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By A. P. Purgin, M. G. Viduetsky, I. F. Garifulin

"The combined treatment process for mine, tailings storage facility, quarry, circulating, and waste water in the mining and metals industry brings together the conventional chemical treatment processes and pneumatic flotation cells of the KFM series. The key principle of the process is preparing the water for treatment by saturating with finely dispersed air bubbles in the flotation cell blowers. Gas-air lift dispersers located in the lower part of the cell body additionally saturate the cell’s contents with finely dispersed air. Due to the residual content of flotation agents in the treated water, hydroxide ion-air aggregates form at the aerator outlet, supporting the efficient precipitation of hydroxide ions of heavy non-ferrous metals, calcium and magnesium ions. This process was tested in the pilot plant KFM-180 with a raw (untreated) water capacity of up to 18 m3/h per 1 m3 of the flotation cell volume using a mixture of the tailings storage facility and mine water from JSC Safyanovo Copper. The treatment process included raw water treatment with lime, aeration in KFM cells, and filtration in a sorbent bed. The content of metal ions in the treated water is lower than in the feed water by a factor of up to 170,000 and approaches the standards: aluminum 0.016-0.02 mg/l, copper 0.0043-0.0045 mg/l, zinc 0.049-0.052 mg/l. circulating water of Soryin Tailings Storage Facility at JSC Svyatogor. The treatment process included raw water treatment with lime and alkali, aeration in KFM cells, and filtration in a sorbent bed. The content of metals in the treated water is lower than in the feed water by a factor of up to 9000: copper 0.022 mg/l, zinc 0.012 mg/l, iron 0.012 mg/l, manganese 0.015 mg/l, nickel 0.132 mg/l, arsenic 0.016 mg/l. Water hardness is significantly lower: calcium - 12.6 mg/l, magnesium - 1.1 mg/l. This process can be used in the treatment of mine, quarry, tailings storage facility, and circulating water at mining and non-ferrous metals projects."

Jan 1, 2018

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By Valentine Chanturiya, Irina Khabarova, Maria Ryazantseva, Igor Bunin

"XPS investigations of the influence of HPEMP - treatment duration on the surface composition for natural chalcopyrite and sphalerite are described. HPEMP is a video pulse with a nanosecond front lasting between 5 and 10 ns. The electrical field component can reach 30 kV, whereas pulses repetition frequency is 100 Hz. In general, the formation of metal-deficient surfaces, polysulphides or elemental sulphur and oxides/hydroxides, were determined during the treatment for both sulphides as well as the essential differences of the way of mineral surface transformation during the treatment. The chalcopyrite surface shows the formation of elemental sulphur under the HPEMP treatment at 103 pulses while appearance of unstable sulphite species was detected at the chalcopyrite surface within 5 seconds (0.5•103 pulses) under the same treatment conditions. The results indicate that the quantity of adsorbed water (at.%) is changed considerably during the HPEM - treatment depending on treatment duration for both minerals. The concentration of water onto the chalcopyrite surface decreased during 30 seconds (3•103 pulses) of the HPEMP - treatment and it rose after the treatment at 5•103 pulses. The inverse dependency was obtained for sphalerite surface. Single mineral flotation tests have shown the significant increasing of the minerals recovery."

Jan 1, 2014

By Y. Kumagai, F. A. Souza

"Electroless plating process has been used in many fields such as automobile and electronic industries. Solutions used in these processes must be disposed or treated. Commonly, in these solutions metal ions, organic materials and others chemicals are in very high concentration. It is very difficult to keep the environmental regulations for disposal of these materials, and the cost of the plating process becomes higher.The objective of this study was to investigate the recovery of components of those baths in order to decrease the cost of the plating process as well as to meet the environmental regulation.In this study the recovery metal ions, sulfate ions, phosphite ions and organic compounds were investigated. Organic compounds used in electroless plating solutions are the organic acids. In this work the solvent extraction of the most used organic acids included citric, lactic, succinic, tartaric and malic was studied. The solvent phase considered in these studies was ethyl acetate.About 95% of the metal ion was recovered by chemical plating onto mica powder. The hypophosphite remained is oxidized to phosphite and with the sulfate ion, both are recovered as calcium salts by selective precipitation in pH 7 and 2 respectively. Organic acids were recovered by solvent extraction using ethyl acetate as solvent phase and the best results were for lactic acid and succinic acid.Along with this study, was developed the analytical parameters to perform wastewater analysis by using Ion Chromatography, High Performance Liquid Chromatography (HPLC), Fourrier Transform Infrared Spectroscopy (FTIR). Ion chromatography was used to perform analysis of sulfate and phosphite ions in liquid matrix, HPLC was used to perform analysis of organic acids in liquid matrix and FTIR was used for characterization of the solids obtained in the recovery processes."

Jan 1, 1997

By K. K. Kelley

The heats of formation of two lead vanadates (Pb2V207 and Pb3V208) and manganese vanadate (MnV206) were determined by hydrochloric acid solution calorimetry, supplementing previous Bureau of Mines measurements of the vanadates of calcium, magnesium} and sodium. Heat and free energy data for 11 vanadates were assembled on a common basis. The stability of comparable vanadates (with respect to the oxides) increases in the following order: Magnesium, manganese, lead, calcium, sodium.

Jan 1, 1963

By Gui Hua Wang, Xin Chang, Zhong Ying Han, Yuan Fang Cheng

"According to the geometrical characteristics of triangular meshes, Triangular Mesh Split Model (TMSM) based on a finite element method is proposed to simulate cracks propagation of fractured rock. With TMSM, stress intensity factors at the tip of cracks are obtained by far-field contour integral. Meanwhile, vector cross multiplication is adopted to fix the cracking unit, and maximum circumferential stress criterion is used to determine the crack propagation angle. Then crack dynamic propagation simulation is realized through local mesh split or node movement at crack tip. With this method, the crack can split apart a unit or extend along the mesh boundary, so the crack could extend along an arbitrary path and is not restricted by the initial mesh. The applicability of the mesh split algorithm is verified by the crack propagation examples of wing crack and multi-fractured rock mass with holes. The results show that this method not only has higher accuracy of fracture parameters calculation, but also can accurately simulate the crack initiation and propagation of rock under complex stress state such as tension, compression and shear. In addition, the far contour integral is introduced to determine the crack tip stress intensity factor and there is no need to reconstruct a singular element at the crack tip or to intensify the meshes. Compared with the existing mesh reconstruction algorithm, this method significantly improves the computational efficiency.INTRODUCTIONGenerally, rock is neither the full continuum, nor entirely discrete body, but rich in geological defects, such as joints and cracks. A large amount of geotechnical engineering practice shows that most fracture of rock is closely related to the internal joints, cracks and crack expansion (Horii et al., 1985; Wong et al., 1998). Although the classical theory of fracture mechanics established the theoretical foundation of crack initiation, propagation, so far it is still extremely difficult to characterize the propagation of airfoil-typed crack and the interference problem of multiple cracks. Up to now, the micromechanics mechanism research of crack propagation of fractured rocks has still been a hot research topic of rock fracture mechanics."

Jan 1, 2015

By Bjorge, Guy N.

MINING method improve through the gradual process of evolution and in 1340 there were no marked outstanding innovations. On the other hand refinements of detail and betterment: in equipment design continued to progress. Among the most important changes have been the increased application of trucks and highway equipment, including tractors and bull- dozers, to open-pit mining as exemplified by Phelps Dodge's Morenci operations; the Mesabi iron range; and the Tri-State district. Mass or bulk handling contributed its part underground with slurhers and conveyors at Consolidated Coppermines and slushers at Climax; and in open-pit mining. conveyors found increased use on the Mesabi range.

Jan 1, 1941

By B. Whisner, A. Smith, J. Carr

"Electromagnetic based proximity detection systems (PDSs) are utilized on mining machinery to protect workers from being pinned or struck. These systems generate magnetic fields covering the space around a machine, and a miner-wearable component (MWC) detects the field. The PDS determines the distance of miners relative to the machine based on the detected magnetic flux density in the magnetic field. This information is used to establish warning and shutdown zones around the machine. Maintaining a stable magnetic field is essential for system accuracy. However, components used to generate magnetic fields can be influenced by temperature changes. Depending on ventilation conditions and seasonal alternation, a PDS can be subject to significant temperature fluctuation. To better understand and quantify this phenomenon, researchers from the National Institute for Occupational Safety and Health (NIOSH) developed an experimental apparatus to study the influence of temperature on magnetic field generator circuits used in PDSs. Results from the study show that the electric current through a generator can be influenced by both ambient and internal temperatures, modifying the magnetic field that is produced. These findings show that temperature can significantly influence the ability of PDSs, used in underground coal mines, to accurately determine a worker’s position in relation to mining machine. INTRODUCTION Electromagnetic based proximity detection systems have been developed to reduce machine-related accidents in underground coal mines. The first proximity detection systems installed in underground coal mines were developed for continuous mining machines (CMMs). There are five of such proximity detection systems that are approved for use in U.S. mines by the Mine Safety and Health Administration (MSHA) (Mine Safety and Health Administration, 2013; Mine Safety and Health Administration, 2015). There are several basic components that interact within an electromagnetic proximity detection system (PDS). A PDS includes two main elements: a set of generators to create magnetic fields around a CMM and a set of magnetic probes to detect the fields. These systems can determine if a miner is located at a safe distance from the machine based on the detected magnetic flux density. Stability of the magnetic fields is essential for system accuracy."

Jan 1, 2018

By R. J. Fantel

To determine the availability of phosphate rock from domestic re- sources, the Bureau of Mines evaluated the potential production of phosphate rock from the demonstrated resources of 130 mines and deposits. The evaluation included an estimation of resources, engineering methods, and capital and operating costs, and an economic analysis to determine each operation's average total cost of production over the life of the mine, including a 15-pct discounted-cash-flow rate of return on all investments. Quantified but not evaluated in this report are substantial phosphate resources at the inferred and hypothetical resource levels. The 130 mines and deposits contain 6.4 billion tons of recoverable phosphate rock product, about 20 pct from producing mines. At total production costs of under $30 per ton in January 1981 dollars, about 1.3 billion tons of phosphate rock product is potentially available, over 90 pct from producing mines. This study suggests that production from low- cost, high-grade phosphate mines now in operation will decline during the next decade, and new higher cost, Lower grade mines will have to be developed to satisfy demand into the next century, In addition to the demonstrated resources evaluated in this study, 7 billion tons of inferred-level and 24 billion tans of hypothetical- level phosphate rock are potentially recoverable, which, in part, includes material containing high amounts of magnesium, Much of this material could likely become available in the near future.

Jan 1, 1983

By Z. I. Zaki

Synthesis of TiC /A1203 Composite from TiO2, Al and graphite using combustion technique has been investigated at different initial temperatures; room, 400 and 600 °C. The effect of initial temperature on the composition of the product, wave velocity and combustion temperature of the reaction was studied. The measured combustion temperature and wave velocity were increased with increasing the initial temperature of the combustion reaction. The maximum wave velocity obtained was 5.9mms-1 when conducting the combustion reaction at initial temperature of 600 °C. Oxidation resistance of the obtained composite was also studied at the temperature range 300-800 °C. No oxidation is detected before 400 °C while it takes place effectively at 700 °C forming different titanium oxides. Wave velocity measurements method was used to calculate the activation energy of the reaction between the starting materials. It was found to be 316.34 kJ mol 1 at the temperature range that was studied.

Jan 1, 2007

By E. Fockedey

he destruction of free cyanide on a Co3O4 doped carbon felt was studied. The experiments were done with an eiectrochemical filter press cell on dilute alkaline solutions containing 250 mg/l NaCN. No chloride ions were added to the solutions. The cobalt oxide protects the felt against corrosion and has a catalytic effect on the degradation of the cyanide. This kind of electrode allows working with current density as high as 1200 Aim without any visible degradation of the felt. The most interesting results were obtained with a current density of 400 Aim' at which the cyanide concentration can be lowered to 5 mg/l with a current efficiency of more than 70 % and a specific energy consumption of about 10 kWh/ kg CN.

Jan 1, 1998

MR. J. F. MYERS, Consulting J3eneficiation Engineer, Greenwich, Conn.: In the written discussion contributed by Mr. F. C. Bond in item ( 2) (page 515), speaiking about the significance of the ratio of mill diameter to the make-up ball diameter, he states: "When this ratio exceeds 100 the power and capacity of the mill are de-creased"; and the paragraph ends with a reference to the 30 per cent ball volume "with some de-crease in mill capacity". I believe this broad statement is incorrect. When we are dealing with a non-cataracting mill, pre-ceded by a good rod mill, there is a slight increase in capacity, but the power does drop. The second point that I consider needs consideration is Mr. Bond's item (8), Proper Mill Speed (page 516). This paragraph should be qualified to cover single-stage mills only. It does not apply where a rod mill is followed by a non-cataracting ball mill. The statement as is, with no qualification, gives an erroneous idea of proper mill speeds.

Jan 1, 1957

By Dever Ashmead

ANTHRACITE was first mined in the Wyoming Valley and sold as an article of commerce in 1808. As some preparation has always been necessary to make it ready to burn, the preparation of anthracite must date back over a hundred years. Two vital factors have determined to a large extent the degree and method of anthracite preparation. These are, first, the character of the beds worked and the methods by which they were mined and, second, the equipment used and practices followed in the burning of the coal. It is not the intention here to go deeply into these phases of preparation as a paper of no mean length could be prepared on the history of either. Rather, the intention here is to point out the main considerations and to show the influence they have exerted on the preparation of anthracite. MINING METHODS AND THEIR RELATION TO PREPARATION In the beginning f the nineteenth century, the coal beds were virgin with the possible exception of some outcroppings that had been worked, to a slight extent, by the Indians. It is known that the American aborigines had a knowledge of the use of this fuel, because when the Wyoming Valley was purchased from them, in 1754, they mentioned the fact that, by selling the land, they would lose their coal.

Jan 9, 1921

By J. Howarth

Two electrochemical processing methodologies have been used to electrogenerate bromine-laden solutions for gold-leaching purposes. In the first process, a laboratory-scale cell in which the anode and cathode compartments were separated by a cation-exchange membrane was employed. The bromine produced by electrolysis of a 4% bromide solution was used to leach gold from a low-grade ore. The pregnant leach solution was then returned to the cell to recommence the cycle. High current efficiencies (90-93%) were maintained over six cycles. In the second process, an undivided hypochlorite generating cell (Chloropac"') was used to generate bromine from a simulated leach solution. Electrolyses were performed on a pilot-scale (100-150 gallons) with solutions containing different levels of bromide ion. The current efficiencies were also high (80-90%) and unaffected by the bromide concentration (over the range 2.5-5%) provided the electrolysis was run to low conversion « 15%). The Chloropac module was capable of delivering 0.6 kg bromine per hour at a power cost of $0.09 per kg. Using these figures, a detailed economic assessment for a 1000 metric tonnes (MT) per day gold ore processing plant was made. Electrolytic regeneration of bromine in a gold leach/recovery circuit dramatically improves the process economics over cyanidation.

Jan 1, 1991

By H. Maleki

The U.S. Bureau of Mines pioneered the use of borehole deformation gauges and overcoring techniques to measure in situ stress. These measurements provide input to structural mine design and support selection for specific geologic conditions. This paper presents recent stress measurements in a western U.S. coal mine where the orientation of the stress field remained relatively unchanged over distances of several kilometers. The horizontal stress magnitude increased with depth of cover and in relation to major geologic structures. Local variations in roof stress profiles were used to develop generic models relating stress arching to strata stiffness and the inelastic behavior of mine roof.

Jan 1, 1994

By Philip Antunes, A. E. (Tony) Reschke

"INTRODUCTION Tunnel Boring Machine (TBM) operations require the injection of material into the annular tail voids as the machine advances ahead of the segmental concrete lining. This annular gap is created because the cutting diameter of the TBM has to be larger than the outer diameter of the concrete segments of the tunnel lining. Fundamentally, the two basic types of annular grout are thick, concrete like mortars and thin, mobile, two-component grouts. While some European countries seem to still favor the concrete like mortars, from a global perspective it is now the two-component type grouts that dominate the industry. Two-component type grouts are comprised of an “A” component grout (typically cement, flyash, bentonite and a retarder/stabilizer) and a “B” component accelerator (sodium silicate or water glass as it is sometimes known). They are thus sometimes referred to as A/B type or bi-component grouts and were pioneered by the Japanese over 30 years ago. They offer a host of operational benefits over thick mortars, such as reduced settlement (Feddema et. al., 2001), effective penetration of the void space, with less energy, and reduced strain on the segmented linings (Robinson et. al., 2007). Two-component grouts are highly mobile and can be pumped many kilometers. The use of a retarder/stabilizer can also extend the shelf life of the “A” component grout for several days while the early strength of the accelerated grout stabilizes the ground and supports the segmental liner almost immediately. The batch plants that prepare the two-component grouts use one of two possible mixing methods for preparing the “A” component grout. The simplest plants use paddle type mixers and numerous tunnels worldwide have been successfully grouted using this technology. However, a superior type of mixer is available, namely the high shear colloidal mixer. Keller Colcrete successfully pioneered the development of the colloidal mixer back in 1937 and for over 75 years colloidal mixers have been internationally recognised as the most efficient method of mixing cement based grouts (Houlsby, 1990). These mixers are used in grout preparation for radioactive waste encapsulation, hydro dam grout curtains, soilcrete jet grouting, soil nailing, and numerous other geotechnical applications. In tunnelling, these mixers are also used for ground treatment, compensation grouting and for the preparation of bentonite lubrication for pipejacking. It has been only within the last decade however that these high-shear colloidal mixers have been adapted for use in the preparation of two-component grouts."

Jan 1, 2016

Large deposits of eudialyte, a low grade zirconium bearing mineral, occur on the Southern Coast of Greenland in the Ilimaussaq intrusion. Various processes were tested in the laboratory to recover eudialyte from these ores, including flotation, leaching, gravity and magnetic separation. A combination of dry and wet magnetic separations has the advantage of simplicity and the least environmental impact for the location. This paper summarizes the results of laboratory testwork to develop a two-stage treatment process to recover the eudialyte by magnetic separation.

Jan 1, 1993

By Ann M. Hagni

Microscopic and sub-microscopic gold commonly occurs in the sulfides pyrite (FeS2) and arsenopyrite (FeAsS). To recover refractory gold from pyrite and arsenopyrite, these sulfides are roasted to create porosity and permeability prior to cyanide leaching. A new technique of adding Ca(OH)2 and roasting. lime roasting. is being tested for retention of contaminant sulfur and arsenic and effectiveness of gold extraction. The lime roasting of pyrite at 500°C contains anhydrite (CaS04). oldhamite (CaS). calcium sulfite (CaS03). hematite (Fe2O:J), magnetite (Fe304). and minor amounts of pyrrhotite (Fe1.xS) and pyrite. At 600°C. 650°C and 700°C. the main constituents are anhydrite. oldhamite. and hematite. At 750°C. 800°C. and 850°C. anhydrite and hematite are the predominant phases with minor oldhamite. The roasted arsenopyrite at 450°C contains arsenic sulfides. calcium sulfite. hematite. and minor oldhamite. magnetite. and pyrrhotite. At 650°C. 700°C, 750°C. and 800°C, anhydrite, oldhamite. arsenic sulfides, and hematite are present. At 850°C. the same minerals are present with only minor oldhamite. The textures indicate excellent porosity and permeability at high temperatures. At lower temperatures, rims of low porosity and permeability surround many of the pyrite and arsenopyrite particles, and the complete oxidation process from pyrite to pyrrhotite to magnetite to hematite can be observed in individual particles. Additional process mineralogy techniques employed in this study are electron spectroscopy for chemical analysis (ESCA) and cathodoluminescence microscopy (CIM) in the determination of the calcium-sulfur-oxygen phases. Automated scanning electron microscopy-energy dispersive spectroscopy was utilized to analyze particles for gold content. Reflected light microscopy (RIM) revealed arsenopyrite and pyrite encapsulated in quartz particles of the gold-bearing concentrate, gold roast calcine, and cyanide leach residue.

Jan 1, 1991

By Erik C. Westman

Knowledge of the orientation and relative magnitude of in-situ stresses at the mine scale is important for safe and efficient production from an underground mine. With this knowledge, stope location and scheduling can be optimized. Passive seismic tomography was used for imaging horizontal stress distribution at the mine scale. Microseismic measurements from the Creighton mine were used as input for the tomography calculations. The double-difference tomography algorithm was used, which provides the most precise results. The results clearly show a low velocity zone in the previously mined areas bounded by two high-velocity lobes located adjacent to the mined openings at locations consistent with those expected due to the horizontal stresses at the mine. The overarching goal of the research is to provide a tool that can augment both numerical modeling results and underground geotechnical measurements to allow the mine operator to produce in the safest and most efficient manner possible.

Jun 1, 2012

By A. Elsayed

Lightweight metals such as magnesium show potential in replacing aluminum alloy castings for engine cradles, cylinder heads and transmission cases. Unfortunately, magnesium alloys are susceptible to entrapping oxides and other impurities during casting that hinder strength and ductility. The current study examined various filter sizes and configurations with the aim of improving the mechanical properties of permanent mould cast AZ91E. The unfiltered casting had a yield strength, tensile strength and ductility of 93.3 MPa, 153.3 MPa and 2.2 % respectively and increased to 96.5 MPa, 167.0 MPa and 3.1 % with the use of a fine mesh filter within the well of the mould. The increased strength and ductility was likely due to the filtered castings containing fewer inclusions on their fracture surfaces as compared to the unfiltered castings.

Jan 1, 2011