Search Documents

By Zhihe Dou, Guozhi Lyu, Liping Liu, Yi Luo, Ting-an ZHANG, Xijuan Pan, Zhuolin Liu

Due to the high energy consumption, long technical process, low usage rate of vanadium during the traditional smelting vanadium steel process, a new method for decarburization by CO2 to directly smelt vanadium-containing steel in blast furnace was proposed. In this paper, the thermodynamics of CO2 decarburization in molten iron process was calculated out by FactSage. The thermodynamic calculations indicated that in standard state, the transformation temperature of C and V was 1357 °C; the oxidation order of element was Si, C, V, Mn and S when using CO2 as oxidant. The experiment of blowing CO2 temperature showed that decarburization reaction temperature was 1550 °C, carbon content could be decreased to 0.676%, the decarburization rate was 88%. There was no effect on vanadium content in molten iron during the decarburization process, vanadium content was 0.323%, which meets the request of vanadium mould steel.

Mar 1, 2018

By Qingguo Xue, Jingsong Wang, Yingli Liu, Guang Wang

In the dropping zone of blast furnace (BF), primary slag absorbing ash of pulverized coal and coke become to be intermediate slag. Due to viscosity and surface tension of slag and the pore between cokes, some slag remained in coke layer and affected the permeability of blast furnace. The flow behavior of slag with different basicity (0.55–1.10) and Al/Si (0.35–0.50) were studied. Meanwhile, the viscosity and surface tension of slag were calculated. The results showed that, with the increasing basicity of slag, surface tension increased and viscosity decreased. With the Al/Si increase, surface tension and viscosity increased. The smallest pore that all slag can pass through was 4.5 mm. However, the height between slag droplets and the bottom of crucible indicated that the ability of slag to pass through pore were weakened with the increasing basicity and Al/Si. Thus, slag which absorbed ash from fuel become difficult to pass through coke layer.

Mar 1, 2017

By E. Salinas Rodríguez, I. Rivera Landero, E. G. Palacios Beas, J. Hernández Ávila, E. Cerecedo Sáenz, M. A. Mesinas Romero, M. I. Reyes Valderrama

For this study, a sample of 5 g of copper powders obtained by grinding printed circuit boards of computers fixe to 50 mesh (270 μm) according Tyler® series was used. This sample was wholly characterized by XRD, SEM–EDS and AAS. The leaching medium used wasO2S2O3 2. From the evaluated variables it was obtained an apparent order of the reaction of n = 2.34 s−1, whereas according the effect of partial oxygen pressure it was obtained an apparent order of reaction of n = 0.9516 and the activation energy of system was of 6.5 kJ mol−1, the results so achieved suggest a transport control to the solid–liquid interface. Under certain work conditions such as: S2O3 2 ¼ 0:5M, 500 mL, 750 min−1, P/PO2 = 1 atm, 338 K, 5 g of sample and 9000 s of reaction time, it is possible get up to 97.35% of leached copper.

Mar 1, 2017

By S. N. Monteiro, E. B. Zanelato, J. Alexandre, M. T. Marvila, A. R. G. Azevedo, G. C. Xavier

One of the parameters used in the study of mortars is the adhesion resistance, which indicate show much the mortar adhered to the substrate. The usual study is done at 28 days, to worldwide standardization. Few researchers study the adhesion of mortars to ages other than 28 days. In this scenario, the adhesion strength tests of conventional mortar with a 1:1:6 mass scale (cement, and sand) at 7, 14, 28, 56, 91, 182 and 364 days were performed in order to understand the behavior of this material. The usual characterization tests of the mortars were carried out to correlate the values obtained with the adhesion results. The obtained results demonstrate that the mortar continues to gain resistance with the passage of time. For the trait studied the gain was considerable, indicating that over time the cement continues to hydrate, reacting and contributing to the strength of the material.

Mar 1, 2018

By Iván Aguirre Palacios, Jean Guiroux Toro, Eduardo Valdés Guerra

Currently, mining operations seek to be competitive in the market. To achieve this, one of the relevant factors is to maintain and improve the productivity of the extractive processes, mainly the loading from the point of opening of the mineral bodies. To do this, many techniques suggest reducing production costs, with the first opening of your free-face up raises. However, there are different ways to carry out these open-face raises up opening processes, where the balance of costs and construction time must be well planned to meet production plans. Operationally, there are different techniques for its construction, the most common being Blind-Hole up Raises and those with drilling with current production equipment that operates mining operations. This study shows a methodology and the results of the implementation of access stack drilling with production drilling rigs for a maximum height of 15 m with electronic detonators in production blasting. Within the methodology used, Qa/Qc processes were considered in cargoes with explosives, instrumentation for monitoring (vibrations), VOD registration, among others. As a result, of a total of 12 raises up blasts, construction time was reduced by 45% and the cost of drilling and blasting (P&V) was reduced by 50%, for up raises with a maximum height of 15 meters. Regarding the efficiency of the heights, this was 97% compared to the planned drilling design.

Jan 26, 2026

By Johan Hillman, D. Scott Scovira, Thomas Gustavsson, Alexander Bihlar

Hydrogen Peroxide Emulsion (HPE) explosives are an alternative to conventional commercial explosives. HPE does not contain nitrates or ammonia thus eliminating post-detonation NOx fumes and aqueous nitrate discharge. Production of HPE is less carbon intensive than industry standard ammonium nitrate-based emulsions (ANE) and employment aligns with end users seeking to meet Scope 3 ESG emission targets. Swedish tunneling contractor Implenia Sverige was awarded the Högdalen Depot Expansion Project by the City of Stockholm. Implenia Sverige partnered with Hypex Bio to be the first to pilot the application of a nitrate-free explosive system in a large-scale civil construction tunnel. The purpose of the joint project was to evaluate the operational suitability of replacing conventional nitrate-based bulk explosives with HPE in a large-scale tunnelling project. When the project commenced in September 2023 both standard nitrate-based emulsions and HPE emulsion were used in parallel (Tunnel Right and Tunnel Left) to enable operational, performance, and environmental comparison. Identical drill patterns and initiation techniques were applied to both tunnel headings. Performance data collected included round advance, usage, and perimeter quality. Implenia managed all drilling and charging operations and Hypex Bio provided technical support, including technicians and chemists. HPE is viscous and pumpable using conventional emulsion pumping delivery systems. Variable density functionality enabled loading different charge weights into cut, lifter, production, and perimeter holes. The primary rock type was hard sedimentary gneiss with approximately 150 MPa [21,755 psi] Uniaxial Compressive Strength (UCS). Fracture systems with infilling occurred in both tunnel directions. Rock quality factor was “Good to Very Good” on the RMRb (Rock Mass Rating) scale. Epiroc Boomer rigs were used to drill rounds averaging 4.9 m [16 ft] deep with high accuracy and precise reference positioning.

Jan 26, 2026

By Hong Peng, James Vaughan

Thermal activation of bauxite has been proposed to enable bauxite dissolution at a reduced digestion temperature and also to reduce the organic content in the liquor. Research has been carried out on phase transformation of its main hydroxide components (gibbsite, boehmite and kaolinite) during calcination. However, there is limited information available on phase bauxite phase transformation during thermal activation. In this study, two bauxite ore samples were heated from 25 to 700 °C at a rate of 50 °C/min while monitoring the phase transformation using Rigaku in situ XRD. Different phase transformation pathways for gibbsite in the bauxite compared with pure gibbsite was observed. Boehmite and kaolinite in bauxite behaved similarly to their pure phases. The temperature of phase transformation depends to some extent on the bauxite sample. Samples were also characterised by scanning electron microscopy (SEM) to reveal changes in the microstructure.

Mar 1, 2018

By L. Diaz, J. Serp, L. Massot, P. Chamelot, M. Gibilaro

The discovery of NdFeB permanent magnets helps to perform technologies with reduced weight and gives them access to miniaturization. The industrial process of production of the Nd-Fe alloy by electrolysis used to manufacture NdFeB magnets consists in reducing Nd3+ ions dissolved in molten fluoride salts. The electrochemical behavior of neodymium is studied in LiCl-KCl and LiCl molten salt systems, examining reduction mechanisms, potential deposition, and faradaic yields.

Mar 1, 2017

By Chen Tian, Tingfeng Wu, Qinghai Pang, Junhong Zhang, Zhijun He

Microwave technology as new aided tool has been applied on waste water treatment and metallurgical fields. This paper explores the affected factors such as microwave power, microwave irradiation time, polyaluminium chloride (PAC) amount and addition of phosphoric acid on treatment of Blast Furnace gas washing water by utilization of coagulation associated with microwave. Through the orthogonal experiment, the optimum experimental parameters were obtained in the course of treatment of 300 ml Blast Furnace gas washing wastewater: 396 W microwave power, 2 min of microwave irradiation time, 0.12 ml Added PAC and 0.8 ml added phosphoric acid. It indicates the affected factors in descending order on removal of SS in BF gas’s washing water: Added PAC level, added phosphoric acid level, time of microwave irradiation, and microwave power while those parameters that can affect suspended solids(SS)’s hardness reduction in descending order are added phosphoric acid level, added PAC level, time of microwave irradiation, and microwave power. Also, it demonstrates those parameters that can affect washing water’s turbidity in descending order: Added PAC level, time of microwave irradiation, added phosphoric acid level, and microwave power. The results showed that PAC coagulation associated with microwave on treatment of Blast Furnace gas washing wastewater has several benefits: short treatment time, strong sedimentation velocity and other excellent characteristics, it can effectively remove suspended solids in wastewater, the SS hardness and turbidity can be reduced.

Mar 1, 2017

By Ruixuan Zhang, Yan Li, Shusen Cheng

The measurement of raceway temperature in the blast furnace is a critical issue, which is very significant for judgment of, prediction and diagnosis of the racewa yburning state. This paper deals with mathematical models by Monte Carlo method to approximately simulate the radiation heat transfer in the race-way and establish matrix equations using CCD cameras, which are solved to obtain the three-dimensional temperature field. Due to the existence of fluctuation error, CCD camera measurement error and others,this is analyzed and random error is added in the measurement data to demonstrate the effectiveness and stability of the reconstructed temperature field. The results show that the reconstructed three-dimensional temperature field of the raceway is very close to the exact temperature.

Mar 1, 2017

By Lin Li, Wen Shi, Hua Wang

"Specimens of the ultra-low carbon bake hardening steel were soaked for 1 min to 5 min, and then cooled by water quenching. The internal friction experiments were carried out to detect the spectra of the specimens. Results show that Snoek peaks are present in all the specimens, however, an obvious Snoek-Koster peak is found only in the 5 min-annealed specimen. Besides, tensile results indicate that the bake hardening values increase with the annealing time prolonging from 1 min to 3 min, but decrease as the annealing time prolongs further to 5 min. The solute distributions in the specimens were characterized by three dimensional atom probe. Some segregated C and V are found in the 1 min-annealed specimen, and the C and V contents decrease as annealing time prolongs to 5 min.1. IntroductionAs an excellent member of automotive body panel materials, various types of bake hardening (BH) steels have been developed since 1980s. Bake hardening property, as one of the most important mechanical properties, has been studied by many researchers [ 1-5]. As is known, BH phenomenon is generally controlled by the interaction between solute C and dislocations. The Snoek peak of internal friction (IF) is very popular in the investigation of solute C [6-9]. However, result of internal friction cannot suggest the distribution pattern of solute C as well as its influence on BH phenomenon.Three dimensional atom probe (3DAP) can diagnose solute element atoms as well as nano-sized precipitates, and it is the only instrument that currently can identify the identities of individual atoms in a material and measure their spatial coordinates with the resolution close to 0.3 nm [10]. There have been a number of studies about using 3DAP to detect solute elements as well as nanometer sized precipitates [11-19]. For example, Hono et al. [16] used 3DAP to determine the solute elements in an age-hardened Mg-Ca-Zn alloy, and they also obtained the distribution patterns of the observed elements."

Jan 1, 2011

By G Harbort, D Clarke, D Morgan, C Sola

Northparkes Mines commenced production in 1994 and the mine has significant reserves to allow operation into the future. There are a number of potential future concentrator feed sources with variable sulfide mineralogy and grades.In February 2012 a comprehensive flotation survey was conducted to allow mass balancing and evaluate the operation of the flotation circuit. A rudimentary, copper element only, unsized flotation simulator was developed to evaluate high level potential for optimisation and improvement. In 2013 this flotation model was expanded to produce a mineral based, floatability component model to estimate the effect of future concentrator feed source on metallurgical performance. This revised model allows various circuit configurations to be simulated to provide a high level blueprint for the long-term planning to maximise performance.This paper provides a review of the process followed to develop the model, including an analysis into the mineral floatability component model and its calibration against plant operations. The effect of varying feed mineralogy and feed quality on future performance has allowed an internal review of potential circuit changes needed to accommodate the changing future feed.CITATION:Clarke, D, Harbort, G, Morgan, D and Sola, C, 2014. Northparkes Mines – flotation and planning for the future, in Proceedings 12th AusIMM Mill Operators’ Conference 2014 , pp 203–208 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 1, 2014

By G. G. Richards, Y. Oyediran, V. Chow

The oxygen softening process for partial removal of arsenic and antimony from lead bullion has been in use at Teck Cominco's Trail smelter since 1986. In this process, industrial oxygen is injected into bullion to remove As and Sb with the formation of an oxide slag. In Trail, the levels of these elements are reduced to concentrations suitable for processing in the Betts electrorefining plant. Recent moves toward the treatment of higher arsenic-bearing feeds have necessitated an increase in the process capacity to meet the specifications for drossing plant bullion. Process intensification trials were conducted in-plant to develop an operating strategy for higher bullion processing rates. This was preceded by a study conducted with McGill University to develop a fundamental understanding of the therm ochemistry and kinetics of the process. The results have yielded more effective control of the operation, and identified opportunities for further improvements.

Jan 1, 2008

By L. M. Wang

Chengmenshan Copper Mine Concentrator adopts the new process of preferential?bulk stage floatation and utilize reground, largely increase the mineral processing index of the copper and the sulphide concentrates. In addition, the paper describes the remarkable economic benefit of the new process through the comparison of the new and the old processes.

Jan 1, 2014

By A. W. Khair, M. Ahmad

"Bit wear has been proven to have a significant effect on respirable dust generation in coal cutting system. The mechanism of bit wear can be adhesion, abrasion. oxidation, or diffusion. depending on cutting conditions. This paper presents a portion of an extensive ongoing series of studies to better understand the principles of bit wear and dust generation. Used bits collected from underground coal mines were analyzed to identify the basic principle of bit wear in coal and rock cutting. Distribution of weight loss and conical height loss of worn bits were studied and bit wear was divided into four stages according to weight loss. Utilizing these worn bits, Laboratory experiments have been carried out to study the effects of bit wear on coal cutting system and respirable dust generation. An Automated Rotary Coal Cutting Simulator was use to perform the experiments. Acoustic emission monitoring is applied to study the effect of bit wear on fracture formation and dust generation. INTRODUCTIONContinuous miners were introduced in the 1950’s and became the major equipment in underground coal production. Now the larger production in the coal industry has increased the demand for continuous miners and their use. It is well known that serious dust problem is also introduced with the use of continuous miners, especially with recent increase in productivity. On the other hand, legal restrictions are made ·more strict by the Mine Health & Safety Administration for the respirable dust generated by the continuous miners to prevent coal workers from incidence of pneumoconiosis. The incidence of pneumoconiosis depends on dust concentration, exposure time, and physical properties of dust. Of them, dust concentration is the best parameter for the assessment of the risk of pneumoconiosis. Although a lot of research work has been done to reduce dust concentration substantially, some areas are still required further investigation to meet the strict regulations. One of the areas is about bit wear and dust generation. In this area, the principles of bit wear and effect of bit wear on dust generation are major concerns."

Mar 1, 1992

By M. Ganster

Austria’s biggest supplier of oil and gas, transports gas through the West Austria Gasline for domestic consumption. In addition, the OMV also works as gas carrier and ensures the transit into neighbouring countries.

Jan 1, 2010

By S. K. Kawatra

Many mineral oxide and multi-component oxide (basalt) specimens break down into powders upon expo-sure to sodium vapor at elevated temperatures for extended times. This paper examines several possible mechanisms of oxide breakage by sodium vapor, both experimentally and from a thermodynamic viewpoint. The oxides for which reduction by sodium was thermo-dynamically favorable all exhibited some degree of fragmentation. The oxides which were not favorable for reduction by sodium did not exhibit fragmentation, with the exception of rutile, a titanium oxide. The rutile fragmentation was caused by the reduction of iron that was in solid solution in the rutile crystal structure.

Jan 1, 1995

By K. El-Barawi, Hussein M. Kamal

Chlorination was performed of iron-rich chromite ore from Barramyia, United Arab Republic (UAR), together with its concentrate. The effects of change of grain size, chlorine gas flow rate, time and temperature were studied. The extent and mechanism of chlorination were followed through chemical and structural analyses of the feeds and complete chemical analysis of the chlorination products. By conducting the chlorination process for short periods at 600°C or lower temperatures, products having high Cr-Fe ratios suitable for ferrochrome production can be obtained.

Dec 1, 1971

By Qing-hua Tian, Li-then Cheng, Xue-yi Guo

In order to recycle valuable metals from silver separated residue, a novel method using alkaline smelting at low temperature was proposed. The main factors affecting the main metal recovery such as the smelting temperature, smelting time, liquid-to-solid ratio and alkali addition were investigated comprehensively. The behavior of the main metal elements, such as Pb, Sn, Sb and Bi in silver separated residue was also discussed. The results indicated that amphoteric metals such as Pb and Sn can be smelted into the melt, while other metal elements, such as Sb and Bi were left in the residue.

Jan 1, 2011

By Robert G. Ditchburn

The NW caldera hydrothermal vent field at Brothers volcano, of the Kermadec-Tonga arc, has associated massive sulfide mineralization. This includes an abundance of black smoker chimneys that contain significant concentrations of copper, lead, zinc and gold (de Ronde et al., 2005; de Ronde et al, 2010, under review). [ ] The oldest volcanic massive sulphide (VMS) samples recovered so far from Brothers have been dated using radiometric methods at GNS Science and found to be c. 1000 years old. By contrast, a volcanic cone that has formed in the southern part of the caldera has no associated VMS. Only elemental sulphur and Fe-oxide crusts are present here, samples of which have been analysed for their trace elements. From d34S values of sulfates and native sulfur, and the volume of gas (dominated by CO2 and H2S) discharging at the cone site, elements being deposited here are considered more directly magmatic in origin (de Ronde et al., 2005; 2010 under review). It has been discovered that deep-seated changes in volcanic activity at Brothers affect the NW caldera and cone site simultaneously, though the mineralogy at each site is so very different. Thus, the cone site is being studied to determine if elements being deposited there can be used as predictors of potential future VMS mineralisation as similar sites have been found at other volcanoes along the Kermadec arc and elsewhere. The frequency of these deep-seated magmatic events is considered important in the formation of Cu-Au-rich mineralization along arcs. The analysis of Fe within resulting hydrothermal plumes (surveyed by surface vessels), and trace elements in rock and mineral samples, are used to help determine the influence of magmatic contributions to the hydrothermal system. To verify that plumes are a reliable proxy for hydrothermal events depositing iron on the seafloor, Fe-oxide crusts from Brothers volcano cone have been dated to see if their emplacement coincides with highly Fe-enriched plumes in the water column. The radiometric dating techniques developed for barite-rich VMS, i.e. using 228Ra and 226Ra, were unsuitable for the Fe-oxide crusts because 210Pb was the only isotope detected by gamma spectrometry. Therefore, new techniques using 210Pb, 10Be and arsenic have been established.

Jan 1, 2010