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By Georgios N. Anastassakis, Nickolaos Georgiou

"Soil contamination by oil as well as by other organic pollutants poses a major problem to the environment. Various methods have been used to remove organic contaminants from soil, such as: biological, thermal, chemical and physical. Methods based on Mineral Processing principles have also been used (cyclone separation, gravimetric separation, attritioning and washing). This paper studies the possibility to remove a rich-in-contaminant soil fraction by applying flotation. The contaminated soil was artificially prepared by mixing soil with diesel fuel. Sodium dodecylsulfate (SDS) and a tertiary amine (TA) were used as collectors. The effect of collector quantity added and conditioning time was studied. The results showed that the removal of a rich-in-contaminant soil is feasible while a clean fraction is also obtained. In several cases, the removal of oil-contaminated soil approaches or reaches 100%. Introduction Human activities are intimately associated with environmental pollution to the air, water and soil, as well. Soil pollution from inorganic and organic compounds is of equal importance with that of air and water, as it results in soil degradation and its concomitant problems with respect to meeting the human needs (house building, agriculture etc). Heavy metals along with their compounds are encountered among the most usual soil inorganic pollutants. The corresponding organic soil-pollutants are oil, oil-derivatives, pesticides, various aromatic (benzene, phenols, cresols, toluene etc) and poly-aromatic (naphthalene, anthracene etc) hydrocarbons, as well as various other organic compounds (pyridine, cyclo-hexane etc). Oil remains the basic energy source sharing 38% of the global needs, being followed by coal and gas with a share of 26 and 21% correspondingly [1]. The entire activities related with oil production, transport and consumption promote pollution in the air, water and soil. Consequently, soil pollution from oil is favoured at refineries, storage sites (due to possible pipe and tank leakage, tank cleaning works, loading and transportation) and, finally, at the oil-selling sites. Oil (or diesel-oil) fuel is a mixture of hydrocarbons, with 10-20 carbon atoms in the chain of each. It is mainly composed of paraffins, naphthenes and various aromatic compounds. In general, oil is composed of 20-30% in aromatic compounds, 5-6% in naphthenes and the rest is paraffins [1]."

Jan 1, 2008

By Marta Cabral, C. A. Nogueira, F. Margarido

"Physical processing of spent batteries which includes shredding and sieving operation is the first step for chemical treatment by hydrometallurgy. A laboratory study was carried out to evaluate physical processing efficiency, by analysing the resulting particle size, of alkaline and saline mignon-type Zn-MnO2 batteries. After shredding with a tip shredder, results obtained showed that alkaline batteries were more efficiently size reduced than saline batteries. Difference in particle size distribution was larger for granulometric fraction -20+11.2 mm and also higher for saline batteries. Average diameters (d50) for saline and alkaline batteries were respectively 9.1 and 6.2 mm. Chemical composition carried out on several granulometric fractions allowed to identify metals distribution through size categories. This analysis showed that zinc concentration with the grain size was almost constant, while manganese decreased when particle size increased. More than 95% of iron scarp from the battery cases had a particle size higher than 5.6 mm.IntroductionRecycling process of spent batteries includes physical unit operations which involves a fragmentation step in order to open the battery cases and to allow the access of chemical reactants to the electrode materials, on further chemical unit operations. Shredders are usually used for that purpose, using cutting mechanisms and allowing efficient fracture of residues in order to promote further processing of the contained materials. Batteries are complex products with a large variety of sizes and shapes which causes serious difficulties for predicting and carrying out its fragmentation.Domestic-type batteries are essentially of the Zn-Mn systems and with cylindrical shape, varying from the large size Mono (or D) type to the small size Micro (or AAA) type [1]. Recycling of batteries involves collection, sorting [2] and metallurgical processing [3, 4]. In some processes, the first step of metallurgical processing is dismantling and size reduction by shredding. Research work on spent batteries considering grinding/shredding and physical separation of fractions is scarce [5-7], but investigation in this domain is very necessary."

Jan 1, 2008

By Wantae Kim, Jaechun Lee, Tatsuya Oki, Sungbaek Cho, Sangbae Kim

"Effect of attrition scrubbing on the recovery of platinum group metals(PGMs) from automotive catalytic converter was discussed. The attrition scrubbing as comminution and separation process was effective for the recovery of the catalyst layer, ?-alumina, from ceramic supporting matrix, cordierite, by physical impact and shearing action between particles in the scrubbing vessel. The catalyst layer was dislodged from the surface of the supporting matrix into fine particles less than 45µm by attrition scrubbing. The production of fine fraction less than 45µm increased as the residence time for attrition scrubbing increased. The fine fraction obtained at the residence time of 40min contained 19.25% CeO2, 1.93% ZrO2 and 418.8ppp PGMs. The recovery of ?-alumina in the fine fraction increased as the residence time increased. Simultaneously, the recoveries of CeO2, ZrO2 and PGMs increased and reached up to 82.9% CeO2, 78.7% ZrO2 and 78.9% PGMs at the attrition scrubbing time of 40min. The production of the fine fraction and recovery of ?- alumina increased when the solid concentration and initial feed size increased.IntroductionThe automobile catalytic converters contain appreciable amount of PGMs. Currently several million tons of used catalytic converters are disposed annually worldwide, each containing about 0.5-1g of platinum and 1-2g of all PGMs1). The recovery technologies of PGMs from spent catalytic converters have been thoroughly reviewed by numerous researchers since last decades. Two types of methods, wet and dry processes, have been commercially operated. In the wet process, the PGMs on the spent catalytic converters were dissolved mostly in the form of chlorocomplex, MCl6 2-, by contacting with aqueous solutions. Subsequently the resulting solutions are treated to concentrate and the precious metal ions are reduced by introducing metals such as Al, Fe and Zn in the concentrated system2). In the dry process, the spent catalytic converters are melted, in some case with CaO, at an elevated temperature to produce a low viscous slag. The PGMs in the melt are separated by allowing them to adsorb on Fe or Cu having high specific gravity7). Although highly pure precious metals could be obtainable, the recovery technologies of PGMs currently operated seem not to be cost-effective since PGMs embedded in these types of catalytic converters are present in very small quantities."

Jan 1, 2008

By Isabella Lancellotti, Fabrizio Passarini, Luisa Barbieri, Fernanda Andreola, Ivano Vassura, Luciano Morselli

"The techniques able to incorporate wastes by means of a heat treatment present the advantage to fix the residue with chemical bonds. Among these techniques there are vitrification and sintering which are characterised by different operating temperatures in the range of 950-1500°C and the involved raw materials develop silicatic crystalline phases and glassy matrices capable to immobilize heavy metal contents in the waste matrix. In this work incinerator bottom ash, polishing and glazing ceramic sludges have undergone to thermal treatments in order to valorise the waste as secondary raw material for the obtainment of re-products. The chemical efficiency of the process adopted has been evaluated by comparing the results of release tests applied to the as-received wastes and to the thermally treated materials in order to verify the effectiveness of the different matrices to fix the waste components.IntroductionVitrification is one of the most promising technological options for the treatment of some kinds of waste. The high temperature involved in the process (1200-1500°C) leads to the complete destruction of organic pollutants, such as dioxins, and glassy network formed can incorporate heavy metals. Some vitrification processes naturally occur: glasses produced by volcanic eruptions, such as obsidians (Na2O-K2O-Al2O3-SiO2) and basaltic (CaO-MgO-Al2O3-SiO2) rocks, are basically inert materials even when they contain toxic elements, because these are embedded in an extremely stable glassy matrix. The disadvantage of vitrification is that it is an energy-intensive process involving relatively high costs, therefore its use is better justified if a high-quality product with optimised properties can be fabricated. The most effective way to improve the properties of the vitrified material is the transformation into glass ceramic. This is a fine-grained polycrystalline material (typically from 50% to 98% of the volume may be crystalline) formed when a glass of suitable composition is heat treated and hence undergone to controlled crystallisation (phenomenon named devitrification). The three key variables in the design of a glass-ceramic are: glass composition which controls glass viscosity related to the effectiveness of nucleation and rapidity of crystallisation; glass-ceramic phase assemblage (that is, the types of crystals and the proportion of crystals to glass) which is responsible for many of the physical and chemical properties; nature of the crystalline microstructure (crystal size and morphology and the textural relationship among the crystals and glass) which is the key to many mechanical and optical properties. In particular, a partly crystalline material can be obtained by powder sintering."

Jan 1, 2008

By Susan Fredholm, Randolph Kirchain, Jeremy Gregory

"Jurisdictions across the world have struggled to create and finance systems that can effectively collect and process electronics waste (e-waste). Many different system architectures have been proposed and implemented, but it is difficult for policy-makers and system architects to compare the costs and benefits of different systems, particularly when the systems operate in different contexts. This paper presents a systematic methodology that seeks to address this challenge and uses data from several existing electronics recycling systems across the world to illustrate its implementation. The methodology characterizes three main system characteristics: architecture (e.g., financing and collection methods), context (e.g., jurisdiction population, density, and wages), and performance, both economic and materials collection. A comparison of systems in Europe and North America with different system architectures and contexts illuminates the importance of using the methodology to discern the extent to which architecture and context drive system performance.IntroductionElectronic waste (e-waste) recycling offers several environmental benefits when processing is done responsibly. The controversy around e-waste recycling systems rarely debates such benefits; rather, it focuses on the characteristics of an effective system and whether benefits outweigh costs. Historically, the costs of recycling most electronics have outweighed the value of the scrap recovered. Thus, in the absence of legislation, e-waste recycling systems have been limited to private recycling of high-value waste with minimal consumer participation. E-waste recycling systems now exist in many locations worldwide including Asia, the European Union, Canada and the United States and the amount of related legislation continues to increase. Numerous approaches have been proposed including landfill bans, extended producer responsibility (EPR) and consumer advance recovery fee (ARF) funded recycling systems."

Jan 1, 2008

By S R. Pecover

AustraliaÆs opal and sapphire mining industry has fallen from its peak in the 1980s and 1990s into a significant low today. This is not due to exhaustion of the resource, but instead an over-reliance of the Australian miner on achieving a fair price for the gemstone product from offshore middlemen dealers. Gemstone and geological research is also at a low as Federal higher education expenditure has fallen with research institutions relying increasingly on private funding in an environment of restricted autonomy and flexibility for researchers. What little remaining research skills the universities have is being bled into the private sector as a result of the mining boom and encouraged by lower than average academic salaries. Nevertheless, some highly innovative research has been taking place, often by self-funded individuals and retired academics simply with a desire to advance the understanding of the particular branch of science in which they are interested. New models for the formation of sapphire and opal are now beginning to be applied to the exploration for these gemstone commodities. This research, together with well thought out plans for managing the gemstone product through its value-adding steps to the jewellery retail level, has the potential to bring about a resurgence in the Australian gemstone industry.

Jan 1, 2008

By N. M. S. Balbinot, A. L. Rodríguez, C. M. Mahlmann, R. de C. de S. Schneider

The use of sunflower oil co-products it was studied for production thermoplastic composites. Thermoplastic composites have been processed in polyethylene matrices of virgin linear low density polyethylene (LLDP) or recycled. Samples have been formulated with 10% mass fraction of sunflower bran, seed coat and mixture of bran and seed coat. The material characterization has been achieved by mechanical tensile test and Shore D hardness and by density physical testing. The results have demonstrated better properties to thermoplastic composites with sunflower seed coat.

Jan 1, 2008

By Javier Antoñanzas, Susana Caballero, Eduardo Fernández, Jorge Aragón, Juan Carlos Múgica, Lourdes Yurramendi

Air Pollution Control (APC) residues treatment by plasma was studied as a technology for vitrification. During the project a protocol to verify the plasma technology was developed and afterwards applied to a specific case study: the APC residues from Municipal Solid Waste Incinerators (MSWI). Different operational conditions were tested and the vitrified products obtained were analyzed using standardized leaching tests in order to evaluate their new properties concerning safety storage. Two leaching tests were used for the evaluation, the European EN 12457-4 compliance test for leaching of granular waste materials and the French XP X 31-211 test for the determination of the leachability of a solid waste material initially massive or generated by a solidification process. Finally, conclusions about the environmental performances of the technology were obtained.

Jan 1, 2008

By Ludwig Hermann

"Phosphorus is required by every cell of living organisms and essential for plant growth. It is a non-renewable resource that must be mined from natural deposits, going gradually into depletion. Abundant secondary resources are available in sewage sludge and meat and bone meal, with the highest exploitable P concentrations in ashes that remain from their widely used combustion with energy recovery. ASH DEC has successfully removed heavy metals and transformed sewage sludge ash into a marketable P fertilizer by application of a thermo-chemical treatment process. Pilot scale investigations in which ash was treated proved that generally heavy metal limits required by fertilizer legislation can be attained. To achieve a high P availability for crops – an essential fertilizer quality feature – was a more challenging R&D task. Our presentation demonstrates the scientific approach and R&D results that lead from assessment of market requirements to licensed products.IntroductionPhosphorus (P) is required by every cell of living organisms. It is one of the major elements for plant nutrition and therefore essential for crop production. P supply in plant nutrition depends entirely on external inputs into soils [1]. This is achieved by P-fertilizers deriving from rock phosphate deposits that are gradually going into depletion. Serious prognoses anticipate that rock phosphate will be the first low running resource in the world [2]. In the EU, last year 2.530 kt of phosphorus (P2O5 in fertilizers) was consumed and only 313 kt (P2O5 in rock phosphate) was mined. Since 2007, rock phosphate prices have increased by 500% because of a tight supply situation [3].For these reasons, P recycling is becoming an increasingly important issue. Suitable secondary raw materials with regard to their high P-content and abundance are sewage sludge and meat and bone meal. In the EU 989 kt P2O5 are accumulated annually in theses materials, of which 632 kt P2O5 are permanently lost to landfills and other forms of disposal. The main reasons for their limited recycling are concerns on heavy metal contents and organic pollutants that may incite health hazards. As an additional shortcoming, the availability of P from these materials to plants is poor and storage and transportation are problematic issues [4, 5]."

Jan 1, 2008

Objective: Improve the dust control effectiveness of enclosed operator cabs on surface mining equipment.

Oct 1, 2007

By Verónica Zeballos

"Las empresas mineras deben mantener una economía dinámica y eficiente que genere costos competitivos basados en la calidad de sus productos. En ese sentido, el planteamiento de un Proyecto de Modernización de la Fundición Southern existente contribuye a alcanzar el éxito que puede ser medido a través del impacto de éste sobre las condiciones ambientales generadas. Por ello, el presente texto revisa la aplicación de tecnologías ambientalmente aceptables tomadasen cuenta en la Modernización de la Fundición de Ilo, mostrando un enfoque orientado a la gestión, a su ejecución y a la creación de valor."

Sep 9, 2007

By Orlando Bernal

El presente texto aborda el aspecto termodinámico del sistema de lixiviación -en tanto predice los fenómenos que ocurren en el interior de la pila para luego continuar con el análisis del mecanismo cinético. La metodología aplicada en cuanto a los mecanismos de lixiviación, difiere de otros trabajos porque aquí se considera los tres mecanismos por separado (óxidos, sulfuros secundarios y primarios) basados en el análisis secuencial del cobre. Asímismo la cinética per se obedece las leyes de la termodinámica ergo, cuyo aspecto no puede ser ignorado en un análisis global. En este sentido, se presenta el modelo de desarrollo matemático como una herramienta óptima que controla y predice este proceso del lixiviación por medio de la simulación utilizando la ecuación de continuidad, la cual supone flujo tipo pistón de la fase líquida en el interior de la pila.

Sep 9, 2007

By Lytman Jordán

En la actualidad, el proceso de Ore Control de Tintaya se convierte en un reto porque la naturaleza del yacimiento Metasomático de Contacto Tipo Skarn presenta una mineralización compleja a manera de pasas en una torta. En ese sentido, la cultura Sigma -que presenta poderosas herramientas estadísticas y de gestión de procesos-, logró conceptualizar el proceso de ore control e identificar y optimizar tres sub-procesos críticos: el muestreo de Blasthole, preparación y análisis de Muestras de Blasthole y el Ore Control Operativo. Por ello, el presente texto señala la optimización del oro control de Tintaya a través de la metodología Six Sigma, donde se logra mejorar el proceso desde el muestreo de blasthole hasta el envío de mineral a las plantas, se minimiza los eventos de fuga de mineral a los botaderos y con la data confiable de los blasthole, se elaboran modelos de corto plazo que permiten generar planes predecibles de minado.

Sep 9, 2007

By Víctor Siña

El presente trabajo describe una alternativa de sistematización de las observaciones preventivas generadas en las áreas operativas de la minera Antamina a través del programa de Prevención de Riesgos para así reentrenar, reforzar y evitar perdidas por accidentes en cualquier tipo de industria. En ese sentido, cada miembro ya sea propio o socio estratégico de Antamina, es conciente de la prevención mediante la observación. Dicho enfoque evidencia no solo lo malo, sino también todas las consecuencias que esto conlleva. Por ello, la base de dicho programa es la detección anticipada de los actos y condiciones que nos puedan generar pérdidas.

Sep 9, 2007

By Aquiles Vivar

Ante los problemas de sismicidad inducidos por el sistema de minado en la Compañía minera Milpo, se planteó una solución a través del sistema de monitoreo sísmico único, donde se da una distribución espacial de 20 censores entre uniaxiales y triaxiales distribuidos en 3 niveles de producción en el área de influencia de las actuales operaciones para así ubicar, cualificar y cuantificar el fenómeno a efectos de realizar los análisis interpretativos del caso. En ese sentido, el presente texto describe el sistema de monitoreo, cuyo software sísmico está diseñado para determinar nuevas estructuras formadas a partir de los eventos sísmicos pre existentes reactivadas por la sismicidad inducida, así como el desarrollo de planos de isocontornos que permiten la diferenciación entre zonas de altos y bajos esfuerzos.

Sep 9, 2007

By Roberto Chambi

"El presente trabajo señala la expansión de la producción de la mina Condestable a través de las innovaciones tecnológicas en clasificación de molienda como: la utilización de estas zarandas derrick de cinco pisos cada uno, donde se aumenta la capacidad de cada molino instalado en planta en un 17% en promedio, así como el grado concentrado supera el promedio de 26.35%."

Sep 9, 2007

By Edgardo Orderique

El presente texto describe el modelo de desarrollo del proyecto minero Antapaccay, de forma que cada etapa en el proceso de determinación de reservas, sea rigurosamente evaluada y estimada. La secuencia comprende el programa de taladros exploratorios, explicación geológica y mineralógica del yacimiento, interpretación y modelamiento geológico, modelamiento de leyes, definición de parámetros de optimización del pit, generación del pit final, planeamiento estratégico de fases de minado y secuencia anual del mismo, siguiendo el objetivo de maximización del NPV. Asímismo, se explican los aspectos de medio ambiente y relaciones comunitarias.

Sep 9, 2007

By César Arce

El presente texto establece una plataforma de comunicación oficial entre la empresa y sus socios estratégicos logrando la estandarización del comportamiento empresarial y humano en temas relacionados con medio ambiente, salud, seguridad, relaciones con las comunidades, recursos humanos y la legislación vigente. En este sentido, las empresas que trabajan en forma directa o indirecta para el titular, impactarán directamente en los resultados y reputación del mismo, sino mantienen una visión, objetivos y comportamientos similares

Sep 9, 2007

By Emmanuel Portilllos

Every paste backfill system is typically unique, this being due to the particular tailings characteristics, the backfill recipe and requirements of mine planning. Key to successful transport to the underground workings through the boreholes and the distribution pipelines is the quality of cemented paste, being free of lumps and recipe components uniformly mixed. Certain types of mixer require that the mixing environment is required to be intensive as possible. In this sense, the present paper point out some of the general aspects of paste plant design, a short discussion on paste recipe and process equipment, followed by a technical comparison between a batch mixing and a continuous mixing process, currently applied to the production of cemented paste tailings for mine backfill.

Sep 9, 2007

By José De Piérola

En los procesos de flotación y lixiviación de la producción de cobre se utilizan aguas recicladas y agua fresca. Este último es un insumo indispensable para ambos procesos, ya que constituye un elemento determinante del volumen de producción, así como un medio de vinculación obligado con el entorno social de las operaciones. En ese sentido, el presente texto describe la utilización del agua- en tanto representa un componente de rentabilidad relacionada al costo, al equilibrio del aprovechamiento con el comportamiento de la fuente y a la sostenibilidad con el entorno social, lo cual implica compartir el agua y recursos económicos para una planificación y adecuada priorización en su asignación.

Sep 9, 2007