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By D. R. Hay, E. Scala

Electrotransport has been superimposed on the rate-limiling- step in zone refining which is the impurity diffusion through the liquid at the solid/liquid interface. The efficiency of zone refining is increased and relative resistivity ratios (P300°k/P4 2°K) he increased by 50 pel in tungsten for a given number of posses using- the electrotransport field-aided method. The effiect of zotze refining in the presence of an electric field on the relative resistivity ratio is examined as a function of its intensity and polarity. THE effect of electrodiffusion on the effective distribution coefficient of zone refining has been discussed by Pfann and Wagner.' Control of the distribution coefficient in zone refining is of twofold interest. A distribution coefficient of unity can be increased or decreased, making possible the transfer of some previously inseparable solutes. The general efficiency of zone refining can also be increased. In the conventional zone-refining process impurities are removed by their retention in the molten zone and subsequent deposition at the end of the rod after a complete passage of the zone. In higher-melting-point systems a second mechanism may also operate, the volatilization of impurities from the molten zone. It has been suggested by schadler2 that, in refractory metals, vacuum distillation plays the predominant role in purification. In Koo's results,3 the resistivity ratio decreased beyond a zone-refined length of 6 in. from the starting end, indicating that some purification does in fact occur by true zone-refining action. Hay and scala4 showed that the degree of purity as measured by the relative resistivity ratio method depends on the square root of time in the molten zone (number of passes) and thus appears to be limited by diffusion in the boundary layer at the solidifying interface assuming good mixing in the body of the molten zone where a linear rate would prevail. The final concentration of impurities in electron-beam floating-zone purification depends very much on the operating conditions and results obtained by various investigators2,3,5 are difficult to correlate. The diameter of the starting material, operating vacuum, and rate of traverse are among the factors to be considered. There are, nevertheless, some general observations to be obtained from the literature. Lawley5 reviewed the literature up to 1962 and concluded that the major contaminants generally remaining in tungsten after electron-beam zone refining are molybdenum and carbon. Molybdenum due to its high melting point and distribution coefficient of nearly unity would be expected to be difficult to remove by either volatilization or zone refining. Carbon is not only a common contaminant in vacuum systems, but is also very difficult to remove by conventional vacuum melting. even with vacuums of 10-7 mm Hg. For each of those impurities removed by zone refining the equation of Pfann and Wagner may be applied: It relates the effective distribution coefficient k to a superimposed driving force which accelerates the solute away from the interface with a terminal velocity L" and to the more conventional zone-refining parameters; v = rate of traverse, t = thickness of the diffusion layer at the solidifying interface, D = diffusivity of the solute in the molten zone, and ko = equilibrium distribution coefficient of the impurity.

Jan 1, 1965

By L H. Chapman, I J. Kelso, N H. S Oliver

Utilisation of modern 3D visualisation tools, can improve our ability to correlate between different datasets, and thus to produce more accurate geological models. Here, we present an application of such techniques to the Century Zinc Deposit, northwestern Queensland, Australia. This stratiform orebody is the second largest Zn resource in the world (167.5 Mt at 8.2 per cent Zn, 1.2 per cent Pb, and 33 g/t Ag). It is hosted in the Page Creek Syncline affecting Mesoproterozoic shales and siltstones of the Wide Supersequence of the Isa Superbasin. As in other deposits, (eg McArthur River, Lady Loretta, George Fisher and Dugald River), the mineralised sequence is bound by an important regional structure, the Termite Range Fault, which partly intersects the deposit along its Eastern side. This fault is thought have been active during sedimentation and probably also during mineralisation of the lowest part of the Wide Supersequence. The anastomosing geometry of this fault system and crosscutting relationships with other NE trending structures indicate that it was reactivated several times from Mesoproterozoic to at least late Devonian times (>1000 million years in total); as a result, the ore sequence is subdivided into several fault blocks.Using two different computer modeling packages (GOCAD and 3ds max), we have reconstructed and restored the stratigraphic horizon with the highest Zn content, realised a series of isopach maps for each mine scale stratigraphic unit, plotted the three-dimensional distribution of Zn, Pb, Ag, Fe and SiO2, and have begun to evaluate the degree of correlation between thickness changes and sulphide zoning. With this approach it is possible to better understand the timing of mineralisation from a genetic perspective, because the origins of the orebody are controversial. Three-dimensional reconstruction is a vital tool for identification of syn-sedimentary and post-sedimentary fault activity. In conjunction with sulphide precipitation, these are factors that greatly influence the stratigraphic thickness distribution. Post-sedimentary deformation can be recognised directly by core logging and pit mapping, but the effect of tectonic movements during sedimentation (growth faults in particular), that represents a substantial variable when we attempt to reconstruct basin evolution, is difficult to evaluate without this methodology. The 3D models improve our understanding of the local basin architecture, identifying similar grade characteristics at different structural levels and thus suggesting that much faulting and folding are post-mineralisation events. In addition, we identified several growth faults adjacent to thickened layers, representing two possible sedimentary depocentres. These thicker domains apparently relate to the highest Pb content. If further analysis of rocks, thickness and grade distributions support this preliminary correlation, then a syn-sedimentary model for mineralisation might be applied, and would contrast with the sub-surface model for mineralisation of Broadbent et al (1998).

Jan 1, 2003

By Larry Kaufman, Morris Cohen

THE solid phase equilibria' and the martensitic transformation in the iron-nickel system have been the subject of considerable study. In addition, there have been numerous investigations on the calorimetric and thermodynamic properties of iron-nickel alloys. The purpose of the present work is to extend the existing information concerning the martensitic reaction in the iron-nickel system, and to develop a general thermodynamic treatment which will encompass the equilibrium and non-equilibrium phase

Jan 1, 1957

By S. MacGregor

The role of horizontal stress, its orientation and magnitude, in defining the behaviour of strata in underground coal mines has been well established. Poor panel layouts have led to gate end stress concentrations, roof falls and lost production. The ability to define the horizontal stress regime over a mine site has historically been limited to point measurements, in part due to technology and cost. Recent advances in the application of geophysical tools, notably the acoustic scanner (borehole televiewer) have resulted in a new technique to conduct stress measurements. By quantifying the nature of borehole breakout and the mechanical properties of rocks in which they occur, this technique provides the ability to: obtain a vastly greater number of measurements, both at different depths and spatial distribution, than other techniques such as overcoring or hydraulic fracturing readily obtain depth versus stress relationships define geotechnical domains on the basis of stress direction and in-situ stress magnitude for mine planning purposes This paper presents an overview of the technique and presents case histories in its application at a mine site in the Sydney Basin, Australia.

Jan 1, 2002

By Hans W. Schreiber, Rudi P. Fronk

IINTRODUCTION Widespread activities in precious metal projects in the western U.S., Australia, Canada and other parts of the world have opened a flood-gate of consul- ting expertise to aid and accelerate the development process. Utilization of outside expertise has taken on many shapes and forms that have in some instances actually "decelerated" or "retarded" project progress. Small mines are especially vulnerable to apparent false-starts and misdirections, be- cause of their generally lower capital commitments, shorter lead times and limited mineral in-house expertise. Mine development for small mines requires fundamental approaches by knowledgeable consultants that are timely and cost-efficient and in line with accelerated development, if they are to be successful. The development process is obviously that process which brings a given deposit into production. Or, put another way, the process comprises all activities, decisions and commitments which take place from the moment an authorizing entity (usually a board of directors) com- mits to development and production (usually on the basis of a final feasibility study) until the first ton of ore is processed to a saleable product. The activities, decisions and commitments over a development period--such a period can range from as short as a year or less to as long as 5 years or more--are many, highly varied, and often interdependent. The development period is also particularly risky, not only because of the varied and interdependent decisions and commitments, but also because of capital demand amounts. Delays in the development process are thus particularly costly - sometimes so costly that small and often undercapitalized mining companies, failing to reach production and a cash flow within a planned period, face, if not bankruptcy, at least severe equity dilution or particularly onerous and restrictive covenants on additional loan financing. It therefor behooves especially small mining companies to examine ways to accelerate development. By doing so, the development process may actually meet planned scheduling. The development process generally comprises environmental impact studies completion, final engineering, permit- ting, financing, equipment and machinery procurement, contractor selection and construction -- such activities largely being overlapping. The paper addresses what the small mines operator or the small mining company can do with consulting firms to accelerate development. By "small mines" is meant open pit operations of 2000 tpd or less and underground operations of 500 tpd or less. By "consulting firms" is meant entities who do not possess an engineering and construction capability, such as Derry Michener Booth & Wahl, Pincock Allen & Holt, Behre Dolbear-Riverside, etc. The paper concentrates on gold projects. PRIORITY CONSIDERATIONS Of the items listed in the previous paragraph which comprise the development process, the two which most consistently appear to cause delays are permitting and financing. The former's delays can be due to political overtones and thus the delays may not be reasonably foreseeable. The latter's delays are most often due to inadequate preparation, and thus are avoidable. For the reason stated above, and considering that financing is fundamental to all of the activities which constitute the development process, the paper focuses on financing as the priority item which can most assist in accelerating or retarding the development process.

Jan 1, 1987

By E. C. Harder

AT a Meeting of the New York Section, on May 23, 1918, the sole subject of discussion was the nature and occurrence of iron ores in certain parts of the world.? Owing to the importance of this subject, it has been deemed' advisable to publish the remarks made at that meeting in the form of a paper, for presentation at the Milwaukee Meeting, instead of in the usual place, under News of Local Sections. The remarks related to the following districts: Brazil, by E. C. Harder, of the U. S. Geological Survey; Scandinavia, by Waldemar Lindgren, of the U. S. Geological Survey; Cuba, by C. M. Weld, of the U. S. Bureau 'of Mines; Southern Europe, by A. C. Spencer, of the U. S. Geological Survey; China, by H. Foster Bain, of the U. S. Bureau of Mines; Alsace-Lorraine, by Sidney Paige, of the U. S. Geological Survey. BRAZIL By E. C. Harder During the years immediately preceding the war, the iron ores of Brazil were attracting the attention of iron operators both in Europe and in the United States. This was clue to the large quantities of practically undeveloped ore available, and to its great purity. It is reasonably safe to state that had capital not been diverted from the exploitation of these deposits to war purposes, Brazilian iron ores would probably now be offered in European and American markets. It is certain that after the war these ores will play a prominent part in the economic reconstruction of Europe and perhaps in the development of America.

Jan 9, 1918

By Thomas Varley

Data on the consumption of reagents used in flotation during the years 1923 and 1924, in metallurgical plants in the Unites States, are presented in this paper. Two previous reports Lave been issued by the Bureau of Mines on consumption of oils and other reagents used to flotation - namely, "Statement of Flotation Oils," by O. C. Ralston, issued in 1913, and Serial No. 2203, "Consumption of Reagents Used in Flotation," by Thomas Varley, for the year 1919, issued in January, 1921.

Jan 1, 1925

By C. -G. Berg, J. T. Tuominen

Since the beginning of the 20th century, energy efficiency in copper smelting has been improved by a factor of 30 as a result of adopting autogenous smelting processes with more and more efficient waste heat recovery systems, increasing use of oxygen enrichment and countless smaller improvements. Nevertheless, energy in the form of electricity and fuels continues to be the biggest contributor to smelter operating cost. Metallurgists around the world are under constant pressure to find ways to save those precious megajoules wherever they can. One area that is often neglected is the removal of water contained in concentrates. Copper flotation concentrates, as delivered to a smelter, typically contain some 8–12% moisture. This moisture must be removed and the only way to do this is by evaporation, which consumes a lot of energy. Several studies have shown that the most efficient way of removing this moisture is to use a steam- heated indirect dryer—the least efficient way being the feeding of wet concentrate directly into a smelting furnace. Even in the most efficient smelters that employ modern steam drying, the energy needed to remove the moisture from the concentrates constitutes over 15% of the total energy consumption of a smelter – acid plant complex. The major steps that have been taken in the past to lower the energy consumption of moisture removal are the use of drying in general and the adoption of steam drying. The energy efficiency of concentrate drying has been improved by 25% over the last 20 years. The latest giant leap in this area, the Kumera Heat Recovery Dryer, is the result of Kumera’s long-term development in improving the efficiency of concentrate drying. The Heat Recovery Dryer is a novel application of steam drying that uses the waste heat from dryer exhaust gas for drying concentrates, thus, cutting the energy consumption by a further 30%. This paper discusses energy consumption in copper smelting in general and analyzes the energy consumption of concentrate drying in detail. Different dryer types are compared especially from the perspectives of energy consumption and environmental emissions. Applicability of different energy sources for drying is evaluated and discussed. The principle of the Kumera Heat Recovery Dryer is presented along with results from extensive continuous pilot plant tests. Potential applications and the feasibility of Kumera Heat Recovery Drying technology are discussed.

Jan 1, 2019

By d&apos, Kathleen J. Amico

This summary appears in Minerals Yearbook volumes I-II, and III, which cover mineral production in the United States, its island possessions, the Canal Zone, and the Commonweath of Puerto Rico, as well as the principal minerals imported into and exported from the United States. The sections of this chapter and the area chapters in volume III contain further details on production. A summary table comparing world and U.S. mineral production also is included. Mineral production may be measured at any of several stages of extraction and processing. The stage of measurement used in the chapter is normally what is termed "mine output." It usually refers to minerals in the form in which they are first extracted from the ground, but customarily includes for some minerals the product of auxiliary processing operations at or near mines.

Jan 1, 1967

Many persons hold the opinion that the metal indus- ries are fortuitous and that the occupation is one of sordid toil, and altogether a kind of business requir- ing not so much skill as labour. But as for myself, when I reflect carefully upon its special points one by one, it appears to be far otherwise. So wrote Georgius Agricola in 1556. He could have been espousing the sentiments of an indus- trial archaeologist investigating mining sites in 1986. South Australia has a very rich legacy from its industrial past-especially in the area of its mining history. Industrial archaeology, which is part of the broad field of archaeology, is concerned with the material and documentary remains of this industrial past. This includes the products and processes of manufacturing, industrial, technolog- ical and engineering activity and their relation- ships to people and the environment. `Archaeology' immediately conjures up the image of excavations in Greece or Eygpt. Excavation however is only a part of archaeological methodology. Industrial archaeology utilizes documentary historical rec- ords combined with field survey techniques (both above and below ground) to create a composite picture of the past. Interest in our recent past has burgeoned in Australia in the last few years. This interest manifests itself in many ways-the unprecedented popularity of Australiana and col- lecting, the plethora of Australian historic films, the growth of the National Trust, local historical societies and genealogical research. Fortunately these trends have been reflected in academic and legislative circles. Various univers- ities, institutes of technology and colleges of advanced education run courses in aspects of cul- tural resource management and conservation of the historic environment. These courses are com- prised of archaeology, architecture, geography, his- tory, materials conservation, museum studies, and national parks management and planning.

Jan 1, 1987

By R. V. Ramani, R. Stefanko, G. W. Luxbacher

MINE VENTILATION NETWORK ANALYSIS

Jan 1, 1977

By Arthur E. Bousu, C. T. Eddy, L. W. Eastwood

The recrystallization and grain-growth phenomena of cold-worked metals have considerable industrial importance because of their role in the fabrication of metals. For this reason, and because of the general academic interest in the subject, these processes have received considerable attention since the time of J. E. Stead's paper1 on The Crystalline Structure of Iron and Steel. There are considerable differences of opinion regarding the theory of recrystallization and grain growth and also differences in the observation of the modus operandi of the processes themselves. The value of many of the existing quantitative data on grain growth is decreased by the failure to distinguish between the grain sizes just after complete recrystallization and those resulting from coalescence. For this reason also, the value of the diagrams of stable grain sizes, like those produced by Bass and Glocker2 and Czochralski3, is lessened in so far as an interpretation of the facts of recrystallization is concerned. It is hoped that the data presentcd in this paper will help to clarify and to simplify the facts relating to recrystallization, and at the same time will show that some of the present-day conceptions are untenable. A paper on the theory of recrystallization, with additional data, will be completed in the near future by the writers. Since the literature on the subject has been adequately and frequently reviewed, the only referenccs to it in this paper will be those necessary in the discussion of the data presented.

Jan 1, 1935

By Enever JR

In-situ rock stress measurements conducted in the Phillipines and on Bougainville have revealed stress fields significantly different from expectations based on intraplate experience. The results have potential significance in regard to both engineering practice in the Pacific Rim region as well as in helping to understand the geological processes occuring near subduction Zones.

Jan 1, 1987

By Yu A. B

An experimental study of the packing of a coal heap has been carried out. The bulk density of a coal heap is considered as a function of a number of variables, viz flow rate, conveyor belt speed, the height of the disengagement point of the conveyor belt, coal particle density, moisture content, the size of the heap and coal particle size distribution. The effects of the dimensionless numbers resulting from dimensional analysis on the packing density of a coal heap have been experimentally examined and analysed. Based on the experimental results, equations have been formulated for the estimation of the bulk density of a coal stockpile. The validity of these equations are checked by comparing the predictions with measurements of real industrial Stockpiles.

Jan 1, 1991

By Yinxiang W, Chunlai Y

In older to improve efficiency of surface pre--grouting in sealing off water in heavily water-bearing strata, such as sandstone,siltstone and limestone, several methods have been used in China, they are ; intermittent pre-grouting, adjusting pre-grouting parameters and stepwise repeated pre-grouting methods. The paper describes effect of deviation on water sealing in pre-grouting. Deviation correction measures, like mechanical, technological and changing hole position methods have been introduced with satisfactory results in practical engineering projects without increasing the volume of engineering project and without causing delay.

Jan 1, 1988

By D Sidea

There has been increased focus in Australia on large diameter raise boring for ventilation shafts and orepass excavation in good quality, brittle, highly stressed rock. As mining in many parts of Australia progresses to deeper levels, more vertical openings are being excavated in highly stressed ground conditions. However, whilst shafts have been successfully raise bored in highly stressed rock, it is often at a significantly increased risk of loss or damage to inhole equipment. It is important for both mine owners and contractors to have an appreciation of these risks at the planning and tendering phases of raise boring contracts. This paper provides an understanding of the risks associated with large diameter raise boring and a review of methods to predict failure in highly stressed rock.

Jan 1, 2005

By LaBrooy SR

A number of gold processing plants in Western Australia have nickel in their ores, leading to significant levels of nickel on their loaded carbon. The presence of nickel during leaching, adsorption and elution'may have detrimental effects on cyanide consumption, carbon inventory requirements, stripping costs, electrowinning efficiencies and may contaminate the gold bullion.This paper discusses the competitive adsorption of gold and nickel cyanides onto activated carbon and investigates changes in solution parameters that may improve gold adsorption and/or inhibit nickel adsorotion.

Jan 1, 1997

By T. Tamenti

The purpose of the project was to conduct a feasibility study to determine if the current operating bottom dump trucks that haul coal should be replaced with rear dump trucks. The engineering availability of the bottom dump trucks was lower than targeted while the operating costs are the highest of all coal haulers within the Anglo Coal opencasts. To determine if it is feasible to replace the current bottom dump trucks with rear dump trucks, a production profile simulation was conducted to determine the number of rear dump trucks that would be required to meet the annual coal hauling requirements. The total capital and operating costs of these rear dump trucks were also determined using a total cost of ownership model. These were compared with the current costs of the bottom dump trucks to determine if it is financially feasible to replace the bottom dump trucks with rear dump trucks. Having considered the capital outlay that would be required to replace the bottom dump trucks with rear dump trucks as well as their respective operating costs, it was concluded that the current bottom dump trucks should be replaced with rear dump trucks. Other factors were considered in coming to this conclusion.

Jan 1, 2007

By A. Mukherjee, C. Kelly, B. Markovich, G. E. Agar, G. E. Robertson, F. Khan, B. Shea

"Laboratory batch flotation tests were performed on a sample of bulk slow cooled converter matte (Cu:Ni = I) to optimize the time in each of the separation stages. Numerical simulations were carried out to estimate a continuous circuit material balance for the conditions selected. An experimental simulation of a continuous circuit (locked cycle test) readily came to steady state and there was reasonable agreement between the numerical and experimental results. The use of nitrogen as the flotation gas and the addition of collector to the grinding mill minimized the oxidation of chalcocite, which has previously resulted in increasing circulating loads, and led to a stable circuit with very low weights in the recycle streams.IntroductionINCO Limited developed a flotation process for separating the components of copper-nickel matte [Sproule, Harcourt and Rose 1945; Sproule, Harcourt and Renzoni 1960] in 1945 to replace the Orford process and continues to use the flotation process in almost the original mode to this day. Initially the matte processed was the result of smelting a nickel concentrate that analyzed about 12% nickel and 2% copper and all of the recycle material that was generated in the smelting process. The matte generated analyzed about 25% copper and 53% nickel, roughly 2: 1 nickel to copper. This matte was blown in Pierce-Smith converters to be sulfur deficient in order to produce a metallic phase that collected the precious metals contained in the smelter feed [Wilson and Stratton-Crawley 1991]. This process continued with little change until 1994 when the separation of chalcopyrite from pentlandite in the Copper Cliff mill was discontinued after 63 years of operation. As a consequence of the elimination of the primary separation of chalcopyrite from pentlandite in the milling process a bulk concentrate was produced for smelting. Bulk concentrate smelting came into practice in 1994 as part of the initiative to meet government legislation that restricted the emission of sulfur dioxide to the atmosphere. Previously, the copper concentrate was smelted in an INCO oxygen flash furnace which resulted in the capture of a high strength sulfur dioxide stream from which liquid sulfur dioxide was produced. Nickel concentrate was smelted in reverberatory furnaces that produced low strength sulfur dioxide gases which were difficult to treat. The action taken by INCO to meet the environmental constraints was to smelt a bulk concentrate in oxygen flash furnaces which would produce gases suitable for the production of liquid sulfur dioxide and another stream that was high enough in sulfur dioxide to be readily converted to sulfuric acid [Bell et al 1990]. The end result of this decision was that all the copper-nickel separation would be done in the matte separation plant."

Jan 1, 1996

By G. A. Reinhardt, Albert Sauveur

Although many metallurgists know that some pearlitic special steels can be made troostitic, martensitic, and even austenitic, without quenching, and, therefore, without exposing them to the dangers of the quenching-bath, the practical significance of such possibility does not seem to have received the attention it deserves. Let us recall briefly the mechanism of the transformation alluded to. In Fig. 1 (after Guillet) is shown the constitutional diagram of nickel-steel; that is, of alloys of iron, carbon, and nickel. Any steel the composition of which falls within the area LPO is pearlitic after slow cooling; any steel the composition of which is represented by a point within the area MLO is martensitic, and any steel within the area MNO is austenitic. Starting with pearlitic steel, then by increasing the carbon-content or the nickel-content, or both, the metal becomes marten-sitic and eventually austenitic; that is, its composition crosses first the boundary-line LO and then the line MO—and it remains martensitic or austenitic after slow (air) cooling.' We have in this way imparted to the metal without quenching it the properties of hardened carbon-steel. In other words, the steel is now self-hardening; Nickel cannot be introduced into solid steel, but by the well-known process of case-hardening it

Jan 1, 1913