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By Liu Jie

Refractory iron ore deposits in China have various genesis and complicated types, the nature of which is poor, fine-disseminated and complex. Therefore, refractory iron ore could scarcely be separated and utilized by traditional mineral processing technology at present. It is necessary to explore deep reduction technology to change the characteristics of refractory iron ore and to use effectively the iron resource. And deep reduction technology is that on the condition of higher reduction temperature than that of magnetic roasting and stronger reducing atmosphere, the iron oxides from iron ore was reduced to metallic iron particle that is easy to dissociate. And then production from deep reduction is easily separated by magnetic separation and iron powder production was obtained finally. Deep reduction technology for Lingyang iron ore from Jilin, China, as the refractory iron ore, was studied in this paper. The influences of such main factors as reduction temperature, time and coal content were investigated. The results showed that the Metallization rate of reduction product was up to more than 90% under optimum conditions, and then higher iron grade and recovery of reduction iron powder were obtained from subsequent magnetic separation. Furthermore, the deep reduction mechanism in the system was studied by the means of XRD and SEM analysis for reduction production and Physical Chemistry of Metallurgy. Analytical results indicated that during deep reduction, the size of iron particle from deep reduction materials was increasing as reduction temperature rising and reduction time extending. The growth of metallic iron particle from deep reduction production was divided into such three stages as reduction nucleation, deep reduction and growth of metallic iron particle.

Sep 1, 2012

By Partha Patra

Numerous proteins of varying properties are available in extracellular bacterial proteins (EBP) isolated from Paenibacillus polymyxa. EBP was fractionated through ammonium sulfate precipitation in a controlled fashion and characterized through SDS-PAGE technique. Different groups of proteins, (Group A~D) exhibited varying degrees of surface affinity to minerals such as quartz, pyrite, chalcopyrite, galena and sphalerite. Interaction with mineral specific bioproteins rendered pyrite and chalcopyrite hydrophilic while surface of quartz, galena and sphalerite turned more hydro-phobic. Specific groups of proteins could thus be used for selective separation of galena, sphalerite and quartz from pyrite and chalcopyrite (as a mixed sulfide) through microbially-induced flotation or selective flocculation.

Jan 1, 2014

By Bent Babel, Martin Rudolph

"The characterization of reagent-mineral interactions in flotation systems of finely intergrown ores holds difficult challenges for the applicability of standard techniques like Hallimond tube tests and contact angle experiments or renders them impossible due to a lack of sufficient samples in terms of quality and quantity. This disadvantage may not apply to more sophisticated techniques, but these often do not work in an aqueous environment. We present the utilization of an atomic force microscope with a hydrophobic colloidal probe to characterize the wettabilities of individual mineral domains of an ore sample, while additional spectral information is gathered by Raman spectroscopy. The exemplary ore sample investigated is mainly containing cassiterite and quartz, therefore the reference measurements like Hallimond tube tests and contact angle experiments were carried out with this binary system as a comparison. The focus of the study lies in the correlation of data gathered by the atomic force microscope and the Raman spectrometer with data from standard techniques. Finally, the applicability of the colloidal probe atomic force microcopy technique for reagent-mineral investigations is critically evaluated.INTRODUCTIONThe focus of this paper is the application of colloidal probe atomic force microscopy (CP-AFM) for theinvestigation of reagent-mineral interactions on a binary system of cassiterite and quartz. This and similar concepts using hydrophobic AFM probes have been applied by multiple authors (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b; Wada et al., 2017; Xie et al., 2017). The hydrophobic interaction is the main interacting mechanism for the hydrophobic colloidal probe with hydrophobic sample surfaces and the long range attractive component has been accounted to nanobubbles on the interacting surfaces (Yakubov et al., 2000). More detailed information on nanobubbles are available in two reviews compiled by Attard and Hampton (Attard, 2003; Hampton and Nguyen, 2010). This paper is based on the work by Rudolph and Peuker comparing different AFM based measuring concepts, additionally gathering data with Raman spectroscopy and correlating results of microflotation and CPAFM measurements (Rudolph and Peuker, 2014a; Rudolph and Peuker, 2014b)."

Jan 1, 2018

By W D. Rech, K W. Keskimaki

As an integral part of the conversion from rail haulage to conveyor haulage at Henderson, over six kilometres of drifting and several large complex openings were mined. The deepest of these areas was nearly two kilometres beneath the surface, bringing all of the challenges of rock stress and heat that come with mining at these depths. Though many mines operate at these depths, the development of the infrastructure necessary to support a 36 000 tonne per day caving operation brought some unique challenges to the development mining activity. The issues handled include: finding experienced staff for a æfast trackÆ development program; rock bursts and ground conditions; inflow of 50 degree centigrade water; acceleration of the project completion; large diameter raise boring and difficult muck handling.

Jan 1, 2000

By E. R. Torak

Custom Coals, International has installed and is presently testing a 225 kg/hr. (500 lb/hr.) micronized-magnetite, fine-coal cleaning circuit at PETC's Process Research Facility (PRF). The cost-shared project was awarded as part of the Coal Preparation Program's High Efficiency Preparation Subprogram. The project includes design, construction and testing of a fully-integrated, bench-scale circuit, complete with feed coal classification to remove the minus 30 micron slimes, dense-medium cycloning of the 300 by 30 micron feed coal using three different size micronized-magnetite mediums, and medium recovery circuits using drain and rinse screens and various stages and types of magnetic separators. This paper describes the project circuit and goals, including a description of the current project status and the sources of coal and magnetite which are being tested.

Jan 1, 1996

By S J. Schafrik, Z Agioutantis, E C. Jong, K Luxbacher

Real-time monitoring of mine operating parameters is available at most mines. However, access to these data for an individual operation is typically underutilised by mine managers and technical personnel. Such monitoring systems are typically designed to provide data streams and alarms to a responsible person, but they are not utilised to extract underlying trends or correlate different data groups. Furthermore, multiple monitoring systems are usually implemented at a given site without interconnection between vendors’ systems or connection to any central management, and mine personnel are only exposed to a minimal subset of such data. Thus, it is not easy to analyse and correlate individual data streams and generate information to enhance day-to-day operational decision-making and improve safety and efficiency.This paper addresses the primary challenges associated with centralising data management and effecting greater utilisation of the vast amount of collected data, while at the same time reducing the time and effort required to manage such large data sets. Furthermore, it presents the conceptual design of a database application that can organise, present and analyse data collected by multiple sensors in different environments. The database is designed to operate in a passive manner so that active mine data management systems are not impacted. An example is given where this database is used for managing atmospheric data collected at an underground coalmine operation in the US. These techniques have a universal application and can be incorporated in a wide range of mining and construction projects.CITATION:Agioutantis, Z, Schafrik, S J, Jong, E C, Luxbacher, K and Karmis, M, 2015. A platform for managing and analysing atmospheric data in underground coalmines, in Proceedings Third International Future Mining Conference, pp 3–10 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 4, 2015

By J. D. Ecuyer, L&apos

he microstructure of galvanneal coatings formed on extra low carbon and interstitial free steel substrates has been characterized using electron microscopy (TEM and SEM) and x-ray diffraction. The coatings are found to consist of a mixture of gamma, delta and zeta phases, of which delta is the main constituent. The amounts of each phase influences the powdering resistance of the coating which was evaluated using reverse Olsen testing and 60" bending. For the three heat input conditions considered, IF coatings were always found to contain a significant amount of gamma and only those which retained zeta phase on the surface exhibited a satisfactory powdering resistance. In much the same way, ELC coatings with relatively thick gamma layers performed satisfactorily only when some zeta was retained. It was also found, however, that coatings with minimal zeta and gamma had an excellent powdering resistance. The latter coatings were produced under galvannealing conditions of lower relative heat input. These results indicate that in addition to the zinc bath composition, coating weight and galvanneal thermal cycle, the base steel chemistry also has an effect on the coating microstructure. Knowledge and control of all aspects of galvannealing is therefore essential to consistently produce acceptable coatings.

Jan 1, 1992

By Richard P. Curtin, John M. Goris, Lewis A. Martin

Cable bolt supports are being recognized as an effective ground control system in under-ground coal mines in North America, and their use has increased considerably during the past few years. The U.S. Bureau of Mines personnel are conducting both laboratory and field tests to evaluate the performance of these supports under a variety of conditions and to establish realistic design guidelines. This paper describes efforts to evaluate the capability of cable bolts to resist the high shear forces often present in longwall operations. Shear tests were conducted on pairs of 0.025 m3 (0.88 cu. ft) concrete blocks having joint surfaces ranging from rough to smooth. Tests were conducted on blocks both with and without reinforcement with 15.2 mm (0.6 in.) diameter steel cables. During each shear test, the loads and displacements along the normal and shear axes, as well as loads on the cable, were monitored. Cableloads were determined using strain gauges attached to the outside surfaces of the barrel-and-wedge anchors used for pretensioning the cables. Test results show that a cable bolt placed across a joint more than doubled shear resistance of shear blocks having both smooth and rough joints.

Jan 1, 1996

By B. K. Mishra

The motion of the charge inside a grinding mill is of considerable practical importance. The dynamics of grinding mills have been the subject of study by a number of workers because it can accurately predict: i) the power drawn by the mill, ii) the distribution of forces inside the mill, and hence the wear rate of balls as well as the liners, and iii) mass transport of milled product through the porous ball charge. Some of the earlier analyses of the motion of a charge of particulate material in a tumbling mill were reported by White (1904), Davis (1919), and Dyer (1945) and have been reviewed by Rose and Sullivan (1958). In these works, frictional force at the wall of the mill and between the colliding balls, and the interaction of different ball trajectories, was not considered. Moreover, it was assumed that the profile of the tumbling charge is independent of the degree of filling, which is generally not true. However, all this work led to the identification of so-called "equilibrium surface" which is the plane that separates the rotating charge into two regions. The inner region is static; here there is no motion relative to the mill shell. The other region is a shear region where either the balls flow down the surface of the charge (cascading motion), or are projected out of the surface and follow approximately parabolic paths (cataracting motion).

Jan 1, 1990

By A. Danaei, A. McLean, M. Barati, C. Ravindran

"The aluminum industry generates about 90 million tonnes of red mud each year. Previous research shows it could be utilized as a refining flux with a high capacity to absorb phosphorus and sulphur from hot metal in the steel industry. The present study was undertaken to evaluate the melting properties of such fluxes, as it affects the effectiveness of the flux. The results show that the melting behavior of red mud is strongly affected by lime addition and the characteristic melting/softening temperatures reach minimum VALUES (at 32.7 wt% CaO. From these findings, a correlation was established between melting behavior and optical basicity. This allows one to adjust the composition of the flux based on the process requirements. INTRODUCTIONThe aluminum industry generates about 90 million tonnes of bauxite residues each year. This residue is usually red in color because it contains a substantial amount of iron oxide. The red mud, as it is called, is a solid waste with a high concentration of sodium oxide, high pH (10 to 13), and high alkalinity, and thus is harmful to many forms of life. Traditionally, the material is stored in large tailings ponds within the plant’s vicinity (Power, Grafe, & Klauber, 2009). Development of solutions for safe disposal or preferably using this residue for other industrial processes or applications could help restore polluted locations and eliminate a negative impact on the environment (Haake, 1988; Power et al., 2009; Yan & Xuegong, 2010).The mineralogy and chemical composition of red mud depends on the quality of the bauxite and refining process parameters. In general, it consists of iron oxide (Fe2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), sodium oxide (Na2O), silicon oxide (SiO2), and calcium oxide (CaO) (Power et al., 2009). Like most ores and soils, bauxite can contain trace quantities of metals such as arsenic, beryllium, cadmium, chromium, lead, manganese, mercury, nickel, and naturally-occurring radioactive materials, such as thorium and uranium. Most of these trace elements stay in the residue (Power et al., 2009)."

Jan 1, 2012

By Hung-Kei H. Lam

Rubidium and cesium were discovered by Bunsen and Kirchhoff about 100 years ago. These two elements are by no means as abundant as sodium or potassium. Their occurrence in minerals is widespread, but usually as minor constituents. There is no known specific ore containing rubidium, but rubidium is found replacing the. other alkali metals in .some minerals.. Perhaps the highest concentration of rubidium found in one mineral is in lepidolite, KLi(OH,F)2A12Si3010, which contains from 0 to 3.5%*Rb20. 0n the average, lepidolite contains about 0.5% Rb20. Other sources of rubidium are carnallite, KMgCl3?6H20; pollucite, H20.2Cs20.2AI203.9SiO2; rhodizite, R20.2A1203-3B203; biotite, H2K(Mg,Fe)3A1(Si04)3; sea water, rivers, marine and fresh water organisms, soils, and plants. Cesium, even though it is the least abundant. of the stable alkalies, has a specific ore. Pollucites a hydrous cesium aluminum silicate, may con¬tain as high as 42.5% Cs20, although again, the average Cs20 content is about 25% among the handful of known deposits. Other cesium-containing minerals are lepidolite and carnallite. Rubidium and cesium are very much like potassium in chemical properties, consequently, they are hard to separate. Because of the difficulty in obtaining pure cesium and rubidium compounds coupled with the scarcity-of supply, prices were high and the two elements enjoyed little industrial use. Just before the Second World War, the world. supply of rubidium and cesium, from Germany, was a matter of tens of kilograms per year and prices were about

Jan 1, 1959

By Mikiya Tanaka, Mikio Kobayashi, Mansour A. S. A1Ghamdi, Kenji Tatsumi, Yukinori Saiki, Hirotaka Senba

"In order to recover nickel ion in a spent electroless nickel - phosphorus alloy plating bath and, at the same time, to remove impurities such as iron and zinc, the applicability of solvent extraction with LlX84I as the extractant has been investigated using actual spent solution. Although the extraction efficiency of nickel from the spent solution is considerably lower than that from the nickel sulfate-nitrate solution, nickel in the spent solution is selectively extracted with high efficiency at the pH of 6 - 7. The extracted nickel is effectively stripped by sulfuric acid at a pH of less .than· 3. On the basis of these results, a· flowsheet for recovering nickel from the spent solution is proposed Chemical equilibrium calculations of the spent solution has shown that the complex formations of nickel with anions such as lactate and phosphonate ions become predominant in the pH range between 2 and 6. This results in the depression of nickel extraction efficiency from the spent solution as compared with that from the .nickel sulfate-nitrate solution. By combining these aqueous equilibrium calculations with the· extraction model considering the extraction stoichiometry and the aggregation of the extractant in the organic phase, the extraction behavior of nickel is quantitatively predicted.IntroductionElectroless plating is indispensable for the recent advanced industries such as the electronic and mechanical industries. Electroless plating baths are repeatedly used by supplying the metal salts; however, the accumulation of the counter anions of the metal ions, the components formed by the oxidation of the reducing reagents in the plating baths, and the metal ions as impurities dissolved from the surface of the objective materials degrades the· quality of the plating. Thus, the baths are finally treated by a precipitation method to form a large amount of metal sludge, which is disposed in dumping sites. Therefore, from the standpoints of environmental protection and resource preservation, it is highly desired to establish a recycling process of the plating baths with minimum emission. Solvent extraction seems to be one of the 'suitable methods to recover metals from the spent electroless plating baths, because the concentration of the metal ion in the baths is relatively high, which is advantageous to solvent extraction as compared with the ion-exchange and adsorption methods. Some studies about the application of solvent extraction have already been carried out using simulated spe11t electroless plating baths [1-3]."

Jan 1, 2000

By E. Divers

This Bureau of Mines report presents results of an underground evaluation to determine the respirable dust and gas control effectiveness of a combined (push-pull) face ventilation system for coal mines. The system utilizes both blowing and exhaust curtain, continuous miners equipped with radio remote control, and flight conveyors. Bureau of Mines tests showed a 97% reduction in respirable dust concentrations from the usual cab position on the continuous miner to the remote control operator's position. This allowed the remote control operator to be well within, and the usual cab position to exceed, Federal respirable dust standards. Tests utilizing a safe tracer gas, sulfur hexafluoride (SF6), to determine the face ventilation effectiveness of the combined blowing and exhaust system showed that the system also has excellent methane dispersion capability. Where wide entries permit, this combined face ventilation system and use of remote control can be a very effective method for dust and gas control.

Jan 1, 1982

A prototype EM Location System was fabricated and tested at the Geneva Mine near Dragerton, Utah. This system consisted of six manpack transmitters and six manpack receivers covering the frequency band from 900 Hz to 2900 Hz as well as a six channel receiver designed for use in a helicopter. Tests showed that EM signals from lightweight (314 lb) transmitters could be detected both on the surface and from a helicopter through -2 as much as 1650 ft of relatively high conductivity (2 X 10 mhos/m) over- burden. Furthermore, the resulting field strength profiles could be used to determine source location to within 150 ft of the actual surveyed location in the mine. Modifications were made to a Monitoring, Locating and Communications System being tested at the Bruceton Mine, Pittsburgh, Pennsylvania. These modifications have improved the performance and quality of the paging and voice telephony mode of the system. Subsurface receiver modifications have improved reception of voice downlink signals.

Jan 7, 1973

By G. Kugler, M. Tercelj

"The 1.2690 high alloyed tool steel is usually applied for cold working and is alloyed with carbide-forming elements Cr, V, W and Mo. It exhibits very poor hot deformability. Since there is no enough available data in literature for elucidation of this problem, hot workability and development of microstructure during hot deformation was studied. Hot compression tests were carried out in temperature range 850-1150 °C and strain rates range 0.001-6 s-1. SEM and OM were used for observation of microstructure. Results revealed very complex precipitation of carbides that depends on deformation temperature as well as on strain rate. It was found that especially at lower temperatures of hot working range the precipitation of carbides strongly depends on strain rate. Three different hot deformation behaviors’ were observed depending on temperature and strain rate range.IntroductionThe hot workability of highly alloyed high speed steels is usually described as relatively poor in comparison to other steels due to their tendency of cracking during hot working especially when inappropriate hot working conditions are applied. Alloying elements such as Cr, W, Mo and V in ledeburitic tool steels form carbides that improve hardenability, strength, hardness, wear resistance, etc., but they decrease hot workability and narrow hot working temperature range in comparison to conventional steels. The size, distribution, type and fraction of carbides, as well as the thermomechanical history of material and hot working parameters have major influence on the hot workability. The microstructure of ledeburitic tool steels during hot deformation can be characterized as a two-phase system consisting of an austenite matrix and a combination of ledeburitic carbides [1-4]. In the soft-annealed condition the total volume fraction of carbides is in the range 19-30% and in the quenched condition in the range 9-25%, depending on the chemical composition. During heating before deformation a large quantity of carbides dissolve, but non-dissolved carbides can have an extremely diverse influence on the hot workability due to variations in their composition, size, distribution, hardness and shape, and their different behavior during the deformation phase [5-7]."

Jan 1, 2011

By Arne Landsberg

The Bureau of Mines has undertaken research to elucidate the chemistry involved in the efficient recovery and control of minor elements in base metal smelting operations. These elements should be effectively recovered not only because they have commercial value, but also because of their potential hazard to workers' health and the environment, if they are not controlled during processing. Cadmium, a minor metal in zinc ores, is the subject of this report. The roasting step of the complex zinc-smelting process was chosen for investigation because of the high potential for removing cadmium by volatilization during this primary stage. Commercial roaster feed materials were used to determine the sequence of reactions and the effect of these reactions on the volatilization of cadmium. Electron microprobe examination of both the commercial roaster product and oxidized sulfide solid solutions prepared in the laboratory showed that oxidized iron was of prime importance in preventing cadmium volatilization. The mechanism by which iron prevents cadmium volatilization is proposed, and a preheating technique is recommended for more effectively recovering cadmium prior to roasting.

Jan 1, 1981

By Bruno Michaux, Markus Reuter, Martin Rudolph

"It is relatively well-established in the literature that the flotation of calcium minerals using fatty acids as collector is very sensitive to the process water composition. In particular, hard waters have often been reported to strongly reduce the target mineral recoveries due to the formation of insoluble compounds such as calcium and / or magnesium dioleate, thus reducing the amount of collector available for adsorption onto the mineral surface. In this study, the flotation of a fluorite pre-concentrate was performed with tall oil, an industrial collector essentially containing fatty acids. The tests were performed in a variety of synthetic waters to simulate multiple degrees of water hardness, and to differentiate the role of magnesium and calcium ions on the flotation performance. The flotation tests revealed that, under the studied conditions, a significant difference between flotation in calcium-rich and magnesium-rich waters was observed, suggesting strong ion-specific effects in the system. Specifically, calcium-rich waters slightly improved the fluorite recovery, whereas magnesium-rich waters caused a decrease in recovery by as much as 20%. This paper is focused on the flotation kinetics aspect of the system. This approach highlighted the interesting finding that calcium ions did not simply increase the fluorite recovery, but also significantly increased its flotation kinetics. The magnesium ions, on the other hand, had the exact opposite effect.INTRODUCTIONAs the mining industry is facing an increasing number of issues related to its fresh water consumption, the idea of using alternative water sources for mineral beneficiation is gaining significant momentum. As a result, a proper understanding of the role of water chemistry in flotation is becoming more and more urgent, leading to an increasing number of studies on this topic."

Jan 1, 2018

By E. Açma

Sivas-Divrigi flotation plant has a capacity of 90,000 tpy. Beneficiation of the tailings of iron ore magnetic separator seems to be attractive, because of its Cu, Co, and Ni contents. In the experimental work, sulfidic flotation concentrate is produced from these tailings. A roasting-leaching-H2S precipitation procedure is used to treat this concentrate, containing 0.55% Cu, 0.51% Co, 0.74% Ni, and 0.027% Zn. Sulfatizing roasting is carried out in a rotary furnace at 690°C. Roasted product is leached with 10 gpl HzSOl at 70°C and 30% pulp density. For the precipitation of desired metal, H2S is bubbled through the concentrated solution of repeated leaching, under controlled temperature and pH. Final metal recoveries of 91% Cu, 91% Co, and 50% Ni, and 92% Zn are attained. Roasting gases with their 13% SO2 content are suitable for H2SO4 production and the leach residues can be integrated with the iron ore processing plant as they contain 57.4% Fe and very low non-ferrous metals.

Jan 1, 1993

By Cang Daqiang, Li Yu, Liu Xiaoming, Zong Yanbin

"Utilization of high-quality heat in melting slag is a great challenge for iron and steel industry. In the paper, a new method is put forward to concurrently utilize heat and slag by converting the melting slag directly into high valued materials, slag glass-ceramic. A glassceramic with a higher basicity of 0.7 than traditional basicity of 0.45 was prepared from steelmaking slag in order to utilize more hot melting slag. Effects of Alz03 on its crystallization processes were researched by XRF, DTA, XRD and SEM. Results show that Alz03 in glassceramic would have great effected on its property. When the Alz03 content ranges within 12%-15%, glass-ceramics with basicity of0.7 could reach the best performances. The change of dominant phase in glass ceramics from akermanite and wollastonite to akermanite and gehlenite would significantly degrade its mechanical property. An increase of Al2O3 content leads to a rise of the viscosity and crystallization activation energy of the glass, while results in increasing sintering temperature and crystallization temperature of glass, which contributed to its fully crystallization and densification process.IntroductionSteel slag is a by-product under a process of converting iron to steel at above 1600°C, and 0.1-0.15 ton molten steel slag would be discharged for producing per ton of steel in the process. The discharged steel slag at 1600°C has heat of 68 kgce/t. In 2012, China's steel output reached 716 million tons, and produces about 100 million tons of steel slag and 68,000 tee of heat in it [1,2]. But at present, utilization of both slag and its heat at 1600°C is a great challenge for iron and steel industry.Dry granulation of melting steel slag by air and then recovering the heat of the hot air are a traditional technology which have not yet been put into practice for very low heat conductivity of the slag and low efficient of heat exchange among the different processes [3,4]. Therefore, a new method for high efficient utilization of both steel slag and its high temperature sensible heat is put forward [5,6], which is on-line reducing and extracting iron from molten steel slag and then directly preparing glass-ceramic by use of the residual molten slag."

Jan 1, 2014

By M. J. Ferrante

Relative enthalpies of high-purity disodium hexatitanate (Na2Ti6013) were measured at the Bureau of Mines to provide new thermodynamic data needed to advance the technology of materials. Measurements from 298.15 to 1,478 K were made by drop calorimetry with a copper block. Tabulated values are listed for the standard relative enthalpy, heat capacity, en-tropy, and Gibbs energy function between 298.15 and 1,500 K. Enthalpy data are also given in equation form and are combined with thermodynamic data from the literature to derive values of standard enthalpies of formation, Gibbs energies of formation, and logarithms of the equilibrium constants of formation. Similar calculations were made for the reaction of Na20 with Ti02.

Jan 1, 1986