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By R. M. Damodaran

The flotation performance of Florida phosphate rock was evaluated in terms of the mixing behavior of reagents with particulates during anionic conditioning of phosphate slurries. The various conditioning variables that influence mixing, namely, solids loading, agitation speed and the conditioning time were investigated to determine their effect on reagent coating on the particles. The phosphate recovery was used to monitor the conditioning efficiency. The mixing characteristics of the phosphate feed were evaluated in terms of the ratio of the mixing power P, to the minimum power Pm' required to keep the slurry in suspension. It was found that mixing conditions govern the conditioning time required to obtain high recovery. Reagentization was slower at lower P /P m ratios. At higher P /P m ratios, the flotation recovery was optimized and the agitation speed was found to have no significant effect on it. Optimum mixing conditions were obtained for a 74 wt% slurry at an agitation speed of 450 (47 rad/s) rpm. Under the optimum conditions of mixing, recovery was improved at low collector dosages and short conditioning times.

Jan 1, 1995

By Edward L. Burwell

The Bureau of Mines conducted laboratory experiments to determine the change during retorting in the apparent permeability and the degree of compaction of beds of broken oil shale. Grades of oil shale studied ranged from 20.6 to 46.7 gallons of oil per ton (gpt), and the simulated overburden pressures applied to the shale were from 300 to 900 psi. Linear regression analysis of the data produced equations describing the response of the oil shale. Oil shales of approximately 20 gpt experience only minor apparent permeability reductions under test conditions, but richer shales (30 to 50 gpt) lose essentially all permeability. The permeability reductions were accompanied by corresponding decreases in bed height that ranged up to 37 percent of the original bed height.

Jan 1, 1974

By Lucy van de Ruit, Megan Becker, Aubrey Mainza, Jenny Wiese

"UG2 chromitite ore is a complex, highly disseminated platinum ore from the Bushveld Complex in South Africa, with typical platinum group mineral (PGM) grain sizes below 15µm. The introduction of stirred mills to the platinum industry has enabled grinding to finer product sizes, which has improved liberation and recovery of the finely grained PGMs. However, reduction in particle size leads to an increase in chromite entrainment in the flotation concentrate, which has a negative impact on the subsequent smelting process. Factors such as particle size, froth structure, solids concentration and water recovery have all been identified as impacting entrainment, but whether particle shape also has a significant effect is unclear. The purpose of this study was to determine whether the recovery of chromite particles by entrainment during the flotation of UG2 ore is affected by particle morphology. A laboratory vertical stirred mill with inert ceramic media was used for grinding UG2 ore which was then floated in a batch flotation cell. Flotation feed and concentrate samples were analyzed using QEMSCAN to quantify the angularity and aspect ratio distributions of the particles. The stirred mill product was found to have relatively broad aspect ratio and angularity distributions, with the major mineral components (chromite and silicates) having very similar shape characteristics. Analysis of flotation feed and concentrate samples suggested that particle shape does not have a significant effect on chromite entrainment."

Jan 1, 2014

By James R. Craig

The General Image Processing System (GIPSY) is being employed for the quantitative textural analysis of complex sulfide ores from the Southern and Central Appalachians and for the determination of liberation characteristics of the mineral constituents during grinding. Optical images from a microscope-mounted TV camera or from 35mm film are converted into digital images which are subsequently analyzed by GIPSY, a transportable image processing software package. Properties measured by GIPSY include spatial distribution of mineral constituents, grain sizes, grain shapes, grain orientation and mineral co-occurrences.

Jan 1, 1982

By P. Condori

Palabora Mining Copper (PMC) has two autogenous mills that have been in operation since 1976. The mills were originally designed to treat 30 000 t/d of open cast copper ore in a closed circuit with cyclones. As the ore body went deeper the open cast method of mining was changed to block caving, a consequence of this was the dolerite content (hardest barren material) increased significantly, increasing the production rate of pebbles and thus reducing the milling capacity. In order to cope with the increased ore hardness and to increase mill capacity, a second ball milling stage and pebble crushing were incorporated to the circuit. The above actions created new challenges to the circuit operation and bottlenecks in different areas of the milling circuit. This paper reports the holistic work performed on the Palabora autogenous milling circuit including the implementation of a mill constraint control scheme, the implementation of a pebble removal system from the circuit and a new circuit configuration. The achieved plant stability and increment of ore throughput are also reported in this paper.

Jan 1, 2012

By C. J. Chindgren

A refractory-lined, garage-type automobile incinerator with a natural gas afterburner for air pollution control was cooperatively constructed and tested by the Bureau of Mines and the Wasatch Metal & Salvage Co. in Salt Lake City, Utah. The incinerator is capable of relatively smokeless burning of 32 to 60 cars per day, dependent on the degree to which the cars are stripped prior to incineration. Preliminary burning campaigns indicate the cost of incineration to be approximately $2.75 per car.

Jan 1, 1970

By John B. Gayle

During studies of the various methods for determining and specifying the factors that indicate whether a particular coke is better or worse than other cokes for metallurgical uses, questions arose as to the precision of screen-analysis tests on coke. Although the usual index of precision, the standard deviation of the test result, gives a measure of the precision of these data, the experimental determination of the standard deviation for a particular set of conditions requires tests on a large number of duplicate samples. Because this procedure necessaily involves a great deal of labor, an equation for predicting standard deviations from theoretical considerations has been developed. Results predicted with this equation agree satisfactorily with the experimental values and are applicable to tests on coal, coke, gravel, and other bulk materials.

Jan 1, 1952

By Jorge Alberto Soares Tenório, Denise Crocce Romano Espinosa, Kellie Provazi

"The purpose of this paper is to study metal separation and recovery from a sample composed of a mixture of the spent household batteries main types, using liquid-liquid extraction and metals electroplating. The electrolytes preparation consisted: grinding the waste of mixed batteries, reduction and volatile metals elimination using electric furnace and acid leaching. From this solution were studied the liquid-liquid extraction using Cyanex 272 [bis(2,4,4-trimethylpentyl) phosphoric acid] with tributyl phosphate as extracting agent. After study of solvent extraction and stripping has been recover and separate the metallic ions and with electroplating was recovered the manganese, copper, nickel and cobalt in their metallic forms.IntroductionCurrently has increased the consumption of electronics devices such as mobile phones, laptops, wireless phones, comcorders, etc., especially portable devices that use batteries as a power source, and consequently has increased the disposal of such material.Increased consumption of this devices is caused by several factors including increased popularity of consumer electronics devices, has become essential of modem life. Therefore, recycling of batteries is important because its reduces the waste of raw materias and nonrenewable resouces used in manufacturing these materias and help prevent potential environmental risks associated with improper disposal of these products together with household garbage.The batteries have a very diverse composition, containing metals such as zinc, lithium, nickel, lead, mercury, cobalt, cadmium, iron, copper, manganese and rare earths. Some components may contain hazardous materials such as cadmium, mercury and lead, and can contain acids or bases.This research line is a pioneer in dealing with a single process for recycling a mixture with all batteries types, for only processes that exist in the world are based on the recycling a mixture with all types of batteries, for only processes that exist in the world are based on the recycling of one or two types of batteries [1-4]. This process necessitates the previous separation of the batteries by type."

Jan 1, 2012

By Wei Wang

The SMCO copper plant is located in DR Congo, and was designed by China NERIN Engineering Co., Ltd. The process is a typical hydrometallurgical plant with Leach-SX-EW, with the project treating the oxide minerals with agitation leaching, followed with three stage of solvent extraction and two stages of stripping, and using permanent SS cathodes to produce LME grade copper. Because of the special characteristic of the ore, what contains 2 different type of oxides (one high carbonate oxide and the other low carbonate), there are several new technical measures that have been developed and adopted for the plant. For example, different grinding, leaching, and filtering are used to treat different oxides. This paper, presents the project process, engineering design, construction and commissioning. The paper also describes some of the problems encountered during plant commissioning, such as the agitation leaching tank issues, and corrosion in the settler-mixer. This paper discusses some NERIN solutions to these problems, and explains the use of the CN filter, which is used to filter PLS to treat high level suspend solids, instead of the traditional sand filter. Finally, this paper also proposes steps / measures for further improvement for future plant operation.

Jan 1, 2014

By V. I. Lakshmanan

Recycling helps to save energy and is good for the environment. It is also important for preserving the limited natural resources. In addition, recycling creates economic benefits and frees up space at the landfill sites. Process Research Ortech Inc. (PRO) has conducted extensive testwork in the area of waste processing and recycling. A process was developed for the recovery of Zinc from galvanized steel by alkaline leaching followed by solvent extraction and electrowinning. Extensive testwork has been conducted at PRO to obtain a useful by-product from rice husk. Rice husk was combusted in a gas/solid reactor to obtain an environmentally acceptable amorphous silica ash suitable for use in high strength concrete. In another development, vanadium was recovered from fly ash by separating carbon first, followed by alkaline pressure leaching, solvent extraction and precipitation. PRO has also developed an environment friendly process for treatment of industrial wastewater for its reuse to obtain zero or minimal effluent discharge. In this paper, four case studies related to recycling of zinc scrap, controlled combustion of rice husk, processing of fly ash, and reuse of waste water will be discussed.

Jan 1, 2011

By T. J. Ballard, Austin B. Clayton

"The Union Copper mine is in the Gold Hill district, Rowan and Cabarrus Counties, N. C.The mine was discovered in 1799 and first worked as a gold mine; but copper was encountered at depth, and the property became an important producer of copper. It is estimated that the mine produced 5,000,000 pounds of copper before operations were discontinued in 1907.As part of the strategic minerals program, the Bureau of Mines conducted a development project on the property from July 1943 to November 1943. Eight diamond-drill holes, totaling 2,500 linear feet, were drilled to delineate the ore body. Analyses of 205 core samples were made.Tabulations of sample analyses and drill-hole logs are presented in this report.The project work embodied in this report was under the immediate supervision of Austin B. Clayton, project engineer, and the general supervision of H. B. Ewoldt, district engineer for North Carolina and Tennessee. The preliminary report, written by Austin B. Clayton, was revised and the various figures redrawn for publication by T. J. Ballard under the general supervision of M. H. Kline, chief, Raleigh Branch, Mining Division.Acknowledgment is due the Metallurgical Branch for analytical determinations of the samples.The mine property is 1.5 miles southwest of the village of Gold. Hill, N. C. (fig. 1). Gold Hill is on U. S. Highway 52 between Salisbury and Albemarle and on a branch line of the Southern Railway. The latitude is 350 30' and longitude 80° 21 The tract consists of 553-1/2 acres in Cabarrus and Rowan Counties.A tentative list of the surface-rights ownership is as follows: William Hoy Barringer - 16 acres, A. W. Tucker - 1 acre, Frank Wagoner - 4 acres, and George Barringer - 3-1/2 acres, in Cabarrus County; A. W. Tucker - 2 acres, H. N. Hedrick - 54 acres, and William Atkins - 473 acres, in, Rowan County, N. C.The mineral rights are owned by Alfred Rossiter, Alice R. Hesslein? and the estate of the late Bella Rosenblatt. The attorneys for the owners are Neidle & Taylor, 6 East 45th Street, New York City.The Union Copper mine is in the Cold Hill mining district of North Carolina where gold was first discovered in 1799. The upper parts of the veins in the district were first worked for gold; however, the increase in the sulfide content of the veins with depth rendered the amalgamation process for gold recovery ineffective, and the mines were closed.The period of greatest activity at the Union Copper mine was from 1899 to 1906. At an earlier period the oxidized and leached part of the lode near the surface was mined from a working known as the ""big cut,"" the reported yield of which was $300,000 in gold.3/ The mine has not been operated since 1907.J. T. Pardee3/ lists the probable value of the production of the Union Copper mine as $1,050,000, of which about $675,000 was the value of some 5,000,000 pounds of copper produced."

Oct 1, 1948

By Kevin Andrews, Scott Nelson, Terry Hamrick

"In the process of Geologic Hazard Mapping (GHM) for underground coal mining, geologists evaluate the effects of various geologic and geotechnical conditions to assist with optimization of mine productivity and with selection of more favorable areas for future development. The methodology involves correlation of multiple geologic factors (such as overburden depth, proximity to sandstone channels, and areas with weak immediate roof strata) with conditions encountered during mining (roof falls, floor heave, pillar spalling, etc.). Such studies yield maps that identify areas where mining is likely to be difficult and allow mining engineers to foresee favorable and unfavorable mining areas when planning new or expanding mines. To expand the benefits of GHM, work has been done to correlate geologic factors with room-and-pillar mining advance rates. Average mining advance rates are mapped and then correlated to different areas, as characterized by GHM. This process exposes the geological characteristics that have a material impact on mining rates of advance, improving the rates of advance into future mining areas with similar geological conditions. The final result of the work allows mine planners to not only design the mine qualitatively accounting for areas of unfavorable conditions, but also allows the mine planner to more accurately apply rates of advance for mine timing and production sequencing. The use of GHM to predict mining advance rates in unmined areas enhances the benefits of traditional hazard mapping and provides quantitative data that can be incorporated into mine sequencing models.INTRODUCTIONThe role of a geologist in the coal mining industry has evolved significantly over the last 30 to 40 years. Geologic Hazard Mapping (GHM) mapping for coal mines began in the late 1970s and early 1980s (Chase, Newman, and Rusnak, 2006). Since its beginnings, the GHM process has evolved significantly and continues to take on new levels of sophistication. Numerous case studies of GHM application to predict future mining conditions exist in the literature. For example, Artrip, Nelson, and Newman (1993), documents the geotechnical characterization of roof and floor for mining in the Imboden Seam in Virginia where previous mining efforts had been abandoned due to adverse mining conditions. In addition, Keim and Miller (1999) summarize evaluation of geological influences on a longwall mine in West Virginia. In both examples, significant geotechnical and geological information was available, including the opportunity to compare predicted mining conditions against actual conditions as mining progressed."

Jan 1, 2018

By Masao Miyake, Eiichiro Matsubara, Tetsuji Hirato, Yasuhiro Awakura

"Zn-Cr alloy coating with around 15 wt% Cr has been found to have much higher chemical corrosion-resistance to steel than conventional zinc plating, while· its structure has not been clarified. The Zn-Cr alloy plating is performed at high current densities around 1 A cm-2 and for 10 to 20 sec using acidic aqueous sulfate solutions with some additives in the iron-steel industry. Due to the high current densities, it seems reasonable to consider that the Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings have a non-equilibrium phase and have a structure change in the .direction of thickness. In this research, the crystal structure of the Zn-Cr alloy coating electrodeposited at high current densities and change of the structure in the direction of thickness were examined by X-ray diffraction. The coatings containing under 20 and 35-40 wt% Cr had hcp and bee structure, respectively, while the coatings containing 20-35 wt% Cr comprised two phases with the hcp and the bee structure. The structure of the coating varied in the direction of thickness; both the hcp and bcc phases coexisted in the vicinity of the substrate, while the hcp phase became predominant with increasing distance from the substrate.IntroductionRecently it has been reported that Zn-Cr alloy coating containing around 15 wt% Cr has much higher corrosion-resistance to steel than conventional zinc plating.1-3) The corrosion-resistanc·e of Zn-Cr alloy plated steel sheet with a plating amount of 20 g m·2 is, for example, superior to that of Zn plated steel with a plating amount in the range 60 to 90 g m·2 , which is widely used for automotive bodies today.4l The Zn-Cr alloy plating is obtained by electrodeposition at current densities over 0.5 A cm·2 from a sulfate solution containing zinc and trivalent chromium ions and some additives.5•6) The deposition current densities mentioned above are much higher than those for usual electroplating processes, e.g., Zn, Cu and Ni plating, carried out about 0.05 A cm·2 • Therefore, the time required for plating is very short; around 10-20 sec. Due to the high current densities, it seems reasonable to consider that the· Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings do not have a phase expected from equilibrium diagrams; no phase diagram of the Zn-Cr system with a full composition range has been available. 7). In other words, the alloy phase plated would be a non-equilibrium phase with unknown structures."

Jan 1, 2000

By Maribel Guzmán Córdova

Ante la problemática del tratamiento de drenajes ácidos de mina (DAM) se ha previsto solucionarlo a través del uso de tecnologías convencionales existentes como la precipitación química, osmosis inversa, intercambio iónico y separación por membranas. Sin embargo, estas técnicas presentan significativas desventajas como son los requerimientos de reactivos y costos de energía; además de la generación de lodos tóxicos. En este sentido, el presente texto describe el uso de “lodos activados”- en tanto materiales de desecho que procedentes de un proceso industrial, pueden remover metales pesados de un drenaje ácido de mina,

Sep 14, 2009

This paper describes results of an investigation of fracture during tube expansion of 5052 and 5754 aluminum seam-welded tubes to optimize the forming of aluminum tubes during hydroforming. The tubes were produced in laboratory by press forming of tubular blanks and pilot-scale high frequency induction welding. The effect of property mismatch between the weld and base metal has been investigated. The material work-hardening was obtained by roll forming of sheet blanks in the 0-temper and H32 temper condition. The results showed that a significant work-hardening can be present in aluminum tube without causing weld fracture during tube expansion. The work-hardening increases the yield-strength mismatch between base metal and weld. Annealing reduces the hardness of base metal leading to more uniform deformation during tube expansion. As a result the occurrence of weld fracture is reduced. The study showed significant deformation of the welds during tube expansion. Weld thinning can be as large as parent-material thinning before fracture. To avoid fracture at the weld joint, good formability and high yield strength of the weld is needed. FEM simulation showed that minimizing the width of the weld joint can reduce thinning of the weld.

Jan 1, 2004

By Ralph L. Merklin

One of the most commonly employed set of calculations in mill design and research is the material balance, known in wet beneficiation plants, as an Ore and Water Balance. For mill designers, the balance is one of the principal requirements in determining the proper size of launders, pipelines, process equipment, etc. In process development, one of the major goals is the establishment of an optimum balance. The usual procedure for calculating a material balance involves a manual technique utilizing reference tables, pre -obtained data, and a slide rule or desk calculator. With these, the engineer must perform a series of calculations which are repetitious in nature and time consuming. Figure I is the flowsheet of the grinding and flotation circuits for a copper concentrator. The initial ore and water balance was calculated manually and required approximately 24 manhours. Later, a number of changes were made in the balance, each of which required an average of 8 manhours.

Jan 1, 1967

By David G. Dixon

A mathematical model is derived in dimensionless form which simulates the effluent concentration response of reagents from spent heaps under both fresh and recycled water rinsing. The model is based on dispersion from isochoric pathways distributed in length and cross-section, oriented normal to convection channels in ideal plug flow. The effects of heap height, rinsate flow, and initial reagent concentration are examined. It is shown that the rinsing cycle undergoes a distinct shift between fast and slow rinsing at a certain time depending on the amount of stagnant solution in the heap, and the distribution of dispersion pathways. Results of preliminary column rinsing tests on both agglomerated and unagglomerated ores are presented which partially validate the model.

Jan 1, 1994

By James E. Palmer

Geologic constraints on mining and recoverability include the following: coal seams too thin or thick for conventional mining methods; coal seams with insufficient stratigraphic separation; unstable roof or floor strata; discontinuous or lenticular seams; coal seams that have high dips or are intensely faulted; water problems due to proximity of aquifers; and coal quality problems such as excessive sulfur, ash, chlorine, sodium, etc. The demonstrated reserve base for western coal of 220 billion tons is considered misleading as it does not adequately incorporate the above parameters in estimating procedures. Current reserve base estimating procedures involve an abstraction of data from generalized resource estimates. The authors believe the reserve base should be determined independently beginning with well-known deposits, with all mining and recoverability constraints fully incorporated.

Jan 1, 1981

By Y. Luo

Although considerable progress has been made in the last decade in predicting surface subsidence over longwall panels, a number of important issues deserve further studies in order to improve the techniques and accuracy of subsidence predictions. Some of the problems are: (1) subsidence over the chain pillars between mined longwall panels; (2) subsidence development process after face stop due to either a vacation or the completion of a longwall panel; and (3) subsidence initiation and development process over the setup entry area in the initial stage of mining a longwall panel. In this paper, the measured data related to the targeted problems are presented, the data analysis techniques are briefly introduced, and some of the prediction methods developed based on the collected data are proposed. The proposed methods can be used as supplemental tools for the existing subsidence prediction models to improve their prediction accuracy.

Jan 1, 1991

By W. Kobal

The extraction of nickel (Ni) and cobalt (Co) from the laterite deposit of Ramu nickel-cobalt Project in Papua New Guinea was performed in this study. Chemical analysis by Inductively Coupled Plasma (ICP-AES) atomic emission spectrometer, SPS-3000 (Seiko Instruments (Inc.), shows the ore contains 48% Fe, 1% Ni, 0.1% Co, 1.8% Al, 0.14% Mg, and 0.8% Mn. Characterization by X-ray diffraction (XRD) analysis of the laterite ore obtained from the mine site shows the ore contains 70 to 80% goethite (FeOOH), assuming Fe content of 48% is mainly from geothite. The main leaching parameters investigated include; slurry temperature, leaching time and sulphuric acid (H2SO4) concentration to evaluate nickel and cobalt extraction. For all experiments, 10g batch samples are put into 300 ml beaker containing 100 ml of sulphuric acid of varying concentrations (1M, 2M, 4M). During the leaching period, 5 ml slurry samples are withdrawn at different times and filtered to obtain filtrate for ICP analysis to monitor nickel and cobalt extraction. Solid samples at the end of all tests are also obtained by filtration and after drying, XRD and ICP tests are performed to monitor nickel and cobalt contents. According to the test results performed at normal atmospheric pressure, over 99% of nickel and over 50% cobalt were extracted into solution within 120 min at 95ºC in 2M H2SO4 solution. Similar results were obtained when only temperature was reduced to 90ºC, but cobalt extraction increased to over 70% when leaching time was increased to 240 min. Further reduction in temperature to 80 and 60ºC resulted in reduction of nickel and cobalt extraction. At the end of each leaching test, magnetite was seen to attach to magnetic stirrer. The study showed nickel can be completely leached into solution but cobalt only up to 70%. Keywords: atmospheric pressure, sulphuric acid leaching, nickel laterite

Sep 1, 2012