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In the late 1970's Western Mining Corporation, Exploration Division considered the purchase of a major multi-element spectrometer as an adjunct to our existing atomic absorption spectrophotometers. The analytical work proposed for the unit included barium, uranium and rare earth elements from Olympic Dam, uranium, sulphur, vanadium and strontium on Yeelirrie type deposits, major element and whole rock analysis, multi-element analysis of samples from the laterite, chromium and manganese exploration programmes and tin and arsenic analysis. These were all analyses that were not readily or easily performed by flame atomic absorption or were where we expected that a simultaneous multi-element instrument would be an advantage. Also the turnaround times for the commercial laboratories was considered unacceptably long for some determinations. Other factors, important when considering the spectrometer were the ability to ensure confidentiality of results and the ability to assign our own priorities and not to have to rely on commercial laboratories. The two techniques considered were X-ray Fluorescence Spectrometry and Inductively Coupled Plasma Optical Emission Spectrometry. The decision was made in favour of the ICP unit for several reasons. The ICP fitted in with our existing methodology, ie samples digested for atomic absorption or colorimetric techniques would also be suitable for ICP analysis and vice versa. The technique was suitable for water samples and for major element analyses and for rare earth elements. X-ray fluorescence spectrometers were installed at the Kambalda and Belmont laboratories and would be available to us for routine checking and for elements not suitable for ICP analysis. The final consideration was price. ICP was considerably cheaper than XRF.

Jan 1, 1987

By Morrison RD, Peberdy NJ

Simulator training provides a cost effective method of training operators in both the process and control aspects of a metallurgical plant. The components and requirements of a training simulator are described along with the benefits to be gained from simulator training. A table summarizing some applications of metallurgical training simulators is Given.

Jan 1, 1991

By L Cooper, J Sharma, M J. Hendry

Thick clay tills below potash mine tailings and brine ponds are important natural barriers protecting fresh water aquifers in Saskatchewan. Centrifuge modelling was applied to assess geochemical processes and impacts of dilute brine (0.1 M NaCl) migration through clay till core samples obtained from non saline, unoxidised clay till at a mine site. At accelerated gravity of 876 + g, during each day of centrifuge modelling, flow driven through a 52 mm length core simulated transport through a 45 m thick clay over ~2100 years. Hydraulic conductivity, monitored continuously before and during brine permeation, was low and relatively constant (8.5 + 10-12 m/s), confirming that confining stresses prevent permeability increase. Core density and porosity measurements confirmed that reactive transport occurred under realistic in situ conditions. Breakthrough (defined by C/C0 = 0.5) of non-reactive Cl- occurred at 25 days. The slight delay for Na+ breakthrough, associated with small increases in Ca2+ and Mg2+ concentrations in the effluent were attributed to ion exchange, but carbonate reactions were relatively unimportant. Cation exchange analysis of core samples was inconclusive without corrections for porewater Na+ and carbonate dissolution. Geochemical processes that were observed during centrifuge modelling were successfully simulated using the 1D geochemical transport code PHREEQC. Solute transport was dominated by diffusion with limited ion exchange to delay Na+ migration. Brine would not break through a 45 m thick clay for tens of thousands of years. Based on these findings, the thick clay till at this site, if laterally extensive and undisturbed by drilling activity, is likely to act as an effective natural barrier to vertical brine migration over the long term.

Jan 1, 2003

By J. Campbell

The hydrostatic tensions in pure metals and long freezing range alloys are evaluated theoretically considering the viscous flow of residual liquid and the general plastic collapse of the casting. The former mechanism operates until the radii of the remaining liquid channels are of the order of 10-3 cm radius, after which the second process limits the attainable negative pressures which range from —1500 to -4200 atm for nickel, aluminum, copper, and iron. In previous reports1'2 the maximum possible hydrostatic tensions developed during solidification have been evaluated employing spherical symmetry. This inevitably involves the concept of totally confined liquid regions, the reality of which has recently been brought into serious doubt3 following observations of the freezing of various transparent materials. Regions of interdendritic liquid which are apparently about to be isolated by the growth of dendrite arms are observed not to be cut off because the advance of the dendrite tips is arrested until the region has completely solidified. Although this may be the result of the very low melting point liquid available at this late stage in freezing, or the result of a higher rate of heat transfer to the dendrite tips because of the acceleration in liquid flow rate near the completion of solidification, this point need not concern us. In this paper an attempt is made to approximate more closely to real conditions; thus the assumption of confined liquid regions is abandoned and cylindrical symmetry adopted. It has also been necessary, therefore, to consider the viscous flow of residual liquid through the remaining channels in the pasty zone. Furthermore, the rather special conditions of spherically symmetric solidification led to extremely high solidification rates and hence unusually high tensile stresses as solidification neared completion; the cylindrical Symmetry appears to yield solidification rates and stresses which are more typical of real castings. The rate of solidification is first considered since this critically affects both the flow of the liquid and the creep of the solid.

Jan 1, 1969

By Frederic P. Dewey

The Bureau of the Mint of the United States Treasury maintains 13 ofEces for the purchase of gold-bullion, and this paper describes an investigation to establish the reasonable differences in the assay-results at the various institutions which may be commercially allowable in the settlements between them. Beginning with the comparative assay of proof-gold at the Philadelphia mint and the Utrecht mint, which shows 0.00002 as the closest agreement now possible, nine tables of comparative results, taken from the regular work of the service, are given..These tables begin with very fine gold, produced in an electrolytic refinery, showing close agreement in the assay-results, and follow through decreasing gold fineness and increasing amounts and complexity of base metals to very impure and complex bars produced at cyanide-mills, some of which give widely-varying results. Next is given a series of results on samples, prepared and sent out to various laboratories in the service, to test the influence of different metals and various combinations upon the agreement of the assay-results ; 11 samples were sent out and each one was assayed from 44 to 71 times, making a total of 623 assays. To these ire added 107 assays of identical samples of coin-gold. On a previous occasion,' I have endeavored to show the degree of accuracy that may be expected in the ordinary everyday analysis of various materials, and on another occasion,2

Jan 1, 1910

By Seneviratne SP

The excessive displacement of the seam floor in headings (i.e. roadways) called 'floor-heave' is often experienced in the underground mines of the Southern Coalfield of New South Wales. Apart from interfering with the mining operations, the phenomenon could be detrimental to the stability of the pillars left for support leading to an unpredictable increase in the subsidence of the overlying strata. The latter could pose a serious problem, particularly in the design of partial extraction layouts of mining for areas where subsidence is to be controlled. The susceptibility of the floor of different rock materials and thicknesses in a given `panel and pillar' partial extraction geometry was examined by two- dimensional Finite Element Modelling of the displacements, stresses and failure zones around the excavations. The modelling, assuming elastic behaviour of the materials, indicated that the maximum vertical displacements of the floor increased substantially as the Young's Modulus of the material decreased to less than 7GPa and the thickness of the layer increased. The results also discount the possibility of a properly designed panel and pillar geometry in the Southern Coalfield of New South Wales being unable to adequately control surface subsidence through the pillar, or its core independently of the yielded ribs, penetrating the floor.

Jan 1, 1992

By Tumilty JA, Douglas WD

With a view to characterising activated carbons with respect to their ability to adsorb gold from cyanide solutions, an attempt was made to establish correlations between the equilibrium capacity constant of the activated carbon for gold (k value) and five other parameters. These parameters were percentage ash content, iodine number, methylene blue value, surface area, and pH respectively. Twenty four different proprietary brand activated carbon products were examined, the correlations being established by means of linear regression analysis. It was shown that a significant correlation only existed between k and pH value. This was interpreted in terms of the presence of oxide complexes on the activated carbon surface. Further test specifications as developed at the Anglo American Research Laboratories are also outlined with a view to the selection of activated carbons suitable for use in' a carbon-in-pulp operation. Methods for assessing both the capacity and the kinetic response of carbons for gold adsorption are presented, while the measurement of attrition resistance, particle size distribution and moisture and solubles content is also outlined. The measurement of the capacity constant for gold adsorption together with attrition resistance are considered to be necessary in the initial selection of a suitable carbon.

Jan 1, 1982

By R. Hogg, S. Chander

An overview of various physical and interfacial characterization methods for use in mineral processing is presented in this paper. The availability of a large number of characterization techniques and commercial instruments requires that the reliability and limitation of each be carefully examined. The choice of a method may depend upon the manner in which the information is to be used, for example, in development of new processes, plant and process design, plant control, problem solving, etc.

Jan 1, 1987

By R. W. Raymond

That the death of Martin Coryell, which occurred at Lambertville, New Jersey, on Monday morning, November 29th, touched the sympathies of a wide circle of professional associates and personal friends, was amply testified by the gathering at the funeral services on Friday. Like his distinguished friend and neighbor, the late Ashbel Welch, Mr. Coryell was one of those pioneers in American engineering to whom we owe the great railway and canal systems which lie at the base of our national prosperity, and who have consequently enjoyed the respect and esteem of their successors of the present generation. Martin Coryell was born July 20th, 1815, at New ope, Rucks County, Pa., and was educated principally in the schools of his native town arid of Lambertville, New Jersey, to which place he returned for permanent residence fifty years later. With the exception of a brief period in youth, during which, to restore his failing health, he learned and practiced for a few months the carpenter's trade, and another brief period, later in life, when he read law for a time in the office of B. H. Brewster, of Philadelphia, afterwards Attorney-General of the United States, Mr. Coryell may be said to have spent his life as an active civil and mining engineer. Even these two episodes can scarcely be said to have been deviations from that profession, since they served to give him more thorough preparation for constructive and administrative work. The Delaware Division Canal, the Raritan Canal, and the Brunswick Canal, are among those upon which Mr. Coryell was employed. For the Raritan Canal Company, under the superintendence of Ashbel Welch, he located the greater part of the Belvidere Railroad (now the Belvidere division of the Pennsylvania Railroad), and directed its construction from Trenton to Lambertville. He was also active as a mining engineer, being one of the early pioneers of mining in the Lake Superior copper region, and had much to do with the development of the Hazleton coalfield and the railroad which has since expanded into the Lehigh Valley system. In 1862, he removed to Wilkes-Barre, where, in 1864, he became manager of the Warrior Run Mining Company. One of the editors

Jan 1, 1887

By W. T. Abel

The Bureau of Mines tested 48 materials for their ability to absorb H2S from hot simulated producer gas (1,000°-1,500° F). The material found best from the standpoint of absorption capacity, durability, and amenability to regeneration was sintered pellets of 75 percent fly ash-25 percent Fe203. The performance of this absorbent under simulated and actual conditions is described. The effect of absorbent composition, absorbent temperature, steam content of the gas, and tar vapors and dust in producer gas is discussed.

Jan 1, 1974

By A G. Grice

Surface disposal of mining processing wastes is usually perceived as an undesirable consequence of meeting societyÆs needs for metals and minerals. Environmental disasters associated with the discharge or storage of such wastes, though infrequent, can have very damaging consequences for the environment and the industry. Reducing or eliminating the potential for such events may be achieved by placing some or all of these processing wastes back into the voids created by the mining operations. Processing operations may limit or enhance the opportunities for using tailings and other waste products as a backfill material. Backfilling is a truly multi-disciplinary process and requires the informed involvement of mining, metallurgical, engineering and environmental specialists. This paper describes the range of fill types currently being used in Australian mines, particularly those utilising processing wastes as constituents. It focuses on how processing operations can affect the suitability of these materials for the various types of fill, the resulting fill properties, fill performance and costs.

Jan 1, 2002

By J. A. Snyder, W. L. Finlay

SEVERAL notable studies of the effects of sub- stitutional solutes have been reported. Outstanding among these for its elucidation of general principles, is the summarized work of Hume-Rothery and coworkers.1 For a systematic study of the effects of substitutional solutes on the mechanical properties of the solvent lattice, the work of Brick, Martin, and Angier² on copper; of Frye and coworkers³,4,5 on copper and silver; and of Lacy and Gensamer6 and of Austin7 on iron may be mentioned. Titanium is one of the few elements offering the possibility of a similar study of interstitial solutes since, unlike most metallic elements, it exhibits extended solid solubility for most of the interstitial solutes—hydrogen, boron, nitrogen, oxygen, and carbon. This paper reports a survey of the effects of dilute solutions of nitrogen, oxygen, and carbon on the mechanical properties of high-purity alpha titanium. Previous Work: Van Arkel and De Boer showed" that high purity titanium was quite ductile and De Boer, Burgers and Fast established".' that not only were oxygen and nitrogen very soluble in solid titanium but that, long before the limit of solid solubility of either had been reached, these interstitial solutes rendered the metal brittle. Their electrical resistance data as a function of

Jan 1, 1951

Jan 1, 1954

By J. A. Singmaster

A REPORT that it did not pay to use present-day galvanized iron on account of the short life of the material, accompanied by proofs of the state-ment in the form of a tabulated history of the first costs of various kinds of building materials and their main-tenance expense, started an investigation of modern galvanized products. At the very outset it was apparent that our experience with galvanized products was by no means unique. Correspondence with the State Agricultural Depart-ments, the Agricultural Experiment Stations, the County Agents and State Granges all over the United States brought a mass of complaint on this same score. Visits to large buyers of galvanized sheet and wire revealed the same condition coupled with an ever-increasing use of substitutes for galvanized iron. We believe, therefore, that the title of this article is fully warranted by the experience of the consuming public. A study of the proceedings of the various societies having to do with the testing and use of sheet iron and steel products revealed a tremendous amount of work on the life of the base metal itself. Great stress was laid on differences in life of various types of iron and steel, the difference amounting at best to months rather than years. Very little recent attention has been paid to a study of the life of the zinc coating and the causes of its present-day lack of durability. There have been some real exposure studies published, how-ever, which show that the weight of the zinc coating determines the protection afforded by the galvanizing, which is of far greater influence on the life than the base-metal composition. An interesting paper was published by the Phillipine Journal of Science in 1916, entitled: "Galvanized Roofing in the Phillipines," a contribution from the Bureau of Science of the Phillipine Island Government. The author, Mr. Arguelles, found on 18 old galvanized sheets, after from 30 to 35 years' exposure, from 2.3 to 4.1 oz. of zinc per sq. ft. of sheet and sums up the study by saying: Of the various factors influencing the durability of galvanized iron which have been studied with a view towards accounting for the difference in behavior of old and modern sheet, it appears evident that the greater weight of zinc per unit of area on the former accounts for the greater durability.

Jan 10, 1922

By Graham Bright

Before the arrival of central-station power, all coal and metal mines generated their own power and, in many cases, these isolated power plants gave a fair continuity of service. In coal mines that produce considerable gas, it is essential that power be available at all times for operating the ventilating fan and the hoist, if the mine is of the shaft type. In the case of an isolated power plant, if trouble should develop with the fan the men can be hoisted quickly when the mine is of the shaft type. On the other hand, if trouble develops with the hoist, the fan can be kept in operation, and there will be no necessity of haste in getting the men from the mine. Now that central-station power is being used so extensively for mine service, the continuity of service with gaseous mines is very important. : Inherently, the central station is much more reliable than any isolated plant, but trouble may occur on the transmission lines which may prevent the transmission of power for a considerable time. : Some mines have kept their steam equipment intact and ready for operation in case the purchased power should fail. This is expensive procedure, for the boiler plant must be fired at all times so that the emergency power will be quickly available. In a number of instances, gasoline-engine driven generators have been installed to furnish emergency power for the service hoist. As most service hoists are of the alternating-current type, the generator of the gasoline-engine driven set is usually of the a.c. type and is arranged to drive the service hoist motor at full speed, or an extra motor that can be thrown into gear on either the main or service hoist and the hoist operated at a greatly reduced speed. This arrangement is used because it is difficult and expensive to obtain and install large gasoline-engine driven units. The author has recently developed a plan by which the main hoist and the fan can both be operated at reduced speeds, in case of loss of power from a central-station power system. In this plan a gasoline-engine

Jan 1, 1923

By E. H. Tenney

A discussion of the probable future use of coal for power development involves the study of several basic factors, such as future demand for power, the quantity and availability of fuels in direct competition with coal, the price of coal, and a closely related factor—the efficiency and cost of fuel utilization. Predictions based on purely statistical analyses of past coal consumption have definite limitations. For example, statistics showing the relation between coal utilization and total energy consumption from all sources between the years 1890 to 1930 indicate that during that period the energy consumption per person in the United States increased five times, while the coal consumption per person increased only twice1, and there has been an actual decrease in per capita coal consumption since 1920. Figures such as these, compiled by authentic agencies, emphasize the need for caution in attempting estimates as to the future use of coal, and, incidentally, would seem to offer little basis for optimism in the coal industry. They also suggest the value of analyzing broadly the part played in the past by the related factors of power consumption, competitive fuels, coal prices and the efficiency of utilization. Proper weight must also be given in such a study to the present status and limitations of power-plant developments, arid to the question of what the coal industry itself can do to further its own interests arid influence the consumption of its product.

Jan 1, 1936

By H. E. Rorschach

Activity in Oklahoma fields declined in 1938 from the banner year of 1937. During the year, 1768 wells were completed as compared to 2632 completed during the year 1937. The following tabulation sets out details regarding the wells completed during the year: These computations do not take into account the wells drilled for repres-sure and salt-water disposal, and other nonexploratory wells. Purchasers' reports filed with the Corporation Commission of the State of Oklahoma show a total of 168,789,229 bbl. of oil purchased from Oklahoma leases in 1938, or a daily average of 462,436, a decrease of about 25 per cent from the year 1937. The outstanding operation of the year was the further development of the Ramsey pool, in western Payne County, the producing horizon being classified as the Wilcox. This pool was discovered on the last day in the year 1937, by the Mid-Continent Petroleum Corporation drilling on a unitized block in see. 18, T. 18 N., R. 2 E. The map in Fig. 1 shows the development at the end of the year 1938. An important discovery of the year was the Champlin Refining Company's No. 1 Boehm, in Garfield County, sec. 4-24N-8W., the producing horizon being the second Wilcox found at a depth of approximately 6700 ft. This pool was assigned the name of Hillsdale. Some of the offsets to this discovery well had not come up to expectations at the end of the year, but the discovery seems to be important as indicating that the Wilcox sand is productive in the Anadarko Basin area, providing that the right structural conditions are present.

Jan 1, 1939

By J. J. Thomas, J. H. Nead

This investigation was undertaken to determine, if possible, the relation between static and dynamic tensile tests as measured by the work required to break test specimens slowly, in a tensile testing machine, and rapidly, by means of a falling weight. It was hoped that the investigation would throw some light on the role played by ductility under different rates of application of load. In problems of design, it is usually assumed that the moduli of elasticity of all steels are equal; viz., about 30,000,000. The stress-strain diagram within the elastic limit is a straight line, as shown in Fig. 1, where OA is the curve of a hard steel and OB that of a soft steel. If the modulus of elasticity is constant, as assumed, the slope of the line OC

Jan 1, 1922

By Guy W. Jordan, David P. Hale

High-iRon cements have a number of advantages over cements carrying little or no iron. The presence of iron in Portland cement aids in the manufacture of the cement and also imparts certain advantageous physical properties to the finished product. In manufacture, the presence of iron lowers the fuel consumption, increases the ease of proper"burning, and lessens the destructive action of the charge on the kiln refractories. In the finished cement the presence of iron reduces the expansion and contraction, adds strength, adds increased resistance to"freezing and thawing, and increases the resistance of the cement to sea "or sulphate waters. [" During the past few years the construction of numerous dams through- "out the Southeast by the Tennessee Valley Authority has stimulated the "production of high-iron cements. At present a great number of specifica- "tions call for an iron cement, and the industry is supplying this demand "with a Portland cement carrying approximately 5 per cent iron oxide. "Several manufacturers are now making practically all of their cement "of this type and a number of others manufacture it as a special cement "over short periods to meet demands from the Tennessee Valley Authority "and other buyers. " The recent increase in the use of iron in Portland cement has created "a market for iron products that previously was nonexistent. The chief "sources of supply for the cement manufacturers at present are iron sand, "iron sinter and slag, and ocher. The Copperhill mining district, Ten- "nessee, supplies both iron sinter and slag for use in cement. The Carters- "ville district supplies iron sand, ocher, and some iron resulting from the "magnetic separation of iron from barite. The advantages of these "products vary according to the chemical properties of the raw materials "and the methods of handling used by the different manufacturers. Where "the iron is to be handled by conveying belts and in hopper cars, the iron"sand and sinter and slag are preferable. Where the silica content must "be raised, the iron sand is doubly advantageous because it supplies both

Jan 1, 1942

Alluvial gold exploration is aimed at recognizing areas of anomalous gold content as evidenced by the nature of the drainage system, its age, geomorphic history and other features of the geological environment including the provenances. Subsequent studies to quantify the findings are governed by the need for accurate data based upon precise measurements. Computerization allows the use of more complicated mathematical procedures than are feasible manually, thus promoting the development of more advanced technological aids. Data banks provide the means of storing vast quantities of information for instant recall.Sample representivity is a major problem and a clear understanding of both sampling and analytical requirements is essential for dealing with problems arising from variations in sample size and particle size distribution. Field samples must always be large enough to ensure adequate representivity or the sampling has failed in its purpose.

Jan 1, 1984