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By C. A. Nogueira, F. Margarido

"A research work has being carried out annmg at evaluating the possibility of treating simultaneously several electrochemical systems of spent batteries using the same process, in order to overcome the high costs and difficulties of selective collection and sorting. Zn-Mn02 systems, representing more than 75% of portable battery market, shall be treated in dedicated processes. The treatment assessment using a single hydrometallurgical process of the other major systems (NiCd, NiMH and Li-ion), having Ni and Co as main metals, was the aim of the research work here reported. Sulfuric acid leaching was demonstrated to be adequate for dissolving more than 90% of the metals of interest contained in batteries. The subsequent separation of metals by solvent extraction, using organophosphorous extractants like DEHPA and Cyanex 272, allowed the production of pure solutions of rare earths, cadmium/manganese, cobalt, nickel and lithium, enabling their further recovering.IntroductionRecycling is the best approach for end-of-life management of spent batteries mainly by environmental reasons but also motivated by resources conservation and, in some cases, by economic profits. Most relevant electrochemical systems of portable cells are Zn-Mn02 (ZMB, alkaline and saline), nickel-cadmium (NiCd), nickel-metal hydride (NiMH) and lithium-ion (LIB). These batteries are collected, sorted and usually treated separately, applying for pyrometallurgical or hydrometallurgical technologies, the former being the most common.Several processes have been developed and some of them industrially applied, as described in some available review papers [l, 2]. In Europe for ZMB systems the oldest processes are Batrec [3] and Citron [4]. Although having differences in details, both are based on pyrometallurgical recovery of zinc by distillation, in metallic or oxide forms, being manganese retained in the slag together with iron. Hydrometallurgical alternatives are also available, like Zincex [5] and Recupyl [ 6] processes, both using sulfuric acid solutions as leachant. The application of the existing technologies to battery recycling, instead of using dedicated processes, is other alternative already tested, being the Waeltz furnace or the Imperial Smelting some examples."

Jan 1, 2012

By Sang-Beom Lee

For thermodynamic prediction, the deoxidation equilibrium of aluminum in Fe-36%Ni alloy was studied with a cold crucible under Ar gas atmosphere at 1773K. For the deoxidation reaction in liquid Fe-36%Ni base, i.e.: A12O3(s) = 2A1 + 3O The interaction parameters and the equilibrium constant between aluminum and oxygen in liquid Fe-36%Ni alloy are given in the following: eo Al = -3.8, roA1=0.9, eAl° = -6.4, rAl° = 700, rAIAIo = 3.1, roA1o = 833 within the composition range of [Al] < 1 mass%. The temperature dependence of the equilibrium constant was obtained in the range of 1773K < T < 1973K by using reported data and present results as follows: log KAo= 0.58-24463.7 / T The deoxidation equilibrium with aluminum in Fe-36%Ni could be thermodynamically well described in the range up [Al] < 1 mass% with first and second order interaction parameters as well as the equilibrium constant determined in this study.

Jan 1, 2002

By John Campbell, Miller. W. E., G. W. Jones

"INTRODUCTION Because of its interest in accident prevention, the Federal Bureau of Mines has cooperated with city officials and utilities in investigating the causes of explosions in sewers, manholes, and other underground spaces and has aided in the development of means to prevent such explosions. For several years this Bureau has cooperated with the Boston Edison Co. and the Boston Consolidated Gas Co. of Boston, Mass.,for the purpose of detecting and eliminating combustible and physiologically harmful gases in manholes in Boston and vicinity.These investigations 5/ have shown that combustible gases from the usual sources — leakage from gas—distributing systems and underground tanks and gasoline wastes — can be located and the dangerous conditions remedied by a well—planned, adequately supervised, systematic, and continuous manhole survey. However, other types of gas contamination, termed ""soil"" gases, are present in manholes at times and are more difficult to eliminate because they have no fixed origin and because seasonal and barometric chances affect their production and passage into the manhole. Soil gases usually are abnormally high in carbon dioxide and low in oxygen and contain varying amounts of methane. They are especially dangerous to men entering manholes because they lack sufficient oxygen to support life."

Feb 1, 1940

By K. Lillkung

The use of secondary sources has become a very attractive option in the production of platinum group metals as the demand for these metals has increased. One of the promising sources are the spent catalysts, which provide an attractive source as they have relatively high metal content compared with the ores where the metal is originally extracted from. The concentration of platinum group metals in catalytic converters is in the range of 0.1-1 mg/g as the concentration in ores is usually less than 10 ppm. Aqueous chloride solutions are claimed to be a cost effective way in which platinum group metals can be brought into solution and concentrated. In this work the effect of different parameters on the dissolution rates of Pt, Pd and Rh were investigated. The parameters investigated were the Cl- concentration, the temperature and applied potential. Chloride concentrations used were 62.5, 90, 125 and 250 g/l. Temperatures were 25, 40, 60, 80 and 94°C. Potentials were 950, 1050, 1150 and 1250 mV vs. SCE for Pt and Rh and 380, 410, 440 and 470 mV vs. SCE for Pd. Dissolution rates were calculated from the current densities determined by potentiostatic measurements. Thin wire electrodes were used in the measurements. As expected, higher temperature, higher potential and higher chloride content generally increasedthe dissolution rate. However, the effect was nonlinear and slightly different for different metals. The results show that strongly oxidizing conditions are needed in order to achieve reasonable dissolution rates. With the highest chloride content and at potential of 1250 mV vs. SCE and 94°C the dissolution rate of Pt was nearly 1 mm/h, whereas in similar conditions Rh achieved a rate of only nearly 100 µm/h. Similarly, with the highest chloride content and at potential of 470 mV vs. SCE at 94 °C the dissolution rate of Pd was nearly 1 mm/h. Keywords: Pt, Pd, Rh, redox potential

Sep 1, 2012

By den Bulck A. Van

In Europe, 50% of the copper originates from recycling. High-Cu containing scraps are regularly rich in impurities like Fe, Ni, Sn and Pb. Many high-Cu containing scraps are fed directly into anode-furnace casting installations or furnaces with limited refining capability. The impurities levels of the anodes produced in these processes should however remain acceptable for further electro-refining. The distribution of Sn between copper and slag has been investigated for conditions relevant to copper converting. Unlike previous studies, this work focuses on the behavior of Sn relevant to fire refining conditions, which are essential for anode refineries.In this study, liquid Cu–1Sn and CuOx–FeOy–SiO2 slag, with CaO additions, were equilibrated at 1300 °C in vacuum sealed SiO2 ampoules. After metal–slag equilibration, the samples were quenched in water. The composition of the slag and Cu metal was investigated with Electron Probe X-ray Microanalysis. The distribution coefficients of Sn between slag and Cu metal were determined as a function of slag composition.

By P. Kerr

Iron segregation is pre-dated by copper and nickel segregation processes for which the experimental methodology and reaction chemistry were established. The accepted reaction sequence for segregation involves the generation of hydrogen chloride, the chloridization and volatilization of the metal chloride, and precipitation of the metal from the metal chloride in the vicinity of carbon. Iron segregation roasting offers a potential extraction solution for processing oxide deposits with complex mineralogy or waste streams such as Minette-type iron deposits, nickel laterites, ilmenite, red mud, electric arc furnace (EAF) dust, mill scale and slag. After subsequent magnetic separation, one is left with a high grade metallic iron powder which can be marketed for powder metallurgy or briquetted to serve as a direct reduced iron (DRI) product. The non-magnetic product is typically concentrated oxides including rutile, alumina, or oxides of V, P, and rare earths, etc. that may be economically recoverable with subsequent processing. While operating conditions vary for different metals, they share the requirements of an elevated operating temperature and a mixture of oxide ore, carbonaceous additive and a chloride additive in varying amounts all in a closed reactor to allow for reducing conditions and contain the volatile chlorides. This process is then followed by some form of physical separation. Testwork performed by the authors shows promising results that may aid in future development of the process. Segregation roasting of iron will likely never displace traditional beneficiation and ironmaking technologies; however, it has great potential in niche markets where traditional technologies have failed or current technologies generate substantial waste.

By Ying Gu

Automated mineralogy methods and tools, such as the Mineral Liberation Analyzer (MLA) and the QEMSCAN, are now widely used for ore characterization, process design and optimization. Several case studies published recently demonstrate that large gains can be obtained through grinding and flotation optimization guided by automated mineralogy data. However, since automated mineralogy can only provide the information pointing to where the process gains can be made, it does not directly impact the production gain. Thus, a question is often asked: how to value the contribution of automated mineralogy to process improvement of a particular plant. This appears to be a difficult question. On close examination however, it is found that this is essentially a question of the value of information and it is reasonably well documented in various other industries. Hubbard (2010), in chapter 7 ?Measuring the Value of Information?, dealt with exactly this type of problem. The value of information is the reduced risk of an investment and opportunity loss. The methods Hubbard developed can be applied to estimate the value of automated mineralogy, as well as metallurgical test work, which also produces information that reduces the risk of investment. This paper first introduces Hubbard?s theory on the value of information and how to measure it. It then applies his methods to estimate the value of automated mineralogy, using Anglo Platinum?s fine grinding project as an example. In this case, the value of automated mineralogy includes the reduction in investment risk worth US$ 62.5million, in project rejection worth US$197 million and in opportunity loss worth US$320 million. In the end, a general model is developed to allow the simulation of the value of automated mineralogy in different mining operations constrained by different parameters.

Sep 1, 2012

By Stoyan Gaydardzhiev, Michel Shengo, Pierre Kalenga

Lab-scale flotation of copper and cobalt oxidized ore from the Luiswishi deposit in the Katanga province (DRC) has been done focusing on the influence of the degree of process water recycling on metals recovery. Results have shown that at 20 % recycling rate, the recovery of copper and cobalt in the cleaner stage have been respectively reduced to 23 % and 45 % in comparison to 53 % Cu and 63 % Co if process water has not been recycled. At 10 % recycling rate however, the system could still tolerate the effect from recycling, since Cu and Co recovery has remained respectively at acceptable levels of 52 % and 60 %. In order to explain the reasons for the observed worsening of flotation results if process water was recycled at rate higher than 20 %, electrochemical investigation of the pulp has been performed. It has been established that the chemical compounds formed in the pulp when process water was recycled, do influence the sulphidization of malachite and heterogenite and impact further collector adsorption. To confirm these assumptions, the effect from thiosulphate ions presence during the sulphidization of high purity malachite has been studied. It has been found, that thiosulphate ions depending on their concentration in water induce variations in pulp properties such as DO content, pH, Es and contribute to formation of undesirable chemical compounds on mineral surface as identified by DRIFT spectroscopy.

Jan 1, 2014

By Máximo Simón Zavala

El presente texto describe el cambio tecnológico en la disposición de relaves en la unidad minera de producción Marañón a través de la utilización de relaves filtrados para así mejorar la estabilidad física para las condiciones estáticas y pseudoestáticas de los nuevos depósitos de relaves operativos de la unidad de producción Marañón. Asimismo, asegurar la estabilidad hidrológica e hidrogeoquímica, y el cumplimiento de estos requerimientos.

Jan 1, 2015

By S. D. Graham

"The extractive metallurgy of gold is largely controlled by mineralogical factors such as the presence of refractory gold, particle size, gangue mineral associations, presence of preg-robbers, oxygen and cyanide consumers, and locking characteristics in base metal sulphides. Light microscopy and automated mineralogy techniques are regularly used to characterise the effect of these variables on gold recovery. However, despite their widespread application there are a range of limitations when grades are low. Typically, the analysis of low-grade samples requires the preparation and analysis of numerous polished blocks. This is often costly and time consuming, with complexities regarding analysing statistically representative particle quantities and problems overcoming stereological bias. This is compounded by the “nugget” effect and high tenor nature of gold mineralisation. X-ray Microscopy techniques have the potential to overcome many of these problems, in particular the statistical representivity of analysis, removing stereological bias and effectively locating phases that are present in ultra-trace proportions. In this paper we outline the potential benefits of employing X-ray Microscopy (XRM) in characterising gold losses from a typical Cu-Au porphyry project, which were illusive in 2D based analysis. The talk will also outline additional application areas of XRM within the extractive value chain."

Jan 1, 2017

By H. L. Liu

With the exploitation of mineral resources, valuable minerals are more and more finer and poorer. Priority reclaiming liberation grind particle under rough grinding, will help to pervert loss of melts, raise dewatering efficiency of concentrate, reduce consumption of reagent. And it is propitious to reduce energy consumption and raise the utilization rate of resources. With the feature of coarse particle?s desorption and deposition, CLF flotation machine has special pulp circulating way, which is not only apply to treat coarse particle but also normal size particle. The paper advanced the history, the design principle, the structure feature and the application of CLF flotation machine.

Jan 1, 2014

By B. W. Naugle

This report describes the carbonizing properties of coals from the principal beds in Cambria County, Pa. Samples of coals from Upper and Lower Freeport and Upper and Lower Kittanning beds having estimated minable reserves of 50-million tons or more were studied by the Bureau of Mines. Cambria County coals rank either as medium-or low-volatile bituminous. A preparation study indicated that all coals tested in this county, except one sample from the Lower Freeport bed, were responsive to cleaning and would yield a product with satisfactory chemical properties for metallurgical coal. All coals tested from Cambria County yielded strong coke; however, they expand excessively when carbonized singly, and should be used only as minor constituents in metallurgical coking blends when carbonized in slot-type ovens.

Jan 1, 1959

By Noan Tonini SImonassi

As fibras naturais extraídas das folhas do curauá estão entre as mais fortes fibras naturais utilizadas como reforço de compósitos poliméricos para aplicações em engenharia. Tais compósitos, até agora, são limitados em relação às propriedades mecânicas e energia de impacto. Assim o objetivo do presente trabalho é de investigar a possibilidade da melhora da resistência à tração bem como a energia de impacto dos compósitos de matriz poliéster reforçados com fibras de curauá com variados parâmetros de processamento. Os parâmetros observados foram a quantidade de fibras com diâmetro fino e pressão aplicada durante o processamento. Utilizando 60% de fração volumétrica de fibras finas (diâmetro médio variando de 50 à 80 µm) contínuas e alinhadas foi possível se obter resistência à tração superior 200 MPa. Ainda, aplicando-se 30 MPa de pressão durante a cura foram obtidos mais de 270 MPa de resistência a tração. Já para resistência a impacto Izod, uma resistência de 340 J/m foi obtido pelos corpos de prova com entalhe feito em sentido perpendicular ao alinhamento das fibras.

Oct 30, 2017

By E. G. Ozhogina, O. B. Kotova

"The ores of black, non-ferrous, rare, noble metals are mostly distinguished by a variety of mineral types and complexity of their material composition.The article is devoted to the promotion of the concept of mineral processing in modern realitiesof the deficit of high-quality ores and increase their demand.Normative and methodical documentationsfor specific types of analysis with the definition of the field of application are shown. For example,the pyrochlore-monazite-goethite ores from one of the deposits from Eastern Siberia - Chuktukonskoe ore fieldare tested. The development of mineralogical methods, and testing of specific raw materials are shown.The method of small-angle X-ray (and also synchrotron) scattering, which was developed for solving problems associated with structural high-resolution diagnostics, was tested for bauxites of Vezhay-Vorykvinskoye field. KEYWORDS Technological mineralogy, rebellious ores, ore quality assessment, ?mineralogical-analytical methods INTRODUCTION A highly intense production of many types of mineral raw results in gradual depletion and deterioration of mining-geological and mining-technical conditions of development. Relatively easily accessible and rich deposits are getting exhausted in the first place, and it is necessary to involve poor and rebellious ores into production and processing. Traditional technologies can hardly be applied (Chanturia, 2017; Bazin et al., 2014; Ponaryadov, 2017). The urgency of development of the concept of technological mineralogy focuses on the confirmation of new methods and approaches to the development of mineral raw, creation of scientific and methodological prerequisites for solving the problem of rational development of mineral raw, maximal extraction and integrated application of all minerals (both principal and associated), expansion and strengthening of mineral and raw base. The article is aimed at updating tasks that should be addressed within the applied mineralogical researches: – the forecast of quality of ore at early stages of exploration and technological indicators for the redistribution of raw, – interactive monitoring of these indicators by mineralogical and analytical methods; – assessment of environmental consequences of mining and processing of minerals and measures that eliminate these consequences."

Jan 1, 2018

By Matthew Wilcock, Kenichi Soga, Peter Wright

"This paper discusses how an existing grey cast iron segmental tunnel lining responds to construction of a new SCL tunnel transversely beneath with zero clearance; how the damage assessment for the existing tunnel was conducted for impact of longitudinal movement; how the tunnel is subsequently instrumented to observe both movement and stress manifestation at its longitudinal connections and how the results from the instruments compare with the prediction. An assessment of neutral axis of the tunnel in longitudinal flexure is also explored using interpolated horizontal displacement data from a conventional monitoring system. INTRODUCTION The Royal Mail Tunnel (RMT) (formely Post Office Tunnel or ‘Mailrail’) was constructed using semi-mechanised deep level construction techniques from 1914 and 1917 (Lee 1938). Commencing full commercial operation in 1926, the system was until 2003; conveying parcels the 6.5 miles between seven sorting offices in the center of London, and linking the system with main line rail stations, Paddington and Liverpool Street (The British Postal Museum & Archive 2013). A single tunnel of 2.74m internal diameter facilitated a bi-directional twin narrow-gauge (~611mm gauge) railway road system for electric driverless operation. The tunnel lining is segmental grey cast iron (grade 10) made up of six flanged segments and a smaller flanged key segment; constructed into a ring of width 508mm The external diameter of the tunnel is 2.971m. For further details of the tunnel lining and material properties are outlined by (Devriendt & Alhaddad 2014).London Underground Bond Street Station is a major station of the London Underground system in the very center of London; in its vicinity, the RMT runs west-east perpendicularly above the north south Jubilee Line tunnels. Historic survey record of the Jubilee Line’s (the then Fleet Line) construction in 1974 and its impact on the RMT case is documented in (Crossrail 1993): it is one of only a hand full of case-studies frequently cited when assessing the impact of new construction scenarios of this type; not least including the assessment of the same tunnel, at the same site some 40 years later, and the subject material for this paper: It noted significant vertical displacement of ~90mm to the RMT without noticeable serviceability or operational impediment."

Jan 1, 2016

By Sebastian Ernst Volkmann, Felix Lehnen

"INTRODUCTIONWhile today’s mine planning of land-based ore deposits follows methods, which are well established, mining standards for the deep-sea have not established. Having gained a basic understanding of geological settings, there is still a lack of tools and methods to assess and plan future mining projects in the deep-sea. In the framework of the “Blue Mining” research project (2014-2018) technologies and methods for the exploration and exploitation of deep-sea minerals are developed that will bring deep-sea mining a step closer. The “Blue Mining” project receives funding from the European Commission (EC; Framework Programme 7; GA No. 604500) and addresses all aspects of the value chain in the field of deep-sea mining. The project philosophy is that deep-sea mining is planned and executed in the most responsible manner: Ensuring societal benefits and profitability at acceptable resource utilization and lowest possible environmental footprint (Volkmann 2014).Inspired by the high-tech farming industry, a concept to mine seafloor manganese nodules (SMnN) was developed. Mining is considered to be similar to the potato harvest on land (Figure 1), which involves mining a field partitioned into long, narrow strips (Volkmann and Lehnen 2017). The proposed mining system composes of one mining support vessel (MSV), one or two self-propelled, crawler-type seafloor mining tools SMT(s) and different types of underwater vehicles. The MSV follows the mining route of the SMT(s), picking up the about potato-sized nodules from the seafloor. The ore is pre-processed in situ and is lifted on board of the MSV, where the ore is dewatered and loaded onto bulk carriers for transport to the purchaser. Processing and refining of ore is not subject of “Blue Mining” research."

Jan 1, 2017

By Ali Dehghani Ahmadabadi

Gravity separation technique is widely used in mineral beneficiation practices for its low cost, ease of operation, and eco-friendly nature. The most commonly used gravity methods for beneficiation of iron ores are shaking table, jig and spiral methods which aren&apos;t very effective for iron mineral fines. Multi-Gravity Separator (MGS) is suitable for the treatment of fines with a maximum particle size of approximately 500 µm. This study was performed on a low-grade haematite iron ore from Chadormalutailing dams. Detailed mineralogical, physical and chemical characteristics of a goethiticlateritic iron ore showed that the sample contained porous and friable oxides and hydroxides of iron. The ore sample had a feed grade of 35% Fe, 1.1% FeO, 15.5% SiO2 and 8.5% Al2O3. Haematite and goethite are the main iron-bearing minerals while quartzite and kaolinite are the major gangue mineral constituents. In this paper, the statistical evaluation and optimization of grade and recovery using a factorial design of experiment (DOE) method has been carried out for Chadormalulow grade ultra-fine haematite tailings with MGS. The input process parameters considered are drum speed, tilt angle, wash water flow rate and pulp density. The results show considerable improvements in both the quality characteristics such as grade and recovery with statistical evaluation and optimization, compared to the initial value of grade and recovery. Keywords: multi-gravity separator, mgs, statistical evaluation, optimization, haematite

Sep 1, 2012

By C. J. Im

As market conditions become more competitive, U.S. coal producers are faced with the increasing need to find methods of lowering production costs in their operations. One area worthy of investigation is the additional recovery of fine coal that is normally discarded in the preparation plant waste stream. United Coal Company is currently assessing the capability of the Deister Flotaire, a new application of a column flotation cell, to recover additional, saleable coal from preparation plant waste. This paper presents the technical data obtained to date. Work with a 0.76 m (30 inch) diameter cell installed in a plant shows considerable coal recovery is possible from a nominal 0.595 run (28 mesh) X 0 refuse stream.

Jan 1, 1986

By E. Bakhtavar

It is considered that the most economical method for the exploitation of Gol-e-Gohar Area 3 iron ore mine is to combine open-pit and underground methods. In this regard, the most critical problem is the determination of optimal final pit depth. In this paper, a method which was recently introduced on the basis of economical block models of open-pit and underground is used to determine optimal final open-pit depth of Gol-e-Gohar Area 3 mine with due regards to the future underground mining option. Considering a low cost and productive underground method as a feasible alternative for extraction of the lower part of this deposit, room and pillar was selected. It is concluded that after the assessment and comparison of different values for depth, optimal final open-pit depth was determined to be equal to 285 m.

Jan 1, 2010

By J. T. Liu

Packing in a flotation column is one way to increase separation efficiency and effective descending flotation-column height. In this paper, the difference between filling packing and sieve packing is described, and the flaws of filling packing in flotation columns in industrial application are pointed out. A change of flotation process and its effect on flotation results are reported. Based on sieve-plate filling, a high-efficiency mixed packing mode consisting of screen-plate packing and honeycomb-tube packing has been proposed, with the packing mode optimized in the cyclonic static microbubble flotation column in the separation zone. In the mixed packing mode, the honeycomb tubes are used to reduce the vortex effect at the base of the column and weaken the radial dispersion of jetting bubbles, and the sieve plates are used to comminute bubbles in the separation zone, to lengthen the bubble migration path, and to stabilize the foam layer. The superiority of honeycomb-tube packing is analyzed using bubble-particle collision theory, and the dynamic equations of collision probability are derived. The role of mixed packing in guaranteeing mineral recovery is analyzed by the axial dispersion method, and a dimensionless axial dispersion model is derived. When a high-turbulence flow is maintained, a static separation environment is formed in which secondary mineral processing is rendered more effective. In this way, a nonlinear separation environment is formed in the flotation column. Finally, mixed packing was applied in an industrial test. A large vortex developed at the base of the column. It was observed that the bubbles in the radial flow were homogeneously dispersed, the residence time of the pulp was prolonged, and the froth layer became thick and stable. Based on the test data, it was found that the sieve packing has the potential to yield a product of approximately 25.83% copper concentration with 91.78% recovery from a feed concentration of approximately 0.727%. If mixed packing were used, the product concentration could be further increased to 27.60% from a feed of approximately 0.739% concentration with 93.38% recovery.

Jan 1, 2014