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By Zhucheng Huang, Zhikai Liang, Lingyun Yi, Tao Jiang

"In this study, reduction of iron ore pellets was carried out at 800-950°C by simulating the atmosphere of typical coal gasification gas. The effects of temperature, gas composition and reduction degree on swelling were investigated respectively. Reduction degree was obtained according to the weight loss records. And volume changes of pellets during reduction were evaluated by infrared photography. Results showed that the pellet swelling increased with temperature and decreased slightly with hydrogen content in the reducing gas. The swelling peaked when reduction degree reached about 40% and then decreased to be stable finally. The microstructures of pellets during reduction were examined by reflected light microscope and relatively rational explanations were proposed for their swelling behaviors.PrefaceDirect reduction iron is an important and indispensable raw material for high-purified and high-quality steel in the electric furnace smelting. Gas-based shaft furnace direct reduction process has very strong competitative ability; however, this technique requires natural gas as reducing agent, so its development has been restricted by gas source and area. Compared with gas-based reduction method, coal based reduction method has the disadvantages of higher production cost and lower productivity. In China, coal resources are abundant and coal gasification technology is mature, and the development of coal gasification shaft furnace direct reduction process is promising. [1] The gasification methods of fixed bed method (Lurgi method), fluidized bed method (Undok method), airflow bed method (Texaco coal water slurry method and Shell dry powder coal method) have been put into use successfully. These syngas generated by different methods can meet the actual production requirement of shaft furnace. However, the compositions of the effective reduction gas in the syngas are quite different. The ratios of hydrogen and carbon monoxide (H2/CO) of Undok or Shell coal gas, Texaco coal gas and Lurgi coal gas are 0.4, 0.6~ 1.0 and 1.6~2.3, respectively. [2] In the coal gas direct reduction process, the swelling behavior of iron ore pellets is various due to the differences of the gas composition, reduction temperature and reduction degree, and it seriously affects the normal operation ofDRI production. [3-9] Therefore, the research on the swelling behavior and its mechanism of iron ore pellets in direct reduction were carried out in this paper."

Jan 1, 2013

By Kenneth L. Driggs

The 1988 shift in primary smelting facilities from low grade matte (35%) reverberatory furnaces to high grade matte (63%) flash smelting heavily impacted a very stable and successful converter operation. Low matte grade converter campaigns averaged 36,000 short tons of copper and revert production/consumption was in balance. The conversion to high matte grades necessitated oxygen enrichment of converter blast and revisions in operating practices. After two years of operational development, campaign life has risen to over 40,000 short tons and revert production/consumption is again in balance.

Jan 1, 1991

By G. Frithum

In the present paper a new and highly economic route for Fe-separation from HCl leaching processes in hydrometallurgical applications is described. In most ore leaching processes, Fe is involved and needs to be separated; HCl has become an interesting leaching agent, because it can be recycled. Usually a mix of Fe2+ and Fe3+ is obtained which can be hydrolyzed directly (in case only Fe3+) or roasted via pyrohydrolysis (in case of Fe2+) to ferric oxide. Economic oxidation of Fe2+ to Fe3+ is described, and potential technologies for regeneration of HCl with separation of Fe are shown and compared.

Jan 1, 2014

By Pedro Miranda

El planeamiento de minas a cielo abierto es una operación compleja donde intervienen varios factores que deben ser aplicados con optimización para así obtener la mayor producción a menor costo. En ese sentido, el presente texto señala los factores que intervienen en el planeamiento de minas de Toquepala tales como: la ley mínima de explotación, ley mínima de explotación, talud, relación de desbroce y respecto a los controles de minado están: el control de minado por tonelajes, control de material extraído, control de tonelajes extraídos por categorías, control de almacenamiento, transporte, voladura y el control de las reservas disparadas.

Nov 1, 1970

By Wenjun Duan, Kun Wang, Qingbo Yu, Qin Qin

"A novel oxygen production technology noted chemical looping air separation (CLAS) was introduced and properties of Cu-based oxygen carriers used were investigated. The oxygen carriers were prepared by mechanical mixing. Al2O3, Fe2O3, ZrO2, TiO2 and SiO2 were used as binders during the preparation. XRD patterns show that spine! oxides are formed using Al2O3 and Fe2O3 as binders. Phases of CuO and binders keep stable using ZrO2, TiO2 and SiO2 as binders. BET values of oxygen carriers increase in the order of ZrO2>TiO2>SiO2>Fe2O3>Al2O3. The effects of temperatures, binders, particle sizes and flow rates on reduction/oxidation reaction rates were studied in TG experiments. The reduction reaction rate increases in the order of ZrO2>TiO2>SiO2. The effect of binders on the reactivity of oxidation is not obvious. The reduction and oxidation reaction rates both have the tendencies of increasing with the temperature increasing and with gas flow decreasing. However, the effects of gas flow and particle size are little.IntroductionChemical looping air separation (CLAS) is a novel oxygen production technology. The oxygen carriers used in CLAS release oxygen in reduction reactor and regenerate in the oxidation reactor. Selecting suitable oxygen carriers is the key for CLAS. Oxides of CuO, Mn2O3, Co3O4, Pb3O4, CrO2, SrO2, PdO2 and CeO2 have the property of releasing oxygen at suitable temperature and oxygen partial pressure [1]. Among these oxides, CuO, Mn2O3, Co3O4 are the most common compositions used to prepared oxygen carriers for chemical looping combustion (CLC) or chemical looping with oxygen uncoupling (CLOU) [2-5]. Moreover, thermodynamic calculations and preliminary experiments were carried out on oxides of Cu (CuO/Cu2O), Mn (Mn2O3/Mn3O4) and Co (Co3OJCoO) by Moghtaderi to ascertain their feasibility for CLAS process [6]. CuO has the highest oxygen transport capacity (0.1 g 02/g CuO compared to 0.03 g 02/g Mn2O3 and 0.06 g 02/g Co3O4). However, agglomeration is the biggest issue for copper oxides used at high temperature because of its low melting point (l 450°C for CuO, 1235°C for Cu2O and 1075°C for the mixture of CuO and Cu2O) [7]. In order to improve the capability of anti-sintering and stability ofCuO, binders (ZrO2, MgAl2O4, TiO2, SiO2, Fe2O3, Al2O3, cement) are added during the preparation of Cu-based oxygen carriers [8]. In this paper, the Cu-based oxygen carriers were prepared by mechanical mixing method. TiO2, Al2O3, Fe2O3, ZrO2 and SiO2 were selected as binder. XRD, BET and SEM were used to analyze the phase, surface area and surface morphology of oxygen carrier prepared. The reactivity of oxygen reduction and oxidation of oxygen carriers prepared were investigated in STA409PC thermal analyzer."

Jan 1, 2014

By Ruixiang Gu

The de-confinement mechanisms of unstable failures as they occur in deep coal mining conditions are investigated using a distinct element numerical modeling code. The Mohr-Coulomb and continuously yielding joint constitutive models were used to study the compressive failures in coal and slip behavior of coal-rock interfaces, respectively. The effect of strength variations within interfaces on the failure mechanism of mining faces is also studied. The stability of interface slip failures was found to have a significant role in the failure mode of coal sidewalls. When the interfaces experience stable slip failures, the sidewalls are more likely to fail in a stable manner. With occurrence of unstable slips at interfaces, unstable compressive failures of sidewalls are triggered. The numerical modeling results support the proposed de-confinement mechanisms and emphasize the importance of including the coal-rock interface behavior in the analyses of unstable compressive failures. The significance of the proposed mechanisms in underground mining conditions is that rock discontinuities with large cohesion drop can become potential factors, inducing unstable compressive failures at ribs and mining faces. Therefore, the de-confinement mechanisms should be taken into consideration in mine design.

Jan 1, 2014

By Lucas L. da Costa, Sergio N. Monteiro, Romulo L. Loiola, Tammy G. Rodrigues Portela

"The fibers extracted from the petiole of the buriti palm tree are relatively strong as compared to other lignocelluloses fibers, with a potential for composite reinforcement. In this work, polyester matrix composites incorporated with these fibers were investigated for their flexural behavior. Specimens with up to 40% in volume of continuous and aligned buriti petiole fibers were bendtested until rupture. The results showed an increase in both the composite mechanical strength and the stiffness with incorporation of these fibers. A fractograph analysis by SEM disclosed a moderate adhesion mechanism between the buriti petiole fiber and the polyester matrix. This mechanism is apparently responsible for the improved performance of the composites.IntroductionIn recent years, the substitution of energy-intensive synthetic materials for natural ones is being considered in many industrial sectors including automobile, packing and textile [1]. A typical case is that of natural fibers, mainly those obtained from cellulose-based plants also known as lignocelluloses fibers. They have being investigated in the past two decades, aiming to replace synthetic fibers, particularly the glass fiber, commonly used as polymer composite reinforcement [2-8]. From the engineering point of view, lignocellulosic fibers present today important environmental, economical, societal and technological advantages already discussed [7-8]. Moreover, several lignocellulosic fibers are known since the beginning of our civilization and still cultivated or naturally extracted all over temperate and tropical regions of the world. According to Kalia et al [1 ], these fibers can be classified by their origin, as shown in Table 1."

Jan 1, 2011

By S. Owada

A national project of ?Establishing ?Green-Hydrogen (G-H)? Society in Honjo-Waseda Area? is now being developed by Waseda University together with four other universities and ten companies. The project involves three tasks of technological development of, (1)?G-H? production, (2)?G-H? refining, transportation and storage, and (3)?G-H? utilization. This paper focuses the first task of ?G-H? production from aluminium dross. We developed the physical treatment process by combining selective grinding with vibrating rod mill and electrostatic separation, in order to produce two kinds of materials, one is metal aluminium concentrate to recover it and the other is raw material to produce ?G-H? and aluminium hydroxide which can be generated by the treatment with sodium hydroxide aqueous solution. Here, we described the concentration mechanism of metal aluminium in the selective grinding and electrostatic separation and proposed a separation flowchart for optimizing the ?G-H? system in Honjo-Waseda area.

Jan 1, 2014

By R. M. Zhao

The process conditions and mineral characters of cleaning separation stage in magnetite concentration plant are studied in the paper, and the affecting factors and the methods to increase the concentrate grade are analysed and given. The BKJ cleaning special drum magnetic separator is developed specially for the cleaning stage according to process conditions and mineral character. The separation mechanism, structure characters, separation process and excellent adaptability of BKJ special magnetic separator are described. The results in Zhangjiawa Concentration Plant show that the BKJ special drum magnetite separators play an important role in increasing the concentrate grade and improving the economic benefit.

Jan 1, 2014

By Camilo A. Alvarez, Stephen K. Harris, Brian R. Zuckerman, Philip J. Meymand, Danielle M. Steinmetz

"The sleek new air traffic control tower at the San Francisco International Airport stands at 221 feet tall and is set to replace the existing air traffic control tower by 2016. This aluminum-clad, torch-like structure and three-story Integrated Facilities Building at the base are situated between Terminal 1 and Terminal 2 adjacent to the tarmac. Berkel & Company Contractors, Inc. and Simpson Gumpertz & Heger Inc. worked in conjunction with structural engineers from Walter P. Moore Engineers and Consultants, geotechnical engineers from URS Corporation, architects from Fentress Architects, and general contractors from Hensel Phelps Construction Company on the performance-based design of a foundation to support this critical facility, which is located in a high seismic zone and situated on the very soft soil of the San Francisco Bay margin. With the loading demands and performance criteria established and Young Bay Mud thicknesses ranging from 44 to 47 feet thick across the site, the design team employed a total of 214 24-inch diameter Auger Pressure Grouted piles, which were drilled into the underlying Franciscan Formation as deep as 148 feet below existing grade. Pile reinforcement included full-length confined cages.The piles were designed to resist Maximum Considered Earthquake axial demands as high as 1,400 kips in compression and 700 kips in tension. The performance-based pile design included verification of shear capacity under double-plastic-hinge flexural mechanisms, verification of pile ductility via non-linear moment-curvature analyses, and consideration of curvatures due to kinematic as well as inertial loading.The team implemented an extensive pile load test program including a full-scale static compressive load test on a sacrificial test pile and five non-destructive high-strain dynamic load tests, four of which were performed on indicator piles that were later used as part of the foundation system. These piles were monitored with extensive embedded instrumentation throughout their length, including strain gauges and accelerometers."

Jan 1, 2017

By G. V. Sedelnikova

Biohydrometallurgical studies were performed on the sulfide gold-arsenic concentrate obtained in treatment of refractory ore from a deposit located in northern Russia. Gold is disseminated in sulfides-arsenopyrite, pyrite and antimonite (their content is 10.0%, 30.4% and 0.7%, respectively). Gold extraction is only 11.8% by cyanidation. Results are given for test bacterial oxidation of the concentrate in continuous mode at temp. = 28~32°C using mesophilic bacteria and at temp. = 32~38°C using the association including moderate thermophilic bacteria. The paper shows that the use of moderate thermophilic bacteria allows to speed up sulfide biooxidation and reduce its time to 96 hours compared to leaching at temp. = 28~32°C for 110~120 hours. The optimal range of pH = 1.5~2.0 of biooxidation process was determined where bacterial solutions are produced with the molar ratio Fe:As > 3 necessary for precipitation of hard-to-solve, environmentally safe arsenical precipitates. Electron microscopy showed that sulfide biooxidation results in liberation of disseminated gold with nanoparticle-level sizes. High sorptive activity of carbonaceous matter and other compounds of bacterial residues cause low gold extraction into cyanide solution ? 28.7%. 10% resin load makes it possible to extract 88.1% Au. Aeration of pulp in calcareous medium enhances extraction to 95.7% and decreases cyanide consumption from 17kg/t to 8 kg/t.

Jan 1, 2014

By Z. C. Shen

As core part of flotation column, aerator has been always priority research. A new type of porous aerator made of stainless sintered microcellular material is designed , which diameter is between 20µm to 40µm. High bubble surface area flux is obtained at low air pressure 20kPa by this type of aerator in water. In order to extend its applied range ,experiments were carried out in alkali slurry (pH=12) , resulting with porous aerator clogged after working 20 days . Sampling the cross-section of aerator detected by microscope and X-ray diffraction ,the reason clogging was found. Then plugging aerator was reactivated after putting it in acidic liquor treated by ultrasonic for about ten minutes. On-line aerator maintenance can be done in no down time , and it can be repetitive-used after recovered ,so reduced capital costs.

Jan 1, 2014

By Guolin Zheng, Jian Pan, Deqing Zhu, Xianlin Zhou

"In ferronickel production, nickel oxide and part of the iron oxide are reduced to metal by agglomeration and smelting in blast furnace. Due to the physical and chemical properties of the laterite ores, a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality. In this paper, the process of pelletization of nickel laterite was developed, and some parameters to strengthen the pelletization of nickel laterite have been optimized. The results show that the compressive strength of fired nickel laterite pellet can reach over 2000 Newton per pellet while firing at the temperature of 1220 °C~1250 °C in 12 min. The product pellet can be used as high-quality burden for blast furnace to manufacture ferronickel.IntroductionIn recent years, the global stainless steel market was developed exuberantly, which greatly promoted the needs of the basic raw material of stainless steel smelting - metal nickel. Currently nickel sulfide ores are only 40% of global nickel reserves, but offer 60% of all the nickel production. However, with the deficit of resources, the nickel sulfide ore (high grade ore) is depleting, so there is an increasing focus on the utilization of low-grade nickel laterite. Recent research has focused on the wet treatment process to utilize nickel laterite, and less on the use of other technologies [1-8]. The economical and efficient technology relies on the reduction of nickel oxide and part of the iron oxide metal by agglomeration and smelting in blast furnace in China. Some domestic steel companies have adopted this process [9, 10]. Unfortunately a large fraction of fines is generated during the pre-treatment stages and the strength of agglomeration is weakened, which results in low productivity and bad quality of fired pellets. In this study, the process of pelletization of nickel laterite was developed firstly, and some parameters to strengthen the pelletization of nickel laterite have been optimized, and the product pellet can be used to produce stainless steel and ferronickel alloy by blast furnace."

Jan 1, 2011

By W. G. Stevenson

With the author's background of extensive experience, this paper delineates the role of the prospector in modern-day exploration programs. The stages in the development of a prospect to a producing mineral district are outlined, and examples are given from the Ross River area of the Yukon Territory and the Peachland and Highland Valley areas of British Columbia.

Jan 1, 1970

By Gaom M. W.

The Mount Isa copper concentrator started operation in 1973. Its secondary grinding circuit consisted of two 5 meters diameter ball mills in closed circuit with 505 mm cyclones. At the design throughput of 800 t/h, the 80% passing size of the circuit product (P80) was about 140 µm. The then Mount Isa Mines Limited (?MIM?) installed two autogenous grinding (?AG?) mills in 1991 to replace two stages of crushing, a rod milling stage and one primary ball milling stage. One of the AG mills was later converted to semi-autogenous grinding (?SAG?) operation by the addition of a steel grinding medium to achieve the designed plant throughput of 800 t/h. The cyclone over-flow P80of the secondary ball mill circuit was reduced to 120 µm by the increased operating power in the AG/SAG mill circuits. The two secondary balls mills had a grinding power of 5.2 MW. A mineralogical study of the milled products indicated that half of this grinding power was sufficient for adequate chalcopyrite liberation. Eliminating one of the secondary ball mills could reduce energy and operating costs by more than A$2 million dollars per year. An optimisation project team was established to achieve the predicted power saving. Grinding circuit simulations were conducted for different circuit configurations. Ball mill parameters such as ball size, ball charge and feed slurry density were optimised. Cyclone body diameter, spigot and vortex finder sizes, and cyclone types were tested. The secondary ball mill circuit was redesigned and several proposed circuits were run as trial production campaigns to determine their operability and efficiency. The plant trials confirmed that one of the secondary ball mills could be decommissioned. Significant cost savings were achieved as a result. The success of the project demonstrates optimising grinding circuits can not only deliver the plant performance, but also a much lower unit operating cost through energy and maintenance savings.

Jan 1, 2014

By Per Hedvall, Jan-Eric Ståhl

"The main objective of this study is to introduce the new Sandvik’s production cost-model within Crushing & Screening (C&S) technology. So far, there have been different ways of determining different production costs in the industry, however, the previously published and presented methods have not been very efficient in calculating the costs per product and metric ton. Accordingly, the current study has been planned and started in collaboration with Lund University to provide an accurate and easy to implement cost estimation program to determine the costs for crushing and screening plants worldwide.The proposed model has been adapted to fit the C&S processes of different rocks/ores fractions. The result is presented as cost per ton of the end product(s).Within this paper the cost estimation results for 3 different crushing and screening plants are presented based on the information obtained from the following sources: a) documents at Sandvik SRP, b) Sandvik’s crushing & screening internal/external machines/plants data and information, c) literature studies, including the use of Sandvik’s internal/external simulation and software programs, d), visiting the crushing and screening plants ,e) interviews, information systems’ data, and, f) testing and observations by ourselves.In order to improve the level of accuracy and the validity of the attained results, simplistic Monte-Carlo simulations have been used, where needed. The achieved results, so far, have proven the reliability of the model. The calculated cost estimations have shown an accuracy over 80% when they compared with real cost data obtained from plant practices.The current cost calculation model, will offer the possibility of:•,Calculating the production costs in proposed and/or existing C&S plant.•,Making detailed cost analyses for the end product(s) in proposed and/or existing C&S plants.•,Determining the profitability of each finished product when it’s required.•,Cost optimization by potentially cutting the cost for part of C&S plant with an existing plant practice"

Jan 1, 2016

By Ö. Y. Gulsoy, L. Ergün, I. B. Celik

"In this study, the studies to develop a flowsheet for a low grade chromite ore are presented. The existing concentrator had to be suspended due to the decreasing metal prices. The study commenced with mineralogy and liberation profile of the chromite. The valuable mineral is chromite and the major gangue mineral is forsterite together with small amount of brucite and calcite. Heavy liquid tests were performed on different size fractions without any acceptable success. The concentration tests were performed using teetered bed separator (TBS) +shaking table, spiral concentrator+TBS+shaking table for different grind size. Based on the test results, 100% finer than 0.4mm was found to be optimum for grind size. Comparison of alternative circuits showed that the performance of both alternatives would be similar. A flowsheet was designed and operated for as 25 tph trial circuit in the existing plant. The results showed that the performance of the plant predicted was very close to the actual plant data. The paper describes the methodology used, presents the experimental data and actual performance figures.INTRODUCTION Turkey is one of the largest chromite producers in the world. Since 1850, chromite mining found industrial applications and geographically spread along six different regions in Turkey. Although the reserves in these locations are not as rich as the big producers, they are regarded as very valuable due to Cr/Fe ratio in terms of chromite utilization standards (1, 2). In this period, significant portion of high grade (=35% Cr2O3), directly marketable ore deposits have already been produced. According to General Directorate of Mineral Research and Exploration (Turkey) data; 83% of the known chromite deposits of Turkey which makes 242 341 000 tons in total, is consisting from the deposits those have a Cr2O3 grade lower than 10%. Only 5% of the known deposits (13 087 000 tons) has a grade of directly saleable (2, 3). Gravity concentration methods are well-known processes for chromite beneficiation and there are plenty of plants in the world and Turkey using these methods. As different equipment combinations can be used for the same enrichment method, different methods can also be used in combination for plant designs (4). Beneficiation of low grade and problematic chromite ores may lead to use these method and equipment combinations (5, 6). Ore liberation, the grades of Al2O3, SiO2, FeO and Cr2O3 in the obtained concentrate, Cr/Fe ratio, some physical and chemical properties between gangue and minerals (i.e. specific gravity, magnetic property, color, etc.) designate the selection and combination of these methods and equipment (7)."

Jan 1, 2017

By N. Valkanov

This paper presents results of an investigation into the connection between minerals liberation management and flotation, responding to lead-zinc concentrator ?Erma reka?, in Bulgaria. Monitoring of a Zn flotation circuit was carried out. The causes for the high silica content in the final Zn concentrate were established. Quartz is present mainly as liberated particles (> 60?80 %) in the fine fractions of the products; therefore the selectivity of the flotation process is not effective. Two approaches were tested to reduce the quartz content of Zn concentrate: froth washing in Zn cleaner flotation and new gangue depressants in the Zn circuit. Experimental results from bench-scale flotation and industrial tests show that it is possibile to reduce the silica content of final Zn concentrate more than 2 times without the need for extensive regrinding. The depression of liberated quartz particles on all operations of Zn circuit using stage depressant addition is the right solution to produce high-grade Zn concentrate that meets the metallurgical requirements.

Aug 1, 2013

By C. J. Thompson

Two sulfur compounds--the 2,2,5-trimethyl- and the 2,2,5,5-tetramethyl derivatives of thiacyclopentane--were identified in Wilmington, Calif., crude oil, using microdesulfurization and gas-liquid chromtography techniques.

Jan 1, 1963

By Z. D. Tan

The continuous digestion technological conditions of phosphate tailings with high magnesium content in sulfuric and phosphoric mixed acid is studied in this paper. The influences of excess coefficient of sulfuric acid, weight liquid to solid, reaction temperature and time on conversion of P2O5 and MgO are discussed. The influence of infiltration capacity of phosphogypsum by the concentration of liquid-phase SO3 is discussed too. Under the optimal technological conditions, the conversion of P2O5 is 95.56% and MgO 98.63%, the filtration rate of phosphogypsum increases with the increasing of liquid-phase concentration of SO3, the optimal apparent concentration of SO3 is 0.135~0.14g? mL-1 in liquid-phase. The filtration rate of phosphogypsum is 1473kg? m-2? h-1. N-P-Mg compound fertilizer was produced by adding magnesia powder and inflating ammonia in filtering medium.

Jan 1, 2014