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By James S. Browning

The purpose of this investigation was to develop a dependable and economic method for recovering spodumene and mica from pegmatites of the type found in Gaston County, N. C. Laboratory batch tests and continuous flotation tests were made by the Federal Bureau of Mines to determine the feasibility of treating the ore by flotation to recover high-grade spodumene and mica concentrates. The spodumene flotation circuit yielded concentrates containing 6.50 percent lithia (Li20), with an overall recovery of 81.8 percent of the lithia in the ore, The mica circuit yielded concentrates containing 97.5 percent mica, with a recovery of 82.5 percent of the mica in the spodumene tailing.

Jan 1, 1961

By W. J. Whiten, D. W. Grinsberg

Most cluster analysis techniques are not well suited to the analysis of engineering data as they have been designed for more qualitative data that tend to produce compact clusters. A clustering technique is described which develops and uses local cluster shapes to build clusters that are suitable for use in engineering applications. The technique is finding application in the analysis of many types of data, particularly where multiple trends and outlying points occur in multiple dimensions. Applications of particular interest are the calibration of on-stream analytical equipment and the analysis of data on plant performance. In both cases the multidimensional nature of the data renders manual analysis very difficult

Dec 1, 1991

By Anja Pfennig, Axel Kranzmann, Phillip Zastrow

"Properties of pipe steels for CCS technology require resistance against the geothermal corrosive environment (heat, pressure, salinity of the aquifer, CO2-partial pressure). To predict the reliability of two different injection pipe steels with 13% chromium and 0.46% carbon (1.4034, X46Cr13) as well as 0.20% carbon (1.4021, X20Cr13) steel coupons were heat treated by comparable routines prior to long term corrosion experiment (60°C, 100 bar, artificial brine close to a CCS-site in the Northern German Basin, Germany). In general higher carbon content exhibits better corrosion resistance with respect to corrosion rate, amount of pits and maximum intrusion depth in the case of local corrosion. At 100 bar hardened steels with martensitic microstructure have the lowest corrosion rates with an average of 0.003 mm/a after 2000 h exposure time. At ambient pressure normalized steels show the lowest corrosion rates, indicating that the corrosion is driven by grain boundaries.IntroductionEngineering a geological on-shore saline aquifer CCS-site (CCS Carbon Capture and Storage [1-3]) corrosion of injection pipe steels may become an issue when emission gasses, e.g. from combustion processes of power plants, are compressed into deep geological layers [4-8]. Typically 42CrMo4 (1.7225, AISI 4140) is used for casing, and for injection pipe the steel X46Cr13 (1.4034, AISI 420 C) or X20Cr13 (1.4021, AISI 420 J) is used. Saline formations are the most favorable storage sites in Germany [9], because of their large potential storage volume and their common occurrence. Leakage of CO2 back into the atmosphere may be a problem in saline aquifer storage, especially around the water level within the borehole. Carbon dioxide corrosion may cause failure of pipelines and wells as known from the oil and gas industry [4,6,10,11, 12].From thermal energy production it is known, that the CO2-corrosion is sensitively dependent on alloy composition, contamination of alloy and media, environmental conditions like temperature, CO2 partial pressure, flow conditions and protective corrosion scales [6-8,13- 20]. Considering different environments, aquifer waters and pressures, the analyzed temperature regime between 40 °C to 60 °C is a critical temperature region well known for corrosion processes as shown by Pfennig et al. [21-23] and various other authors [10,24-28] (figure 1). Here a maximum around 4.7 mm/year was found for the pit intrusion depth of 13% Cr steel X46Cr13. Still this may be predicted by the rather conservative Norsok-Model used in the oil and gas industry to calculate surface corrosion rates of carbon steels [29]."

Jan 1, 2014

By Robert F. Shurtz

This paper discusses and compares methods of statistical analysis of the information relating to the evaluation of an asbestos deposit. From a study of 10-ft. lengths of drill core, the separate effects of visual evaluation errors were determined, as well as the deviations between evaluators and the deviations produced by a slight displacement in the center lines of the check drill holes. The importance of careful statistical analysis of such information is stressed.

Jan 1, 1966

By Armando Rivera, Ángel Cueva

El proyecto Mirador, ubicado en la provincia de Zamora Chinchipe en Ecuador, es un sistema mineralizado del estilo pórfido – cuprífero, tipo cobre – oro. Constituido por una zona superior de óxidos, adyacente a un área transicional de óxido –sulfuro dentro de una zona mineralizada con sulfuro hipógeno (calcopirita– pirita), tiene potencial para generar drenaje ácido de roca (DAR), lo que crea preocupación ambiental respecto de los recursos de agua superficial y subterránea. En este artículo se describen diferentes etapas de muestreos de los núcleos de perforación con variación en profundidades y litologías, el análisis de los factores que influyen en la transformación de residuos sulfurosos, y la realización de pruebas estáticas estándares y cinéticas.

Feb 28, 2019

By A. Pezzuto

"Pipes are used on mine sites in a variety of applications including transport of slurry, conveying clean and processing water, and in mine dewatering. Mine waters and slurries can cause pipe wear and failures via several mechanisms (or combinations thereof) such as abrasion, scaling, and corrosion. Polyethylene (PE) pipe materials have grown in popularity over the past several decades due to their chemical and mechanical properties (e.g., inertness, flexibility, relatively low density) and low cost. While PE is generally resistant to corrosion, it is subject to abrasion. To combat this, a novel, rubber-like liner is in development. In addition to comprehensive abrasion testing, however, the liner must be evaluated to see how it performs under other conditions. Here, a brief field study is described that tested PE pipes with the new liner against traditional PE pipes to specifically assess mineral scale buildup. The study was conducted in the Reiche Zeche study mine in Freiberg, Germany in six different locations with varying water qualities and flow conditions. INTRODUCTION Water and slurry conveyance are major operations on and around mine and mill sites, from mine dewatering, to tailings transport, to water treatment processes. Conveyance systems in such applications can include great lengths of pipe materials along with pumps and monitoring instruments, and thus represent significant capital investments. Due to the variability of the physical and chemical properties of water and slurries, pipe materials are subject to a wide range of conditions. These can cause pipe wear and eventually failure leading to serious economic, environmental and social, consequences. While pressure-induced pipe failures (e.g., ruptures or ""bursts”) can be immediate, most failure mechanisms involve gradual processes. Scaling and sedimentation can present major problems for pipe systems conveying highly mineralized waters. Sedimentation generally refers to the deposition of suspended solids, such as sand, clay, silt, or organic matter onto pipe surfaces. This phenomenon can occur due to a decrease in water velocity or particle collisions with the pipe wall. Scaling, on the other hand, commonly refers to the deposition of precipitated mineral salts (including oxides and hydroxides) onto pipe surfaces. Mine waters often have extremely high ion concentrations (i.e., high dissolved solids content) due to their interaction with enormous surface areas of minerals, which are exposed during mining and processing operations (Brown and Barley, 2002). As these waters are transported, slight changes in temperature, pressure or chemistry (e.g., pH or ORP) can cause instability with respect to ion solubility such that salt precipitation begins to occur. “Seed” crystals can rapidly grow and attach to pipes, either due to local surface phenomenon near the pipe wall (e.g., which can promote coagulation) or sedimentation of the precipitated solid. Whether due to suspended or precipitated solids, as the solids begin to stick to pipe walls, “aging” or hardening processes can commence; and the build-up of scale can become self-perpetuating as the scale itself provides an attractive “nucleus” for further attachment of particles or crystal growth (Muryanto et al., 2014). Over time, scale-buildup reduces the effective pipe diameter, which can ultimately result in decreased flow velocity, clogging and, in some instances, bursting (Dirany et al., 2016)."

Jan 1, 2017

By Ingvar Ymén, Anders Sandc, Jan Rosenkranzc, Lisa Malma, Ann-Sofi Kindstedt Danielssonb

The understanding of particle surface properties is essential for the study and evaluation of froth flotation phenomena, particularly in the investigation of various chemical or reagent effects. Dynamic Vapor Sorption (DVS) is a method used for the analysis of surface properties of powders for instance in the pharmaceutical industry. To the knowledge of the authors, it has however not been used before in applications related to mineral processing. The DVS technique involves measurement of the water uptake of a relatively small amount of sample as a function of the relative humidity (% RH) in a temperature-controlled environment. The purpose of this work was to evaluate the method and investigate how it can complement existing techniques for surface characterization in mineral processing. Four samples (feed, CuPb concentrate, Cu concentrate and Pb concentrate) from the Cu – Pb flotation process in the Garpenberg concentrator, Sweden, were analyzed by DVS and the traditional capillary absorption technique (Washburn capillary rise). This enabled comparison between the two methods and evaluation of their respective advantages and disadvantages. Both methods give the expected ranking of the hydrophobicity for CuPb concentrate, Cu concentrate and Pb concentrate, but a discrepancy was observed for the feed. Washburn gave a value for the contact angle which was in the same range as for the CuPb concentrate, whereas DVS gave a value for the moisture uptake which was much higher than for the CuPb concentrate. Thus, DVS ranks all samples correctly, but with an unexpectedly high value for the feed whereas Washburn gives good ranking for three samples out of four. Potential reasons for the discrepancies are discussed.

Jan 1, 2018

By Luis R. Bittencourt

Research efforts have been made to characterize a refractory Brazilian bauxite ore composed basically of gibbsite, kaolinite and quartz. Detailed polished-section microprobe analysis of the unbroken ore has been used to describe the liberation characteristics and the association between mineral phases. The linear grade distributions for selected particle size fractions were determined by means? of a particular implementation of King's Random Fracture Model that uses the exponential model for the distribution of linear intercepts through both dispersed (kaolinite) and continuous (gibbsite) phases. The corresponding volumetric grade distributions were then determined by means of a constrained optimization technique for the solution of the transformation equation. Batch flotation experiments were carried out to determine the kinetics for particles of different sizes and the results correlated with the liberation spectrum for each size class.

Jan 1, 1991

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By Howard Lum, Sergio Valles, John Bednarski, Gordon Enas, Jay Arabshahi

"Water drawn from the Sacramento-San Joaquin Delta provides water supply to 66 percent of California’s population and supports the state’s agriculture industry. The existing through-Delta water system is outdated and unreliable with environmental risk to some fish and wildlife species. The Bay-Delta Conservation Plan (BDCP) has been established to environmentally retrofit and modernize California’s water delivery system through the Delta by restoring habitats, constructing new diversion points in the north Delta and providing a means to transport water supplies under the Delta, rather than through sensitive natural channels.Under BDCP, the Delta Habitat Conservation and Conveyance Program (DHCCP) has developed several alternatives to convey water from the Sacramento River in the north to the existing pumping facilities in the south Delta through an isolated conveyance system. The new conveyance system would become an integral part of the State Water Project (SWP) and the federal Central Valley Project (CVP) by transporting water to the export pumping plants for each of these projects. The DHCCP is managed by the California Department of Water Resources (DWR), while state and federal water contractors provide technical support to the program.The initial conceptual study efforts on the overall program commenced in 2007 and examined various options for the proposed conveyance system. Several conveyance alternatives were analyzed at that time. The Conceptual Engineering Report published on Oct. 1, 2013 identified the modified pipeline/tunnel option (MPTO) as the preferred alternative to be included in the BDCP environmental documents. MPTO includes three river intakes and pump stations along the Sacramento River, various sizes of pipelines and tunnels, junction structures and two forebays that are capable of delivering up to 4 million gpm (9,000 cfs) from the Sacramento River to the SWP and CVP. The river intakes are located near Hood in Sacramento County approximately 64 km (40 miles) from Clifton Court Forebay (CCF) in Contra Costa County. This route would cross portions of Sacramento, San Joaquin and Contra Costa counties. Figure 1 depicts the configuration of the MPTO alternative."

Apr 1, 2016

By D Connelly

Magnetite orebodies generally means mining lower grade iron ores, crushing and grinding with significant energy costs in processing and the capital costs being significantly higher than for direct shipping ores (DSO). Overseas, the mining and processing of magnetite ores has a long history of production due to the lack of DSO deposits. This raises the question as to why the new magnetite projects have been so problematic and also whether there is a future for the long list of potential magnetite projects in Australia.The quality of the magnetite concentrate product is superior to most DSO products and the magnetite contains energy benefits when converted to hematite in sintering or pelletising. The industry’s hopes for new projects have been dashed and questions are being raised as to the financial viability of such projects.A comparison of Grange Resources Savage River, Arrium’s Project Magnet, the Sino Iron Project and Gindalbie’s Karara Iron Project is used to understand the differences between the projects and why some are more successful than others.CITATION:Connelly, D, 2015. What is the future for magnetite projects in Australia and why have some of the new projects been so problematic?, in Proceedings Iron Ore 2015, pp 107–114 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 13, 2015

By R. E. Lindstrom

Electrooxidation techniques were investigated on a bench scale by the Bureau of Mines to determine the applicability of the process for extracting molybdenum and rhenium from low-grade molybdenite concentrates. Parameters affecting the extraction, such as pulp density, power consumption, reagent requirements for pH control, and electrolytic cell configuration, were studied. Molybdenum and rhenium extractions of 98 to 99 percent were achieved from several concentrates containing 4.76 to 28.6 percent molybdenum and 180 ppm to 1,000 ppm rhenium. Optimum results were obtained by maintaining pH values between 5.5 and 7.0 during electrolysis and allowing the final pH to rise to about 8.2. Reagent consumption was 4 to 6 pounds of sodium carbonate per pound of molybdenum extracted. The power consumption declined from a range of 12 to 25 kilowatt hours per pound of molybdenum extracted with immersion electrodes to 9.7 kilowatt hours with a bipolar flow-through cell; however, molybdenum extraction was independent of cell configuration.

Jan 1, 1973

By Christopher Robben, Alexander Mosser

"X-ray transmission (XRT) sorting has been introduced into the minerals industry in 2006 and has found various applications in diamonds, industrial minerals and metal ore processing since. The technology offers planar projections of the atomic density of single particles similar to the principle known from airport scanners, but being capable of treating up to 150tph per metre working width. In 2010, a pilot operation using a belt-type sensor-based sorter went into production at the Mittersill mine to treat the fraction 16-28mm. After an optimisation phase, the results were superseding expectations and therefore in 2012 a bigger production plant was set up. Two XRT-based sorters are parallel in operation since. One is treating the fine fraction 16-30mm while the other one is treating the coarser fraction 30-60mm after the secondary crushing stage. The XRT sorters are operated with the objective to reject barren waste before it enters the mill and flotation plant. 105,000tpa of waste material are rejected per year and can be sold as aggregate for road construction. This means that about 22% of the run-of-mine ore are rejected at an early stage with a waste reject grade lower than 0.03wt%WO3. The installation has not only led to lower specific operating costs but also led to reduced tailings disposal in an environmentally sensitive area. This allows the mine to reduce its headgrade which allows for a longer mine life. Alternatively it is possible to produce more tungsten concentrate, which is delivered to the smelter. This article will introduce the technological principle of XRT-based sorting and will discuss the flow-sheet of the Mittersill mine. Experiences that have led to the current plant design are described as well as the impact it has on the operation."

Jan 1, 2014

By A T. Spathis, M G. Wheatly

Some preliminary dynamic pressure data were obtained from several charges detonated in a tunnel situated in massive granite rock. The context of the work is the potential for desensitisation of explosives, failure of detonators, and sympathetic detonation due to the close proximity of inter-hole and inter-deck explosive charges to each other. Dynamic pressures were measured using piezoelectric gauges in water-filled 45 mm diameter holes adjacent to the charges. Some of the first arrival peak pressures were noisy, and although not fully resolved, may be due to reflections and the physical arrangement of the transducers and their size with respect to the monitoring holes. The estimated peak pressures were between 0.1 to 8.7 MPa at approximate distances of 2.8 to 0.8 m, respectively. Further work is planned with gauges that are disposable, have a higher pressure range, and can be used within a few borehole diameters rather than the piezoelectric gauges used in the present work.

Jan 1, 2016

By M. Misra

The dissolution of mercury during gold cyanidation is the cause of many environmental, health and processing problems. A study was undertaken to find a suitable reagent for the removal of mercury bearing complexes from the leach liquor. Removal of mercury from synthetic solutions and process water from a gold mine was investigated using sodium sulfide, sodium and potassium dimethyl dithiocarbamates as precipitating reagents. The results have shown that efficient mercury removal could be achieved by addition of potassium dimethyl dithiocarbamate (KDTC), by formation of stable mercury compounds. The resultant mercury-potassium dimethyl dithiocarbamate precipitates are stable under present plant operating conditions and do not have any deleterious effect on gold adsorption by activated carbon. Furthermore, it is also possible to stabilize the mercury in the heap during cyanidation by adding dimethyl dithiocarbomate.

Jan 1, 1998

By Xiangwen Wang

Electrochemical measurements associated with the electrowinning of lead metal from concentrated brine (NaCI) - lead chloride (PbCI,) electrolytes at temperatures in the range 328 to 353°K (55 - 80°C) were conducted. The electrodeposition of lead metal onto a lead rotating-disk electrode may be described by the electrodic reaction: {PbCl 4 2 + 2e- = Pb° + 4Cl-} The deposition-overpotential requirements are low (approximately 41mV per decade of current density - Am+), with a corresponding high exchange current (approximately 0.018 A.cm2). The diffusion coefficient of the electroactive PbC142- species in a 3.5 NaCl electrolyte at 353°K was insensitive to the total PbCI, concentration (0.01 to 0.1M), and its value was found to be (1.21*0.1)~10-5 cm2Is with a temperature-sensitivity coefficient (E,/R) of approximately 1.98x103K-1 (328OK(T<353OK).

Jan 1, 1993

By R. MacRosty

The demand to increase production levels in smelting furnaces has driven the increase in the power levels. Consequently, greater cooling capacity of the furnace shell has been necessary, resulting in the widespread use of water-cooled elements to protect the refractory linings. Since water ingress into the furnace is an explosion hazard, monitoring and maintenance of the water-cooled elements is of key importance. Some of Hatch&apos;s recent research and development efforts have been focused on methods to provide an increased level of monitoring of water-cooled furnace elements; this paper focuses on two technologies developed for this purpose. The first involves the installation of a fibre optic temperature sensor in a water-cooled tapblock. The sensor is capable of providing high accuracy temperature measurements with a fine spatial resolution throughout the tapblock. Hatch has already developed a diagnostic system that uses multivariate statistical analysis to interpret the large quantities of data generated by the sensor. A second technology under development is concerned with enhancing the operating integrity and safety through detection of leaks in the water circuits. A successful leak detection strategy requires minimal maintenance and the ability to detect minute leaks. An instrument that meets these criteria has been investigated and is currently under development. This paper focuses on the technology and results from the test work that has been completed to date.

Jan 1, 2007

By H. Y. Sohn, M. Pérez-Tello, P. J. Smith, K. M. Riihilahti

A three-dimensional computer model for the Kennecott-Outokumpu flash converting process for copper matte is presented. The model incorporates the transport of momentum, heat and mass, and reaction kinetics between the gas and particles in a particle-laden turbulent gas jet. The k-E model is used to describe gas-phase turbulence in an Eulerian framework. The particlephase is treated from a Lagrangian viewpoint which is coupled to the gas phase through the source terms in the Eulerian gas-phase governing equations. Matte particles were represented as Cu2S·yFeSx. Based on experimental observation, the oxidation products were assumed to be Cu2O, CuO, Fe3O4, and SO2. A reaction mechanism involving the external mass transfer of oxygen to the particle surface and diffusion of the oxygen through the oxide layers of CuzO/Fe304 and CuO/Fe3O4 is proposed. Predictions of the mathematical model were compared with the experimental data collected in a large laboratory furnace. A reasonable agreement between the model predictions and the measurements was obtained in terms of fractional conversion of the oxidation reactions and of sulfur remaining in the reacted particles. The simulation of an industrial flash converting furnace was also performed. Higher oxidation rates, more even distribution of particles, and thus a more efficient use of the reactor volume are predicted with a burner having a distributor cone, than with a single-entry burner.

Jan 1, 1999

By D. H. Baker

THIS REPORT presents the technique and equipment used in determining the hardness of titanium sponge. Detailed descriptions are given of the methods used in preparing test samples for chemical analysis and hardness testing, the method of melting and surfacing test ingots, and the technique of reading Brinell-hardness impressions. The arc-melting furnace described, for which engineering drawings are included, will produce from 70 to 90 double-melted buttons each 8 hours of operation. Experimental data are also presented depicting the effect on hardness of the methods of surfacing specimens, temperature of test specimens, and the effect of time at test load. These data show that surfacing of the specimen involves no critical machining operations but that the test surface must be paralleled by a relatively flat surface for contact with the anvil of the Brinell tester. The heating of a specimen to 150° C. during surfacing does not materially affect the results if the ingot is cooled to room temperature before the hardness impressions are made. The optimum time at load appears to be approximately 30 seconds, but load times of as much as 1/ ½ minutes will not cause major errors.

Jan 1, 1959

By James C. Cawley

This report presents results of recent Bureau of Mines research to establish the probability of spark ignition as a function of current (or voltage, for capacitor circuits) for resistive, inductive, and ca-pacitive circuits in 8.3% methane-air atmospheres. The data presented quantify the explosion hazard created when low-power electronic devices catastrophically fail in an explosive mine atmosphere. Previous litera-ture dealt with levels of probability between 10-3 and 10-4. This re-port extends the probability data to levels as low as 10-7. This study has verified that when the probability of ignition, PI, is plotted on a log-log coordinate system versus the current (or voltage), a continuous, straight-line relationship is formed. An interesting result that can be statistically hypothesized is that at some low level of igniting current the ignition process ceases altogether.

Jan 1, 1988