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By W. K. Collins

Engineered Scavenger Compounds (ESCs), developed by the U.S. Bureau of Mines, are a novel class of compounds that can selectively recover a desired element from a solid or molten alloy. Lithium titanate (Li2Ti3O7 or L'20-3T'02) is being used as an ESC to recover lithium (Li) from Aluminum-Lithium (Al-Li) alloys. X-ray diffraction measurements have shown that lithium titanate undergoes a phase change from an orthorhombic structure to a hexagonal structure. This change is due to the incorporation of Li in the matrix of the material and the effect of temperature. Although both are metastable, the hexagonal phase that forms during the scavenging of Li from Al-Li alloys appears to be the more stable phase. Recovering Li from the ESC by electrodeposition does not cause the structure to revert to the orthorhombic phase. Both the orthorhombic and the hexagonal structures of Li2Ti3O7 have similar scavenging capacities for Li. This paper proposes a new mechanism for the phase transformation.

Jan 1, 1993

By Yan Zeng

Lithium metal silicates (Li2MSiO4, M = Fe or Mn) composed of abundant and non-toxic elements are important cathode materials for Li-ion batteries (LIB). In contrast to solid-state or sol-gel methods, hydrothermal synthesis conducted in pressure reactors is a favorable processing route as it provides the potential for scalable production and is environmentally benign. However, the key is to control the precipitation reaction to obtain powders with desired properties to meet battery specifications. Through a systematic study, we have found that Li2MSiO4 with tunable size from 300 nm to 1.5 μm can be produced by adjusting precursor concentrations, temperature, and reaction time. Under optimum conditions, high purity Li2MSiO4 with minimum defects were successfully produced and examined as an LIB cathode. The use of complexing agents promoted the formation of unique hollow particles via the self-assembling of elongated crystals. A four-step formation mechanism is proposed based on extensive characterizations with XRD, HR-TEM, SEM, and Mössbauer spectroscopy.

By Kimio Itagaki, Makoto Ohtsuka, Kouki Chiba, Minoru Matsumoto

"The properties of Ni-Mn-Ga films such as chemical composition, crystal structure, microstructure and transformation temperature were investigated with respect to sputtering conditions in the present study. The Ni-Mn-Ga films were deposited on a polyvinyl alcohol substrate with a radio-frequency magnetron sputtering apparatus using the NisoMn2sGa2s and Nis2Mn:«1Ga24 targets. After separating from the substrates, the films were annealed at the temperature between 873 and 1273 K for 3.6 ks. The chemical composition of the films depended on the radiofrequency generating power, however, there was no dependence on the heat treatment temperature. Each deposited film had a columnar grain structure. After heat treatment, the width of columnar grains widened and then became indistinct with increasing heat treatment temperature. The Heusler type cubic crystal structure of the fi4n with heat treatment at 1073 K changed to the tetragonal one through the martensitic structural transformation during cooling. The martensitic structural transformation temperature increased with increasing nickel content of films, while the Curie temperature decreased. The film obtained at 200 W using the Nis2Mn24Ga24 target after heat treatment at 1073 K showed one-way shape memory effect through the reverse martensitic structural transformation during heating.IntroductionThe ternary intermetallic compound NiiMnGa has a Heusler-type crystal structure and is an intelligent material, which has a shape memory effect and a ferromagnetic property. The martensitic structural transformation occurs within the ferromagnetic temperature region. The cubic crystal structure of L21 at high temperature changes to a tetragonal one through the martehsitic structural transformation during cooling. The films of this compound can be applied for an actuator of micro-machines."

Jan 1, 2000

By Georgene Renner, Chee Theng, William Gleason

"In February 2018, drawn in part by the states’ proud mining heritage, SME took its Annual Conference & Expo to Minneapolis, MN for the first time. More than 5,000 people and 554 exhibitors converged on the Minneapolis Convention Center for three days of networking, exhibiting and technical sessions.The state’s mining legacy, one that continues today, is fueled in large part by its vast iron ore resources in the northern part of the state. The historical significance of the mines in the Mesabi Range, otherwise known as the Iron Range north of Lake Superior, cannot be understated. “Mining is a way of life here,” said U.S. Congressman Rick Nolan of Minnesota’s 8th Congressional District. A native of the Iron Range, the three-term U.S. congressman was one of the featured speakers of the opening keynote session. “We like to think we contribute enormously to the well-being of this country and the world. We were the source of the iron ore and steel that helped win two world wars. And we like to think that we are part of the progress that has taken place in the United States ever since.” Nolan kicked off the keynote sessionthat focused on innovation and its part in the mining industry. The session included Rene Aquilar, vice president of corporate affairs and sustainability, Antofagasta Minerals Group; Bob Anderson, vice president for research and development, 3M; Rolf Weberg, executive director, Natural Resources Research Institute, University of Minnesota-Duluth and Christopher Beck, executive vice president and president, Nalco Water. The panel session looked at U.S. and global minerals production, and the importance of the United States to maintain a major role in the minerals industry, both as a producer and as a technology leader. The panel also touched on the global mining industry and the issues that impact mining around the world. Sustainability, the use of water in mining and earning a social license to operate were among the topics discussed by the panel.Speaking of the importance of mining, Nolan conceded that talking about the benefits of mining to the crowded auditorium at the SME conference might be akin to a preacher speaking to the choir, but, following the adage that all politics are local, he continued to illustrate his point by emphasizing the importance of mining to the Great Lakes.“A study by Homeland Security concluded that 13 percent of the nation’s GDP comes out of Lake Superior through the locks at Sault Ste. Marie and most of that is iron ore,” said Nolan. “That study found that, if those locks fail, it would create a national depression. It would put millions of people out of work. That ore and those minerals supply the steel mills, the auto industry, the heavy industrials. They are the heart of our economy. The study concluded that if the states that make up the Great Lakes were a nation, it would be the fourth largest economy in the world.”"

Jan 5, 2018

By D Johansson, C Yi

Blasting techniques are widely used to fragment rock masses into smaller pieces. Numerical modelling is an efficient method employed by many researchers in the blasting field. It is difficult for a conventional continuum-based approach such as the finite element method (FEM) to model the rock fragmentation by blasting and the expansion work on the rock by explosive and its detonation products. In this paper, the particle blast method (PBM) was employed to model the behaviour of the detonation and a bonded particle model (BPM) was used to model the brittle material to be blasted. A mortar cylinder with a centrally placed hole for the explosive was modelled and the results were compared to the experimental data. The blast process from crack initiation to fragment formation was analysed. The influence of coupling ratio on fragmentation was also investigated.CITATION:Yi, C and Johansson, D, 2015. Discrete element modelling of blast fragmentation of a mortar cylinder, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 793–798 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By P. G. Corser

A gold and silver open-pit mine located in northwestern Chile contracted ACZ in 1991-92 to assess the stability of their spent ore pile and to determine the cause and magnitude of cyanide contamination associated with leaching operations. The mine is a conventional open-pit located at an elevation of approximately 4,800 meters (m.) (15,744 feet). A spent ore pile is located approximately 2,000 m. southwest of the mine and approximately 1,000 m. northeast of the active pad and plant facilities. The pile was constructed on a gentle northwest slope dipping 12 to 13 degrees. The pile is bordered by a small river to the northwest and by a larger river to the northeast. Both rivers eventually flow into Bolivia. Heap leaching and processing commenced at the mine in 1988. Since 1988, nearly 6.0 million tons of ore at an average grade of 1.96 grams/ton (0.07 ounces/ton) of gold and 52 grams/ton (1.83 ounces/ton) of silver have been treated by cyanide heap leach methods with zinc (Merrill Crowe) precipitation. In approximately three years of operation, the mine has yielded more than 225,000 ounces of gold and over 1.5 million ounces of silver. Currently ore is agglomerated and hauled to the leach pad by truck and is top loaded to produce a 5-meter lift height. Four contiguous reusable (on/off) leaching pads were constructed with an asphalt layer above a carefully compacted sub-base of High Density Polyethylene (HDPE) liner and screened fines. Leach solution of pH 10-11 containing 1.2 to 1.5 gram/liter of cyanide is applied to the heap at a rate of 10 liter/hour/square meter for a total active application period of 30 days. Leached (spent) ore is transferred to the spent ore pile located approximately 1,000 meters to the northeast. The pile currently contains approximately 6 million tons of spent ore. The pile liner, which has been constructed over a prepared sub-grade consists of three geosynthetic layers (geotextile/flexible membrane liner/geotextile). Long term objectives include washing the pile to recover an additional 3 to 4 percent gold and silver.

Jan 1, 1993

By J. Qiu

By means of natural sedimentation, two different bentonite samples from Shandong province were purified, this paper studies the Hydro-properties of the two purified montmorillonite samples. Firstly, the layer charge of two purified montmorillonite samples were calculated by crystal structure formula reckon method and general hydro-properties were also measured. The research results showed that the layer charge of montmorillonite correlated well with its hydro-properties: mont-morillonite with lower layer charge had better hydro-properties, such as Mont-1, which had higher swelling volume and gelling value with lower CEC; while, montmorillonite with higher layer charge had worse hydro-properties, such as Mont-2, which had lower swell volume and gelling value with higher CEC; it proves that the hydro-properties of montmorillonite depends on its layer charge characteristics, layer charge characteristic is the inherent factors deciding the hydro-properties of montmorillonite, montmorillonite with lower layer charge has better hydro-properties than the one with higher layer charge. In this paper, the relation between the medium condition and colloid performance of Mont-1 are also studied. The results show that the hydro-properties of Mont-1 could be changed by changing slurry concentration (w/w) and shear rate or adding certain amounts of inorganic cation electrolytes, dispersants and surfactants. The viscosity of montmorillonite slurry could be enhanced by increasing slurry concentration,adding univalentcation electrolytes (less than 4% w/w) or proper amounts of dispersants and surfactants (less than critical micelle concentration); The slurry viscosity could be reduced by decreasing slurry concentration, increasing shear rate, adding proper bivalent (more than 4% w/w) cation electrolytes or proper quantities of dispersants and surfactants (more than critical micelle concentration).

Jan 1, 2014

By Theodore H. Eyde

In 1971, the Minerals Division of The Superior Oil Company acquired exploration rights to an unpatented claim group in the Superior (Pioneer), Arizona mining district, lying west of the Concentrator fault. This major post-mineral fault displaces the Magma vein-fault, which is mined in the Magma Mine at Superior, Arizona. The Magma vein-fault and the enclosing section of pre-mineral rocks consisting of Paleozoic and younger Precambrian sediments and diabase, is overlain by a thick section of post-mineral rocks, consisting of the Gila conglomerate, the Apache Leap dacite, and the Whitetail conglomerate. Geologic information on the thickness and attitudes of the rocks obtained from previous diamond drilling indicated that the section of post-mineral rocks might be from 3,000 to over 4,010 feet thick in the target area. (Figure 1) The Magma vein-fault is a steeply dipping vein which has produced nearly a billion dollars of copper, zinc, silver, and gold. It has been mined continuously for nearly 10,000 feet along the strike and nearly 5,000, feet vertically down the dip. It ranges from less than a foot to over 50 feet wide and contains sulfide mineralization con¬sisting of pyrite, chalcopyrite, bornite, and chalcocite.

Jan 1, 1973

By Arkady Senchenko, Andrey Vasiliev, Alexander Aksenov, Metodi Zlatev

"This paper considers the issue of treating argillaceous oxidized ores with low gold grade (around 1.0 g/t). These ores according to their gold recovery level can be treated by heap leaching and agitation cyanide leaching, but low gold grade makes this treatment uneconomic. Heap leaching of argillaceous ores requires high consumption of binding agent for pelletizing to create suitable hydro-physical properties of material, which leads to increasing process cost and makes the material treatment unprofitable. Agitation cyanide leaching of this ore requires grinding processes; these expenses would not be paid back by the amount of gold recovered. Considering the above, poor argillaceous oxidized ores are recommended to be treated according to a combined technology including fractionation of ore, heap leaching of coarse fraction and agitation leaching of argillaceous fraction. Complex approach application allows one to avoid expenses incurred for material grinding and high consumption of binding agent for pelletizing. The success of this technology implementation will firstly depend on the quality of material fractionation, therefore the section of disintegration and division of ore into different components will be the most important part of flowsheet development for gold production. When disintegrating minerals at positive temperatures both standard (mechanical disintegration - scrubbers) and innovative (hydraulic method of disintegration - HydroClean units) equipment is applicable. HydroClean units are characterized by lower energy and water consumption. In a number of cases it is required to treat frozen ores. When treating frozen material standard approaches to disintegration are not reasonable due to their low efficiency. In order to treat frozen material a two stage disintegration flowsheet with screening after each stage is recommended. The first stage is recommended to be performed in a scrubber, the second - in a HydroClean unit. This technological flowsheet will provide high and steady values for ore separation into fractions at low energy consumption for disintegration."

Jan 1, 2014

By Tuula Mäkinen, Lauri Pesonen, Peter Björklund, Jouni Pihlasalo, Mikko Korpi

Outotec Direct Blister Flash Smelting technology has proved to be an efficient and environmentally friendly way to treat copper concentrates from the Zambian Copperbelt at Konkola Copper Mines' (KCM) Nchanga smelter in Zambia. The modeling of slag chemistry and thermodynamics with MTDATA software played a central role in deciding the operation parameters for the smelter. Outotec FSF Online Process Advisor is used to calculate the process parameters and to give valuable information of the process state for the operating personnel. The pre-calculated slag liquidus graphs are also integrated to the Online Advisor.

Jan 1, 2011

By G. V. Sullivan

The Bureau of Mines conducted preliminary beneficiation studies of a gold-bearing graphitic schist from Blue Hill, Tallapoosa County, Ala. The average analysis of the material was 0.08 oz/ton gold. Tabling of minus 35-mesh material recovered 83 to 94 percent of the gold at grades of 6.925 to 2.165 oz/ton, respectively. A combination of jigging and tabling resulted in a concentrate assaying 24.3 oz/ton gold and contained 87 percent of the total gold. Treatment of the material by jigging, tabling, and amalgamation recovered 86.5 percent of the gold.

Jan 1, 1969

By John D. Thornley

Alaskan villages typically store a one-year supply of fuel to reduce significant delivery costs. Alaska Village Electric Cooperative (AVEC), an electric utility cooperative providing power to 51 Alaska villages, has made a concerted effort to upgrade and improve their undersized and aging facilities. The Village of Stebbins, located south of Nome on Norton Sound is receiving upgrades to its AVEC bulk fuel facilities. Stebbins offered unique challenges from a foundations perspective due to the nature of the soil. The geotechnical investigation found the soil below roughly a third of the footprint of the bulk fuel facility to be thawed with seasonal freezing and the remainder was found to be warm permafrost with ground temperatures of between 30°F and 32°F. This is a unique and challenging arctic engineering design issue because foundations are designed differently for frozen ground conditions. Driven piles were selected because of site constraints, such as the design flood elevation and the change from thawed to frozen ground conditions. The pile design specified that the pile embedment depths would be selected based on the results of pile driving analyzer (PDA) testing during construction in the thawed ground and maintained within the frozen ground portion of the footprint. Difficulties during pile driving in the frozen ground resulted in several piles becoming severely damaged, requiring subsequent removal. This resulted in a reevaluation of the means and methods for pile installation. Additional fieldwork was performed to further characterize the subsurface soils and their frozen nature. Options for installation of piles in difficult areas were evaluated including ground thawing, predrilling, and reducing embedment depths. Presented within this paper are the findings from the initial and subsequent field explorations, discussion of the design methodology, and the decisions that led to successful installation of piles at this challenging remote village.

Jan 1, 2017

By D Laurence, L Ge

This paper demonstrates use of remotely sensed imagery in promoting sustainable mining. Remote sensing technology can be used during all phases of a mining project û from evaluating the resource, to making extraction more cost-effective, through to monitoring, mine closure and remediation. Use of the new generation of satellite platforms with the capability of acquiring satellite data with higher spectral and spatial resolution have the capability to emerge as essential indicator for sustainable development in the minerals industry. A life cycle approach to satellite imagery is discussed. The use of an imagery of the site prior to mining activity establishes the environmental baseline, guides mitigation measures and eventual help in suggesting remediation. Remote imagery provides the cost-effective means of monitoring reclamation, including the growth of planted vegetation, of the mine site and surrounding area. The latest advancements in satellite remote sensing are highlighted to meet the newer challenges of sustainable mining practices. Some of the worldwide successful remote sensing applications for the measurement and evaluation of the sustainable development impact of mining operations are described. Presently available source of imagery and its comparative advantages and disadvantages are provided as a guide. Finally, the limitations of this tool are indicated.

Jan 1, 2009

By W. Kasprzak

Modern light metals processing technologies are very complex and involve a diverse set of variables that must be quantitatively evaluated. The most effective way to design new casting processes that deliver specified metallurgical and mechanical properties is to develop a method of simulating the "real-time" process within a test sample of sufficient size. The results can then be analyzed and the required optimizations can be performed. This paper presents a novel method of simulating the industrial casting processes in a laboratory environment using an experimental apparatus based on the principle of high frequency induction heating. The applicability and accuracy of the proposed analytical method is demonstrated, for example, by simulation of the solidification and heat treatment of a test sample composed of two dissimilar materials. The simulation can be used to develop a stress model for an engine block made from an aluminum based alloy with iron cylinder liner inserts.

Jan 1, 2002

By N Robb

This paper gives an account of the laboratory testing, plant testing and final inclusion of the two-stage sulphuric acid leaching process in the Milliken mill. Operational results for September, 1962, are presented, showing a uranium extraction of 95.5 per cent, with a saving of some 16 lbs. of 100 per cent H~S04 and some 9 lbs. of lime per ton milled. Methods for effecting further improvements in the process are indicated. HISTORY P RIOR to the incorporation of two-stage leaching, the process for the treatment of uranium ores at Milliken consisted of a single-stage sulphuric acid leach, followed by a solution recovery step involving washing in thickeners and two-stage filtration. The thickener overflow solution was subsequently concentrated and purified by ion exchange, and the uranium was recovered, by two-stage precipitation, as ammonium diuranate. Figure I illustrates this flowsheet. For satisfactory extraction of uranium from the. Milliken ore, a high residual acidity, of the order of 40 grams per litre of free acid in the discharge solution, must be

Jan 1, 1963

By G. R. Parslow

U, Fe, Mn, Ni, Cu, Zn and Co data for the sediment in both Key and Seahorse lakes, which overlie portions of known economic uranium deposits in the region, are presented. With the exception of U, Fe and Mn, the elemental distributions can be considered anomalous, in a statistical sense, in both lakes. The U values are of particular interest in that Key Lake is not anomalous, whereas Seahorse Lake is markedly anomalous. Tentative correlations made with background data from other surveys in an attempt to differentiate between anomalous and background values indicate that deviations from linearity in a distribution, and not absolute mean or maximum values, are indicative of anomalous samples within the distribution.

Jan 1, 1979

By T. Tumidajski

The purpose of the separation processes in coal processing is obtaining products of certain ash contents. In the most of cases it is assumed that the separation process is described by one, selected parameter, which usually is grain size or material density. The separation may be described by means of statistical distributions of random variables, what allows forecasting the separation results of certain enrichment method. There are very well known the applications of approximations of Tromp separation curves or distribution functions of Erasmus, Meloy or Weibull. It is necessary to say that if the fitness of the approximation more suitable, then the characteristics of the process itself is also better. In purpose of obtaining more appropriate results, these methods were modified by application the mathematical functions, as i.e. hyperbolic tangens function. Furthermore, on the basis of empirical data, so-called interpolations may be performed in purpose of getting more appropriate results of approximation. One of the most known techniques of interpolation is Hughes method. This method for interpolating standard data involves breaking down each interval into a number of smaller sub-intervals. The results of such one-dimensional approach not always contain the full in-formation of the searched distribution. It happens because such interpretation of the problem is not completely correct. In practice, the separation process depends not only on the one parameter (i.e. grain size), but also on many other features characterizing certain material (i.e. its density). It seems then that in some cases the application of multidimensional grain characteristics distributions will be more appropriate. In this paper, the technique of joining the distributions of grain size and density by means of so-called Morgenstern distributions is shown. The general form of these distributions is as following:

Jan 1, 2014

By Norihiro Murayama

Syntheses of zeolitic materials were carried out from coal fly ash by alkali hydrothermal treatment as part of the reuse and recycle technologies of coal ash, For the obtained zeolites, the cation exchange capacity and acid resistance, which are very important in the practical use of cation exchanger in aqueous solution, are investigated during this stufY, The cation exchange amounts of the NaP, CaP and K-CHA zeolites are measured for various cations such as K+, Na +, NH4+ Ca2+, Mg2+, Pb2+, Cd2+ and so on. The change in crystallization degree are researched as a function of pH. The simultaneous removal ability of NH4+ and PO43- in solution is examined for an example of the water purification with CaP zeolite. From these results, the characteristic and its mechanism of cation exchange are clarified for the various zeolitic materials obtained from coal fly ash.

Jan 1, 2003

By Tiago Nunes Lima

As ligas titânio beta têm sido desenvolvidas devido as suas excelentes combinações de boas propriedades mecânicas e alta resistência a ambientes corrosivos. Novas ligas de titânio ao nióbio estão em desenvolvimento e apresentam grande potencial de aplicação em diversas áreas da engenharia. O presente estudo tem como objetivo verificar propriedades mecânicas da liga Ti42Nb2Sn na condição deformada e também envelhecida. Um lote de amostras foi laminado a frio com 80% de encruamento e outro lote foi laminado e envelhecido na temperatura de 400 °C durante 48 horas. Foram realizados ensaios de tração, medidas de dureza, metalografia e microscopia das superfícies de fratura. Foi possível observar baixo valor de módulo de elasticidade e alta ductilidade para a amostra deformada e alta dureza e módulo de elasticidade para a amostra envelhecida.

Aug 16, 2017

By William H. King

Preliminary examination of the Virgin River manganese deposit was made by C. H. Johnson, Bureau of Mines engineer, in March 1941. During, April and May 8 trenches were dug, a 48-foot inclined shaft was sunk, and 719 linear feet of channel samples were cut. McKelvey and Wiese, of the Federal Geological Survey, completed mapping the deposit, including the entire area of overlying formations comprising the point of land between the outcrop and Lake Mead. The geologic maps, maps, and ore estimates resulting from these examinations formed the basis for a preliminary report by C. H. Johnson, who recommended further exploration by diamond drilling.

Jan 1, 1949