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By C. W. Fitzgerald

INTRODUCTION Continuous mining machines are used in regular flat ore beds having uniform thickness. Since coal is the most common type of material occurring in such beds, most continuous miners are used for the extraction of coal from underground mines. The first continuous mining machine for under¬ground coal mining was introduced in 1948. In one machine, the continuous miner combines the functions performed by a conventional face drill, a cutting ma¬chine, and a loading machine. It breaks or digs the material out of the surrounding solid and transfers the material back through the machine chassis by means of a chain conveyor. The conveyor carries the material to a haulage system, usually a rubber-tired vehicle known as a shuttle car. Generally, continuous miners are used in seam heights from 890 to 3660 mm (35 to 144 in.). For seam heights of 1070 mm (42 in.) or less, the haulage system may be a multiple-bridge conveyor or battery-powered tractors that haul low-bed trailers. Proj¬ects are being undertaken by private industry and through government contracts to develop a continuous haulage system for all seam heights. As of 1976, the majority of continuous miners were of two types. The first type is the drum miner, which mounts the cutting elements on a series of drums across the cutting head of the machine, sometimes using a cutting chain to cut clearance for the gear drive. In the drum-type machines, the cutting head rotates parallel to the material face. The second type is the auger miner, which utilizes cutting elements mounted on two auger-type cutting heads. One head is located on each side of the machine, with the heads mounted per¬pendicular to the material face. Chain-head ripper-type miners/miners having rotary cutting elements with oscillating motion and twin-head boring-type miners have all been popular within the last 15 years. Although these are considered obsolete, some machines are still being supplied for specialized applications. GENERAL DESCRIPTION This chapter describes only continuous mining ma¬chines available as manufacturers' production models as of September 1976. Figs. 1 through 11 illustrate some typical machines currently in use. Cutting Elements The cutting elements are the interface between the machine and the material being mined. In describing the cutting elements, consideration must be given to the differences between the drum- and auger-type machines, the bit-tip speeds, and the bit types. Drum-Type Continuous Mining Machines: Three of the four principal manufacturers of drum-type miners use multi-motor designs that provide separate a-c motors for driving the cutting elements. Gear trains are used to reduce the speeds of the motors to the rotational speeds of the cutting elements. One of the three suppliers drives the cutting elements of its low-seam models with a heavy-duty drive chain that is equipped with cutting bits; all other functions of this machine have separate motor drives that are either electrical or hydraulic. The fourth principal manufacturer generally provides two a-c electric motors, utilizing gear reducers, drive shafts, and hydraulically operated engaging clutches to power all of the operating functions, including the cut¬ting elements. Some drum-type miners use trim chains, equipped with cutting bits, to cut clearance for the gear drives. These trim chains vary from two 305-mm (12-in.) chains to one 760-mm (30-in.) chain per machine, de¬pending upon the manufacturer's design concept. In all machines other than the low-seam models that use chains to drive the heads, the trim chains are driven by sprockets on the drive shaft of the final cutterhead drum; therefore, the trim chains are not used for power trans¬mission to the cutting elements. In addition to cutting clearance for the gear drives, the trim chains provide uniform bit spacing all the way across the head and assist in moving the cut material to an area where it is either loaded directly into the miner's conveyor or is easier to load into the conveyor. On a drum-type mining machine, the cutting ele¬ments all rotate from the top to the bottom. Therefore, the recommended procedure is to raise the cutterhead to the maximum seam height, sump the entire machine forward to maximum depth by means of a crawler drive, and then shear downward until the cutter elements reach the floor level. The maximum sump depth varies ac¬cording to the drum diameter, the type of material, the floor conditions, and the operator's abilities. It normally varies an average of 460 to 760 mm (18 to 30 in.). Cutter drums are supplied with two types of cutting bit holders. Weld-on holders are attached permanently. Pin-on holders are replaceable at the face. Cutter-drum diameters over the bit tips vary from 660 to 965 mm (26 to 38 in.), depending upon the chassis height of the machine and the range of cutting heights. Auger-Type Continuous Mining Machines: As cut-

Jan 1, 1982

By Robert W. Waytulonis

Mining regulations pertaining to the use of diesel engines were solicited from foreign countries with mining operations by the Bureau of Mines. Responses were received from 27 countries; the information received and U.S. regulations were reviewed, and those parts pertaining to the use of diesel engines in underground mining were synopsized according to the following subject categories: types of engines permitted, testing and certification procedures, fuel quality specifications, emission control requirements, procedures and frequency of testing exhaust gases, mine air quality and quantity (ventilation) requirements, procedures for testing mine air quality and quantity, and noise standards. All categories except the types of engines permitted and testing and certification procedures are summarized in tables. Contacts are provided for each country to facilitate inquiries concerning regulation revisions or interpretation.

Jan 1, 1987

By J. O. Lewis

In its efforts to reduce waste, and increase efficiencyin oil production, the Bureau of Mines is investigating methods of increasing the recovery from the underground sources of supply, which are the foundation of the petroleum industry and the many allied industries wholly or partly dependent on it. In the face of a demand that is increasing faster than the production and that, in the consensus of opinions of well-informed authorities, is soon likely to outstrip the productive capacity, it is well to consider whether it is not possible to extract more oil from the known sources of supply. It is universally acknowledged that by the usual production methods much oil is left underground, the general opinion being that at least 50 per cent of the oil in a field remains unrecovered when the field is abandoned as exhausted. From the writer's own investigations he believes the average recovery is even less, and if any considerable portion of this oil being left underground could he made available it would have a tremendously favorable influence on the petroleum industry and all the industries dependent on it. In this publication are considered the principles involved in increasing recovery and methods of extracting more oil from the oilbearing formations than by the usual ways of producing. These methods are: The use of gas or vacuum pumps, forcing compressed air or gas through the oil-bearing formations, displacing the oil by water, and better utilization of the natural pressures in the oilhearing formations. Especial attention is being given to a processcommonly known as the Smith-Dunn-for forcing compressed air through oil-bearing formations because it is believed to hold most promise for the future.

Jan 1, 1917

By W. S. Hargratt

THE present era of exploitation of the Little Long Lac and Sturgeon River areas commenced in 1925, when Beardmore Gold Mines started development of what is now the property of Northern Empire Mines. A shaft was sunk in 1927-28 and a very limited amount of underground work was carried out, following which the property was shut down. It remained idle until 1932, when Empire Star Mines, a Delaware Company, optioned the property. This Company formed the Northern Empire Mines Company, Limited, to operate the mine, and immediately instigated an aggressive programme of surface and underground development. By the summer of 1933, sufficient ore was indicated to justify the installation of a small mill. The decision was also reached to bring in electric power. A power-line was built from Hydro, the Ontario Power Commission's development on the Nipigon river, to the mine, a distance of approximately 50 miles. This work was entirely financed by Northern Empire Mines. Mill construction was commenced in October, 1933, and completed by March, 1934, thus making this mine the first producer in this district.

Jan 1, 1940

By A. F. Baker

Tests were conducted in commercial foundries to determine the suitability of calcined anthracite as a cupola fuel. The calcined anthracite performed satisfactorily at two of the three foundries where iron-melting tests were conducted. Performance at the third installation was unsatisfactory because metal temperatures deviated widely and, in general, were lower than is desirable for the type of castings being made.

Jan 1, 1963

By R. J. Sheets

In 2009 the Gold Quarry open pit mine, located 11 km northwest of Carlin, Nevada, USA, experienced multiple large-scale slope instabilities of the upper east highwall that reduced gold ore extraction for nearly 18 months. The slope instabilities occurred within a weak, consolidated sedimentary sequence that exhibits strength characteristics that are transitional between soil and rock. Instability initiated as mining exposed the lower clay-rich sub-units of the Carlin Formation (Fm.). This deformation created preferential flow paths that allowed groundwater from the upper sandy sub-units to infiltrate low permeability clay-rich sub-units, thereby enhancing deformation of the slope toe which in turn destabilized the upper portion of the highwall. The outcome was a 160 m high slope instability that had a lateral run-out of 850 m. The effort to return the pit to ore production required both the geotechnical and hydrogeological investigations and the preliminary remediation mining activity to be concurrent. This approach required the development of detailed safety procedures and a requirement to modify the remediation design as new results were obtained. An initial challenge was to mitigate a near vertical, 90 m headscarp with blast induced, localized slope failures. Back-analyses applying numerical modeling indicated that the failure surface did not coincide with initial interpretations based on field observations; drilling results eventually confirmed this alternative failure geometry. The final remediation design incorporated shallower slope geometries and an approximately 3 Mt buttress along the base of the Carlin Formation and bedrock contact to reinforce the lower clay-rich sub-units. The outcome is a stable highwall within the Carlin Fm. following nearly ten years of repeated slope instability, and an example of the necessity to conduct appropriate geotechnical and hydrogeological studies during the early stages of a new layback evaluation or new open pit development.

Feb 23, 2014

By Frank J. Wiebelt

Under a general program to extend the resources of mineral deposits, the Bureau of Mines examined the Quien Sabe antimony mine in October 1948. The preliminary evaluation demonstrated that a diamond-drill program was warranted co establish the tenor and persistence of the veins and permit an estimation of antimony reserves. The Bureau of Mines conducted a diamond-drilling program on the property from December 1949 to May 1950. Ten holes aggregating 2,483 feet were drilled. Nine of the holes encountered antimony-bearing vein material.

Jan 1, 1956

By P. J. Le Roux

"Mining worldwide and definitely in South Africa, is constantly under pressure to reduce its cost structure so as to sustain profitability. In underground gold mines where an open stope mining method is employed, dilution often has a significant effect on the viability of sustaining profits. Target Mine practices Open Stope mining Method and it was found that in some open stopes dilution was in excess of 10%, which has a significant impact on the sustainability of the mine.Dilution in excess of 10% can result in the reduction of the recovered grade from 5,5 to 4,5 grams per ton (g/t). The reduction of 1 g/t in recovered grade results in a potential loss of about ZAR21 Million per month bases on a gold price of ZAR240 000 per kilogram. Based on Life of Mine projections the potential loss of income could be as much as ZAR3,3 Billion. A reduction in dilution would have the opposite effect. There are a number of factors which affect dilution of which falls of ground in open stopes is a major contributor. The falls of ground can be attributed to a number of factors such as beam failure as a result of a larger than normal expected roof area (hydraulic radius too large), poor ground conditions, and poor blasting. The cost of damage to or loss of trackless equipment as a direct result of the falls of ground in open stopes, is very significant. The review of financial figures has indicated that this could be as high as ZAR491 million. This combined with the added cost of transport, hoisting, secondary blasting, milling and plant treatment costs of ZAR293 results in an estimated opportunity loss of ZAR784 million.Currently there is a significant amount of data available in the mining industry which could be effectively used to develop suitable back analysis techniques but to date this has not been used effectively. If dilution can have such an impact on current and future mining ventures then the optimization of back analyses for the prediction of dilution in open stoping could assist significantly in the reduction of dilution in massive open stopes. Rockmass classifications, geotechnical information, blast techniques, blast design, the stress strain environment and hydraulic radius all have an effect on, or play a role in the evaluation of dilution. Each of these factors will be taken into consideration to ultimately determine a measurable or calculated percentage of dilution in massive open stopes.The amount of overbreak in an open stope can be determined by subtracting the planned stope volume in m3 from the actual measured final stope volume in m3, which is obtained from the CMS (cavity monitoring system). This is in turn divided by the planned stope volume in m3 to determine the percentage overbreak. The CMS wireframe is imported into the geological model and its grade re-evaluated. From this the actual percentage dilution for this open stope can be determined. The dilution obtained can result in a major reduction of recovered grade for the open stope, but can also increase the recovered grade. The latter is normally the exception rather than the rule.When analysing data from Target mine the following was achieved:• Using 11 years of data a method of measuring and predicting the percentage dilution in open stoping was developed. This took into account rock mass quality, stress-strain state, and the hangingwall hydraulic radius (size of stope hangingwall exposed).• Implementation of this prediction method resulted in a reduction in falls of ground in open stopes. The benefit of this was a reduction in the damage to mechanised equipment resulting from less falls of ground which had a positive effect on the profit margins of the mine. As a direct result the recovered grade from the open stopes increased due to the reduction in the amount of dilution.• A design criterion, Dilution Stress-Strain Index (DSSI), was developed which allows the user to calculate, with certainty, the stability of the open stope and determine if m"

Jan 1, 2015

By W. N. Hamilton

As a result of a test-drilling program conducted by the Research Council of Alberta in 1968, a gypsum deposit averaging 30 feet in thickness, with a chemical purity of 84 per cent gypsum, has been proven to underlie the Clearwater River valley for a distance of 18 miles at depths ranging from near-surface to 300 feet. This and other subsurface deposits in the vicinity of Fort McMurray, Alberta are the product of local hydration of anhydrite beds believed to be the water-insoluble remains of the leached Prairie Evaporite formation of Middle Devonian age, the thick salt section of which is preserved down dip. The effects of salt solution are seen in the disturbed bedding and the intermixture of greyish green shale with gypsum in the core, the shale content being responsible for the rather low chemical purity of the deposit. A similar gypsum deposit, but probably of higher purity, is postulated to occur beneath the Athabasca River valley about 60 miles north of Fort McMurray.

Jan 1, 1969

By B Levasseur, C Olsen, E Ghasemian Langeroudi, F Larachi, F Safizadeh, C Gagnon

Gold recovery by the cyanidation process is often accompanied by the leaching of other species. This leads to the depletion of the level of free cyanide and oxygen available for gold cyanidation. The largest proportion of the consumed cyanide is diverted by the cyanicides (eg S, Cu, Zn, Fe, etc) into non-valuable complexes.COREMÆs Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during preoxidation and cyanidation. Flotation tailings and single mineral samples such as pyrite, sphalerite and chalcopyrite, along with their different combinations, were analysed to highlight the influence of ore mineralogy on the operating conditions. The effects of different kinds of oxidants (oxygen, hydrogen peroxide, ferricyanide and ozone) and chemical additives (ammonium sulfate) were investigated.Experiments conducted in alkaline solutions reveal that mineralogy is a key parameter since pyrite, chalcopyrite and sphalerite react quite differently during preoxidation and cyanidation. A significant increase in sulfur dissolution, especially on pyrite, was observed by applying preoxidation. H2O2 preoxidation showed a positive effect on increasing sulfate formation, a desirable by-product from the cyanide consumption point of view. Preoxidation of synthetic ores with ferricyanide resulted in boosting thiosulfate formation. Tests conducted on flotation tailings from a polymetallic mine revealed that a short preoxidation increases the dissolution of the ore leading to higher gold recovery and lower cyanide consumption. Regarding the formation of thiocyanate, the most undesirable by-product of the cyanidation, ferricyanide and ozone were found particularly efficient to hinder their formation. Finally, the addition of ammonium sulfate during the cyanidation process showed some promising results in terms of both gold dissolution and cyanide consumption.CITATION:Ghasemian Langeroudi, E, Levasseur, B, Safizadeh, F, Olsen, C, Larachi, F and Gagnon, C, 2013. Optimisation of operating parameters for cyanidation of sulfide-bearing gold flotation tailings in order to prevent the impact of cyanicides, in Proceedings World Gold 2013 , pp 111-120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By G. A. Van Wielingen

"The conditioning of natural gas to meet contract pipeline specifications involves in the majority of cases in Western Canada, the appropriation of substantial capital expenditures for treating and processing installations. It is therefore of vital importance to the owners and producers of natural gas to arrive at an appreciation of the economics pertaining to the production and surface handling of their gas reserves at the earliest possible stage of field development. The treating and processing of natural gas often results in considerable changes in composition and related physical characteristics between the wellhead and the point of delivery of the saleable gas. This paper presents a general outline of engineering calculations which can be applied in the pre-determination of the effects that surface handling of gas will have on the composition and physical characteristics of sale-able gas. Emphasis has been placed on the calculation of hydrocarbon dew-points, heating values and shrinkages prevailing at the various stages in the surface handling of natural gas. It is believed that advance information indicating the approximate ranges of these physical properties will facilitate process selection and will provide a basis for the estimation of capital and operating costs of process installations."

Jan 1, 1960

By C. M. Palencia

The Bureau of Mines evaluated the potential availability of molybdenum resources from 88 mines and deposits that account for more than 90 pct of the demonstrated resource base in market economy countries (MEC's). For each property, tonnage-cost relationships were developed that indicate the molybdenum potentially available at different average production costs, including a 15-pct rate of return on invested capital. From the 23 MEC primary deposits, 2.5 billion 1b Mo was determined to be potentially available at a price of $411b, rising to 4.7 billion 1b Mo at $8/lb. Copper price-molybdenum tonnage relationships were developed for those mines and deposits from which molybdenum can be recovered as a byproduct of copper production. This analysis showed that another 3.4 billion lb Mo is potentially available based on a copper price of $0.7511b, rising to 4.3 billion lb Mo at $l.00/lb. The United States has been the world's largest molybdenum supplier since 1924. Its remaining resources are sufficient to meet the domestic demand of 57 million lb/yr Mo (averaged for a 10-yr period) through the end of the century. Production from primary domestic mines was suspended during most of 1983 because of oversupply of materials. A major concern is the cheap molybdenum byproducts from foreign copper operations in which employment and the need for hard currency override economics in meeting production goals.

Jan 1, 1985

By Thomas J. Peters

The Snowbank study area, which had been proposed as Wilderness, lies about 5 air mi southwest of Cascade, Idaho, and about 60 air mi north of Boise. The eastern boundary of the north-south-elongate study area lies 1-to 2-mi east of Cascade Reservoir; the western boundary is contiguous, in part, with the western boundary of Valley county. The 8,200-acre study area is underlain by Cretaceous granitoid rocks of the Idaho batholith. Three prospects were found in or near the study area during a library and field search. Gold occurs at one 30-ft adit, but the gold-bearing structure appeared too narrow to contain resources. Two other prospects appeared essentially unmineralized. No evidence of geothermal activity was observed. Rock in the area is not potentially useful as dimension stone because it does not split into flat slabs. To be used as aggregate, the rock would require crushing and hauling to distant markets. One of 18 alluvium concentrate (placer) samples contained free gold, worth $1.07 per cubic yard of gravel (at a $350 per oz gold price). No alluvial bars were seen; deposits were too small to contain gold resources or be considered gravel resources.

Jan 1, 1993

By A. Hajati

The main purpose of this study was to find the optimum values for factors affecting the Zn recovery rate using oxine or dithizone as a chelating agent collector during flotation in a Hallimond tube. Eight control factors, including four levels of pH, oxine/dithizone, corn starch, sodium thiosulfate, sodium citrate, sodium silicate, conditioning and floating durations were considered in a Taguchi experimental design technique. An L32 orthogonal array was applied to determine the signal-to-noise (S/N) ratio. Analysis of variance (ANOVA) was used to determine the optimum conditions and the most significant parameters affecting the reaction rate. Analysis of the experiments using the Taguchi approach indicated that pH had the highest contribution to the recovery rate of zinc oxide particles. The results showed that the recovery rate of zinc increased by 43.4 ± 3.0% and 24.9 ± 3.2% using oxine and dithizone, respectively, under optimum conditions with a confidence level of 90%.

Jan 1, 2010

By T. J. DeMull

The business of heap leaching requires accurate forecasting of metal production from the heaps. Business forecasts typically follow a format that project periodic (monthly, quarterly, or annual) product shipments based on anticipated operating results, e. g., tons of ore placed, grade of ore, and rate of leach extraction. Since revenue and cash flow are dependent on the metal production stream, forecasts of metal production are very important for project evaluation and business planning purposes. Nevertheless, production forecasts, particularly for new heap leach projects, have been prone to errors. The present paper identifies some of the pitfalls that would be encountered in preparing production forecasts for new heap leach operations and provides a checklist of considerations to assist in preparing a forecast. Also, the paper presents a case study of copper production forecasting used for the Sanchez Project, a heap leach operation located near Safford, Arizona, that is presently under development by AZCO Mining, Inc.

Jan 1, 1995

By N. Agron-Olshina

The application of the QEM*SEM image acquisition and analysis system to the measurement of the mineral matter in coal and the materials in fly ash is described. A new sample mounting technique was developed using iodinated epoxy to provide a backscattered electron contrast between the coal, the mounting medium and the mineral matter. Several comprehensive and detailed species identification programs for silicate minerals and materials were developed to analyse the 1000 count x-ray spectra used for the measurements. Case studies are presented to demonstrate the capabilities of the new technique to distinguish different coals and fly ashes by their mineral and material composition rather than by conventional chemical analysis. Applications of the new technique are aimed at demonstrating that composition and size distributions obtained from OEM*SEM measurements can be used: 1. to characterize coal with respect to combustion problems in power stations, 2. to characterize coal for fine coal cleaning, 3. to characterize fly ashes in relation to problems such as erosion in combustion systems and the ease of precipitability in dust collection facilities, 4. to refine the classification systems used in marketing coal for pulverized fuel firing and fly ashes as a component of cement and building materials.

Jan 1, 1992

By S Lloyd, J Chow, S Fitzpatrick, D Greenup

The Tropicana deposit was discovered in 2005 after AngloGold Ashanti followed up an unexplained gold-in-soil anomaly. Discovered in a remote, barely-explored area of Western Australia not previously thought prospective for gold, Tropicana is the most significant gold find in Australia for more than a decade. The new, large scale open pit gold mining operation will produce an annual production of around 330 000 to 400 000 oz over a ten year mine life mining around 60 Mt/a.Process plant construction started in early 2012 and is due to finish in the December 2013 quarter. The mining contract was awarded to Macmahon Holdings (Macmahon) and mining commenced in July 2012 using conventional drill and blast, truck and excavator open cut methods.As a construction and start-up project in a greenfields location, the establishment of mining activities at Tropicana Gold Mine (TGM) involves the implementation of technical and operational systems, including the mining contract. Some of these systems and likely challenges were identified during earlier studies, while others were not foreseen until they were encountered. Alternatively, the time frames around implementation change depending on the changing knowledge of the project and industry environment. These systems include those common to the industry and those specific to the operation and location.This paper examines the implementation and development of a number of the systems specific to the establishment of mining operations, including the history, process and some outcomes. Although expected to be discrete systems to implement, they become interdependent. This linkage between systems further offers challenges and opportunities for the continuous progress of each system and for TGM as a whole.CITATION:Chow, J, Fitzpatrick, S, Greenup, D and Lloyd, S, 2013. Tropicana Gold Mine - mitigating the challenges of a mining start-up, in Proceedings World Gold 2013 , pp 51-60 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By E. J. Ostrowski, P. L. Woolf, J. P. Morris, Norwood B. Melcher

By injecting natural gas through auxiliary tuyeres into the smelting zone of the Bureau of Mines ' experimental blast furnace in January 1959 , the investigators succeeded in reducing the coke consumption by approximately one - third that of the base period . This caused a 30 - percent increase in pig iron production with no increase in wind rate . The maximum gas addition in these experiments was 4,665 cubic feet per ton of metal produced . Sharp reduction in gas consumption occurred when high hot blast and high wind rates were used , although the gas injection rate in percent of air blown remained constant . As the heat energy produced by burning natural gas to carbon monoxide and hydrogen is much less than burning coke to carbon monoxide , greater blast temperatures were required during the test runs . The gases produced from the methane were , however , more effective reductants ; so it was possible to increase the production rate while reducing the total heat requirements per ton of metal produced . During a base period with an all - sinter burden , before introduction of natural gas , a coke rate of 1,484 pounds per net ton of pig iron was attained , using an average blast temperature of 1,518 ° F. Gas was introduced gradually over a two -week period until an average 7 percent of the air blown was reached . During this period , the wind rate was adjusted downward to maintain a constant flow of gas in the bosh . The production rate of the furnace remained relatively constant . The quality of pig iron, however , improved as the sulfur load on the furnace was reduced as a result of the substitution of gas for coke . Blast temperatures were increased during this period from 1,518 ° F. to 1,939 ° F. , when the maximum gas addition was reached .

Jul 1, 1960

By Robert J. Brennan, Edward R. Navrocky, John W. Buch

In an effort to establish a highly productive mechanized mining system for anthracite beds pitching between 10 ° and 20 ° , for which conventional mobile equipment is not adaptable , the Bureau carried out an experiment in longwall mining using an Anderton- type drum cutter loader and friction - type yielding steel roof supports . The roof- support system proved to be inadequate for breaking the overhanging roof at the break line supports , with the result that the roof broke over the solid coal . The accompanying subsidence destroyed the continuity of the roof in the work area , and the project was discontinued .

Jan 1, 1964

By L. B. Pankratz, R. Barany, W. W. Weller

Experimental determinations were made of the heats of formation at 298.15 ° K of cuprous ferrite and cupric ferrite ; the heat capacity of cuprous ferrite was measured over the temperature range from 50 ° to 298 ° K and the entropy at 298.15 ° K was evaluated ; the heat contents of cuprous ferrite and cupric ferrite above 298.15 ° K were measured to 1,500 ° K and 1,100 ° K , respectively . These thermodynamic values were combined with other pertinent data to obtain heat and free energy of formation values at high temperatures . The stability of the two ferrites with respect to their constituent oxides is discussed . Thermodynamic values are included for the decomposition of cupric ferrite to form cuprous ferrite , magnetite , and oxygen .

Jan 1, 1964