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By K. Liddell

Current practice for the recovery of platinum group metals (PGM) from flotation concentrates is by energy-intensive smelting processes followed by separation and refining of the base and precious metals. Energy costs are rapidly increasing in South Africa and this trend is forecast to continue in future years. Moreover, the smelting operations are highly susceptible to deleterious constituents, particularly chromite; and the increasing tonnages of UG2 chromititic ore being mined results in an increasing chromite content of smelter feeds. Hence there is a substantial incentive to assess and implement alternative processes to smelting for the treatment of PGM concentrates. The Kell process is a patented hydrometallurgical alternative to smelting that is totally insensitive to the chromite content of the feed concentrate and comprises three commercially proven unit operations (pressure oxidation leaching of base metals and sulfur, roasting and chlorination of precious metals). The Kell process provides the opportunity for existing and new PGM producers to significantly reduce their energy consumption, and in particular their consumption of electricity, by removing the need to smelt PGM concentrates. Energy costs, greenhouse gas emissions and installed power requirements are also much reduced. Compared with smelting and refining these reductions are calculated as: ? Total energy consumption-50% reduction ? Electrical energy consumption-84% reduction ? Energy consumption costs-76% reduction ? C02 emissions-70% reduction ? Installed power requirement 92% reduction. The data obtained from simple laboratory batch amenability testing can be readily applied to the Simulus mass and energy balance simulation procedure to determine energy and reagent consumptions, equipment selection and process optimization. The applicability of Kell to treating low-grade 'dirty' concentrates with high UG2 content as well as to polymetallic concentrates containing base metals as the major payable metals with subordinate PGM means that these savings can also be expected when the process is used for treating a range of concentrate types and grades. Keywords PGM,UG2, Merensky, smelting, chromite, electricity, hydrometallurgy, Kell Process, Eskom.

Jan 1, 2011

By Allen Chung, John Twomey, Christopher J. Greet

"It is widely accepted that the type of grinding media has an impact on the grinding chemistry and subsequent flotation behaviour of the sulphide minerals being separated. There are countless laboratory investigations demonstrating that inert grinding media produces more oxidising pulp potentials, reduced levels of grinding media corrosion products and superior concentrate grades and valuable metal recoveries. However, taking these results to industrial scale has proven difficult.Work conducted at the Ernest Henry Mine, in north western Queensland, Australia, at laboratory and pilot plant scale clearly indicated that using a high chrome grinding media resulted in significant improvements in both copper and gold recoveries. However, advancing this work to plant trial represented considerable financial and technical risk to the mine.This paper provides details of the protocol developed and used during the high chrome grinding media plant trial. It describes the test regime employed to measure changes in pulp chemistry, and the statistical methodology utilised to interpret the results. The work also highlighted the need for close cooperation between the metallurgists on site and the researchers conducting the trial.To date, the trial has produced excellent results: indicating that the copper recovery has improved by about 2 percent. The successful application of high chrome grinding media to the Ernest Henry ore has increased metal value by $18.7 million USD per annum based on current spot price for copper.INTRODUCTIONTheoryThe application of electrochemically inert grinding media to mineral systems has been extensively studied (Table 1). Broadly, these studies indicate that most sulphide minerals are more noble than the grinding media used during comminution. Therefore, the sulphide minerals are cathodic with respect to the forged steel grinding media, and the following reactions apply:"

Jan 1, 2011

By Ambrose Buchanan, Rob Farnfield, Charles Adcock

Beginning on 7th September 1940 the City of London was subjected to 57 consecutive days of bombing in what became known as the ‘London Blitz’. To commemorate the 70th anniversary of this event a television series was commissioned that required the open detonation of World War 2 equivalent bombs close to purpose built structures constructed using period design and materials. The structures were built on a remote test facility in the North of England that is able to fire large quantities of explosive in the air.

Jan 1, 2011

By K. Oraee

Mining of copper ore and the related industries play an important role in Iran?s economy. Copper ore production in Iran accounts for 75% of the total production in the Middle East. All activities related to copper, that is, exploration, production, refinement etc are owned and managed by state owned companies. Decisions have been made to privatize all these activities. To assess the success of this privatization process, different components of the industry must be subject to economic analysis. In this paper, the cost estimation of all operations has been carried out. The total potential and attainable revenues have also been estimated using historical data available from the industry. Risk is a major factor in all mining activities and the copper industry of Iran has been subject to risk factors arising from many internal and external variables. These variables have been recognized and their effects evaluated. The effect of risk on the economic feasibility of the operations in the industry has also been analyzed.

Jan 1, 2011

By Julie Culverhouse, Dennis Grimm, Kieran Harding, Jean-Francois Boulanger

"Agrium’s Canadian Phosphate Business (CPB) is comprised of Kapuskasing Phosphate Operations (KPO) in Northern Ontario, Canada’s only operating phosphate mine, and Redwater Phosphate Operations (RPO) in Alberta, which manufactures the fertilizer from KPO’s concentrate.Production from KPO’s South Pit commenced in 2009 and introduced contaminant problems: high aluminium from crandallite and kaolinite clays. These issues caused a drastic decrease in P2O5 recovery and throughput in both plants. KPO attempted to reduce Al clays by means of aggressive desliming. Meanwhile RPO experienced high amounts of dissolved metals in their feed that are detrimental to fertilizer production.This paper covers the mineralogy of the problem, its impact on contaminant separation at KPO, on RPO’s process and on Agrium’s Canadian Phosphate Business as a whole.Potential solutions to the problem are discussed and analysed, including a process change to deslime high aluminium streams more aggressively and high grade ore flotation, which is atypical at KPO. The latter is a demonstration of the value of communication between the concentrator and the client, as KPO accepted a recovery loss and increased production costs in order to increase overall CPB profits. General lessons learned are discussed, followed by a section on ore blending.INTRODUCTIONAlthough the existence of the Kapuskasing phosphate deposit has been known since the 1970s, it’s only since 1999 that Agrium has been operating the Kapuskasing Phosphate Operations (KPO). The mine consists of three major pits (Center, North and South) from which a mining contractor hauls the apatite ore to the Agrium concentrator. The beneficiation plant processes the ore, separating contaminants such as Fe, Mg and Al which are detrimental to its client, Agrium’s Redwater Phosphate Operations (RPO). The KPO concentrate is finally thickened, filtered and dried before being shipped by rail to RPO.At the Redwater plant, the KPO concentrate is added to a sulfuric acid solution in an attack tank, to create a phosphoric acid solution and gypsum:"

Jan 1, 2011

By G. B. Harris, C. W. White

Cyanide has been used for the recovery of gold since the mid 1800s, but several jurisdictions have already banned its use, and environmental pressures are increasing to finding an alternative. Gold also forms chloride complexes similar to those of cyanide, but the use of chloride has never achieved widespread acceptance. This paper describes a chloride-based flowsheet, wherein the key unit process is the recovery and recycle of chloride ion. It is shown that the chloride-based flowsheet is competitive economically with the conventional cyanide-based flowsheets, and that it has a number of other advantages, particularly environmentally.

Jan 1, 2011

By Fei Ruan, Chang Jie, Jieyu Zhang, Jifang Xu, Kuochih Chou

"Viscosity is an important physical parameter of slag in metallurgical processes. Most studies of aluminosilicate and aluminate systems assume that aluminum occurs in tetrahedral coordination. In this case, the O/Al value was utilized to describe the slag structure in terms of the network character of aluminosilicate and aluminate systems. Composition and viscosity data from the literature and the trends were analyzed according to the O/Al value and temperature. It is shown that the O/Al value explains the trends in more than ten systems, containing more than 200 data points. In aluminosilicate system, the trend that viscosity value changed with the O/Al value which implies that alumina works as network modifier such as basic oxides or works as network former. In aluminate system, irrespective of the system and temperature, viscosity decreased steadily when O/Al value increased.IntroductionMetallurgical slags, which are made of oxides and many also contain fluorides, play an important role in metallurgical processes such as iron making, steel making and secondary refining processes. Aluminosilicate slags are applied in a wide range in metallurgical processes. A polymerizing effect of the addition of aluminum and an association of aluminum with low-field strength cations is further supported by the physical variations in aluminosilicate and aluminate systems. The behavior of alumina in silicate melts has been studied by various authors [1-6]. It is generally accepted that Al2O3 is amphoteric [7] because Al3+ ions can behave in profoundly different ways in a silicate melt. When added to a pure silica melt, Al2O3 acted as a network modifier, breaking the bridging oxygen of the pure silica network, thereby decreasing the viscosity in a similar manner to other network modifiers, such as CaO, MgO etc. to form [1/2Ca (AlO4)]4- complexes. However, when added with alkali or alkali-earth metal oxides, some of the Al3+ ions assumed tetrahedral coordination and replaced Si in the liquid network, the missing charge was compensated by Me+ or Me2+ ions. Therefore Al2O3 acted as network former [8, 9]."

Jan 1, 2011

By Keith Heasley

This paper is a retrospective on the development, application, and enhancement of the LaModel program from a personal perspective. The narrative starts with an explanation of the objectives behind the original development of the program and then introduces some of the unique and very practical features of the program. Next, a demonstration of how LaModel was advantageously used to model stresses and displacements in a multiple-seam mining situation with highly variable topography is presented. This is followed by the details of a number of the major enhancements and expansions of the program over the years. A back-analysis of the Crandall Canyon Mine collapse is then briefly presented, along with the associated development of a recommended calibration procedure for the critical input parameters to LaModel. Finally, some of the present research areas are briefly described, and future enhancements are introduced.

Jan 1, 2011

By Staff

Minerals contribute to U.S. gross domestic product (GDP) at several levels - from mining and processing to the manufacturing of finished products. In 2010, the estimated real GDP of the United States increased by 2.8 percent compared with 2009 and the estimated nominal GDP was about $14.6 trillion (Table 1).Trends in various sectors of the domestic economy are often rejected in mineral production and consumption rates. For instance, continued declines in the construction industry during 2010 were rejected in further reductions in the production and consumption of cement, construction sand and gravel, crushed stone and gypsum, which are used almost exclusively in construction. Performances in other sectors were mixed and less easily characterized. Recovery from the economic decline of 2008-2009 became apparent in 2010, as prices for many mineral commodities continued to rise with increasing demand for those materials or the products in which they are found.

Jan 1, 2011

By Norman O. Lotter

The problem of quantifying the full performance potential of an ore body in a concentrator, and how to configure a flowsheet to achieve that potential, either for a new operation or an existing one, is a strategic challenge. Modern flowsheeting technology that has been developed over the last twenty years has provided a suitable platform to achieve this. The integrated use of geology, compositional and quantitative mineralogy, sampling models, quality controls, and mineral processing, including flotation testing, has evolved into what is now called process mineralogy. Two specific tools have been developed and validated as standard methods in this toollbox. These are statistical benchmark surveying and high-confidence flotation testing. Both of these have borrowed from the sampling theories of Pierre Gy and from geostatistics. Additionally, they work on a replicate measurement and averaging basis, thus reducing the overall random error level. With this arrangement, one is in a position to characterize the ore from true samples and identify and quantify the economic minerals present in a manner that easily brings out the processing implications and likely grades and recoveries. In particular, the approach captures the variation in the ore body, which, if properly translated into the flowsheet design, minimizes the risk that unexpected responses will develop in the concentrator operations. A further advantage is that successful plant trials are now possible and practical. An overview of this approach is presented with two case studies.

Jan 1, 2011

By Q. Wu

Neural network methodology is used to predict mean particle size resulting from rock blast fragmentation. A blast data base developed in a previous study is used in the current study. A part of this blast data was used to train a single-hidden layer back propagation neural network model for each of the similarity groups obtained in the same previous study. Levenberg-Marquardt algorithm provided the most stable and efficient training out of the four algorithms evaluated. An extensive analysis was performed using a part of the blast data to estimate the optimum number of units for the hidden layer for each similarity group. The remaining blast data are used to validate the trained neural network models. Capability of the developed neural network models is determined by comparing predictions with measured values and predictions based on one of the most applied fragmentation prediction models appearing in the blasting literature. Prediction capability of the neural network models was found to be strong and better than the existing most applied model. Diversity of the blasts data used is one of the most important aspects of the developed models. The developed neural network models are suitable for practical use at mines.

Jan 1, 2011

By N. McEwan

Keywords: refractories, chromite, Marico This paper examines the role of refractory-grade chromite in refractories. The chromite deposit at Verref?s Marico Chrome mine is described. The refractory properties of chromite and their role in basic refractories are described. The properties and metallurgical applications of chrome-containing refractories are described and finally environmental issues associated with chrome-containing refractories are discussed.

Jan 1, 2011

By Tyler Acorn

In December of 2009 an estimated one million ton slope failure activated a 10 million ton mass impacting use of the main ramp system in the Newmont Gold Quarry pit. The failure left behind a 400 foot (122 meters), vertical to sub vertical scarp feature and shut down production in the lower benches of the pit.

Jan 1, 2011

By Dan A. Brown

The New Mississippi River Bridge (MRB) employed conventional design-bid-build procurement, but the bidding process included the opportunity for pre-qualified bidders to develop and propose confidential Alternative Technical Concepts (ATC?s) for evaluation and approval in advance of bidding. The ATC process provides a mechanism for value-engineering prior to bid, with incentives and opportunities for both the owner and the bidding contractor. The contract described in this paper is for the river bridge composed of a cable-stayed crossing with two pylons and the anchor piers on each side of the river. The Massman-Traylor-Alberici (MTA) team developed a re-designed foundation system for the main pylon and anchor foundations which utilizes their equipment and experience along with field load test measurements to optimize the foundations. The paper describes the experience with the use of the pre-bid ATC process on the project from the perspective of the bidder, and outlines some of the benefits and limitations of this concept with respect to foundation design and construction. Some keys for success are identified and impediments to the effective implementation of the process are described.

Jan 1, 2011

By Gordon Lovegrove, Jeffrey Leob, Dwayne Tannant

It has long been known that the combination of aluminum (AL) powder to ammonium nitrate (AN) / fuel oil (FO) can greatly enhance fragmentation or ultimately reduce the number of blast holes in a pattern. Decades of research have meticulously provided optimal AL:AN:FO ratios showing dramatic increases in energy output levels, yet widespread use of aluminized ANFO (ALANFO) has yet to replace the use of ANFO in the blasting world today. This may be due to the perception that the upfront, increased cost of materials deters the selection of this advantageously modified explosive. Researchers have explored this question and promote ALANFO by pledge of massive reductions in day-to-day operational costs. However, in these analyses there is a complete disregard for the external costs of the material; the environmental effects and sustainability considerations of the product. A holistic social cost-benefit analysis of ALANFO shows that an admittedly high-cost explosive does indeed provide an output which contains a wealth of operational savings in typical blast patterns. However, the immediate, on-site costs and savings do not define the limitations of this analysis. A complete comparison of the externalities including the environmental and sustainability considerations of the aluminum by-product life-cycle, and the environmental impacts of both the refinement of ammonium nitrate prills and the acquisition of sufficient fuel oil are also assessed. A savings of $216,000 / year through the use of ALANFO in one particular case study was recalculated to an increase in drilling and blasting costs of $188,000 when the external costs of aluminum, ammonium nitrate, and fuel oil are included analysis. The results of this analysis are intended to improve contractors? selection of explosives by providing additional societal and environmental factors into the equation, in preparation for an exponential global shift to greener business operations, while allowing them to remain competitive.

Jan 1, 2011

By P. N. Anyalebechi

"The as-cast microstructure of two commercial-size ingots of aluminum alloy 3004 produced by the electromagnetic casting process was quantitatively characterized. This involved the quantitative determination of through-thickness and across-width variations in dendrite cell size, grain size, macrosegregation of alloying elements, interparticle spacing, and the types, volume fractions, and sizes of the constituent or second phase particles. More than ninety-five percent of the constituent phases in the ingots consisted of the A16(Mn,Fe) phase; the desirable a-Al 12(Fe,Mn)3Si phase was not detected in any of the ingots by Guinier X-ray diffraction analyses or electron probe X-ray microanalyses. A significant microstructural heterogeneity through the thickness and across the width of both ingots was observed. For example, macrosegregation, and the sizes of the constituent phase particles, dendrite cells, and grains increased concomitantly from edge to mid-width and from surface to center of the ingots. There was a -20% depletion (negative macrosegregation) of Mg and a +54-87% enrichment (positive macrosegregation) of Ti in the center of the ingots. With the exception of grain size, there was no significant microstructural difference between the two ingots examined. The causes and practical implications of the observed microstructural heterogeneity in the ingots are discussed.IntroductionThe first step in the fabrication of majority of wrought products of aluminum and its alloys is the casting of large ingots or billets of simple shapes (round or rectangular). The sizes of the ingots vary from 10 mm to 450 mm diameter or 25 mm to 780 mm thick. The quality of the finished products is established at the ingot casting stage. This is because the microstructural characteristics, such as secondary dendrite cell size or arm spacing, amount of alloying elements retained in solid solution, macrosegregation, and the characteristics of second phases, produced during casting cannot be reversed by subsequent processing. Up until twenty-five years ago, the effect of as-cast microstructure of large ingots on the structure and behavior of thin sheets (0.34 mm thick) during drawing and ironing processes was incorrectly assumed to be minimal or nonexistent. This was based on the erroneous notion that the thermal treatments and large reduction (>99.94%) and strain that the ingot undergoes during production of the sheets completely destroys the original ingot structure and its inherent heterogeneity. However, the effects of ingot structure can, a priori, be deduced from the observed effects of constituent phase particle size, type and volume fraction on recrystallization, development of texture during annealing and deformation, and earing. In fact, careful examination of the behavior of products produced from different size ingots or castings have shown that the original microstructure of the ingot has a direct impact on the properties and performance of the end products."

Jan 1, 2011

By P. N. Anyalebechi

"The effects of solidification rate, initial melt hydrogen concentration, and grain refining on porosity formation in aluminum alloy 2024 have been investigated with unidirectionally cooled laboratory-size ingots. The ingots were prepared from melts containing hydrogen concentration of 0.059-0.27 cm3/100 g and solidified at 0.2-37 °C/s. As expected, the amount of porosity, average pore size, and pore number density increased with increase in melt hydrogen concentration and decrease in solidification rate. However, the effect of solidification rate was greater at the very low melt hydrogen concentration (0.059 cm3/100 g). These results are consistent with reported effects of solidification rate and melt hydrogen content on porosity formation in other aluminum alloys. Interestingly, addition of grain refiner slightly increased the amount of porosity and the average pore size, especially at solidification rates above 1°C/s. IntroductionIn shaped castings and wrought products fabricated from ingots, billets, bars, or slabs of aluminum and its alloys porosity formation is a problem. This is because it compromises their tensile strength, fracture toughness, and fatigue properties [ 1-18]. The pores are usually the crack initiation and propagation sites [6,8,9] and the largest pores tend to dictate the fatigue life of the aluminum products [9,10,14]. Porous regions within an aluminum product probably yield first due to the reduced tensile load bearing capacity, causing the concentration of the strain near the voids which subsequently results in premature fracture. In aluminum alloy ingots, billets, bars and slabs porosity formation is particularly problematic because of its persistence through fabrication and potential for reappearance or exacerbation during subsequent thermal treatment processes before and/or after fabrication [19]. In fact, persistence of microporosity is a serious problem in large thick plates of wrought aluminum alloy products that must be rolled from correspondingly large direct-chill or electromagnetic cast ingots. Some of these thick plate products are machined into large aircraft components that are required in service to withstand multi-directional stresses and to possess high fatigue strength, fracture toughness, resistance to stress corrosion cracking, and strength in the short-transverse direction [1,20]."

Jan 1, 2011

By Guan-zhou Qiu, Shui-shi Liu, Yu-feng Guo, Tao Jiang

"The preparation of high-quality synthetic ruitle from electric furnace titanium slag was systematically investigated by activation roasting followed by acid leaching process. The results showed that impurities such as Ca and Mg in titanium slag can be effectively removed and TiO2 grade of the product was markedly improved by the process. High-quality synthetic rutile containing 88.54% TiO2, 0.42% (CaO+MgO) was obtained under the conditions that roasted with 7.5%(wt) H3PO4 at 1000 oC for 2h, followed by two-stage leaching in boiling dilute sulfuric acid for 2h. Mechanism studies showed that anosovite solid solution and silicate minerals were reacted with phosphoric acid in the roasting process. As a result, titanium components in titanium slag turned into rutile (TiO2) and impurities were transformed into acid-soluble phosphate and quartz.IntroductionWith the gradual depletion of natural rutile and the rapid development of titanium industry in China, the natural rutile reserves cannot satisfy the requirement for production of titanium pigment and titanium sponge. Ilmenite is, therefore, becoming main raw material for titanium industry. However, because of its low TiO2 grade, it generally requires preconcentration to titanium-rich material such as titanium slag or synthetic rutile [1-3].Ilmenite resources are extremely rich in Pan-xi area of China, which account for 90.54% of total ilmenite reserves in China [4]. The titanium slag produced by electric smelting of ilmenite concentrate has high contents of Ca and Mg, and is not suitable as a raw material for chloride process and titanium sponge production. Therefore, upgrading titanium slag to prepare raw material suitable for chloride process and titanium sponge production has important significance for the development of China's titanium industry."

Jan 1, 2011

By M. Dupuis

Recently, a new approach to controlling alumina feeding in a H.H. cell has been proposed [1, 2 and 3]. This approach, labeled In Situ aluminium cell control, is based on a correlation between the slope of the cell voltage during a no feed observation period and the dissolved alumina concentration in the bath. Once the dissolved alumina concentration has been estimated, a primary calibration surface uniquely relating the dissolved alumina concentration and the anode-cathode-distance (ACD) to the cell voltage is used to estimate the cell ACD. Once both the alumina concentration and the ACD have been estimated at the end of the observation period, a PID controller can be used to regulate the rate of alumina feeding using only the normalized cell voltage to calculate the error between the estimated dissolved alumina concentration and a target value. The In Situ aluminium cell control algorithm has now been tested with the Dyna/Marc [4, 5 and 6] cell simulator demonstrating that it should be possible to control a H.H. cell in this manner with less variation in the dissolved alumina concentration and other process variables producing a prediction of improved cell current efficiency and power efficiency.

Jan 1, 2011

By S. Slottee

The technology of making and using ?paste? from mine tailings is increasingly well known by the minerals industry. The primary applications are water recovery and ?stacking? of tailings with minimal use of dams and ponds. This paper highlights some applications, other than water recovery and stacking, that have come to the attention of a paste thickener equipment supplier. As generated by thickeners, paste (also called ?thickened tailings?) is a non-settling, relatively high concentration, suspension of solids that can be pumped. Paste deposits with an angle of repose, allowing minimal use of dams. High solids concentration allows more water recovery at the paste thickener than is achieved in conventional and high rate slurry tailings thickeners. This paper is based on paste as produced in a flow sheet that includes a thickener, underflow pumps that are typically centrifugal, transfer pumps that can be centrifugal or positive displacement, and a distribution system at the deposition site. Examples of paste applications other than water recovery or stacking include: ?mine? an existing tailings pond by removing slurry, recovering coal or iron ore values, and return the new tailings to the pond as a paste that does not res-suspend; use paste to seal an existing tailings pond from leaking to groundwater or to an underground mine; extend the life of an existing tailings pond by thickening the tailings to paste; move an existing dry tailings impoundment to a new location by slurrying, pumping, paste thickening, and redeposit; minimize the size of a filter by paste thickening the feed; operate a paste thickener and filter in parallel on a tailings stream with re-mixing to achieve a high solids concentration. The use of paste tailings technology has been expanding over the last 15 years. The applications, both implemented and under consideration, are increasingly diverse and include all minerals tailings. Tailings handling designers should always consider a paste option to the conventional slurry solution.

Jan 1, 2011