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By R. J. Leary

Oxidation testing of copper-clad steel strip was performed in a muffle furnace to determine whether copper in contact with steel scrap could be removed by oxidation in an airstream at high temperatures. Substantially all of the copper was oxidized before any significant iron oxidation occurred. The rate of copper oxidation was not affected by contact with iron. Copper oxide scale separated spontaneously from the underlying metal during cooling. Results indicate the possibility of removing light-gage copper coatings and components from ferrous scrap by oxidation in an incineration process.

Jan 1, 1965

By G. W. Jones

Gas analysis is of great practical value to the combustion engineer as a guide in the proper deli and operation of power and heating plants. The automotive industry, however, has made little use of gas analysis in the design and construction of engines. Tests4 made by the Bureau of Mines have shorn that for the average motor vehicle approximately 30 per cent of the heat value of the gasoline passes out in the exhaust as incomplete-combustion products. The tendency at present is to pay more attention to ease and flexibility of operation than to efficiency of combustion. However, neither condition can be fully realized except where each cylinder gets a mixture of the same composition - that is, when certain cylinders do not "load up" with gas at the expense of the others. When this occurs, due to some of the cylinders having too rich a mixture while in others it is too lean, it is impossible to get efficient combustion from the fuel used. Gas analysis enables the engineer to determine the quality of the mixture fed to the different cylinders with a high degree of precision. Briefly, the method consists in making an analysis of the exhaust gas from each cylinder while the engine is in operation.

Jan 1, 1924

By Akira Ishikuro, Masamichi Shintaku, Futoshi Kusumoto, Takeshi Kudo

"The Bankei-Kitanosawa tunnel that is located in Sapporo, Hokkaido, Japan includes a 450m long section near the arrival point where mudstone which can liquate out natural hazardous materials such as arsenic and selenium exceeding the tolerance stipulated by country as well as weathered mudstone and unconsolidated sedimentary rocks with small overburden and the competence factor less than 1.0 are present. The mucks containing hazardous materials were disposed into the waterproof branch tunnels created from the inside of the main tunnel. The full face early ring closure method was employed to ensure the stability of the tunnel in the low strength rock masses having no stand-up time. As a result, the waterproof tunnels branching off the main tunnel can manage water tightness so as to ensure safety and relief against environmental risks of the hazardous materials. It is also demonstrated that the full face early ring closure method enable construction of the tunnel with a small overburden in the low strength rock masses. INTRODUCTION The Bankei-Kitanosawa tunnel includes a 450m long section near the arrival point where mudstone which can liquate out natural hazardous materials such as arsenic and selenium exceeding the tolerance stipulated by country as well as weathered mudstone and unconsolidated sedimentary rocks with small overburden and the competence factor less than 1.0 are present. In order to overcome the restrictions, the hazardous materials were designed to be disposed into large cross section waterproof tunnels which were newly designed and constructed in high strength and hazardous material free Andesite. The lining for the tunnels was composed of with shotcrete. In addition, full face early ring closure (Sato et al., 2013) was employed to stabilize the tunnel so as to enable safe tunnel excavation in low strength rock masses where a ground arch is deemed unachievable. This paper presents the safe disposal method of mucks which are likely to liquate out natural hazardous materials as well as the full face early ring closure method and its mechanical characteristics."

Jan 1, 2016

By Ahmad Ghahremaninezhad, Rebecca Radzinski

Arsenic is a highly toxic compound that is naturally found in the environment and is released through the processing of sulphide minerals. Arsenate (As5+) is less toxic than arsenite (As3+) and is soluble in water but can form insoluble precipitates when metal ions are present. The arsenic removal processes used in industry assume that arsenic is in its pentavalent state. Hydrogen peroxide can be employed to oxidize arsenite; however, it is expensive. It has been shown that activated carbon can be used to catalyze the oxidation of arsenite with oxygen as the only consumed reagent at ambient conditions with an efficiency of 99% in less than 24 hours. The mechanism which oxidizes arsenite is not yet understood; however, this study shows that a strong oxidizing agent is formed in-situ. The species and amount of oxidant formed were determined via iodimetric titration and electrochemical methods. The production of oxidant was optimized by comparing the amount of oxidant formed in-situ to the relative amount of arsenite oxidized.

Jan 1, 2015

By N. O. Lotter

Studies investigating the evaluation errors in laboratory scale flotation tests for platinum-bearing Merensky Reef in the Bushveld Complex, South Africa, have constructed a quality control model to assure a 95% confidence in the attested data. Specialized knowledge of the mineralogy of the platinum-group elements (PGE), together with acquaintance of evaluation models, validate a systematic checking of the sub-processes of the testwork. These include determination of minimum mill feed sample size, assay head reference distribution, mass balance checks, and specialized sample preparation of flotation test products prior to analysis. A flow schematic of this quality control model is proposed, with an example of test data that produce an error in the metal balance of 0,2% after rejection of outlier data.

Jan 1, 1995

Roasting of molybdenite concentrate is an important stage in the production of commercial molybdenum trioxide. The oxidation kinetic and mechanism of molybdenum sulfide concentrates from two plants were investigated at temperatures from 444 °C to 640°C. The rate of reaction was determined for thin layer samples in a muffle furnace at controlled temperatures, oxygen excess and removal of sulfur dioxide. For both concentrates the rate of reaction is fairly slow at temperatures below 500°C and remains fairly constant from 540 to 600 °C. It was observed that the concentrate from the first plant presents a tendency for sintering or glazing at temperatures above 620°C, whereas the same phenomena was observed at 20 or 30 °C higher temperature for the second concentrate. A kinetic model of two reactions, involving the formation of Mo02 as intermediate oxide for the production of Mo03 is proposed and activation energies of 23.0 and 20.8 kJ/mol for the first and second reaction were calculated for temperatures between 520 °C to 600 °C. These low values of activation energies indicate that the overall rate of oxidation is controlled by mass transfer, particularly in a porous layer of oxides. Therefore, the renewal of the surface by mixing and motion of the concentrate layer is of great importance. Sublimation of Mo03 becomes significant for temperatures above 650 °C.

Jan 1, 2007

By Joe Wickline, Mark A. Van Dyke, Wen H. Su

"Geological factors and mine design contribute to mining-induced seismic activity, and this is especially true in longwall mining. Massive rock units are a key cause of seismic activity due to catastrophic failures that release large amounts of energy. Other factors, such as overburden depth, panel design, pillar design, rock strength, and proximity of the massive rock unit to the coal seam, all have a role in the potential and size of a seismic event. A recent seismic event was recorded by a deep longwall mine in Virginia at 3.7ML on the local magnitude scale and 3.4 MMS by the United States Geological Survey (USGS) in July 2016, which had no impact on the mining operations. Further investigations by NIOSH and Coronado Coal researchers have shown that this event was associated with geological features that have also been associated with other, similar seismic events in Virginia. Detailed mapping and geological exploration in the mining area has made it possible to forecast possible locations for future seismic activity. In order to use the geology as a forecaster of mining-induced seismic events and the energy potential, two primary components are needed. The first component is a long history of recorded seismic events with accurately plotted locations. The second component is a high density of geologic data within the mining area. In this case, 181 events of 1.0ML or greater were recorded by the mine’s seismic network between January, 2009, and October, 2016. Within the mining area, 897 geophysical logs were analyzed from gas wells, 224 core holes were drilled and logged, and 1,031 fiberscope holes were examined by mine geologists. From this information, it was found that overburden thickness, sandstone thickness, and sandstone quality contributed greatly to seismic locations. After analyzing the data, a pattern became apparent indicating that the majority of seismic events occurred under specific conditions. Three maps were created using MineScape geological mapping software. MineScape deploys an interpolator known as FEM (finite element method) and is based on a series of gridded triangles to forecast the probability and magnitude of an event if a particular panel were to be mined. The forecast maps have shown accuracy of within 74%–89% when compared to the recorded 181 events that were 1.0 ML or greater when considering three major geological criteria of overburden thickness of 1900 feet or greater, 20 to 40 feet of sandstone within 50 feet of the Pocahontas number 3 seam, and a longwall caving height of 15 feet or less."

Jan 1, 2017

By G. B. Gait

This report is the fourth in a series concerning the Bureau of Mines program for microfilming maps of abandoned mines in the Pennsylvania anthracite region; a catalog of the microfilmed maps of 70 mines in the Western Middle field is presented. Previous reports were catalogs of microfilmed maps of mines in the Eastern Middle field and in the Wyoming and Lackawanna Basins of the Northern anthracite field. Additional catalogs will be published as the microfilming of significant mining areas is completed.

Jan 1, 1971

By E. Morrice

The Bureau of Mines investigated methods for beneficiating platinum-palladium ores from the Stillwater Complex, Montana. Results of bench-scale and pilot-scale studies employing froth flotation to recover sulfide concentrates containing platinum-palladium values from a serpentinized ore are presented. Best results in the pilot mill were obtained with a sodium isobutyl xanthate-normal dodecyl mercaptan col-lector combination at a natural pH of 8.2. A rougher concentrate con-taining 1.7 oz/ton Pt and 4.7 oz/ton Pd was prepared. Recoveries of platinum and palladium were 96 pet and 86 pet, respectively. Batch cleaner flotation of rougher concentrates yielded concentrates contain-ing 3.7 oz/ton Pt and 9.8 oz/ton Pd.

Jan 1, 1984

By Kristopher John Shelswell

The work in this paper describes the theory, development and analysis of a computer model simulating a mine operation moving material using concurrent decline ramp truck haulage and skipping practices. This simulation was designed specifically to assess the performance of the truck haulage component and to expand on the scope and capabilities of traditional TKM fleet calculations. Haulage fleet simulation results were similar to TKM calculations for the lower to moderate production rate cases. However, comparisons of ramp-up and high production rate scenarios indicated that the simulation model was significantly more sensitive to operating practices and factors not accounted for by calculations derived when using a single TKM figure. Given the proper calibration of inputs and logic, the simulation model was additionally capable of providing information associated with general mine operations efficiency. Further benefits of the simulation model over a TKM approach included logistical assessments such as production schedule feasibility, productivity trade-off quantifications for proposed operating practices, and the validation of mine resource utilization scheduling. The simulation model was able to expand on traditional methods to approach planning and logistics by considering factors such as truck queuing, real-time traffic interactions, random events, and competition for resources on mine productivity.

May 1, 2013

By Yogeshwar Sahai

Submerged gas injection into melts contained in furnaces, ladles, or similar transfer vessels is commonly used in industrial practice. In this review paper, conditions leading to gas bubble formation at the nozzle are first summarized. The increasing gas injection rates and other conditions, such as nozzle size, lead to regimes which are commonly known as "bubbling" and "jetting". These are explained. The gas/melt interactions result in energy transfer to the melt. In recent years, a large number of researchers have investigated the relationships between the energy density and the mixing times. Their work is reviewed, and the mixing mechanisms is described. Finally, computational approaches of modeling submerged gas injection are briefly presented.

Jan 1, 1993

By Elgin D. Bell

Within the next, year or two, Western Canada should overtake Mexico and France. to become the worlds second largest producer of elemental sulphur, surpassed only by the United States, By 1965, it should produce about 25% of the world's total elemental production and, about 10% of sulphur produced in all forms. In 1952 Alberta had but one small sulphur recovery plant. By 1962, it had fifteen plants with a total designed capacity of almost 6,000 long tons of sulphur per day and actual production of almost one million long tons per year. This decade of dynamic growth was the result of Alberta's rapidly developing natural gas industry. More particularly it was the result of approval in 1960 to export natural gas in large volumes into the United States. Prior approval to export gas from Alberta to eastern Canada and relatively modest volumes to the U. S. had resulted in the construction of several plants but none were of the scale required to serve the U. S. market.

Jan 1, 1963

By H. B. Miller

By its nature, underground metal mining is unlike any other business in the industrial sector. Operations are continuously exposed to economic risk as a normal consequence of mining due to uncertainties associated with the? deposit, excavation, and ever changing political, regulatory, and market conditions. Out pacing advances in productivity and technology, these conditions have contributed to the steady decline of underground hardrock mining in the United States. This paper investigates the trends and major factors believed to be responsible for this decline. Special consideration is given to changes in direct operating costs, labor productivity, and production capacity.

Jan 1, 1995

By T. Ueno

Naoshima Smelter & Refinery of Mitsubishi Materials Crop. commissioned a new Mitsubishi continuous copper smelter in May 1991. Process offgas volume of the conventional reverberatory furnace line, one of the previous smelters having been shut down, was very large and thus two acid plants had been operated. It was expected that the offgas volume would, be reduced at the new smelter to about a half of the sum of those from previous two smelters and the sulfur dioxide strength would be increased. So various alternatives were studied to minimize the operation cost. And it was decided to utilize both of the plants with minor modifications by diluting the gas either with air or with dilute gases. The acid plants now receive off gases from the new copper smelter, a sintering machine of a lead smelter and a decomposer of waste acid. The paper discusses plant design, operation, improvements and modifications realized in relation with the retrofitting of the copper smelter.

Jan 1, 1992

By Michael J. McGuire

Rostoker, Inc. has developed a process to smelt solid hazardous/non-hazardous inorganic wastes. Near seven hundred experiments were performed. Actual industrial wastes as well as reagent grade chemicals were used. By mixing a multiplicity of these wastes to proper formulations, then furnacing them, it was determined that saleable end products could be reclaimed; metal, fume and slag. The slag, due to its siliceous structure was tested to be leach resistant (40 CFR). This formed the essence of our patent, #5,180,421 "Method and Apparatus for Recovering Useful Products from Waste Streams". What is unique is that a HTMR (High Temperature Metal Recovery) process has been developed that can treat a multiplicity of wastes within the same furnace. The discussion will include a list of waste streams we have treated, details of proper waste formulation and experimental results.

Jan 1, 1994

By John R. Turney

The success of the Mclaughlin acid pressure oxidatiun process has proved that a complex hydrometallurgical process can be an economically viable means of treating refractory gold ores. Homestake's Mclaughin acid pressure oxidation process was commissioned in August 1985 and ts currently operating at design tonnage of 3,000 tons per day. Mineralogical and process studies on the operating plant are discussed to show the improved understanding: of the process and its future applications. These studies are also compared with the initial process development work, thus illustrating the success of the initial scale up considerations.

Jan 1, 1989

By K. B. Chaudhurl

The thermodynamics of the reactions taking place are examined with the aid of equilibrium diagrams for the Pb-O-S system. Based on investigations of chemical, mineralogical and differential-thermo analyses of intermediate products of different desulphuration degrees, an attempt is made to explain the mechanisms of the reactions in the smelting shaft of the KIVCET furnace. The differences between this and other direct lead smelting processes are demonstrated by these thermodynamic and kinetic considerations. Proceeding from these results, the practicability of direct lead smelting processes is discussed with reference to the composition of the primary feed materials to be processed. This comparison also considers the behaviour of minor metals, the products obtained and their characteristics in respect to further treatment. For assessing the operating costs, the over-all energy consumption is considered taking into account various price relations between electric energy and fuels/reductants. Based on the peculiarities of the various processes, an attempt is made to compare the necessary means of meeting the pollution control requirements. The paper concludes with reference to the criteria and problems involved in comparable evaluations.

Jan 1, 1978

By R. S. Bigelow

Part 1.- Metal Mines Early experiments with mechanical loaders in metal mines were confined largely to machines of the shovelling type and generally air-operated. Although the first application of the scraper to metal mines dates back to 1910, it was not until about twelve years ago that it came to be used extensively. Generally, the scraper gives better results in metal mines than in coal mines, as degradation due to soft bottom and breakage are not factors, but it has a wide range of application and is successfully used in the mining of salt, potash, gypsum, zinc, copper, and a variety of ores, from soft material to hard chunky ore which settles compactly. Today, the scraper has replaced to a large extent the shovelling type of machine in metal mines. Scrapers have offered an inexpensive solution for the mucking problem and are now employed in most mining districts throughout the world. They are operated by labourers of all colours and degrees of skill. Each installation, however, requires individual study on the part of the mine mechanical department to determine the type of scraper, horsepower of hoist, and most economical speed of rope, as well as method of rope rigging. Unfortunately, the scraper has no power to select pay ore from waste and its suitability for use under circumstances which might require sorting of the ore can only be decided by a weighing of the economic factors involved

Jan 1, 1931

By V. C. Pandolfelli, L. Paulino, C. E. Zangiacomi

The continuous improvement in aluminum industry over the last years has increased metal output at lower cost. The potlining plays an important role in this regard due to high cost involved and more recently in its environmental aspects. In order to increase potlife and thus minimize the aluminum cash cost, a systemic approach is needed, through investigating the main cathode failure mechanisms by using a pot autopsy as a powerful tool, and then making the necessary chances to achieve extended potlife. In addition, preheating and pot start-up may also damage the cathode if not performed with an appropriate technique or even if the lining materials are not specified correctly, among other factors. All these aspects will be presented and discussed in this paper. Increased potlife, especially now that the current is reaching values up to 300kA, will allow aluminum plants to match their goals more efficiently at lower costs.

Jan 1, 2006

By R. F. Stewart

A nuclear meter based on measurement of prompt capture gamma rays is being developed for monitoring the sulfur content of coal streams. Equipment has been built to measure sulfur rapidly, and methods have been devised to compensate for changes in moisture, ash, and bulk density of coal flowing through a bin. Pilot plant tests of the system with various additives to different coals show a precision and accuracy of 0.02 percent sulfur and 0.04 percent sulfur, respectively. Based on these results, a hardwired meter has been fabricated for testing in a commercial coal preparation plant.

Jan 1, 1974