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By Neely H. Bostick

The primary and secondary organic matter in sedimentary rocks changes markedly when it becomes heated as a consequence of thick sediment accumulation and normal geothermal gradients, high geothermal gradients, hydrothermal fluids, or igneous events. Contact zones adjacent to small igneous dikes allow sampling of a single sedimentary bed that has been exposed to temperatures in a range as great as 30-500°C. Dike-heated rocks are, therefore, good sites for research on thermal effects because variation of the original organic matter is minimal, the range of heating is great, and the history of rock heating in a dike zone is relatively well established. In rare cases, such as at the dike near Wolcott, Colorado, described in this paper, the rock samples are sufficiently unweathered to allow analysis of secondary bitumens generated by the heating. We show by optical microscopy, scanning and transmission electron microscopy, and geochemistry the kinds of solid organic constituents in sedimen¬tary rocks and in ore deposits and the effects of heating. The primary phytoclasts that make up kerogen In sedimentary rock and in some ore deposits (pollen, resin, charcoal, humified woody remains, etc.) change in ways that are familiar to coal specialists. Progressive loss of moisture and other volatile matter yields residual kerogen that Is relatively higher in carbon and lower In oxygen and hydrogen, and has greater molecular or polymer ordering. In our contact zone examples, atomic H/C ratios of kerogen decrease from 0.8 (one case from 1.4) to 0.4, the hydrogen index from Rock-Eval pyrolysis decreases from 70 to 5, and the transformation ratio from Rock-Eval pyrolysis increases from 0.06 to 0.5 with increased heating. The visible effects of heating seen by scanning electron microscopy and light microscopy include formation of vesicles and flow structure, the development of optical anisotropy and mesophase, change of color, and increase in the refractive index, absorption, and reflectance. Some of these changes In primary organic matter are observed also in secondary organic matter, for example, in solid bitumens in sedimentary gold ores or In lead-zinc deposits. Quantification of color or absorption changes is difficult because it Is hard to make thin sections of organic matter with uniform thickness. However, natural objects with uniform thickness can be used. We show the colors of pollen In rocks from the Salton geothermal field at temperatures ranging from 100 to 300°C, and of pollen heated in laboratory bombs from 150 to 400°C. Measurement of vitrinite reflectance is a practical way to quantify thermal changes of kerogen and minerals of most sedimentary rocks because vitrinite is fairly widespread In sedimentary rocks of Devonian age and younger. For example, the reflectance of vitrinite rises from the regional level, as low as 0.4 % Ro, to more than 5% Ro adjacent to dikes that cut sedimentary rock. This is equivalent to the rank change from subbituminous coal to extreme meta-anthracite. The rise is most abrupt near thin dikes, but when the distance from the igneous contact is expressed as a ratio of dike thickness the reflectance rise is similar for all dikes. Controlled heating of vitrinite-bearing rocks In the laboratory provides a means to assign known temperatures to vitrinite-reflectance values. The derived plots of temperature In dike contact zones have the same shape and level as those predicted by heat theory, and the temperature lines extend toward dike contact temperatures that are about half those of most magmas, as expected if the intrusions did not flow past the sedimentary rock for a long time. The globular submicroscopic structure of vitrinite and Its heterogeneity, which we show by means of transmission electron microscopy, pose some problems In selecting a uniform type of vitrinite for measurement of thermal changes. At present, routine reflectance values of vitrinite dispersed in rocks have a relative uncertainty as great as 10%. Thermally caused chemical changes in the primary kerogen, especially decrease in the oxygen and hydrogen contents, lead to formation of secondary products in the contact zone. The measured changes of secondary organic products in these rocks include formation of peaks In concentration of total extractable organic matter and in hydrocarbons, and in the saturated/aromatic hydrocarbon ratio over the interval where primary organic hydrogen decreases most rapidly--then destruction or expulsion of these products at high temperatures. The odd carbon-number predominance of the C25-C31 n-alkanes In samples far from the dike disappears by about 1.3% Ro whereas the 13C: 12C ratios of the saturated and aromatic hydrocarbons increase over most of the thermal range. The saturated aromatic hydrocarbon ratio at first increases, corresponding to thermal generation of saturated hydrocarbons, then decreases in the most altered samples. One use of organic petrography, in addition to identifying organic fades or thermal alteration, is recognition of sample contamination such as the solid organic additives used in some drilling muds which may contaminate geochemical samples.

Jan 1, 2013

By David L. Giles

The alkalic igneous province of Montana consists of centers of laccolithic and stock-like intrusive complexes with associated sills, dikes, and breccia pipes (e.g., Judith, Highwood, Little Belt Mts.); isolated plug-like mafic bodies (e.g., Smokey and Eagle Buttes); and clusters of kimberlitic diatremes and ultrabasic dike swarms (Missouri River Breaks). The province extends in a belt throughout central Montana from the North Absaroka Range in the south to the Sweetgrass Hills on the Canadian border. Intrusive activity ranged in age from Late Cretaceous to late Miocene, peaking at about 50 m.y, ago. Diverse types of significant epithermal gold mineralization occur at many of the laccolithic centers. This mineralization took place in large part during the waning stages of, or following, igneous activity. Large remnant travertine blankets in the region attest to comparatively recent hydrothermal activity. The quartz-pyrite-gold mineralization ranges from igneous- hosted stockworks or fracture sets (Zortman-Landusky and Neihart districts) and breccia pipes (North Moccasin Mts.) to replacement zones in flanking and upwarped Madison Group limestone (Gilt Edge and Kendall districts). The latter are mostly localized by intraformational solution breccias in the upper Madison, notably near porphyry contacts. Gold mineralization in the province was accompanied by varying amounts of silver, base metals, sulfosalts, and tellurides, with quartz, fluorite, carbonate, and barite and gangue. Gold occurs as auriferous pyrite, sylvanite, or in native form. Since the 1880's, primary gold production from numerous scattered deposits in the Judith, Moccasin, and Little Rocky Mountains, along with byproduct gold from the Neihart silver district (Little Belt Mountain), has totalled around 2 million oz. The major deposits were in the 1-2 million ton range at an average gold tenor of 0.3-0.6 oz per ton. Most of the ore was mixed oxide or carbonaceous sulfide ore and was treated either by amalgamation or by roasting-cyanidation. Current activity includes heap-leach operations on bulk- tonnage low-grade (approximately 0.03 oz per ton) ores at Zortman-Landusky, and several small-scale, experimental leach or mining operations on carbonaceous replacement ores, as in the Kendall district and Spotted Horse mine. Current exploration efforts for gold are focused not only in the old established districts, but also in and around other alkalic centers, which have been unproductive to date, such as the Crazy Mountains, Sweetgrass Hills, and Bearpaw Mountains. Target concepts in these efforts are porphyry-hosted stockwork or disseminated gold ores and Carlin-type replacement lodes in the flanking Madison or other favorable carbonate units.

Jan 1, 2013

Mining is big business in Ontario. The province is Canada?s leading mining region. It consistently ranks among the top 10 jurisdictions worldwide for exploration spending, reaching about C$1 billion in 2011. More than 26 percent of all exploration and appraisal dollars spent in Canada are invested in Ontario. Minerals produced include nickel, copper, platinum group elements (PGE), cobalt, zinc, diamonds, gold and silver. It was reported that there are more than 600 mining exploration projects in the province. And, recent discoveries of chromite in northern Ontario?s Ring of Fire will add to the province?s mineral production in the coming years.

Jan 1, 2013

By M. Mononen, J. Huuskonen, M. Vauhkonen, J. Kourunen, A. Lehikoinen

"A new approach to measure process conditions in flotation cells is presented. Real scale flotation cells in a Zinc circuit are imaged using Outotec LevelSense sensors based on electrical resistance tomography. The latest results from long period plant tests show that the sensors together with FrothControl analysis give new information that correlates well with other process parameters. The sensors can compensate for electrical contact contamination using an automatic calibration technique and they are basically maintenance free. The results indicate that using the LevelSense sensors and FrothControl solution, the process control and optimization can be done automatically, stabilizing and improving the metallurgical performance of the flotation process.INTRODUCTIONThe froth flotation process is widely used in mineral industry for the separation of minerals from low-grade ore slurry. Different property parameters of froth and slurry could be measured to monitor and control the flotation process: air bubble size distribution, flow dynamics, thickness of the froth bed, amount of solids in the froth, etc. Some techniques already exist that can be utilized in studying these important parameters on-line. Examples of the techniques are the high-speed video imaging, simple conductivity probes, ultrasound techniques, floats and pressure transducers (Maldonado et al., 2008). These techniques, however, often suffer from some limitations. For example, the video imaging only gives information from the surface of the froth, simple conductivity probes suffer from contamination and the floats may get stuck and therefore do not give reliable signal for process control and optimization."

Jan 1, 2013

By A. R. Sorta, D. C. Sego

ABSTRACT Temperature, solute, texture, and thixotropic effects on time domain reflectometry (TDR) measurements of water content in oil sands tailings are investigated. Results indicate that TDR water content measurements are influenced by temperature, residual bitumen, and percent clay in the tailings. A correction of 0.03–0.10/ °C must be applied to the apparent dielectric constant (Ka) to account for the effect of temperature. The Ka-volumetric water content relationships of slurries differ significantly from the commonly used Topp calibration equation. The age of the tailings and the addition of phosphogypsum did not influence TDR water content measurements.

Jan 1, 2013

By David Hersey

The Paseo Bridge was located at the I-29/I-35/US-71 Missouri River Highway Crossing. It was built between 1952 and 1954 by Massman Construction Company. The 1,232 foot long, self-anchored suspension bridge was the longest of its type when built. On Jan. 22, 2003, a connector pin designed to allow the bridge to expand and contract during temperature cycles seized and caused a portion of the bridge deck to raise up and block traffic. This marked the beginning of the end for the old Paseo Bridge.

Jan 1, 2013

By Pinnaduwa H. S. W. Kulatilake

To exploit an underground mine effectively and safely, it is important to have a good understanding of the geotechnical behavior of the rockmass surrounding the underground mine excavation. The aim of this study was to investigate, at the threedimensional level, the geotechnical behavior around a tunnel excavated in a metal mine in China. A three-dimensional numerical model was built by using the 3DEC software package to simulate a tunnel excavation under a high in situ stress condition and by relying on the information available on lithology, geological structures, in situ stress measurements, physical and mechanical properties of intact rock, discontinuities, and interfaces between different rocks. The authors also investigated the effect of the discontinuity network, possible intact rock and discontinuity parameter variability, representation of rock masses as discontinuum or equivalent continuum material and rock support system on the deformation, and stability around the tunnel. A very good agreement was obtained between the collected field deformation monitoring results and the results of the conducted numerical stress analyses with appropriate geomechanical property values.

Jan 1, 2013

By Tao Zeng, Jianchao Li, Chang Jie, Jieyu Zhang, Jifang Xu, Kuochih Chou

"The densities of the selected quaternary Ca0-5%Mg0-Alz03-Si02 slag with low silica were measured by the Archimedean method in a wide temperature range from l 723K to 1823K. Slag compositions were chosen based on five different levels of Si02 content between 0.00 pct and 11.40 pct. The MgO content was equaled to 5.00 pct. The mass ratio of CaO/Alz03 was varied from 0.67 to 2.14. The effects of temperature, Ca0/Alz03 ratio and optical basicity were studied. It is shown that density decrease approximately linearly with an increase in temperature. With the same Si02 content, the density decreases with increasing of CaO/Alz03 ratio and optical basicity. Based on the experimental data as the boundary of the homogenous phase region predicated by F ACTSAGE software, the mass triangle model is used to calculate the density of selected limited homogenous phase region. The results showed that the mass triangle model is working well.IntroductionIt is of great importance to measure density of slag melt not only to the theory research for melt, which that is directly amenable to the structure correlations of molten slags, but also to the industrial application. Many metallurgy phenomena such as inclusion formation in molten melt and its removing, slag foaming, slag-metal reaction are closely related to the density of slag. Density is also required to estimate other fundamental properties, like surface tension, viscosity, and thermal conductivity from thermal diffusivity so that a relatively complete picture in regard to the behavior of high-temperature molten oxides could be made."

Jan 1, 2013

By Xu-ling Chen, Qian Li, Yong-bin Yang, Zhao Jing, Tao Jiang, Guang-hui Li

"It is generally known that alkali metals are harmful to blast furnace production resulting in aggravating RDI of sinters, abnormal expansion of pellets, deteriorating blast furnace lining, etc. Sinters regarded as dominating burden of blast furnace are determined as the main source of alkali metals. In this study, the removal behavior of potassium and sodium oxides by pre-reduction sintering during the sintering process was studied. The removal ratio ofK20 and Na20 was greatly influenced by coke powder content, carbon species, coke powder adding ways, additive and so on. Under the conditions of carbon rate 12% and 5% dosage of CO supplied in the sintering process, the corresponding removal ratio ofK20, Na20 was 69.00% and 32.79%, and metallization ratio could reach 4.65%. This technology provided a novel process for reducing the content of alkali metals in sinters and dramatically improving the quality of blast furnace burden.IntroductionSinter is the main iron-bearing charge of blast furnace for iron-making in China, making up about 80% of the total burden; therefore, its quality has a significant influence on the quality of pig iron and blast furnace operation. Research and practice of numerous years prove that potassium and sodium coming from ores are brought into blast furnace and upgraded, which is one of the essential reasons that lead to blast furnace nodulation and influences its strength. Currently, effective flow sheet to remove potassium and sodium is weak magnetic separation-intensive magnetic separation-flotation [l], while iron ore concentrate is still ofhigh levels of potassium and sodium. As sintering process is also not effective to remove potassium and sodium, blast furnace in China is of high alkali burden, e.g. it reaches 5.6-6.2kg/tFe in Baotou iron making plant, which is greater than international tolerated level of2.55kgltFe [l]."

Jan 1, 2013

By B. Samanta

This paper highlights the use of an innovative mine production scheduling scheme for grade-control planning tasks that take into consideration grade-model uncertainty. The scheduling exercise has been carried out with the help of a multiobjective genetic algorithm (MOGa) for the production scheduling operations. The underlying motive behind the use of MOGa has been the generation of a set of pareto optimal solutions to meet the goals of the target-grade specifications for the considered multiple grade attributes. Several new concepts related to MOGa formulation, in particular the mutation operation and the convergence criteria of this algorithm, are proposed in this paper. The modeling of grade uncertainty into the scheduling outputs has also been incorporated through a set of conditional simulated grade maps. The proposed scheme of production scheduling operations has been applied for the grade-control planning operations in an iron ore mine to meet the targeted grade specifications of iron, silica and alumina, and a risk analysis has been performed to this end.

Jan 1, 2013

By G. R. Morin, A. R. Leggett

"In 2010, closure of the Kidd metallurgical plants along with structural changes to the historical ratios of payable metals led to a review of the operating targets at the Kidd concentrator. Previous operating data indicated that there was potential for significant revenue improvements by lowering the copper concentrate grade. An extended plant trial was carried out in 2011 to quantify the revenue impact of lowering the copper concentrate grade from 27% to 25% Cu, as well as identifying the lower practical grade limit. Analysis of plant trial results indicated that the process change increased net concentrate revenue by $2 M to $3 M per year at current metal prices. Increased revenue was primarily associated with higher silver recovery to the copper concentrate while the marginally improved copper recovery was essentially offset by increased zinc losses and concentrate treatment and freight charges.Details of the plant test work results are discussed in this paper along with the financial analysis of the revenue improvements. Key areas covered are major revenue components of the concentrate contracts, validation of revenue improvements through plant testing and sensitivity of the improvements to market and plant variables.INTRODUCTIONThe Xstrata Copper Kidd concentrator commenced operations in 1966 treating ore from the nearby Kidd volcanogenic massive sulphide deposit in Timmins, Ontario (Thompson, Amsden, & Chapman, 1978). Over the years, up to four separate grinding-flotation divisions were in operation with throughput rates peaking at 4.5 million tonnes per year of ore in the mid 1980’s (Kelebek & Francis, 1998). As the mine production decreased and grinding throughput increased operations were gradually cut back and since 1998 two grinding-flotation divisions have been in operation treating Kidd mine ore. One of the idled divisions has been intermittently used for custom milling operations, most recently the Ni/Cu Montcalm deposit, which was milled from 2004 to 2009. Current budget throughput rates, limited by mine production, are 2.4 million tonnes per year of ore grading 1.7% Cu, 4.3% Zn and 55 g/mt Ag. Concentrate production rates are 150,000 tonnes per year of copper concentrate and 155,000 tonnes per year of zinc concentrate. The Kidd mine is the deepest base metal mine in the world with mining operations down to 9600 ft.In 2010 the copper and zinc plants at the Kidd metallurgical site, which previously treated the concentrate production from the Kidd concentrator, ceased operation due to a variety of economic and market factors. Following the metallurgical plant closures the Kidd concentrator products were shipped off site for treatment. The majority of the copper concentrate is now processed at the Xstrata Copper Horne smelter in Rouyn-Noranda, Quebec with the majority of the zinc concentrate processed at Canadian Electrolytic Zinc Ltd. in Valleyfield, Quebec."

Jan 1, 2013

By Soheil Bahrampour

Void detection and identification of bed separation while drilling holes in rocks for roof bolting can be a great source of information for the evaluation of ground conditions and adjustment of ground control or support measures. This can be accomplished through the monitoring and analysis of drilling parameters by the roof bolter. This paper reviews work currently under way in a joint study between Penn State University and J. H. Fletcher & Co. The detection of voids, along with identification of rock types, can lead to development of 3D roof maps, which can subsequently be used to evaluate ground support and its suitability for given ground conditions in tunneling and mining operations. Existing algorithms for void detection utilize the sensory information of the drill unit, such as feed and rotary pressure, revolutions per minute (RPM), and penetration rate, to detect voids or joints on the roof/ ribs. While the void detection algorithms are being revised to allow analysis of available data from the existing sensory systems of the roofbolters with higher accuracy and lower number of false detections, additional sensors have been added to the drill to improve its ability for accurate detection of the voids and joints. This includes installation of vibration and acoustic sensors on a drilling unit at J. H. Fletcher & Co., and pertinent data analysis which are discussed in this paper. Initial results indicate that the data obtained by vibration and acoustic sensors at high sampling rates can be used to improve the performance of the void detection algorithms independently, and when combined with the modified algorithms using existing sensors, it can substantially improve the capabilities of current void detection system.

Jan 1, 2013

By J. Lee, M. Peart, T. Bhambhani, D. R. Nagaraj, P. Riccio

"Over the past decade or so, our efforts have focused on developing the rationale and concepts for new technology in reagent development and optimization in the processing of base and precious metals. A major outcome of these efforts have been the development of a novel family of collectors, principally driven by the MAXGOLD® and Aero XD-5002® chemistries, for precious metals recovery from primary Au ores and Cu-Au ores. These chemistries was developed to be robust to address the complex mineralogy and gold deportment in these ores. Plant trial data for a variety of ores have confirmed that the both Aero® XD-5002 and MAXGOLD® chemistry are indeed versatile in recovering gold values occurring as gold alloys and/or associated with many types of sulfides, and in altering the deportment of certain sulfides (such as those bearing As, Bi etc). An overview will be given in this paper using plant data to highlight the application of these reagents.INTRODUCTIONThe subject matter of this paper is the flotation of Au containing minerals from their ores. The motivation from this manuscript comes from the several challenges faced with the processing of Au ores, as was articulated in detail by Nagaraj (2008). The biggest challenge is the complex mineralogy; most easy-to-treat free-milling ores bodies are largely depleted. The Au values are distributed in multiple host minerals such as pyrite, pyrrhotite, arsenopyrite and Cu minerals such as chalcopyrite. Au values also happen to be finely disseminated within the various minerals and are sometimes invisible in optical microscopy. Additionally, on any given day, some mines treat multiple ore types, and the mineralogy is different for each ore type.Xanthates continue to be the collectors of choice at most Au and PGM operations around the world. Most primary Au operations tend to consume very large amounts of collectors; the dosage ranges anywhere between 40-400 g/t and this has been attributed to both mineralogical and non-mineralogical factors (non-mineralogical factors include the low cost of xanthates and the mindset that “more is always better”, which is not necessarily the case). In addition, several studies now show that xanthates alone are never sufficient where multiple value minerals are present, and that supplementary collectors are required. The large doses present a substantial cost to the minerals industry, and many mining companies have expressed the need for more efficient reagents that can improve metallurgical performance at low dosages."

Jan 1, 2013

By Brian E. Perrine

Underground mining requires a variety of specialized equipment. With ever-changing mining conditions and methods, some mines have had to resort to purchasing existing industrial equipment and adapting it for underground use. Since this equipment is not made for underground mining or their specific task, the result is often lost time, money, and sometimes an unsafe working condition. One such application is the setting of a CAN. A CAN is a type of cylindrical secondary roof support made from a cement composite and encased in steel. The CAN has become popular because of its simple one-piece design that can handle heaving and sagging better than other available designs. ?Because of this exceptional ability to sustain load through extended convergence and displacement, the CAN is one of the most robust and stable standing supports in use today.?It also promotes better air flow due to the size and shape of the CAN. CAN size and weight have increased over time to handle more difficult mining conditions. Significant down time and inefficiencies with existing CAN setting machines at Twentymile Coal were directly due to the item in use not being designed to be task-specific. They were undersized with very limited movement. The miners had to take extra steps and precautions when setting CANs. Maintenance delays were significant. Twentymile Coal Company realized that they required a safer, more reliable and more efficient machine to handle and set CANs, and looked for a partner to develop a new design-specific machine. They worked jointly with J.H. Fletcher® engineering and sales to design and manufacture a machine specifically made for setting CANs. The objective was to produce a machine that would handle the conditions and methods that the mine required for setting CANs during longwall retreat. The resulting design had to be safe, stable, have a wide range of motion, be ergonomic, simple to use, and easy to maintain. The machine also had to improve efficiency. The resulting machine has been operating for approximately one year at Twentymile Coal and has been proven to improve safety, reliability, and efficiency. In conclusion, with the task-specific CAN Manipulator, the mine is able to better plan daily tasks with the knowledge that the machine will be available throughout a shift, and the employees will be safer because of the machine?s ergonomics, stability and safety. This has resulted in better productivity and a safer environment.

Jan 1, 2013

By M. Kahn

This paper traces the rise of South Africa's mining industry in the context of the different state forms that oversaw its development. It commences with the mining-led industrial revolution through four periods of conflict, each of which contributed to a deepening of the industrial base, with constant battles between domestic and foreign capital and labour, and the rise of both Afrikaner and African nationalism. The role of state-owned enterprises has been crucial in shaping this dynamic so that at its peak the public sector and leading mining houses constituted two massive centres of power. This was followed by a thirty-year period of neo-liberal experimentation. The current debate on the 'developmental state' is an attempt to reconstruct the state as a counterweight to capital. It is argued that while the country has moved toward inclusive political and economic institutions, these are both limited by deep 'extractive' characteristics. This transformation failure provides a fertile ground for populism that presents one of the biggest threats to inclusive growth. Cited examples point to the many ways that states have sought to deal with the bonanza that conversion of mineral non-resources into resources brings. Such greenfield resources on state land, or in areas where the state holds monopoly rights, do not present ownership issues. It is suggested that this is the route that South Africa should follow, as the alternative will be conflictual.

Jan 1, 2013

By F. T. Cawood

This article is a continuation of a series of publications by the authors on the international debate on resource nationalism, with specific reference to South Africa. Previous outcomes have shown that mine nationalization is not a solution for South Africa, and that maintaining stability of the current mineral and tax regimes is fundamental. It will not be wise to replace existing law and policy instruments until there is a better understanding of the distinction between fact and public perception about the impact of the current system. The new scheme of state custodianship linked to a mining royalty that effectively targets economic rents provides for effective resource use. The methodology in this article is to consider how South Africa's mineral tax regime can be tweaked to achieve optimal management and benefit from mineral extraction and associated rents by avoiding changes feared by investors. The major finding is that the current suite of instruments can be considered a suitable platform for optimal management of resource rents. However, it will be necessary to first investigate ways of improving the mineral beneficiation intent of the royalty structure, and secondly investigate whether the mineral rent portion of the royalty formula can be ring-fenced for the purpose of establishing a sovereign wealth fund.

Jan 1, 2013

By N. A. Chapman

The effect of using conventional crushing and HPGR in combination with dry or wet milling was investigated using a base metal sulphide (sphalerite), and a PGM (platinum group minerals) ore in order to determine how these different processes affect the flotation performance. In the case of sphalerite, irrespective of the crushing procedure (HPGR or conventional), dry milling resulted in the highest grades and recoveries of zinc. Conversely, in the case of PGMs, a similar treatment produced the poorest results. The results were investigated further by comparing the relative effects of factors such as percentage liberation, particle size, and surface properties of the samples produced by the different milling procedures as well as the concentrates and tailings obtained from the flotation tests.

Jan 1, 2013

By Deon van Tonder, Chuck Edwards

"Solvent extraction is used in many acid leach uranium circuits to upgrade and purify the uranium bearing solution prior to final product precipitation. A number of strip options are available to recover the uranium from the loaded organic. This paper compares some of these options on the basis of typical capital and operating costs for both the solvent extraction circuit and downstream uranium processing, and also considers other related issues. The aim is to provide an objective comparative assessment of these options that could be used as a qualitative guide in process selection or improvement.INTRODUCTIONIn the 1950s the uranium industry was the first industry to adopt solvent extraction (SX). Since then, the flow sheets have advanced. Notable was the introduction of tertiary amine extractants by General Mills during the late 1950s and 1960s (Mackenzie, 1997; Mackenzie, 2005), which is still today considered ‘state of the art’ technology. Initially solvent extraction was done in combination with ion-exchange, such as in the Eluex flow sheet, followed later by the adoption of direct solvent extraction from pregnant leach solution (PLS). From a strip-precipitation perspective ammonia strip followed by ammonium diuranate precipitation was widely adopted as the norm in the uranium industry. More recently alternative strip systems have been receiving increasing attention due to the environmental, health and safety issues associated with ammonia and the resulting calcined uranium oxide product. This paper explores some of these alternative options in comparison with the ammonia route.It is important to acknowledge that each operation is unique, and therefore the information and philosophy outlined in this paper serve to provide a general guide that can be potentially applied and adapted to any site or project."

Jan 1, 2013

By T. B. Thompson

The Leadville District has been a prominent metal producer since its discovery in 1860. Veins and replacement bodies both have contributed to district production. The latter have been the major metal sources and are hosted within the Paleozoic Leadville, Dyer, and Manitou Dolomites. Igneous bodies representing eight separate events cut the sedimentary section. The main intrusive complex within the district occurs in the Breece Hill area and was the thermal center about which the vein and replacement ores exhibit mineralogical zoning. Precious metal-pyrite-quartz veins (quartz Th= 422 to 469°C; salinity < 4.2 wt. percent eNaCI) occur within or peripheral to the Breece Hill Intrusive Complex, whereas base metal veins and replacement bodies extend from the complex margins outward as much as 2 mi. Pre-ore and post-ore igneous bodies occur, but Fragmental Porphyry dikes immediately post-date the ore event. The Fragmental Porphyry grades downward from a heterolithic breccia with rock-flour matrix to one with a dark, glassy, sulfide- and phenocryst-bearing matrix, commonly with quartz-feldspar porphyry selvages on the dike. Two types of replacement bodies are recognized in the district: 1) the Leadville-type (LTM), massive sulfide (> 60% sulfides) bodies with recoverable Zn, Pb, Ag, and Au, and 2) the Sherman-type (STM), sulfide bodies (low total sulfide) with barite, galena, sphalerite, argentian tetra.hedrite, and minor pyrite. The latter type occurs only within the Leadville Dolomite and is found throughout the Mosquito Range and extending into the Alma District. The Leadville-type replacement bodies are zoned with a pyritic margin and base metal core. Wallrock alteration and trace Pb-Zn dispersion are strongly developed in igneous wallrocks but are weakly developed in carbonate wallrocks. Cu:Zn, Ag:Zn, and Au:Fe ratios increase outward from the center to the margins of LTM. Some of the sulfide bodies are localized on earlier-formed magnetite skarns. Pyrrhotite, pyrite, and marcasite are the earliest formed sulfide phases while chalcopyrite, marmatite, and galena developed later. Tetrahedrite and electrum occur in vugs and fine veinlets cutting the sulfides. Late-stage barite, dolomite, and fluorite occur as minor phases. Pressure-corrected Th for quartz (375-410°C), sphalerite (374-387°C), barite (320-360°C), and dolomite (310-314°C) fluid inclusions with salinities < 5.2 wt. percent eNaCI characterize the fluid responsible for the formation of the Leadville-type orebodies. These values clearly demonstrate the high temperature and low salinity of the ore fluids. Sulfur isotope analyses for galena and barite from LTM are - 1.9 to + 0.9%o and 7.8%o, respectively. Proximity to feeder veins and favorable dolomite hosts are the principal controls on ore localization. The Sherman-type bodies are not internally zoned but commonly have host rock silicification near the orebody margin or in the footwall rocks adjacent to fluid flowpaths along faults. Early quartz, pyrite, dolomite, and white barite precede base metal-silver minerals which are followed by late quartz and golden barite. It is not clear whether the early quartz and the late quartz and barite are part of the STM-forming process. Fluid inclusion analyses yield trapping temperatures as follows: early quartz, 316-341 °C; barite, 264-347°C; low-iron sphalerite, 215-265°C; and late quartz, 260-278°C. All inclusion fluids have salinities < 8.1 wt. percent eNaCI. Sulfur isotope values for barite and galena from STM range from 13.2 to 24.00/00 (avg: 18.4%o) and -6.8 to -3.8%o (avg: -5.5o/00), respectively. A hydrothermal fluid d34SSS of about 15%o is needed in order for galena and barite in equilibrium to exhibit the observed sulfur isotope compositions. Equilibrium sulfur isotope fractionation between barite and galena indicates a 300°C temperature of deposition. Two separate hydrothermal events appear to have taken place to form the distinctive Leadville-type orebodies and those of the Sherman-type assemblage. The STM is known to be older than the LTM. The latter is likely mid-Tertiary in age, post-dating emplacement of the Johnson Gulch Porphyry. LTM is clearly related to meteoric leaching of sulfur and lead (and other metals) from the upper portions of the Breece Hill Stock. Fluids were transmitted along faults, bedding planes, and contacts, and cooled away from the intrusive complex. Early ore fluids were weakly acidic and developed argillic assemblages in the igneous rocks adjacent to the fluid conduits. Reaction/replacement of carbonate rocks occurred where fluids encountered dolomite, but rapid neutralization prevented any wide-spread alteration beyond the ore-carbonate host contact. Pressures based on sphalerite geobarometry and stratigraphic reconstruction were 1.0-1.2 Kb. The high temperatures of vein and replacement ore fluids indicate that chloride complexing was more effective in metal transport than bisulfide complexes. Cooling, dilution of ore fluids, and reaction with carbonate rocks were the major factors in LTM ore deposition. STM formed over wide expanses of the Leadville Dolomite terrain adjacent to (and possibly capping) the Sawatch uplift. Sedimentary sulfur was derived from Pennsylvanian evaporite-bearing sequences adjacent to the uplift. Ore leads are strongly radiogenic (J-type) and are compatible with a crustal-leaching model. Temperatures of ore formation are higher, and ore-fluid salinities are lower than Mississippi Valley-type ore fluids. Superimposed upon dark-gray, diagenetic Leadville Dolomite are several stages of hydrothermal dolomite regionally distributed astride intrusive centers of the Colorado Mineral Belt. The presence of these later dolomites argues for dolomitization and later ore deposition in response to an abnormal thermal gradient caused by emplacement of Laramide batholiths and their generation of convective flow of meteoric fluids.

Jan 1, 2013

By Shufang Ding, Fukun Yan, Zhiqiang Shan, Wei Chen, Cuicui Ji

"To remove aluminum ion from chlorinated rare earth solution, this paper used hydrolysis method to explore the hydrolysis behavior of aluminum ion in aluminum chloride solution and confirm the optimum conditions of aluminum ion hydrolysis, which are pH value, temperature and initial concentration of Al203 and so on. The experimental results show that single treatment can make aluminum precipitation rates of chlorinated rare earth solution reach about 90% by hydrolysis precipitation; and then several recycle disposal can get precipitation rates of 89% for aluminum and 2.86% for rare earth.IntroductionIn China, rare earth resources are very rich and unique minerals, complete variety, and rare earth products are very large in the domestic reserves. Rare-earth and application products have been deep into all areas of our life, permanent magnet material of rare earth is one of the most popular application areas[11. Binary oxides such as praseodymium neodymium have been widely applied in the fields of glass, ceramics, magnetic materials, catalysts and so on. Especially, the advent of the Pr-Nd-Fe-B magnets which makes the world magnetic material into a new stage of development [2•3]With the development of science and technology, for industrial, physical and chemical indicators of raw materials Pr-Nd oxides (such as particle size, specific surface area and non rare earth impurities etc.) are also getting higher and higher. The oxide size has an important influence on sludge formation in the electrolytic process. If the size is too large, added oxides have settled on the bottom of slot before melting, and then generated sludge; if the particle is too small, it can cause dust dispersion, enlarge oxide unit consumption and increase the cost of production in the charging process. Some early processes use oxalic acid to make chloride neodymium praseodymium settle, and impurity can be removed cleanly, but the cost is high, it is not suitable for production. At present, most enterprises are using ammonium hydrogen carbonate to precipitate chlorinated neodymium praseodymium, but chlorinated neodymium praseodymium such as iron and aluminum and so on can easily form gel in the precipitation process, seriously affect the growth of neodymium praseodymium carbonate crystal and often leads to particle meticulous, even may also generate gel-like neodymium praseodymium sediments and cause centrifugal or suction filtration difficult. Now the actions and their removal of impurity such as iron and aluminum have done a lot of research in the production process of rare earth, removing aluminum craft with alkaline (sodium hydroxide) and acid (oxalic acid) has good effect, but the cost is higher[41; used adding complex agent to remove aluminum method which is simple and easy to operate, but aluminum removal rate is not high, and also changed the sediment of crystal type[51, and etc. This paper discusses the removal of chlorine from rare earth solution on the basis of the hydrolysis property differences betweenAJ3+ and rare earth ion."

Jan 1, 2013