size fractions shown. The rate of decrease in pyritic sulfur was gradual above 1.45 specific gravity, but great below 1.45. Greater sulfur reductions were attained on the coarser sizes with decreasing

Jan 1, 1971

By J. A. Cremeens, D. D. Overton, J. C. Varnier

"Slope failures that occurred in 2008 and 2009 at the Pikeview Quarry in El Paso County, Colorado, USA were investigated using three-dimensional discrete element modeling methods. Large scale block sliding failures occurred along weak bedding planes that dip steeply into an excavation located at the toe of the slope. Several mining sequences at the toe of the slope were simulated to evaluate the effects of various degrees of extraction and backfill on slope stability. Slope stability back analysis was conducted using pre-failure and post-failure conditions to determine the joint shear strength properties. Laboratory testing was also conducted to determine intact rock properties. Three-dimensional discrete element analysis was uniquely applicable to this evaluation because it allowed representation of shear stress of the basal sliding surface and it afforded evaluation of several scenarios of extraction and backfill at the toe of the slope. INTRODUCTION The Pikeview Quarry is an aggregate quarry located approximately five miles northwest of Colorado Springs in El Paso County, Colorado, USA. The quarry has been operated by several owners since the early 1900s. The Pikeview Quarry has been a major source of construction aggregate for the Colorado Springs area for many years (MSHA 1986). In the 1950s, the site was mined by Peter Kiewit and Sons to provide limestone for the construction of the nearby Air Force Academy. A large scale slope failure occurred on December 2, 2008, which stopped mining activity at the Pikeview Quarry. A second, related slope failure occurred on September 13, 2009. The second slope failure was located immediately adjacent to the initial December 2008 failure. The objective of this publication is to discuss the three-dimensional slope stability evaluation. The causal relationships of slope instability are not within the scope of this publication. However, omitting the precursors to slope failure would limit understanding of the nature of the slope stability evaluation. The regional and local geology and the history of slope instability at the Pikeview Quarry aid in understanding these precursors. Two main failure mechanisms were hypothesized during the failure investigation to explain the triggering of the 2008 and 2009 large slope failures at the Pikeview Quarry. Both mechanisms are given equal credence in this publication. Quarry excavation was a key factor in the slope instability for both failure mechanisms. The objective of the three-dimensional model was to evaluate the effects of extraction and backfill at the toe of the slope with respect to slope stability. GEOLOGY Regional and local geology are both important factors in slope instability at the Pikeview Quarry. Geologic structure at the quarry is related to regional mountain building and basin development associated with the Laramide Orogeny and the Rocky Mountains. Lithologies at the Pikeview Quarry are also related to regional trends. Localized geologic features, primarily related to weathering and erosion, have also been major contributing factors to slope instability at the Pikeview Quarry."

Jan 1, 2017

By R. E. Moore

The lining systems currently in use in BOF furnaces, certain steel ladles, and the slag line of electric are furnaces were developed during the late seventies through the mid-eighties using a trial and error method of combining aggregate, carbon sources, additives and binders. They are currently based on magnesia, graphite, metal additives and resin binders, the selections of each being tied to the anticipated intensity of the use conditions. The general functions of the respective constituents are well appreciated, however, there is still a great deal that is not known about how the socalled antioxidants protect the graphite nor how impurities from the graphite and the aggregate enter into the wear processes. In a simplified assessment of wear processes, it appears that if the deoxidized layer can be kept very thin, less than 810 mm in depth, and if the viscosity and quantity of the matrix glassy phases can be controlled to resist erosion of the deoxidized layer, lining life can be maximized for the various applications. This paper will discuss the characteristics of the starting materials systems currently being employed for applications requiring a deoxidation function to realize extended wear. It will not attempt to explain all the complex interrelationships between the respective constituents but will point to the potential for improvements through the use of improved constituents.

Jan 1, 1991

By Tim Langmaid, Steve Skelhorn, Stephanie Robillard, Allen Mitchell

"The Port Mann Main Water Supply Tunnel project provides a critical water main crossing of the Fraser River for the owner, Greater Vancouver Water District (Metro Vancouver). The project consists of two 60-metre-deep slurry panel shafts and a 1-kilometre-long, 3.5-metre excavated diameter tunnel located near Vancouver, British Columbia, Canada. The initial tunnel lining is a precast concrete steel fiber reinforced gasketed segmental lining. The final lining is a 2.1-metre-diameter welded steel pipe. This paper describes the challenges encountered during tunnel construction and the solutions implemented. Key challenges include earth pressure balance tunnelling at up to 6 bar pressure—the highest to date in Canada—a water-crossing without surface access for the majority of the tunnel drive, ground freezing from a river platform for a critical TBM intervention, and boring through cobbles and boulders in dense glacial till. INTRODUCTION Metro Vancouver supplies drinking water to 18 municipalities, one electoral district and one treaty first nation, serving a population of more than 2.4 million residents. Water is collected in three mountainous watersheds to the north of the Greater Vancouver area, in southwestern British Columbia, Canada. To supply the growing demands of Metro Vancouver’s customers, treated water must be conveyed across two significant water bodies: the Burrard Inlet and the Fraser River. The existing Port Mann water main is one of several key links between the watersheds north of Vancouver and the municipalities south of the Fraser River. The Port Mann Main Water Supply Tunnel (PMMWST) is the first of a series of upgrades, to increase capacity, enhance scour protection, and improve seismic resilience. The new tunnel is 3.5 metres (11.5 ft) in diameter and 1 kilometre (0.6 mi) long. When completed, it will contain a new 2.1 metre (7 ft) diameter steel water main that will help ensure the continued, reliable delivery of drinking water to these municipalities, and will more than double the capacity of the existing 1.2 metre diameter main."

Jan 1, 2016

By Carlos Soldi S

Dado que la industria minera adolece de técnicas para la administración y control de la fuerza laboral, es necesario que se plantee una nueva forma de mejorar el recurso humano en la productividad. En este sentido, el presente texto elabora un programa donde se analiza las pautas para el requerimiento del personal en la industria minera a través de la administración de la fuerza laboral, la determinación de requerimiento de personal, así como se evalúa la aplicación de estos factores mencionados en la unidad de producción de Casapalca, dada la expansión de las operaciones.

Nov 8, 1984

By M N. Mian

The Cayeli volcanogenic massive sulphide deposit is located in Black Sea region of Turkey. Cayeli Bakir Isletmeleri (CBI) was formed as a joint venture between Inmet (Canada) and Eti Holding (Turkey). CBI is processing complex copper/zinc sulphide ores. The Cayeli concentrator was commissioned in 1994, with a design capacity of 600 000 tonnes/year. The grinding circuit was a classical rod mill/ball mill combination. The rod mill was converted to a primary ball mill in May 1997. The reasons for conversion were to use mill power more efficiently and eliminate feed interruptions during rod charging. The grinding circuit now has a primary ball mill in open circuit, and a secondary ball mill in closed circuit with hydrocyclones. Classification was originally done in two stages with hydrocyclones. Both mill discharges were combined and pumped to a primary cyclopack having two, 500 mm diameter cyclones. Primary cyclone overflow was pumped to a secondary cyclopack for further classification. The secondary cyclopack had ten, 200 mm cyclones. Both unit underflows were fed to a secondary ball mill by gravity. The secondary cyclone overflow, typically 62-64 per cent passing 36 ¦m, at around 42 per cent solids (w/w) was fed to flotation circuit. In order to increase circuit capacity to 1 000 000 tonnes/year and to improve control over the grinding circuit, it was decided to convert the classification circuit from two stage to one stage. For this purpose, six Warman Cavex cyclones having 400 mm diameter were installed. Now, the combined primary and secondary ball mill discharge was classified in single stage with the Warman cyclones in closed circuit with the secondary ball mill. The cyclone overflow goes directly to the copper rougher circuit as flotation feed. The grinding circuit is producing a flotation feed of 70 per cent passing 36 ¦m. The change over to single stage classification at Cayeli was successful. A mill throughput of 1 000 000 tonne/year is being achieved with better control over classification, and improved grind size. Results and comparison between the two classification circuits are presented in the paper.

Jan 1, 2003

By A. Quilodran, B. Jakovljevic, T. McCallum, P. Wong

"Rare earth separation by solvent extraction (SX) requires multiple separation plants each consisting of many extract, scrub, and strip stages to separate the individual metals. SX modeling advances have brought benefits to circuit design and process optimization by quickly narrowing test conditions without the need for exhaustive laboratory studies. Modeling can be used to optimize circuit configuration, O/A ratios, and acidities, which allows for CAPEX and OPEX savings. A comparison between pilot plant data and the results expected from modeling is presented for rare earth separations with CYANEX® 572.INTRODUCTIONRare earth separations can be difficult due to limited separation between the elements (Xie, Zhang, Dreisinger, & Doyle, 2014). This requires relatively complex solvent extraction circuits utilizing multiple extract, scrub, and strip stages as well as multiple SX configurations to achieve the desired metal purities. Designing rare earth circuits can be complex, and significant time and testing may be necessary to determine the required staging and optimal conditions.Circuit modeling for rare earth separations has been introduced to the industry using CYANEX® 572 extractant (Soderstrom, McCallum, Jakovljevic, & Quilodran, 2014). CYANEX® 572 is an acidic organophosphorus extractant formulation which has a weaker ligand-metal complex strength than that of the traditionally used phosphonic acid extractants. This allows efficient extraction while requiring a significantly lower acid concentration for stripping (Wang, Li, Zhao, Dong, & Sun, 2015). The reduced acid requirement in strip is expected to provide OPEX savings.The modeling can be utilized to quickly determine the required acidity and organic/aqueous (O/A) ratio for a given separation. It is also expected to reduce CAPEX requirements as optimal staging can be determined, and implemented.CYANEX® 572, combined with modeling, was utilized to produce a purified dysprosium (Dy) stream. To achieve this separation, multiple SX circuits were designed and operational conditions specified to separate Dy from the mixed rare earth chloride feed."

Jan 1, 2016

By Benjamin P. Hay

Complexation of a metal ion to a ligand often results in structural changes that introduce steric strain within the ligand. A design criterior:1 for ligands that will complex metal ions more strongly is to choose Iigar:1d architecture, that minimizes this strain. This paper describes how molecular mechanics models can be used to define the degree of ligand binding site organization in terms of' ,strain energies associated with conformational reorganization and distortion of the binding conformer. This approach yields a method to predict how modifications to ligand structure will affect metal binding affinity.

Jan 1, 1999

By Zhan-fang Cao, Hong Zhong, Li-feng Li, Shuai Wang, Xiao-yu Cao, Guang-yi Liu, Ming-ming Wang

"In recent years, there has been an increasing focus on the hydrometallurgical processing of molybdenite, with the decline of high-grade and easily handled molybdenum minerals. In this work, a novel method of selective extraction of complex molybdenite concentrate, which is characteristic of high-grade copper ore, has been investigated. The results show that the leaching of chalcopyrite was impacted by the pH of the electrolyte when sodium carbonate and ammonium acid carbonate were added to the electrolyte. The leaching rate of molybdenum reached 99.39%, but chalcopyrite could not be leached at all in 240 min under experimental conditions of liquid-to-solid ratio 25:1, concentration of NaCl 4 mol/L, pH=9, room temperature and agitation speed 400 rpm. The grade of copper in the residue was 21.84%, with a recovery 99.93%. The technology of selective electro-oxidation leaching of molybdenum and recovery of copper from complex molybdenite concentrate is an effective separation method. The diffusion control model can be used to describe the process of leaching of molybdenum. The activation energy of the leaching reaction was found to be approximately 9.21 kJ/mol.IntroductionWorldwide, high-grade and easy-to-handle ore is decreasing, while the proportion of low-grade and complex ore is increasing. Porphyry copper ores with associated low-grade molybdenite are very abundant in China. Molybdenum is a valuable byproduct in the processing of porphyry copper deposits where the molybdenum is present in low quantities in the form of molybdenite (MoS2). In the conventional processing of copper sulfide ores by froth flotation, most of the molybdenite in the ore floats along with the copper sulfides. In this way, a bulk copper-molybdenum concentrate is produced. Afterward, the bulk coppermolybdenum concentrate is treated by differential flotation to obtain a rougher molybdenum concentrate, which requires several successive cleaning steps to produce a final molybdenum concentrate. However, it is widely recognized that flotation alone cannot economically produce a high-grade molybdenite concentrate, i.e., with less than 0.5% Cu. Therefore, in most cases, it is necessary to use a final step of chemical purification of the molybdenite concentrate to reduce the copper content to a level suitable for the market (Antonijevic and Pacovic,1992; Gerhardt et al., 2001; Fu and Zhong, 2003; Reza et al., 2006, Rafael et al., 2013)."

Jan 1, 2015

By Boris Yacksic, R. W. Bruce

"The flotation of a cassiterite ore with oleic acid will recover primary or rougher concentrates assaying over 10 per cent Sn, with a recovery of 80 to 90 per cent. These rougher concentrates cannot be up-graded to a marketable grade by normal reflotation. Experiments were conducted on low-grade tin ores, and a process was developed for up-grading the rougher flotation concentrates by a reverse flotation technique. The process was tested on a number of samples of ore from the Catavi mine in Bolivia. The results of these tests showed that a concentrate assaying 40 to 60 per cent Sn could be readily produced, with a recovery of 60 to 75 per cent of the tin in the ore."

Jan 1, 1967

By Henry L. Ehrlich

This survey compares bioleaching and biobeneficiation by autotrophic bacteria with that by heterotrophic bacteria and fungi Some physiological principles are reviewed. Advantages and disadvantages of autotrophic and heterotrophic leaching are discussed. Principles of anaerobic leaching by autotrophs and heterotrophs are introduced. and the advantages? over aerobic heterotrophic leaching are discussed. Examples of useful organisms in the autotrophic and heterotrophic categories are cited.

Jan 1, 1991

By Ataollah Nosrati

Agglomeration of fine mineral particles is an important step in heap leaching processes employed for a cost-effective hydrometallurgical extraction of value metals from low-grade ores. In this study, the effect of acidic binder composition and feed ore particle size on binder dosage requirement and isothermal, batch agglomeration behavior of siliceous goethite nickel laterite has been investigated. Agglomeration tests performed with tap water and 30, 44 and 98% w/w H2SO4 solutions as binders revealed the key role of binder formulation in controlling ore particle wettability, nucleation and granule growth behavior. Both lower binder acid content and higher dosage led to greater wetting, nucleation and granule growth rates. Variation of feed ore fine/coarse particles? mass ratio dramatically impacted on binder dosage requirement for effective particle wetting, nucleation, and growth agglomeration behavior. Increasing fine (-150 µm) fraction mass content in a -2 mm feed ore, led to higher binder dosage requirement and enhanced nucleation, however the overall agglomeration rate/granule size growth decreased. In contrast, the presence of coarse (5 ? 15 mm) particles in feed ore led to (i) lower binder dosage requirement, (ii) enhanced initial agglomerate size growth rate, and (iii) reduced coalescence. For dry agglomerates of similar sizes, competent coarser feed particles led to remarkably higher compressive strength than did finer feed particles. Microstructure analyses indicated that the granules containing coarser particles exhibited a distinctive, competent core/shell (fines) structure which led to their structural reinforcement. The appropriation of the findings for optimizing agglomeration behavior for enhanced heap leaching of complex, low grade laterite ores are discussed in this context.

Sep 1, 2012