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By C. A. Frenzel

Extensive spectroscopic data are needed in making reliable vibrational assignments for use in calculating thermodynamic functions of polyatomic molecules. The fundamental vibrations of organic molecules may be observed at any wavelength from 2.5 to 200 microns (micron = µ = 10-4 centimeters), but most often in the region from 3µ to 50µ. Raman spectra generally cover the range in which fundamental vibrations occur, but equally important infrared spectra usually are not measured at wavelengths longer than 25µ. This limitation results because most infrared spectra are determined for analytical purposes, which seldom require information outside the region 2µ to 25µ. Measurements of infrared spectra in the range 15µ to 35µ recently were begun by the Bureau of Mines to obtain data needed in making vibrational assignments. This report presents the spectra of the following thirteen compounds: Tetrahydrofuran, 1-methylpyrrole, piperidine, 2-methylpyridine, 3-miuthylpyridine, 2-propanethiol, cyclopentanethiol, 2-methyl-2-butanethiol, 3,3-dimethyl-2-thiabutane, cyclohexanethiol, cyclopentyl-l-thiaethane, 2,4-dimethyl-3-thiapentane, and hexamethyldisiloxane.

Jan 1, 1960

By Jr. Watts, B. K. Cantrell, D. H. Carlson, K. L. Rubow, S. T. Bagley

"Permissible exposure limits (PELs) have been established for gaseous pollutants, carbon monoxide (CO), carbon dioxide (CO), nitric oxide (NO), nitrogen dioxide (NO2), and some gas-phase hydrocarbons emitted in diesel exhaust. There is, as yet, no PEL recommended for diesel exhaust aerosol (DEA), nor is there a standard method for sampling this aerosol.The University of Minnesota and the U.S. Bureau of Mines have collaborated to develop a personal diesel exhaust aerosol sampler (PDEAS) which utilizes size-selective inertial impaction and gravimetric analysis. During the field tests of this sampler, numerous air quality measurements were made in underground coal mines that use diesel equipment.The mine mean DEA concentrations for the five mines surveyed, determined with the PDEAS in the haulageway, was 0.89 mg/m3, with a standard deviation of 0.44 mg/m3. DEA contributed 52 % of the respirable aerosol at this location.In three of the mines filter samples were collected for DEA-associated polynuclear aromatic hydrocarbons (PAHs) and biological activity determinations. Two of the mines were also monitored for the major gaseous constituents found in diesel exhaust. In general, the PAH and biological activity levels were similar for all three mines, and indicate that up to 25 % of the haulageway concentrations may be contributed by outby diesel vehicles. Measured concentrations of CO, CO2. NO, NO2, and SO2, were well below regulated levels.INTRODUCTIONDiesel exhaust contains pollutant gases, such as carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and gas-phase hydrocarbons, as well as DEA. Much of the health-related concern focuses on DEA and associated organic compounds (Watts, 1992a). A wide variety of these PAHs have been identified and some are known carcinogens and/or mutagens. The U.S. Mine Safety and Health Administration (MSHA) has proposed new PELs for these and other contaminants (MSHA, 1989). MSHA has also published an advance notice of proposed rulemaking to establish a separate PEL for diesel particulate (MSHA, 1992)."

Nov 1, 1995

By M. J. Adam

The Bureau of Mines is investigating the feasibility of partitioning complex sulfide minerals to simpler sulfide phases by sulfidation reactions. Such partitioning can afford opportunity to improve selective extraction of mineral constituents of value. This report describes research involving sulfidation partitioning of byproduct chalcopyrite concentrates from Missouri lead ore processing, and a Utah chalcopyrite concentrate from Cu ore processing. Small chalcopyrite samples were sulfidized with elemental S in glass capsules sealed after evacuating and backfilling with He, by heating for 1 to 24 h at specific temperatures in the range of 250? to 500? C, extending from below to above the boiling point of S (-4450 C).

Jan 1, 1987

By Walter C, Smith

Metallic bismuth was known in the Middle Ages and the name is supposed to come from the German Wismut. The origin of the German name is uncertain. References to bismuth are found in the writings of Valentine, Paracelsus, and Agricola between 1450 and 1550. Early specimens of bismuth were very impure and often were confused with antimony, tin, and zinc. About the middle of the eighteenth century, J. H. Pott, C. J. Geoffroy, and Torbern Bergman succeeded in producing fairly pure bismuth and showed it to be an elementary metal similar in many respects to lead.

Jan 1, 1953

By S. H. Ash

Introduction Probably the newest thing in mining safety is the apparent dissatisfaction on the part of the mineral industry, as represented by both management and labour, and the general public of many nations in which mining is conducted, with the safety record of the mining industry. This is reflected by published comments in the technical press;' in labour periodicals, in popular Journals and periodicals, and in the daily press (5, 11). Despite what may be said to the contrary, mining in the United States is becoming safer, and this trend has been evident for several years (see Figures 1 to 4). Because the author's experience has been mostly in the United States this paper will discuss briefly some recent observations in the United States that have a bearing on mining safety. Because coal mining is of primary interest to the Mining Society of Nova Scotia, the paper treats mostly of coal-mining safety; however, many hazards in mining .are common to all mines, regardless of the minerals mined.

Jan 1, 1950

By P. J. Bourassa

Incorporated in 1957 under the laws of the Province of Quebec, Quebec Cartier Mining Co. undertook the development of its low-grade iron ore reserves located at Lac Jeannine in the southwest extremity of the Quebec-Labrador trough. This challenge comprised the construction of a 200-mile access road, two towns, a 191-mile-long railroad from Port Cartier to Lac Jeannine, a hydro-electric generating plant on the Hart Jaune River, and mining, crushing, concentrating and ancillary facilities to support a yearly production of 8.0 million tons of iron ore concentrates at 66% Fe. In order to meet increasing market demands for iron ore concentrates concurrently with the depletion of its Lac Jeannine reserves , Quebec Cartier announced, late in 1969, the first step toward bringing into production a new iron ore deposit, known as Mount Wright, located 70 air miles northeast of Lac Jeannine and 25 miles southwest of Labrador City, Newfoundland. In September 1970, the company announced its decision to develop and bring into production its Mount Wright reserves at an annual rate of 1 8.4 million dry long tons. The scope of this project included the construction of an access road linking the mine, the new town and Labrador City, Newfoundland, the extension of the railroad by some 86 miles, the construction of an ore concentrating plant with all the ancillary facilities, the development: of the mine, the construction of a pourer transmission line and a new town adjacent to Lake Daviault. The Mount Wright story is divided into five individual papers covering: (a) the history and development of the project; (b) the mine; (c) plant control by a process computer; (d) crushing, grinding and concentrating; and (e) the townsite of Fermont.

Jan 1, 1977

By E. S. Moore

DEEP oxidation and-secondary enrichment of ore deposits, although so important in many parts of the world, are comparatively rare in the Canadian shield. Intensive glaciation during the Pleistocene epoch accounts for their rarity. Glaciation has cost Canada much in the destruction of not only enriched ore deposits, but placers that must have been developed near our numerous gold deposits during the long period of weathering that pre-ceded the Pleistocene. There seems to be a very common misconception regarding the average depth of rock that has been removed from the shield by glaciers. These bodies of ice are usually given credit for the removal of the greater portion of the thousands of feet of rock that we know has been eroded from this large area since Precambrian time. As a matter of fact, the average thickness of solid rock removed can be measured in tens rather than even hundreds of feet, although very deep erosion has resulted in some sections where the glacial ice has been constricted in depressions, such as deep valleys and lake basins. On the other hand, there are few areas within the shield where the glaciers have not disturbed practically all of the mantle rock and some feet of the underlying bed-rock. The chances of finding deeply oxidized cappings and enriched ore deposits are therefore comparatively few and these have been found chiefly where favourable structural and topographic conditions for their formation and preservation have existed. Faulting has been responsible for several of these deposits, and easily decomposed rocks, such as. sulphides and carbonates, have been very important factors. Topographic features, such as high and resistant hills, favourably situated with respect to the ore deposits have, in a few cases, played a part in providing protection from glacial erosion and in furnishing head for the descent of surface waters. At least four cases of oxidation to depths quite abnormal in the Canadian shield have so far been found in Ontario. These are the Helen and Josephine iron mines in the Michipicoten district, the Keeley silver mine in South Lor-rain, and the Ross gold mine in Hislop township, Cochrane district. A deeply oxidized zinc deposit of unusual interest occurs in the Precambrian rocks in New York State, not far from the Canadian border, and there arc the well-known iron deposits in the Lake Superior region of the United States.

Jan 1, 1938

By U. Storck

"Shaft sinking for exploitation of the deep potash beds in Saskatchewan involved great difficulties from the very first because of the need to exclude from the shaft the high-pressure water encountered in the overburden. Control of the troublesome Blairmore quicksands was achieved relatively quickly by use of the freezing method and by lining with cast iron tubbing. The unsolved problem remained, however, of sealing the water-bearing Devonian where the formations had extremely low permeability and were thus hard to grout. Long experience in German potash mines had shown that the permanency of the whole mine would be seriously endangered if large amounts of unsaturated salt water were allowed to flow in from the shaft wall and merely removed by pumping. The prevention of water movement and the resulting dissolution of salt in the overburden were known to be most important. In the Alwinsal shaft, water flow from the Devonian has been prevented by the use of a steel and concrete sandwich lining similar in principle to a kind of lining introduced a few years earlier, and for another reason, in German coal shafts. As its installation is neither more expensive nor more time consuming than that of cast iron tubbing lining, this same lining was also chosen as protection against the Blairmore quicksands. The great advantage of the steel lining, in addition to its relatively high strength, is the fact that it is possible to make the joints of the individual segments absolutely and permanently water-tight by means of tested welds. The virtual dryness of the Alwinsal shaft will also result in lower costs because significant corrosion of all its steel installations, including skips, cage and ropes, will be prevented."

Jan 1, 1968

By F. J. Sotiuo

Variability of the quality of phosphate ore feed to the flotation plant has been of great concern for the industry. This variability sometimes resulted in 10% to 50% decrease of P2O5 recovery, a reduction of P2O5 concentrate grade and/or both due to depression of the system. For this investigation, samples of refractory ore and easy-to-float ore were obtained from the same mining area in Central Florida; and then submitted to bench flotation tests using fatty acids (FA). To understand the cause of difference in flotation behavior of these apparently similar ores (grade, mineralogy, and physical appearance), bulk and surface characterization studies were conducted. Based on the results of characterization studies and bench flotation tests on both refractory and easy-to-float samples, it was possible to determine FA surface coverage. It was found that the surface coverage for the refractory ore was between 6.9% and 9.8%, corresponding to 0% and 80% recovery, respectively; whereas the easy-to-float ore showed surface coverage of 17.2% (89% recovery) to 24.6% (98% recovery). Since size analysis, surface area and pore size measurements showed small differences, it was thought that the surface coverage differences could be caused by the ad-sorption of natural compounds onto the phosphate ore surfaces, depressing the system. SEM, EDS, and Leaching and Solvent Extraction (LSX) studies were performed on the phosphate ores to demonstrate the proposed mechanism. This paper summarized our characterization studies, flotation results, and findings. The study showed that the new identified compounds were responsible for the flotation behaviors of the Florida refractory phosphate ores.

Jan 1, 2014

By Champoux. G., E. Ghali, W. Zhang, G. Monteith, A. -M. Lafront, G. Houlachi

The efficiency of the electrowinning process of zinc depends on the performance of oxygen evolution reaction, anode quality and corrosion resistance of lead anodes. Original surfaces of rolled commercial lead-silver anodes were examined using conventional polarisation methods in acid zinc sulfate electrolyte with manganese sulphate at 38 °C. The self-discharge method (potential decay) following 5 h polarisation at 50 mA cm-2 was considered to evaluate electrochemical activity, oxygen overpotential and anode stability. The influence of silver content is compared to that of the microstructure, the fabrication process and the composition of the corrosion products. Polished anode samples have also been examined for microstructural and corrosion performance studies. The experiments show that the duration of the plateau at 1600 mV versus SHE, the potential level (active corrosion state/stationary state) and the rate AEco/At during the decay could be a good indicator to compare the corrosion rates of the anodes in industrial zinc electrolytes.

Jan 1, 2008

By B. R. Boardman

Project Environmental Approval is a multi-faceted issue. From a mining perspective, it is a costly item because of avoidable time delay. The government perspective is that the approvals are a necessary part of meeting departmental requirements to ensure that the wellbeing of other uses of the environment is maintained. This paper outlines some of the problems inherent in the environmental approvals process and makes recommendations to both the proponent and government about improving the efficiency of the process.

Jan 1, 1978

By M. S. Prasad

In earlier work it has been shown that paper filler clay products can be obtained from primary kaolin deposits of Minnesota. The objective of the current work was to reduce silica and iron contaminants and to maximize kaolin recovery to higher value products suitable for paper coating. This results in achieving a finer and cleaner product conforming to paper coating specifications. Cationic flotation and high gradient magnetic separation were used to remove free silica and iron, respectively, while attrition grinding and ultrasonics have been examined for particle size reduction. The results of this work are presented and discussed particularly with respect to application-oriented product properties. Budgetary estimates are presented for a 200,000 ton/year processing plant based on the process flowsheet developed and optimized by the study.

Jan 1, 1991

By J Miedecke

A metalliferous mine has operated at Storys Creek from the 1890s to 1979. Storys Creek drains from a pristine catchment and National Park and remains as the most degraded stream from historic mining in north-eastern Tasmania. It has been the subject of public concern since the closure, particularly at times of high rainfall such as existed in 1985 and 1986. The mine is located on the banks of the creek, which flows into a major river, the South Esk River, which is one of TasmaniaÆs largest rivers and important for recreational fishing and water supplies. For much of the life of the of the operations tailings were directly discharged into the creek, and in latter years stockpiled or very close to it. Little rehabilitation was carried out at mine closure. The result was erosion and subsequent deposition on the banks of the creek downstream. Direct emissions of adit water and the consequential emission of contaminated ground water to the creek continue to affect water quality. Contaminant loads discharging from the mine and tailings comprise 70% of the metal load in the catchment and are by far the largest single source. Acidity data suggested that the introduction of systems to introduce alkalinity could be effective in ameliorating the residual acid drainage impacts in the Storys Creek catchment. After a period of investigations and trials which proved their effectiveness, treatments adopted have included the following: relocation of tailings to a constructed and clay capped disposal area and rehabilitation of tailings area; crushed limestone addition to stream flows; crushed limestone addition to creek banks and exposed tailings; sealing of a drainage Adit; and construction of an anoxic drain to generate alkalinity to surface waters draining to old mine workings. These innovative treatments have resulted in a marked improvement in water quality draining from the area. The anoxic drain is believed to be one of the few, if any, which has been constructed to have generated high levels of alkalinity from clean waters and offers a solution to the clogging problems experienced in such drains in the past. Similarly, the use of crushed limestone in an active stream has proved effective in buffering acid drainage and removing metals from solution.

Jan 1, 2003

By Thomas M. Nasiatka

Tests with a high-pressure water jet were conducted in the steeply pitching Roslyn No. 5 bituminous coalbed in the Roslyn No. 9 mine, Roslyn, Wash., to determine the feasibility of extracting coal from pillars and from a solid coal face in development without drilling and blasting. During pillar mining, using a hand-held monitor, the best results were obtained with a 0.150-inch- diameter nozzle, a water pressure of 3,500 psi, and a flow rate of 38.5 gpm.3 The rate of mining and productivity were 0.74 ton per minute and 16.6 tons per man-shift, respectively. During development mining, using a monitor mounted on a roof jack, the best results were obtained with a 0.148-inch-diameter nozzle, a water pressure of 4,500 psi, and a flow rate of 40.0 gpm. In one section of the mine where the coal was relatively hard, the rate .of mining and productivity were 0.10 ton per minute and 5.7 tons per man-shift, respectively in another section of the mine where the coal was relatively soft, the rate of mining and productivity were 0.51 ton per minute and 8.3 tons per man-shift, respectively. The tests showed that hydraulic mining methods were more productive than conventional mining methods in pillar mining. In development the productivity of hydraulic mining depended primarily upon the coal hardness. Compared with conventional methods, hydraulic mining methods were less productive where the coal was relatively hard and equally as productive where the coal was relatively soft.

Jan 1, 1963

By E. Latorre, T. S. Golosinski

ABSTRACT; his paper proposes new methodology to define the pit limits that yield the maximum net present value (NPV) for a deposit, under a given economic scenario and for a given discount rate. The method uses an algorithm that combines dynamic programming and heuristics. It was tested for evaluating deposits with different sizes and various grade distributions. For the discount rate of zero, the results confirm that the economic pit limits are the same as that defined using Lerchs Grossman method. However, when discount rates higher than zero are used, the pit limits differ, yielding a higher NPV.

Jan 1, 2011

By J. H. Fowler

Canada's gypsum industry began over two hundred years ago in the Maritime Provinces when farmers attempted to supplement their incomes by selling "land plaster" to traders bound for the United States. Rising from such humble beginnings, gypsum now contributes significantly to the economies of nine of Canada's ten provinces. Thirteen open-pit and three underground mines produced a total of 8.38 million tonnes of crude gypsum and seventeen processing plants manufactured 2.49 million tonnes of finished products in 1985. Recent economic growth in North America has resulted in steady increases in gypsum production, however, competition from foreign producers and by-product gypsum poses a growing threat to Canada's gypsum mining industry.

Jan 1, 1987

By George P. Demopoulos, Yan Zeng, Zhibao Li

Precipitated silica is marketed with a rising demand as reinforcing filler in the rubber industry and as a potential raw material for the synthesis of lithium-ion battery electrodes. Due to an awareness of the environmental impact of the existing processes for the production of precipitated silica, a green and sustainable process was proposed by using sodium bicarbonate (NaHCO3) as an alternative to sulfuric or hydrochloric acid in the precipitation reaction with sodium silicates. The use of NaHCO3 allows for better control of the supersaturation and pH to form silica with desired quality. Additionally, Na2CO3 solution as the process by-product is recyclable because it could be recovered to produce NaHCO3 by absorbing CO2. The solubility of sodium metasilicate nonahydrate (Na2SiO3·9H2O) in the Na-CO3-HCO3-OH-H2O system was measured using a dynamic method in the temperature range from 288.15 to 308.15 K. It is found that the solubility of Na2SiO3·9H2O decreases with increasing concentration of either Na2CO3 or NaOH over the investigated concentration range. With the aid of the OLI platform, a chemical model for the Na2SiO3-Na-CO3-HCO3-OH system was established with newly obtained interaction parameters of the Bromley-Zemaitis model by regression of experimental solubility data. The new model predicted the solubility of Na2SiO3·9H2O in multi-component systems with good agreement and was used to conduct a preliminary feasibility study of the new process.

Jan 1, 2015

By D R. Seaman, B Adamson, F Burns, B A. Seaman, P Manton

The Telfer concentrator, located in the Great Sandy Desert of Western Australia, consists of a dual train gold/copper operation processing ore from one underground and, currently, two open pit mines with differing mineralogy. The flotation circuit of each train was designed to operate in several modes depending on the feed mineralogy. The majority of ore mined at Telfer is processed in a sequential mode where copper minerals are first floated into a saleable copper concentrate followed by the flotation of an auriferous pyrite concentrate which is treated in an on-site hydrometallurgical plant (carbon-in-leach (CIL)). Gold is recovered as a gravity product within the primary grinding circuit, to the copper concentrate, and to a lesser extent, the CIL circuit.Since Telfer was re-opened, with a new concentrator, in 2004, the processing plant has struggled with poor copper concentrate grades, partially due to the excessive entrainment of non-sulfide gangue minerals in the copper flotation circuit and, more recently, due to composite copper particles produced when processing ore from a supplementary satellite pit that has not previously been processed through the new Telfer concentrator. Gold recoveries in the CIL circuit have also been below industry standard. This paper presents the implementation of recent changes made to the circuit to address these performance issues. The reconfiguration of the circuit has involved the installation of the following major equipment items: two ISAMillsÖ in ultra-fine grinding applications (one in the copper circuit and one in the pyrite circuit), two Jameson Cells to improve fine gangue rejection and a bank of 5 + Outotec TC30s to recovery copper and gold from the reground pyrite stream. The equipment was purchased direct from vendors and an engineering firm contracted to design and install the multi-vendor reconfiguration upgrade.CITATION:Seaman, D R, Burns, F, Adamson, B, Seaman, B A and Manton, P, 2012. Telfer processing plant upgrade - The implementation of additional cleaning capacity and the regrinding of copper and pyrite concentrates, in Proceedings 11th AusIMM Mill OperatorsÆ Conference, pp 373-382 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Oct 29, 2012

By M. Kaya

This paper presents an experimental method to determine the degree of gangue entrainment in mechanical flotation cells and proposes new and inexpensive methods to lessen it. The applicability of froth washing and vibration was studied in laboratory, pilot plant, and plant scales. The effect of wash water on metallurgical performance was tested with various streams from the Falconbridge Strathcona mill at laboratory, pilot, and plant scales, with the 2nd cleaner at the Eastmaque Kirkland Lake mill, and with the 2nd and 3rd zinc and 3rd and 4th copper cleaners at Les Mines Selbaie mill. It was found that gangue recovery was closely related to water recovery in all systems. Wash water at an optimum superficial rate from 0.03 to 0.07 cm/s reduced entrainment by anywhere from 30X to 70X. Wash water can be further assisted by mechanical and ultrasonic vibration of the froth. A further rejection of 10 to 20X becomes possible. As a result of this work, a number of plants in Canada and in the United States have evaluated and/or are now using froth washing.

Jan 1, 1990

By E. Galán

The largest Spanish kaolin deposits formed on granites occur in Galicia (NW Spain) due to a widespread kaolinization of Variscan granitoids. This paper provides insight of the origin of this kaolinization process on the basis of a mineralogical and geochemical study carried out in two kaolin deposits, presently mined to be used in the paper industry. Mineral composition of the deeply kaolinized rocks is dominated by well-ordered kaolinite with minor quartz, K-feldspar, mica (illite/muscovite), locally gibbsite, and traces of resistant accessory phases (rutile, ilmenite, zircon and monazite). The content and structural order of the kaolinite decrease with depth. Kaolinite formed by extensive replacement of feldspars (plagioclase). Differential mobilization of major and trace elements during kaolinization has been inferred by using a mass-balance approach. Significant amounts of Na, Ca and minor Mn, Sr, P and U were removed from incipiently leachable minerals (plagioclase and apatite), and K, Rb, Cs and Ba were released from K-feldspar and mica. On the contrary, Ti, Zr, Th, Hf and the REE are retained in the resistant trace minerals that are concentrated in the fine fractions of the kaolins.

Jan 1, 2010