Search Documents

By P. R. Taylor

Titanium carbide and titanium diboride powders have been successfully synthesized by direct treatment of ilmenite concentrates in a non-transferred arc thermal plasma reactor. Methane gas was used as the reducing agent and boron oxide was used as the boron source in these processes. Free energy minimization plots were used to predict the behavior of each system under different molar ratios and operating conditions. Products were characterized by XRD, SEM and chemical analytical techniques. The average size of the ceramic product is in the submicron range. Metallic iron apparently is finely deposited on the surface of the titanium carbide or titanium diboride particles. Minor impurities such as silica, manganese and zircon were converted to the carbide form.

Jan 1, 1995

By J. Wiebmer

Some thoroughbred racehorses are great routers (distance runners), others are sprinters. Some racehorses perform best on turf, others on dirt, and some in mud. To be a winner, you have to choose the right horse for the course. It's no different when looking at an electric cable shovel, a hydraulic shovel/excavator, or a wheel loader. Each loading tool has its own zone of application. To be a winner, you have to choose the right horse for your course.

Jan 1, 1993

By Carla Lupi

Zinc electrowinning from sulfate solutions is the traditional industrial method to produce SHG zinc. Over the past few years several efforts have been done to improve process efficiency in order to reach high productivity with low energy requirement. The latter aim can be pursued both by means of a hard purification of the electrolyte and reducing the anodic voltage. This work is a comparative study of the results obtained in several previous researches on zinc electrowinning from both sulfate and chloride solutions. Zinc electrowinning tests on industrial sulfate solution have been carried out by using Pb alloy anodes and by adding organic depolarizers such as ethanol, acetic acid or ethylene glycol. Experiments on chloride solutions, obtained by purification of zinc exhausted electrolyte, have been performed by using DSA anodes and by testing the effect of additives such as TEACI and TBAC\. Comparing the best results obtained with the two methods it can be highlighted that a high quality zinc is electrowon in both cases with comparable energy requirements.

Jan 1, 2000

By N. Arbiter

Evidence for the floatability of sulphide minerals without collector is analyzed and it is shown that results obtained with ores, in contrast to those with single minerals or mineral mixtures, depend on many additional variables, some identified and others not. Because of the prevailing low levels and costs of collectors for most sulphide ores, it is unlikely that collectorless flotation will have commercial applications, so that continued research on the subject may be justifiable on theoretical but not on practical grounds.

Jan 1, 1993

By E. Daniel Baker

"The term ""oxide disseminated gold deposits"" refers to near surface, gold-bearing veins, faults, and shear zones that typically contain appreciable amounts of oxidized ore or gossanous material, resulting from oxidation of sulphides.The concept of oxide gold deposits underwent a dramatic change after the discovery of the Carlin gold mine in north-central Nevada in the early 1960's. Now the term implies large tonnage, low-grade bulk minable deposits that are processed by milling and/or heap leach methods.Oxide gold deposits may now be classified into two types: (1) primacy ores derived directly from the effects of hydrothermal alteration on host rocks, and (2) secondary oxide ores derived from the supergene oxidizing effects of circulating post-mineral meteoric waters on gold-bearing sulphides. Each type of deposit has unique diagnostic mineralogic and metallurgical characteristics that must be addressed to achieve successful exploration strategies and viable metallurgical exploitation.The author would like to thank the management of Newmont Metallurgical Services and Newmont Mining Company for allowing presentation of this paper. Thanks are due Sevkett Acar, Donald M. Hausen, Jerry R. Odekirk, and D. Erik Spiller for their critical review of the manuscript. Also, thanks are extended to all those cited and uncited whose hard work and dedication have led to the discovery and exploitation of near-surface oxide gold deposits. Our knowledge would be greatly limited without the dedication and research of many others."

Jan 1, 1997

By L. Haavanlammi

Iron is a significant component of all copper concentrates leached in the HydroCopperTM process. The metals in the concentrate are leached in a chloride solution by oxidation with cupric ions. Copper enters into the solution as a cuprous chloro¬complex. Iron dissolves at the same time in the ferrous form, but it is immediately oxidized to the ferric state. Oxidation is effected by sparging air or oxygen into the leaching reactors. Because the pH is 1 - 2.5, ferric ion precipitates as akaganeite (T<90°C) or hematite (T> 90°C). Arsenic, antimony and the main part of the bismuth co-precipitate with iron and report to the leach residue. Cupric leaching is faster than iron oxidation; thus, leaching of low-iron concentrates (secondary copper minerals) is quicker than leaching high iron concentrates (chalcopyrite). Pyrite does not dissolve during copper leaching, but is oxidized slowly at higher redox-potentials after the copper has been leached.

Jan 1, 2006

A strategy is presented for a relatively. "low-tech" means for decontamination of streams . containing .low concentrations of toxic metals. Metal ion solutions were . circulate through fluidized beds of activated carbon which support bio-films ?of bacteria .that naturally excrete exopolysaccharides. The attached &apos;biomass is shown to significantly enhance nickel, cadmium and silver extraction from dilute solutions (5- l00mg/l). By heat treating (at 300º C) the metal/biomass/carbon particles, bio-sorbed silver was subsequently fixed to the carbon surface. This approach to metal decontamination may therefore also provide a route for dispersing and fixing catalytic metal particles over an activated carbon surface.

Jan 1, 1991

By C. L. Karr

Researchers at the University of Alabama have developed a method for producing fuzzy linguistic models of mineral processing equipment directly from engineering data. These fuzzy linguistic models rely exclusively on data collected from the processing systems being modeled and do not presuppose an understanding of the physics of the system. The fuzzy linguistic models use descriptive rules and explicit membership functions that provide a precise, nonmathematical description of the processing equipment. A genetic algorithm is employed to simultaneously select rules and tune membership functions used in the fuzzy models. The result is an extremely flexible approach to modelling that is applicable in a variety of linear and nonlinear systems. The effectiveness of this approach to modelling is demonstrated using a four-input, two-output model of a grinding circuit.

Jan 1, 1996

By G. G. Bowser

THE time has come when, as your President, 1 turn the helm over to my worthy successor. When 1 was reminded by our Secretary that 1 had to prepare an address for this meeting, 1 was at a loss for a subject. In the hope of inspiration 1 perused the records of our Society for some years past. 1 found in these records that many problems in need of solution relative to industry in Nova Scotia were discursively dealt with and that sound thought was given to the solution of these problems, with a natural leaning, of course, to problems pertaining to the mining industry. 1 found also that some of the reasoning was remarkably prophetie. Some of these subjects and problems were: The use of pulverized coal to generate power instead of hydro-electric power; rural electrification; the importance of youth training for an efficient place in industry; the proper marketing of coal; the fuels competing with coal; the need for better in-dustrial relations between employer and employee; better education for success in the social field as applied to industry; and Canadian unity. The issue of some of these copies has been forced upon us by war. For instance, there appears to be no marketing problem for coal, nor does there ? seem to be a marketing problem for anything just at present. The problem of the coal producer just now is supply and transportation. Also, at present, coal fe.ars no competitors, such as oil-and not even hardwood. Many large companies now have an industrial Relations or Personnel Manager and department. Furthermore, we have been compelled of necessity to train our young men, and women also, for both industry and war. However, war does not solve these problems and, with the return to normal times, we may be faced with the same troubles in even greater measure. My reason for mentioning these copies is to point out that, as mining men, we are aU desirous of progress in every industry, not only the mining industry; and that mining men are able to see clearly ahead. In normal times, especially in matters not directly affecting the mining industry, we are inclined to let matters take their own good rime, or let the government do it. We do not seem to realize that these necessary and desirable changes can be made in times of peace-instead of being forced upon us by war or other social upheavals-by the method of sound thought and action to the desired end.

Jan 1, 1943

By M. M. Wong

A brief investigation was made to determine the feasibility of electro-refining beryllium in a KCI-LiCI-BeC12 bath. Thin, platelike crystals of beryllium metal were produced by electrolyzing technical-grade beryllium metal beads (about 94-percent purity) as the soluble anode. Operating cell conditions were: Temperatures of 450° to 600° C.; an inert atmosphere; bath compositions of (1) 38.1 mol. percent KC1, 54.8 mol. percent LiCl, and 7.1 mol. percent BeC12 and (2) 36.7 mol. percent KC1, 52.7 mol. percent LiCl, and 10.6 mol. percent BeC12; cell voltages of 0.30 to 0.80; and initial cathode current densities of 50 to 435 a./sq, ft. Current efficiencies ranging from 87 to 96 percent were obtained. Qualitative spectrographic analyses of the metal products indicated that impurities were reduced. This technique offers the possibility of producing a grade of beryllium purer than that now generally available, which may have better mechanical properties.

Jan 1, 1960

By A. D. Davis

The Bear Butte Creek watershed, in the northern Black Hills of South Dakota, shows the effects of past mining activities in the form of dissolved metals and arsenic in stream water. Bear Butte Creek, during normal flow periods, loses all of its discharge to sinkholes that recharge the Madison Limestone aquifer. This work focused on the geochemical transport and fate of arsenic and on understanding ground-water flow conditions in the Madison aquifer through development of a three-dimensional ground-water flow model that was coupled to a geographic information system (GIS). Stream sampling and discharge measurements helped determine sinkhole losses and loading rates. Column laboratory tests provided data on arsenic adsorption and the mixing of stream water with aquifer water, which also was simulated with the geochemical models, pHREEQE and NETPATH. The models and GIS can be updated with new information and will be useful in managing the water quality of the Madison aquifer.

Jan 1, 1997

By Alessandro Boscaro, Daniele Martinelli, Cristina Gabriela Oñate Salazar, Daniele Peila, Carmine Todaro

"The wear phenomenon in TBM machines is not a simple issue, as many parameters are playing an important role on the consumption of the tools during a tunnel excavation. The action of the wear due to the contact with the soil can occur on the excavation tools, on the cutterhead, in the excavating chamber and on the screw conveyor. The test developed at the Laboratory “Tunnelling and Underground Space Center” of the Politecnico di Torino is aimed to reproduce the interaction between the tools and the excavated material, simulating the excavation conditions in terms of soil conditioning and water content. The test, which is not standardized, is studied to evaluate the wear in a global point of view. The present work starts by testing the influence of the use of chemical agents during the conditioning phase on the drop of the wear phenomenon, in terms of metal weight loss. 1. INTRODUCTION The wear phenomenon of the excavation tools used in TBM tunneling machines is playing recently a major role in the design stage of full-section tunnels in both soils and rocks. Concerning EPB excavation technology, the main issue regarding productivity is the wear of its components (Peila et al.,2012), which increases the so called dead time in the whole process. The friction generated between the components and the ground causes the consumption of the tools and other metallic components in contact with the ground, described as primary and secondary wear by Nielsen et al. (2006a). This leads to downtime, with risky and complicated maintenance operations (Peila and Schulkins, 2009), as occurred in recent tunneling works in Liguria (Italy). The study of this argument in granular soils is very delicate, as it encloses not only the properties of the excavation tools, but also the characteristics of the ground to be excavated (hardness, mineralogy composition, shape and dimension of the particles and moisture content). The penetration mechanism is based on the scraping of the ground, by mean of cutting tools, with its consequent consumption. Concerning the rocks, the excavation principle is characterized by crushing the rock mass matrix by applying high compressive stresses through cutting disks. In such a way, to avoid frequent downtimes and their consequent economic losses, it is very important to study this subject and therefore understand and forecast the durability of the components, in order to try to maximize the productivity of the machine by reducing the frequency of maintenance stoppings."

Jan 1, 2016

By Jafar Safarian, Merete Tangstad, Leiv Kolbeinsen

"Silicon and its binary alloys have several applications in metallurgical, chemical, photovoltaic and semiconductor industries. Silicon goes to its liquid state within its production, refining and when it is alloyed with other elements. Therefore, the characterization of silicon melts thermodynamics is important and useful. The liquidus and activities in several silicon binary systems have been recently calculated by the application of two liquidus constants, which were established using the experimentally determined liquidus data. In the present study, the thermodynamic properties of six silicon binary melts, which are simple eutectics, are calculated by analytical approaches. In this case, the changes in the partial and integral Gibbs free energies and enthalpies of mixing are calculated and compared with the experimental data in literature. The enthalpies are calculated by two methods and the calculation results are compared to the data from the literature. It is shown that thermodynamic properties of silicon binary melts can be accurately predicted without the use of complicated thermodynamic software.IntroductionSilicon and its alloys have several industrial applications. Silicon is used for making aluminium-silicon alloys to produce cast parts, mainly for automotive industry. Silicon in the form of ferro-silicon is used to deoxidize and alloy steel and cast iron. The photovoltaic (PV) industry has had a rapid growth in the recent years and silicon is the dominant material used for the fabrication of solar cells. Silicon is primarily produced through carbothermic reduction of quartz in electric arc furnaces and the produced metallurgical grade silicon (MG-Si) contains around 1 wt% impurities. It is further refined to produce solar grade silicon (SoG-Si) with above 99.9999 wt% Si to fulfil the chemical requirement for PV application. Since molten silicon is processed all along the metallurgical route, obtaining fundamental thermodynamics knowledge about silicon melts is valuable for the related industries."

Jan 1, 2012

By A. David Miller, Douglas M. Barber

"The Rocky Mountain Arsenal was used by the military to produce chemical warfare agents and incendiary munitions for use during World War II and later by private companies for the production of industrial and agricultural chemicals. After an investigation performed in accordance with CERCLA confirmed significant levels of contamination due to the common industrial and waste disposal practices of the era and the discovery of over 300 species of wildlife inhabiting the land the Rocky Mountain Arsenal became a wildlife refuge and contamination cleanup efforts began. Three lime basins originally used to treat wastewater from the chemical production were decided to be contained in place, requiring a seepage barrier installed around the perimeter of the site to further prevent groundwater/contaminant migration. This case study will discuss the successful installation of a soil-bentonite cutoff wall around the area using deep soil mixing. Highlights of this case study will also include a discussion of the challenges faced due to construction activities performed with Level B Hazmat PPE requirements as well as added challenges brought on by the Winter season, after the project was delayed due to a positive air monitor detection for the chemical weapon Lewisite during construction of the work pad.INTRODUCTIONThe Rocky Mountain Arsenal (RMA), located just outside of Denver, Colorado, was established by the United States Army in 1942 to produce chemical warfare agents and incendiary munitions for use during World War II. Following the war, and as weapons production decreased, portions of the site were leased to private companies for the production of industrial and agricultural chemicals. The principal lessee, Shell Oil Company, manufactured mostly pesticides at RMA facilities from the early 1950s to the early 1980s.In 1984 an investigation began in accordance with the Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) and confirmed significant levels of contamination due, in large part, to the common industrial and waste disposal practices of the era. It was also discovered that over 300 species of wildlife inhabited the land in the absence of regular human activity, including a group of bald eagles, leading to the passing of the Rocky Mountain Arsenal National Wildlife Refuge Act in 1992."

Jan 1, 2015

By M. Saghaeian, R. Hejazi, L. Hosseini

The specific surface area (Blain value) of iron ore concentrate entering the pelletizing plant is one of the characteristics most effective on the overall performance of the plant such as producing harder pellets, decreasing additives consumption, and decreasing energy consumption. Therefore, preparing the feed entering pelletizing plant is required. The iron concentrate entering Ardakan pelletizing plant located in Yazd province, Iran bears relatively low Blain value (approx. 1600 cm2/g) which necessitates one stage of regrinding so as to increase the Blain value to more than 1800 cm2/g. Studies were conducted and results showed that HPGR is the best regrinding equipment for increasing specific surface area. Conducting pilot plant tests on the concentrate sample revealed that specific throughput is 181 to 263 ts/hm3 and specific energy consumption is 1.6kWh to 2.2 kWh. Pilot tests also showed that one stage of grinding results in 407 cm2/g to 553 cm2/g increase in specific surface area. Based on these results, diameter of rolls, length of rolls, power consumption and grinding force were calculated to be 1.3 m, 0.9 m, 1276 kW and 13800 kN, respectively. Therefore, an HPGR with a roll diameter of 1.52 m, roll width of 1.1 m, power of 1660 kWh and a capacity of 500 t/h has been selected and implemented in Ardakan pelletizing plant. Industrial performance of HPGR and its effects on the plant study results show that limestone and bentonite consumption has reduced about 60% and 30%, respectively. Total Fe of the final pellet has increased from 65.5-65.7% to 66.2%. Cold compressive strength (CCS) and porosity of final pellets are approximately 292 kg/pl and 20.4, which are in the acceptable range.

Jan 1, 2014

By M. M. Swan

A stratiform gold occurrence of Precambrian age located 20 miles southeast of Prescott, Arizona, within the Agua Fria Mining District, displays chemical, mineralogical, structural and lithological patterns indicative of a distal, exhalative volcanogenic environment. Metavolcanic and metasedimentary rocks of the Proterozoic Yavapai Series (1775-1820 m.y.) host the mineralization and are&apos;characterized by greenschist grade metamorphism, steeply-plunging penetrative folds and steeply-dipping schistosity. Mineralization is confined to a 100m thick stratigraphic section that is comprised of a series of thin auriferous massive sulfide beds and intercalated schist .containing disseminated sulfides. The mineralization extends more than 4km along strike. Coincident with, and largely confined to the mineralized strata, are anomalous amounts of As, Sb, Cu, Pb, Zn and Ag and associated silicification, sericitization and carbonatization. This exhalative mineralized system is interpreted to have been deposited in a paleo topographic low on the distal flank of a submarine rhyolite dome and to represent the final episode of a Precambrian volcanic cycle.

Jan 1, 1981

By Corrie Pitzer

Safety performance in many companies and even industries has stalled in the last decade. Accidents rates are improving but more slowly and yet, serious accidents and fatality rates are not: in fact, these rates of more serious incidents have plateaued or deteriorating. In more dramatic cases, organizations that had ?exemplary? safety statistics, suddenly had a catastrophic or multi-fatality event occurring. Popular books such as In Search of Excellence of Peters and Waterman or Good to Great of Jim Collins created many delusional ?secrets? or recipes, to achieve great performance and yet, most of those ?great? or ?excellent? companies have now declined in their performance, some dramatically and some have fallen from grace, like Fanny Mae, a company Jim Collins identified as a ?great? one, that had to be bailed out in the latest financial crisis. These organizations share several ?delusions? about managing a business, and often, these delusions are created by academics, consultants and authors of popular books about (safety) management. More damaging however is that safety management is defined by a set of key practices or axioms: a focus on human error, compliance to rules and regulations, creating consistency of systems and actions, reacting to accidents and incidents and on prevention of those, measuring safety with performance metrics and rewarding employees on those measurements. All of these axioms contain the seeds of destruction, and they create conditions and dynamics that precede the disaster - and ironically, they are all &apos;good things&apos; we do in safety management. For example, a mere focus on safety in the business, and the measurement of it, create a culture of repression of mistakes and incidents, leading to a situation where the organization knows incrementally less and less of risks and risktaking behaviour - until the day it all coincides destructively! This paper discusses seven such safety delusions and how they impact on the views and safety management approaches. They are: ??The delusion of (risk) control, that risks can actually be identified, analyzed and mitigated. ??The delusion of compliance, that mere compliance to rules will safeguard the business ??The delusion of consistency, that standard operating procedures will ensure safe operations ??The delusion of predictability, that accidents and trends tell us everything about the risks of the future ??The delusion of human error, that people are the weakest link and that it can actually be dealt with through discipline and enforcement. ??The delusion of statistical trends, that safety is measurable with statistics ??The delusion of invulnerability, that we have achieved high levels integrity and capability to deal wit risks. Organizations that suffered catastrophes all share some or all of these delusions and this paper traces how these played a role in many disasters, ranging from the Titanic, Challenger, Piper Alpha, Bhopal, BP Deepwater Horizon and many more.

Aug 1, 2013

By Peter Hood

Data on world-wide geophysical activity in mining exploration programs are collected annually by the Society of Exploration Geophysicists' Geo-physical Activity Committee as part of a continuing service to the industry. The data are obtained by sending out questionnaires to all organizations which are known to be carrying out mining geophysical work; the organizations canvassed include mining companies, contractors, government departments and universities. The questionnaire is divided into three sections; namely, ground methods, airborne methods and research. The data compiled from the questionnaires show that world-wide utilization of mining geophysical methods reached a new high in 1967 with total expenditures of (U .S.) $32,323,240. This was divided as follows: ground methods, $18,106,785; airborne methods, $10,-123,405; and research, $4,093,050. For the ground methods, most money was spent on the induced polarization technique ($5,681,780); electromagne-tic methods were second in reported expenditures ($2,010,900). The total reported geophysical line mileage flown was 1,275,072 line miles, with aeromagnetic surveying being the most popular airborne method. The total amount spent on aeromagnetic surveys was $5,832,564 for 895,420 line miles. This gives an average cost of (U.S.)$6.50 per line mile.

Jan 1, 1968

By Jung-Joo Kim, Jong-Uk Kim, Turab H. Jafri, Han-Kyu Yoo

"INTRODUCTION Steel sets such as H-type and lattice girders are often installed in the tunnels before the hardening of shotcrete to ensure the stability of conventional tunnels in soft ground conditions. In practice, while designing the tunnels with the help of numerical analysis, steel sets are generally considered only as temporary support elements. Only a few studies propose the direct application of composite support in the tunnel design, based on large-scale experiments and numerical analysis. In order to assess the structural performance of the composite support consisting of shotcrete and steel sets, large-scale experiments were performed on two types of arch-shaped specimens by applying the combined effects of axial forces and bending moments. Based on the experimental results, numerical analysis was performed to assess the application of composite support in tunnel design. The crown settlement, axial forces, bending moments, and load distribution in the composite support were analyzed in the light of different structural patterns. LARGE-SCALE EXPERIMENTS USING COMPOSITE SUPPORT Preparation and Procedure of the Experiments The preparation setup as well as the organized procedure of the large-scale experiments using composite support is shown in Figure 1. An appropriate geometry of the specimens was selected by considering the standard cross-section of a two-lane highway tunnel in South Korea. Under the loading conditions meant to develop the axial forces and bending moments simultaneously, arch-shaped specimens were assembled with the ends of the specimens subtending a 60° arc angle at the center of the arc circle as shown in Figure 2. The fabrication of six specimens was completed in two groups based on the dimensions of steel sets, with the first group of three specimens being reinforced by H100 (No.1, No.2, No.3) and the other three by H125 (No.4, No.5, No.6). In order to reduce the voids on the boundary of the shotcrete and steel sets, concrete was casted over the steel sets instead of using shotcrete. The specimens were designed to incorporate the uniaxial compressive strength of 21 MPa. Shear keys and steel plates were installed at the ends of the specimens, so that shear failure could be avoided at the ends and the specimens could also be protected from detachment at the fixation. Translational and rotational movements at the ends of specimens were fixed."

Jan 1, 2016

By Run Huang, Xuewei Lv, Lei Lei, Guibao Qiu, Chenguang Bai

"The TiO2-rich slag and pig iron can be produced from ilmenite concentrate by the electric furnace process. In this study, ilmenite concentrate was reduced in a vertical furnace equipped with a weighting data acquisition system. The effects of reducing agent (carbon) amount on the iron reduction were studied. The phase transformation, morphology and chemical compositions of reduced samples were investigated by X-ray diffractometry (XRD), scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS), respectively. It was found that the reductive degree of ilmenite concentrate increased with the increase of reducing time. The phases of reduced samples were mostly iron, rutile, Ti3O5 and Fe2TiO5. The mass loss percentage increased with increasing the carbon amount from 8% to 12%. When the carbon amount exceeded 12%, the mass loss percentage decreased with the increasing of carbon amount.IntroductionIlmenite and rutile are the main raw materials for producing titania pigment and titanium metal. With the development of the titanium industry, huge amounts of titanium resources are needed. As sources of high-grade titania mineral decrease worldwide, more attention should be paid to the processes involving low grade mineral such as ilmenite ore. In ilmenite, MgO and CaO are the gangue parts. Therefore, the ilmenite refining becomes more and more popular. In the previous studies, the methods of ilmenite refining are electric furnace smelting, direct acid leaching, selective chlorination and thermal reduction [1]. Electric furnace smelting method is widely used in the titanium industry, however, which consumes a great deal of energies and has a high CO2 emission. Its essence is to remove iron oxides and obtain a high titania slag. So the thermal reduction of ilmenite concentrate is an important step in titanium industry, which can decrease carbon reagent consumption and save energy.Over the past several decades, many studies have been carried out on the mechanism and kinetics of the reduction of different ilmenite ores, which are as follows: The carbothermal reduction of Panzhihua ilmenite initiated at about 860 oC. In the temperatures ranging from 900 oC to 1400 oC, the reaction rate was changed like a shape of “M”. That was to say that the reaction rate increased with the growth of temperature at first, then decreased, afterward increased again and at last the reaction was arrested [2]. The Mohammad A.R group [3, 4] showed that the carbothermal reduction of primary ilmenite concentrate was faster in hydrogen and initiated at a lower reduced temperature than in argon and helium. The reduction in argon and helium had about the same rate and extent. Titanium oxycarbide started at 1000°C in hydrogen. The conversion of primary ilmenite concentrate to metallic iron and titanium oxycarbide at 1200 °C was completed in 300 minutes. Monoxide as the reductant to reduce ilmenite had been studied intensively by a few research groups [5, 6]. The rate and the degree of reduction depended on the formation of a metallic shell of iron which inhibited the transfer of CO to the reaction zones; titanium had a strong effect on the mechanism and rate of reduction of iron oxides. Wang and Yuan [7] studied the reductive kinetics of the reaction between a natural ilmenite and carbon. At temperature below 1100°C, chemical reaction was the rate controlling step, at 1100 to 1250°C mixed controlling was rate controlling step, above 1250°C diffusion through the product layer controlled the reaction. Zhang [8] investigated the reduction of natural, sintered and preoxidized ilmenite concentrates in hydrogen methane mixtures. Preoxidation and sintering of ilmenite concentrates changed their phase composition and caused a sharp decrease in specific surface area of raw materials and an increase in carburization temperature. Sintering also increased the metallization temperature of iron."

Jan 1, 2011