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By Galen G. Waddell

Dilation and contraction of the rock surrounding horizontal access open-ings of a deep mine were analyzed during stope advance to determine what type of measurements, made with relatively inexpensive instrumentation, would best reflect the rock behavior. A variety of instruments, mostly mechanical extensometers, were used. Detailed descriptions are given of Down-the-hole extensometers, floating rockbolt clusters, transit surveys, and other instruments and measuring techniques. Although all of the radial-deformation-rate graphs illustrated useful rock behavior data, the most informative graphs were compiled from data procured with the radial extensometers that penetrated, to various depths, the rock around the access openings. An analysis is given of measurement data on the rock around lateral drifts and across and adjacent to the nearly vertical vein of the Star mine, Burke, Idaho. Several useful relationships were found between the rock deformation rate and the stoping process. Information was produced on the elastic state of rock around an underground opening, effectiveness of stope support, rheology of rock, zone of influence around stopes, effectiveness of rockbolts, axis of maximum strain in a plane perpendicular to the long axis of the lateral, and other phenomena. This information could be of particular value in determining location, design, and support of underground openings.

Jan 1, 1966

By C. P. Bowie, George L. Gates

"INTRODUCTION Experience in drilling oil and gas wells has shown that the voidance of blow-outs, twist-offs, fishing jobs, loss of circulation, and heaving and caving of shale formations into the drill hole depends largely on how well the drilling-mud fluid serves its purpose. A possible method for the control of the drilling fluids may be seen from a study of the relation between the particle-size distribution and some of the important drilling-fluid properties, such as the ability to build quickly a relatively impervious mud sheath on the wall of the hole in the porous formations penetrated by the bit during drilling operations. In a wartime economy, which urgently requires conservation of steel, proper functioning of the drilling fluid is particularly important because, as Parks 4/ has stated, intelligent use of good drilling fluids makes possible drilling of wells for thousands of feet in open holes without the necessity of setting protective strings of casing to control the movement of salt water, gas, and troublesome formations into the borehole; consequently, especially in deep wells, of proper drilling fluids materially reduces the need for casing and lowers the cost of drilling and completing the wells."

May 1, 1942

By S. Warren Hobbs

The section of the Northwestern United States that includes the northern Rocky Mountains and adjacent areas to the west and east is one of large mineral production and important mineral potential. The metallic ore deposits vary widely in age and type and their geologic settings are similarly diverse. A brief resume of the region's physiographic characteristics and geology sets the framework for the selected ore districts that are described in following papers and makes it possible to place these ore deposits in their proper reference to space and time.

Jan 1, 1968

By C. J. Wilhelm

The Bureau of Mines, under its cooperative agreement with the Kansas State Board of Health, has been conducting a study of the various methods of oil-field brine disposal in the oil fields of Kansas. A previous report5/dealt with this problem in the Ritz-Canton field, McPherson County, Kans. A preliminary survey of the Arkansas River drainage area in western Kansas was made during November and December 1934 and January 1935, and a second survey was made approximately one year later during the months of December 1935 and January and March 1936. In addition to the data on the production of oil and 'brine in the various fields and the methods used for handling the brine, the surface drainage and character of the surface soil in the various oil-producing areas were studied.

Jan 1, 1936

By John B. Knaebel

This paper is one of a series being prepared by the Bureau of Mines on mining methods and costs at various mines in the United States, Canada, and Mexico, and is a description of practice at the Edwards mine of the St. Joseph Lead Co. ACKNOWLEDGMENTS The cooperation and assistance of the officials of the St. Joseph Lead Co. in permitting publication of this paper and providing every facility for its preparation are gratefully acknowledged. Especial thanks are extended R. J. Mechin, manager, R. F. Mitchell, mine captain, and J. S. Brown, geologist, for their generous aid, and the assistance of W. H, Weijola, mine engineer in assembling some of the illustrations is deeply appreciated, The helpful suggestions of C. F. Jackson, principal mining engineer, U. S. Bureau of Mines, are gratefully acknowledged.

Jan 1, 1932

By Alfred Bodenlos

"El presente texto señala los acontecimientos geológicos en la Cordillera Negra y la deposición de travertino por las fuentes termales todavía activas al oeste de la población de Ticapampa. Los minerales fueron depositados principalmente como rellenos de fisuras, siendo cavernosos y en partes bandeados y sus temperaturas conocidas de formación varían desde baja hasta moderada, lo cual, además de su textura porosa, sugiere que están comprendidos entre las clases epitermal y mesotermal, según sistema propuesto por Lindgren. "

Sep 1, 1957

By David B. Dill, Edgar R. Lea

The zinc deposits of the Balmat-Edwards Division of the St. Joseph Lead Company in northern New York State provide some 10 per cent of the domestic zinc produced annually within the United States. These complex ore deposits are contained within marbles of the Precambrian Grenville series, in a repetitive sequence of dolomites and silicated units. The Balmat ore bodies are localized at various intervals throughout some 1800 feet of the stratigraphic column on the northwest side of a band of gneiss that has continuity to the Edwards area, some 10 miles to the northeast. The Edwards ore bodies are located to the southeast of this gneiss. The marble formations are thought to have included repetitive intervals of marine sedimentation that provided mineralized source "beds" and were subsequently folded, flooded, and injected with melts at great depth and were sheared, recrystallized, and reconstituted. Detailed structural and stratigraphic studies throughout the northwestern Adirondacks, in the Balmat-Edwards district, and at each mine in particular indicate the close dependence of the ore deposits on the enveloping structure whether it be local, district-wide, or regional in scope. Primary folding has developed a northeast regional trend with northwest dips. Secondary folding has been developed by an almost horizontal northeast-southwest-oriented shear couple in the plane of the regional trend. The secondary folding has produced crossfolds that intersect the regional northeast trend and plunge north to northwest at various angles. The ore bodies are found within certain stratigraphic horizons where repeated alternation of competent and incompetent beds encouraged unusually complex folding. Analysis of individual mine structures indicates that the location of each deposit is controlled by structural crossing of primary and secondary folding. The ore bodies, which are tabular, lenticular, or pod-like in form, have features that suggest parallelism to true bedding or modified flow banding, developed by northeast-southwest shearing stresses related to the development of the crossfolds. The ore deposits in general follow both structural and recrystallization trends within the wall rocks. Mobilization of the pre-metamorphic ore minerals is believed to have involved a combination of plastic flow under stress and solution of the sphalerite, minor galena, and pyrite. The ore fluids are thought to have been guided by secondary shearing and microbrecciation into structurally prepared areas where reprecipitation took place. The presumed premetamorphic mineralization now exhibits epigenetic high-temperature features related to late-stage metamorphism.

Jan 1, 1968

By D. O. Hamiltion

The ISMS program provided for the development and demonstration of equipment modifications in both conventional and continuous coal mining systems. This report describes activities during the demonstration of the conventional equipment and includes machine performance, results of data gathering, system evaluation, and recommendations for implementing improvements.

Jan 1, 1976

By A. C. Johnson, McHenry Mosier

The Bureau of Mines has adapted its activities to needs of national defense and to conditions brought about by the war program . Its work is now oriented solely to war problems . After studying about 1,600 deposits of war minerals , exploration projects have been undertaken on 96 of the most promising , of which 56 have proved successful . These have indicated that 56 million tons of ore of commercial or near -commercial grade can be utilized to meet war requirements . Included in this amount are 1 million tons of tungsten ore ; 4 million tons of chromite ore, 10 million tons of manganese ore , 2 million tons of antimony ore , 1 million tons of mercury cre , and 28 million tons of iron ore . Work done in connection with exploration projects included 172,000 feet of surface trenching , 210,000 feet of drilling , and 21,000 feet of shaft sinking . Nearly 100,000 samples were taken, on which 500,000 analyses were made . Extensive metallurgical tests were made on ore from many of these deposits , both in the laboratory and in pilot plants , in connection with research to develop metallurgical processes for their treatment .

Jan 1, 1943

By Ernest A. Curth

The Bureau of Mines studied pressure changes in coal pillars by using encapsulated hydraulic pressure cells to measure relative changes in stress developed during mining. The data indicate that (1) abutment stresses were detected when the pillar line is within 42 to 100 feet, (2) vertical pressure increases as coal is mined in the pillars, (3) at first pressure is higher at the edge of the pillar than in the core, but as mining progresses, the higher pressure is measured in the core of the stump, and (4) in the two instances where lateral pressures were measured, they remained lower than the vertical pressures during pillar extraction. The data also indicate that the mean vertical pressure increase, 6P, in a pillar is roughly related to the percent of pillar extracted, A, by the empirical parabolic equation

Jan 1, 1967

By R. D. Irwin, W. M. Mullins, E. A. Medina

"Various stability criteria are introduced and thermo-kinetic models for metallurgical processes are used as concrete examples for evaluation. Kinetic criteria for the process of dynamic recrystallization are proposed. These criteria are compared to the non-equilibrium thermodynamic approaches discussed in the literature. The application of macroscopic stability criteria to materials processing is then discussed.IntroductionThe mechanical behavior of metals at elevated temperature is very well predicted by any of several empirical constitutive relations. Typical is the power-law (or Swift's) form,Equationwhere r-is the stress, y is the strain and m, n , t0, y0 and Q are material constants. This form has been used with some success in the metals processing area [1]. In general, though, all of the empirical constitutive equations are static, failing to account for any dynamical properties of the system they seek to describe.The physics of warm deformation is qualitatively well understood. An example is power-law creep, where the dominant mechanism is assumed to be lattice diffusion limited climb of dislocations, which allows the strain-rate to be determined by the applied stress through"

Jan 1, 1997

By James A. Wasson

This report analyzes the petroleum-production potential of the basal Greenbrier dolomite zone, Sycamore-Millstone field, Sherman District, Calhoun County, W. Va., through the application of certain secondary-recovery methods. The well logs obtained and the core recovered from a well in this formation permitted an evaluation of the productive capability of the reservoir, Approximately 120,000 stb of oil may be produced from a 20-acre five-spot unit at breakthrough if the property is waterflooded. At an assumed limiting producing gas-oil ratio of 20)000 sef/stb, approximately 69,000 stb of oil should be recovered by low-pressure gas drive.

Jan 1, 1967

By Felicia F. Peng

Employing the combination of two types of polyelectrolyte might become necessary to enhance both settling rate of the flocs and water clarity of fine particle suspension in high capacity thickening process. The sequence of addition, mixing, type and dosage of polymer affect the overall performance and capacity of a thickening process. For the sedimentation of copper flotation tailings, the cylinder test results showed that two different techniques may be used to achieve the required performance including high settling rate of flocs, underflow density and overflow water clarity, by either adjusting pH prior to anionic polyelectrolyte flocculation, or using a combination of polymer flocculant and coagulant (dual polymer system). The dynamic thickening testing results showed that only the approach using a dual polymer system is able to meet the required performance. The effects of polyelectrolyte dosage, the sequence and numbers of polyelectrolyte addition, feed concentration, bed level and rake speed on the settling rate, underflow solid, and water clarity were studied in cylinder test and a laboratory dynamic thickening unit with various conditions related to the thickening process. The dynamic test is especially valuable in evaluating the addition and mixing of polymers. The results were evaluated quantitatively, using total suspended solids in supernatant, underflow density and capacity per unit settling area per unit time as the measure of effectiveness. The objective of this study is to quantify and explain some of the parameters involved in the sedimentation of copper flotation tailings.

Jan 1, 1997

By Denis Racicot

"L'Abitibi québécois a produit essentiellement de l’or, du cuivre, du zinc et de I' argent, ainsi que de faibles quantités de nickel, de plomb, de molybdène, de bismuth, de lithium, de fer et d’amiante. Depuis l’ouverture de la mine Horne en 1927, cent-cinquante mines ont contribué à la production de 1 420 tonnes d’or de 4,1 millions de tonnes de cuivre et de 4,7 millions de tonnes de zinc. Les productions minières annuelles ont été d'importance variable: des records de production ont été établis en 1955 pour I' or avec 35 tonnes et, vers 1965, pour le cuivre, le zinc et la quantile globale de minerai extrait avec respectivement 130,000, 275 000 et 13 millions de tonnes. Deux dépressions généralisées ont eu lieu, l’une vers 1946 et l'autre, a lafin des années soixante-dix. Des ralentissements de la production ont été observes pour le cuivre en 1953 et le zinc en 1959. Depuis le debut des années quatre-vingt. I' or et, de façon plus irreguliere, le zinc sont en progression, landis que le cuivre, malgre une hausse en 1983. pour suit son dec/in.La teneur de récupération des mines d’or est demeurée régulière et n’a subi qu’une faible diminution au cours des quarante dernières années. Célie du cuivre a diminué d'environ 50% dans la même période, landis que celle du zinc a subi d’import antes variations, aussi bien positives que négatives. Près des trois quarts des mines d'or ont une durée de vie inférieure à 12 ans et la distribution des tonnages de minerai extrait montre un maximum pour la classe de 100 000 à 1 million de tonnes. Du cote des mines de métaux de base, la durée de vie est plus étalée et les volumes de minerai ont une occurrence maximale dans la classe de 1 à 10 millions de tonnes.Concernant la distribution géographique de la production minière dans l'Abitibi québécois, le camp minier de Rouyn-Noranda vient en tête pour l’extraction de minerai et la production d’or et de cuivre. L’est sui vi par le camp de Val d'Or pour le minerai et l’or, landis que le camp de Chapais-Chibougamau occupe la deuxième place pour le cuivre avec une production équivalence a 60% de celle de Rouyn-Noranda. Le camp de Cadillac-Malartic suit de tres pres celui de Val d'Or pour ce qui est de I' or. Finalement, dans le casdu zinc, le camp minier de Joutel-Matagami domine largement avec une production qui a connu un développement accélère depuis 1963. Une analyse pré liminaire de ces données indique qu' i/ subsiste unpotentiel encore élevé de production d'or, décuivre et de zinc dans I' Abitibi québécois. ABSTRACTThe Quebec portion of the Abitibi belt has essentially produced gold, copper, zinc and silver, as well as some small quantities of nickel, lead, molybdenum, bismuth, lithium, iron and asbestos. Since the opening of the Horne mine in 1927, one hundred and fifty mines have produced 1420 tons of gold, 4,1 millions tons of copper and4,7 millions tons of zinc. Annual mine production has fluctuated: production records were established in 1955 for gold with 35 tons, and around 1965 for all extracted ore copper and zinc with respectively 13 millions, 130 000 and 275 000 tons. Two main recessions have occurred, the first around 1946 and the second during the late seventies. Cut backs in copper and zinc production occurred in 1953 and1959. Since the beginning of the eighties, gold production and to a lesser extent zinc production have been in progression. Except for a small jump in 1983, copper production is still declining.The average recuperation grade of gold mines has been quite steady and has only slightly diminished in the past forty years. The average copper recuperation grade was halved during the same time interval. For zinc there have been important ups and downs. At least three quarters of gold mines have an average lifespan of 12 years the tonnage distribution shows a peak in the 100 000 to 1 million tons class. Base metals mines show a more widespread life expectancy and have a tonnage peak in the 1 to 10 millions tons range"

Jan 1, 1990

By Hu Long

In this, the first systematic study of the oxidation of orpiment (As2S3) in sulfuric acid solution under oxygen pressure at temperatures above 170°C, the effects of retention time, temperature, particle size, oxygen partial pressure, the concentration of sulfuric acid and pulp density were evaluated. The effects of cupric and ferric ions on the oxidation rate of As(III) to As(V) were also examined. The products of oxidation are As(III), As(V), SO42- and elemental sulfur. At temperatures ranging from 170 to 230°C, most of the arsenic was found to be in the trivalent state, and oxidation to As(V) with oxygen was very slow. This was confirmed by attempting to oxidize a synthetic arsenious solution. However, the rate of oxidation of As(III) to As(V) is rapid in the presence of ferric ion. Elemental sulfur was found at all temperatures investigated, which can be further oxidized to sulfate at high temperature.

Jan 1, 1999

By Y. A. Chang, L. M. Pike, C. R. Kao

"Knowledge of the site preference of ternary solute additions is essential to developing an understanding of how these solutes affect the properties of B2 intermetallic compounds. A quasichemical model will be presented which is able to predict the site preferences of dilute solute additions to tliple defect B2 compounds. The only parameters required are enthalpies of formation at the stoichiometric composition. General equations are developed which can be used to determine site occupations and defect concentrations for dilute as well as non-dilute solute additions. These equations use atom pair bond enthalpies as the parameters. It is found that the site preferences of dilute additions are not always in agreement with predictions based on the solubility lobes in ternary Gibbs isothelms. Predictions for dilute additions to NiAl and FeAl are compared to expel1mental results found in the literature. Satisfactory correlation is found between the model and the experimental results. In addition, the predictions from the model on vacancy concentrations in Fe doped NiAl are compared to recent experimental results by the authors.1.0 IntroductionIntennetallic compounds with the B2 crystal structure such as NiAl and FeAl have been investigated recently for possible use as structural materials in high temperature, oxidizing, and/or corrosive environments. The major limiting property of these materials has been a lack of sufficient room temperature ductility. Attempts to improve the ductility have often been made through ternary or higher order alloying. For B2 compounds, substitutional alloying additions can occupy either of the two sublattices and this site occupancy can be crucial in determining how the alloying addition affects the properties of the alloy. In this manuscript we will discuss the use of thelmodynamic modeling to predict the site occupancies of ternary alloying additions in B2 compounds with the triple defect structure."

Jan 1, 1996

ABSTRACT Inco’s Iron Ore Recovery Plant was operated by Inco from 1955 to 1980 near Sudbury, Ontario. As exposures to specific nickel substances have been associated with adverse respiratory endpoints it is important to understand processes giving rise to such substances. This manuscript discusses the process and equipment, the propensity for aerosol formation, and operational procedures used by Inco in roasting a pyrrhotite concentrate, reducing the nickel in the formed oxide, leaching the nickel in ammoniacal solution, purifying the resulting solution, making green or black NiO, and producing iron oxide pellets. Industrial hygiene measurements are also reported.

Jan 1, 2013

By Stephen D. Hill

The Bureau of Mines devised and constructed a modified Knudsen effusion apparatus, permitting a constant measure of the weight of effusing vapor, to determine the equilibrium vapor pressure of metal halides at temperatures up to 1,200° K and over the pressure range 10-5 to 10-2 torr. The reliability of the apparatus was established by determining the vapor pressure of potassium chloride. After correcting for partial dimerization of the vapor, data obtained on solid KCl between 750° and 950° K can be expressed by the following equation:

Jan 1, 1966

By J. Y. Lee, J. Kang

"A selective chlorination process using cuprous chloride (CuCl) was investigated for producing high-grade chalcocite (Cu2S) from chalcopyrite (CuFeS2) feed. The chalcopyrite feed was reacted with CuCl in the presence or absence of sulfur (S) at temperatures between 900 and 1,100 K for five hours under an argon gas atmosphere. The experimental results indicate that iron (Fe) was selectively removed from the chalcopyrite feed as ferrous chloride (FeCl2) at 1,100K and the mass percentage of Fe thus decreased from 31.5 percent in the feed to less than 0.05 percent in the residue, under certain conditions. As a result, high-grade Cu2S was obtained from chalcopyrite in a single step. This new selective chlorination of chalcopyrite using CuCl as a chlorinating agent is therefore feasible for producing high-grade Cu2S.IntroductionCurrently, blister copper (Cu) is commercially produced from sulfide ores by pyrometallurgical methods. These methods entail matte smelting and converting, with the removal of iron (Fe) and sulfur (S) as slag — mainly Fe2SiO4 — and sulfur dioxide (SO2) gas, respectively.In the pyrometallurgical method, as shown in Fig. 1 (Schlesinger et al., 2011), Fe is removed through two steps at high temperatures of around 1,500 K to reduce the loss of Cu during slag formation. However, the slag still contains 1 to 8 percent Cu. Therefore, Cu in the slag is recovered by slag treatment processes, after which the concentration of Cu in the slag decreases to around 0.4 to 1.3 percent. Although Cu is recovered, the slag that had undergone the treatment processes is difficult to use as a feedstock for ironmaking owing to the small amount of Cu remaining in the slag (Schlesinger et al., 2011).In addition, large amounts of SO2 gas are generated by the oxidation of S in the current Cu production process. The SO2 gas generated is captured and used to produce sulfuric acid (H2SO4). However, despite the development of SO2 gas-capture technologies, the emission of SO2 gas is still a problem in terms of environmental considerations.Several studies had been carried out in the past to overcome the drawbacks of the current process. The extraction of Cu from sulfide ores using a chlorination process is one alternative that had been investigated by several researchers. Most chlorination processes used chlorine gas (Cl2) as a chlorinating agent at temperatures between 573 and 1,023 K under an inert atmosphere (Donaldson and Kershner, 1962; Olsen et al., 1973; Kumar, Li and Warren, 1985, 1987; Kanari et al., 1999; Kanari, Gaballah and Allain, 2001)."

Jan 1, 2017

By R. E. T. Hill

"A laboratory study was undertaken to determine the condensed equilibrium phase relations at 600°C in that portion of the quaternary Fe-Ni-Cu-S system which lies in the neighbourhood of the monosulphide solid solution (MSS). The study sought to determine to w hat extent copper affects the temperatures of stability and compositions of iron-nickel sulphides in bulk compositions similar to those of massive Fe-Ni-Cu ores. Experimental data, including stable phase assemblages and phase compositions, are presented.In the quaternary system at 600°C MSS forms stable phase assemblages with pentlandite, chalcopyrite solid solution, pyrite and vaesite. Over the range of bulk compositions displayed by natural ores copper as well as metal/sulphur ratio have a significant effect on the thermal stability of pyrite and pentlandite. Errors therefore accompany the widespread practice of ignoring copper or chalcopyrite when the mineralogical and compositional changes that have accompanied the initial cooling of primary magmatic sulphides or their subsequent homogenization during isochemical metamorphism are being deciphered. These errors are most significant for ores the bulk compositions of which lie tow ard the sulphur-deficient side of the cupriferous MSS. Temperatures as much as 300°C above the copper-absent value are possible for the interpreted upper stability limits of pentlandite in these ores.The experimental data show that up to 2.0 at% copper can occur in pentlandite stable at 600°C in a bulk composition equivalent to natural magmatic ores. This is equivalent to nearly 10 vol% chalcopyrite. Pentlandite contains more copper than coexisting MSS and the copper content of both phases increases with increasing iron."

Jan 1, 1984