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By Darío Innamorati, Jorge Oliva

Cerro Vanguardia is a known gold and silver deposit located in the province of Santa Cruz, Argentina. The mine has been in operation since 1998 and is thought to be one of the most important mines in Patagonia. More than 102 epithermal quartz veins have been identified in the area, with variable lengths, thicknesses, orientations and dips that constitute what is possibly one of the most extensive outcropping vein systems on earth. Veins are vertical and have variable depth. For this reason, the deposit is currently mined with a variety of extraction methods. This operation is made up of more than 60 open pits and 20 underground access ramps to exploit the deepest high grade narrow veins. This study is focused on the combination of underground exploitation with open pit blasting. That is, those production stopes in the upper levels of underground mines and their interaction with the damage levels in the final slope of open pit mines, as well as in the study of the impact of the generation of vibrations from the blasting of open pit mines and their influence on underground mines. Considering the current stage of the mine, after 20 years of operation, Cerro Vanguardia faces the need to mine deeper deposits in the face of increasing costs and declining grades. For this reason, it is essential to study the interaction of these exploitations. From a personnel safety point of view, this interaction must be well coordinated so as not to affect people and equipment. Likewise, the generation of vibrations due to blasting must be studied, which would produce new cracks, potentially generating overbreak and dilution. The main objective of this study is to determine the possible causes and influences of the blasting interaction in open pit and underground mines, seeking an optimization of the blasting process and a safety standard for personnel and equipment. To achieve these goals, this study includes a vibration monitoring plan to analyze the charge performance and determine rock constants. With the use of specialized software, damage modelling and simulations are used to determine values of damage in order to reduce overbreak. In addition, this plan contemplates the estimation of flyrock in blasting where underground work is connected to the surface, determining safety distances when carrying out a blast.

Jan 21, 2025

By Raúl Carretero de la Hoz, Leonardo Soares Chaves, João Paulo Soares Toneli, Francisco Felipe da Silva Dantas, Marcos Peres Lopes, Marcus Vinicius da Silva Gonçalves

The mining activity results in environmental impact and thus requires the adoption of techniques to minimize its effects. The rock blasting process is required to break up and move the rock enabling the haulage of the material, however, it might also cause undesirable effects such as flyrock, overbreak, excessive ground vibration or air-blast at the neighboring communities and damage to civil or geological structures located nearby. The Serra Sul mine, commonly referred to as S11D project, has obligations to preserve two natural tropical montane lakes and several maximum relevance natural cavities whose legal preservation radius represents constraints to the mine development and operation. Controlling measures are undertaken to ensure preservation of the cavities, especially during rock blasting stage, with limitations of the maximum instantaneous charge (MIC) and ground vibration control. The demand for high productivity and the large areas with hundreds of blastholes to charge are challenging factors to the charge control. This work presents the development and field application of a map for limiting explosive charges in the rock blasting process at the Serra Sul mine, used for the definition of maximum charges according to the blast location, ensuring the preservation and compliance with the defined ground vibration limits for each cavity. The map is applied at the mine for every blast and when there is a charge constraint, the map helps to define the areas with different charging profiles in the field contributing to higher charging productivity.

Jan 21, 2025

By Johan Gjødvad, Catherine Aimone-Martin, Charles Dowding, Mathias Jern

A residential structure adjacent to a quarry in Ohio was instrumented to record structure motions, resulting wall strains and existing crack displacements in response to close-in blasting within 82 m (270 ft). The project is a cooperative effort among international experts representing the European Federation of Explosives Engineers (EFEE) and ISEE supported by more than 21 persons from eight different countries to compliment prior work performed at the Aitik Mine in northern Sweden. The focus of this study is to compare blast-induced vibration measurements relative to regulatory compliance limits as a percentage of allowable velocities among eight different countries for a one-story residential wood-frame structure with a brick-and-mortar exterior and full basement. Participating counties included Austria, France, Germany, Norway, Sweden, Switzerland, the United Kingdom (UK) and the United States (US). Geophones were placed on the foundation and in the ground in accordance with each country’s regulations to record peak velocities as a function of frequency or distance to blasting. This study extends the work performed at the Aitik Mine to include interior corner geophones to calculate global wall strains and micro-m (micro-in) displacement gauges mounted over an existing drywall crack to measure blast-induced dynamic crack responses and climatological influences on daily opening and closing of a crack. Structure responses were documented for 68 blasts conducted north of the structure from February through September 2023 of which 17 blasts were selected for detailed analyses. The highest in-ground PPVs recorded were 43 mm/s and 59 mm/s at the NE and SW corners, respectively. Measurements from these blasts plotted within each country’s limits provided a comparison of stringency among the counties. The percentage of compliance limits among counties ranged from an average of 114% for the US, UK, and Austria limits to the highest of 585% for Switzerland. Despite these high percentages of compliance for all countries, the global tensile strains induced by these blasts were at most only 12 μ-strains and occurred with the highest velocity blast that exceeded each county’s limit. This high percentage of compliance and low strain level demonstrates the restrictive nature of the regulations studied. Peak dynamic crack opening and closing during blasting averaged 20 -m (0.0008 in) while the 12-hour weather-induced crack displacement during the time period over which blasting occurred averaged 200 -m (0.008 in) and the largest 12-hr change in crack width was 356 -m. This low level of crack response validates the observation that the studied regulations have highly conservative limits for cracking potential of standard building materials.

Jan 21, 2025

By Gustavo Tressia

Neste trabalho estudou-se a influência da classe do metal duro, sendo elas G30 e G20, utilizada para a fabricação de fieiras de trefilação de latão (ASTM C27000), na resistência ao desgate destas ferramentas. A geometria das ferramentas foi mantida a mesma, variando-se apenas o ângulo de entrada em 10, 13 e 15 graus, a fim de se observar alguma influência deste parâmetro. As ferramentas foram avaliadas após a tefilação de 10 toneladas de material. As superfícies de trabalho foram analisadas em Lupa Estereoscópica e Microscópio Eletrônica de Varredura, visando identificar os modos de desgaste predominantes. Em todas as fieiras foram observados riscos sendo estes mais intensos na fieira da classe G30. Em todas ferramentas também foi observado adesão de material trefilado, sendo que maiores quantidade de material aderido foram observadas também na fieira da classe G30. A ocorrência de maior quantidade de riscos foi associada a menor dureza da classe de metal duro e infere-se a menor vida útil desta ferramenta.

Jul 30, 2018

By Y M. Lee, Y Hong, B C. Kim

Since sintered ore is the primary source for producing molten iron in the blast furnace process, maintaining stable quality despite the utilisation of low-grade iron ore is crucial. However, conventional analysis methods, such as chemical composition, ore size distribution and types of iron ore, have limitations in developing the utilisation of new low-grade iron ore and predicting sintered ore properties. Sintered ores are formed through a complex melting process of granule particles consisting of iron ore, flux and fuel. Consequently, it has been investigated that analysis methods which apply the reactive properties of iron ore to predict sintered ore characteristics. In this study, we estimated the properties of iron ore by simulating the assimilation process of coarse ore, which influences the bonding strength of sintered ores and quantifying the degree of assimilation reaction. Pseudo particles were formed by granulating coarse ore (1–3 mm) with adhering fines, which act as primary melts and sintered at 1623 K. The bonding strength of individual sintered ores, formed from 11 different types of iron ore, was measured using a simplified Tumbler Index (TI) test and each value was indexed as the Iron ore Reactivity Index (IRI). By investigating the relationship between the degree of assimilation depending on iron ore properties and the characteristics of sintered ore, we demonstrated that sintered ores formed from more reactive iron ore exhibited stronger bonding strength. Moreover, when blending conditions resulted in a higher Iron Blending ore Reactivity Index (IBRI), the physical properties of sintered ore improved. The development of this analysis method is expected to not only enable careful consideration of iron ore usability but also allow for the advance prediction of sintered ore qualities by deriving the IBRI.

Sep 18, 2023

By Amalia Giannakou

When designing structures in seismically active areas, foundations of critical structures are typically located away from known faults. Indeed many seismic codes prohibit construction in the immediate vicinity of seismically active faults establishing minimum setbacks from the faults. However, for long structures such as bridges, tunnels and pipelines, a fault maybe unavoidable, and fault rupture risk impossible to preclude. This paper presents a case study of a bridge foundation design that incorporates the consequences of fault deformations passing through the foundation. A series of site surveys were conducted to characterize the fault environment, and fault displacement hazard analyses were conducted to develop design displacement demands. Subsequently, numerical analyses were performed to evaluate the fault rupture-induced demands on a pier foundation in terms of displacements and rotations. Initially, analyses were performed that model the free field fault rupture propagation to the ground surface of the fault to ensure that the basic site characteristics are captured. Subsequently, the foundation elements were introduced in the model and the fault rupture is simulated again. The interaction and influence of the foundation on the fault rupture propagation is calculated, and the consequent demands and distortions of the foundation block provide a basis for structural engineers to design the bridge.

By Daniel Andrade Paes de Lima, Gerson Evaristo de Paula Júnior, Beatriz Fausta Gandra

The gradual reduction of the sinter feed size has been a complicating factor in the maintenance of sintering productivity. In addition, pellet feeds have been used for chemical correction. Because of this, it is necessary an effective cold agglomeration step in sintering to keep the ironmaking competitiveness. Thus, in the present paper, four different technological routes for cold agglomeration with sinter feeds (drum mixer, intensive mixer + drum, double drum and HPS - Hybrid Pelletized Sinter) were evaluated in pilot scale and their impacts on the indicators of the sintering and the sinter quality was obtained. It was found that the best results on granulation index and, consequently, productivity were obtained in the route using HPS. However, the sinter from this process was the most fragile among the analyzed ones. The performance of the double drum process was superior to the intensive mixer from the point of view of productivity and sinter quality.

Oct 1, 2019

By R. G. Diale, H. R. Chauke, T. M. Ledwaba, P. E. Ngoepe

FeCo alloys play an important role in soft magnetic materials with a wide range of technological applications due to their high saturation magnetization and Curie temperature. However, these alloys have low ductility at room temperature. The ductility can be improved by the ternary addition of elements such as V. A density functional theory supercell approach was used to generate B2 Fe50Co50-xVx (0 ≤ x ≤ 50) structures and the properties were evaluated at different atomic percentage compositions to determine the ductility at room temperature. The structures were fully optimized to obtain better equilibrium ground-state properties such as lattice parameters and thermodynamic properties for both binary and ternary systems. The stability of Fe50Co50- xVx was evaluated from the heats of formation, elastic properties, and phonon dispersion curves. Furthermore, magnetic strength was evaluated from magnetic moments. It was found that all structures are thermodynamically stable due to the negative heats of formation. The calculated Pugh’s ratio and Poisson’s ratio confirm that alloying with V effectively improved the ductility. It was also found that Fe50Co50-xVx showed a positive shear modulus for the entire concentration range investigated, in agreement with phonon dispersion curves. The ternary addition of V to the FeCo system resulted in reduced magnetic strength due to a decrease in magnetic moments. These findings reveal that B2 FeCo-V alloys can be used as components and actuators for the automotive industry.

Jun 10, 2024

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By BUREAU OF MINES

PLATINUM

Feb 1, 1922

By T. A. Henrie, E. K. Kleespies

Carbon reduction of rutile and ilmenite in nitrogen and ammonia atmospheres was studied as a method of preparing titanium nitride . Ammonia was a better nitriding agent than nitrogen . The contact between the solid reactants , carbon and rutile , was a prime factor in nitrogen atmospheres and was of lesser import in dissociated ammonia . The reduction process for conversion of rutile to the nitride required carbon . The nitriding of ilmenite- carbon mixtures produced titanium nitride and elemental iron .

Jan 1, 1964

By Federico Pagliacci, Claudio Asioli, Marco Chiarabelli

"""Rigid inclusions"" are a consolidation method that provides improvement of soft soils thanks to the installation of cylindrical columns made up of a material with significant and permanent cohesive properties, whose stiffness is 500÷5000 times greater than the surrounding natural soil’s. ""Rigid inclusions"" find their application in marginal areas (reclamations, polluted sites) to ensure stability of adjacent structures during construction of new buildings and to reduce the impact of natural disasters (liquefaction in the event of earthquakes, embankment collapse in the event of floods). This paper analyses the “rigid inclusion” construction method, related materials and equipment. Moreover, two performed projects will be illustrated. The first is the restoration of Lungarno Torrigiani Embankment in Florence, Italy. In May 2016, the Torrigiani embankment underwent a structural collapse causing a 3 m. displacement of the riverbank towards the Arno River. “Rigid inclusions” (with 300 mm diameter) have been used to re-compact the loose soil and create a stable working platform for the equipment. The second project illustrates the use of “rigid inclusions” (800 mm diameter and maximum depth of 36.6 m) to control the settlement of a new automatic cold store (30 m high with a 65 x 120 m foot print) for fresh frozen vegetables.RIGID INCLUSIONSIn general, the word ""inclusions"" means a type of consolidation that improves the strength of a soil mass through the inclusion of elements constituted by a material having better characteristics than those of the surrounding natural ground, to improve the overall mechanical characteristics of the treated soil. Inclusions are ""rigid"" when the material introduced into the ground has significant and permanent cohesive properties (concrete or cement mortar) and a significantly higher stiffness (500 ÷ 5000 times) than that of the surrounding natural ground.Typically, medium-small diameters (from 300 to 800mm) with low percentages of treatment (from 2% to 10% of the volume of soil) are employed, ensuring a high quality and consistency of the obtained product, both in terms of diameters and elastic modulus.According to the scope of the project and in urban areas, ""rigid inclusion"" columns can also be performed by means of small diameter drilling rigs (micropiles), weighing less than 20-25 tonnes."

Jan 1, 2017

By Z. Tshentu, M. Ngayek, P. Moleko-Boyce

This paper is focused on the development of iridium(IV)-specific quaternary diammonium cations containing electron-donating substituents in the benzyl group of methyl and electron-withdrawing substituents such as triflouromethyl and nitro groups. Quaternary diammonium cations used were tetra- 4-methylbenzyl-1,10-diammonium decane chloride (QuatDMDAMeBnz), tetrabenzyl-1,10- diammoniumdecane chloride (QuatDMDABnz), tetra-3-trifluoromethylbenzyl-1,10- diammoniumdecane chloride (QuatDMDACF3Bnz) and tetra-4-nitrobenzyl-1,10-diammoniumdecane chloride (QuatDMDANO2Bnz). Polyvinylbenzylchloride (PVBC) nanofibres were used as support material, and the functionalised nanofibres were used for separation of Ir(IV) from Rh(III). The sorbent materials were characterised by FTIR and elemental analysis. The efficiency of the quaternary diammonium cations was investigated in a column study under dynamic flow adsorption conditions. Column sorption of [IrCl6]2- and [RhCl5(H2O)]2- on nanofibres functionalised with diammonium cations showed [RhCl5(H2O)]2- was not adsorbed by the sorbent materials while [IrCl6]2- was loaded onto the column. The loading capacities of [IrCl6]2- on the quaternary diammonium sorbent materials increased in the order of F-QuatDMDAMeBnz (3.08 mg/g) < F-QuatDMDABnz (3.39 mg/g) < FQuatDMDACF3Bnz (5.46 mg/g) < F-QuatDMDANO2Bnz (7.10 mg/g). The loading capacity for Ir(IV) with quaternary diammonium cationic nanofibres increased with an increase in the electron-withdrawing nature of the substituent on the quaternising group. The charge delocalising ability of the 4-nitrobenzyl group resulted in the best interaction of the decamethylene diammonium cation with [IrCl6]2-. Keywords: Iridium(IV), rhodium(III), quaternary diammonium, polymer nanofibres, separation

Jan 1, 2020

By K. Sasaki, S. Kuroiwa, H. Miki, Y. Aoki, T. Hirajima, Y. Orii, G. P. W. Suyantara

Selective flotation to separate copper minerals from, for example, Mo- and/or As-bearing minerals is a continuing problem because the selectivity of current systems is imperfect. Selective Cu-As flotation is currently difficult, and the most common Cu-Mo selective flotation method uses NaHS; this must be done in an enclosed system because, under acidic conditions, this method produces hydrogen sulfide. In this paper, some novel alternative flotation processes that use redox reactions are discussed; these methods have a much lower environmental impact. Oxidation and reduction reactions can be used to make copper minerals more hydrophilic and Mo-bearing minerals more hydrophobic. X-ray photoelectron spectroscopy (XPS) analyses indicated that the copper minerals became hydrophilic because hydrophilic iron precipitated and several hydroxides covered the copper minerals’ surfaces, whereas the molybdenum minerals remained hydrophobic because their sulfide surfaces were not covered. Flotation experiments on these minerals after redox treatments indicated that excellent separation of Cu-minerals from Mo-minerals can be achieved. Possible mechanisms for this separation were investigated using detailed surface analyses and thermodynamic calculations. The additives used to initiate the redox reactions are easy to handle and make these new flotation procedures better than current processes because the new methods do not emit effluent gas and because they are commercially viable. Keywords: Flotation; chalcopyrite; molybdenite; oxidation; reduction

Jan 1, 2020

By Maciej Korecki

Pyrowear®Alloy 53 steel is an excellent material for the construction of drive transmission components (gears, shafts, etc.) which have to operate in difficult conditions primarily in the aviation industry (Fig. 1.). Among the properties of such items is a high case hardness and abrasion-resistance, while the core remains flexible and is capable of carrying large impact loads. They can work at elevated temperatures with limited lubrication. The thermal treatment of such materials is based on case hardening by means of carburizing. This paper presents the technology of vacuum carburizing of Pyrowear® Alloy 53 steel. It discusses the methods of establishing different profiles of carbon concentration in a layer and their influence on the hardness profile. The effects of sub-zero treatment and tempering on the properties of the hardened case are also considered. It also presents a SimVaC® simulator of vacuum carburizing, designed especially for Pyrowear® Alloy 53 steel, which provides highly accurate predictions of the outcome of the process as the profile of carbon concentration in the layer, or vice versa: establishes the process parameters which will guarantee the required profile.

Aug 16, 2017

By Felipe Beluche Lima, Caio Augusto Silva Santos

Brazil is the largest producer of crude steel in the Americas by BOF process and many challenges come along with the increasing market demand. In the BOF, a tubular wall hood structure has been showing premature failures related to the overlay welded tube technology placed in the hood wall. The main root causes were: thermal fatigue at 1800°C, hot spot formation, high heat-affected zone (HAZ) leading to susceptibility of stress cracking, carburizing corrosion and superficial wearing. Based on that, co-extruded tube technology (named composite tube by Sandvik) was the alternative chosen to enhance hood performance without compromising BOF process. In order to rises safety and productivity, composite tube has 100% metallurgical bond assuring stable expansion, high heat exchange efficiency, better corrosion resistance and less rough surface finishing. It was highly suggested to many others mills due to similar and already existing reported cases.

Oct 1, 2019

By Allen D. Look

Underground fires often prove difficult to control , and a small fire can quickly grow into a large one , endangering life and causing large property damage . Even a small underground fire may produce enough noxious gases to cause suffocation ; therefore , every precaution should be taken to prevent and control such fires . It is ironic that mine fires should be caused when utilizing materials that are in themselves fire - resistant ; yet , cutting and welding of iron and steel are proving to be common causes of underground fires in metal mines . This paper includes 19 examples of underground fires of this nature , and undoubtedly this is only a fraction of the number of similar fires that have occurred in the last few years . This paper will review some metal - mine fires caused by cutting or welding and point out precautions to be taken to prevent other fires from this cause .

Apr 1, 1948

By H. Vigil Fernandez, G. Peach

The Musaimeer pump station and outfall project located in Doha Qatar, was designed to collect and manage ground and stormwater and then discharge the treated waters offshore. The project constructed a long outfall tunnel using an EPB TBM with segmental lining, each tunnel ring being 1.35 m in length with an internal diameter of 3.7 m.. The diffuser structure was a 6-arm structure, measuring 294m by 40 m connected to a central manifold in turn connected to the TBM constructed tunnel via a riser shaft drilled from an off-shore barge. This technical paper will discuss the planning, methodology and construction practices employed to connect the TBM tunnel to the diffuser structure 10.2 km offshore.

Jun 13, 2023

By Junfu Chen, Jiann-Yang Hwang, Yong Zhou, Lijun Lu, Likun Lia, Jixiong Liu

The sheet-like NiS-ZnS heterostructured composites were prepared by the microwave hydrothermal. The fabrication of the heterojunctions broadened the range of light response of ZnS. The photoexcited electrons of ZnS migrated to the redox potential of NiS/Ni2S under visible light irradiation, which can facilitate the effective separation of photogenerated electrons and holes in space. The visible photocatalytic activity towards hydrogen production for NiS/ZnS nanosheet heterostructed composites without co-catalyst achieved 0.28 mmol h–1, and the quantum efficiency was up to 18.6% under the wavelength with 420 nm visible light irradiation.

Jan 1, 2015

By Jean Igor Margem

Nestes dias materiais ecológicos como compósitos com fibras naturais em matriz polimérica estão chamando a atenção de pesquisadores científicos, devido ao seu bom desempenho na substituição de materiais como madeira, polímeros à base de petróleo e outros. Neste trabalho foram avaliadas as propriedades de tração de compósitos de matriz poliéster reforçados com diferentes espécimes de fibras lignocelulósicas. Compósitos reforçados com até 30% em volume de fibras longas, contínuas e alinhadas de malva, sisal e bambu foram testados em uma máquina Instron a temperatura ambiente. A fratura foi analisada por SEM. Os resultados mostraram alterações significativas nas propriedades mecânicas com a quantidade dessas fibras. Estas propriedades mecânicas foram comparados com outros resultados em compósitos testados em ensaio de tração. Como esperado, a análise da fratura revelou uma fraca interação da interface fibra / matriz, o que corrobora o comportamento típico das fibras naturais quando incorporadas em matriz polimérica.

Oct 30, 2017