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By E. S. Yan, R. Graley

"The StackCell was developed to overcome the engineering and design challenges that are commonly associated with existing flotation technology such as pneumatic, self-aspirating cells, mechanical cells, and flotation columns. These challenges include high energy consumption, large floorspace requirements, and size. They are most evident when designing systems to process streams containing a high volumetric flow rate coupled with a significant float yield. Unlike many metalliferous and industrial mineral applications, fine coal flotation circuits are typically characterized by feed streams containing a low solids content (<5%, by weight) where up to 85% of the feed can report to the product launder. With input from major engineering houses and end-users, the Eriez Flotation Division (EFD) developed the StackCell technology with the goal of providing an additional flotation option for end-users. This technology was designed specifically to overcome these challenges by providing an efficient method of separation in terms of metallurgy, but also with respect to equipment size, energy consumption, and installed costs. Besides being placed in tandem with existing cells to provide cost-effective supplemental capacity, this technology can be installed in a stand-alone arrangement as recently demonstrated at Patriot Coal’s Kanawha Eagle preparation plant. This manuscript provides an understanding of the underlying fundamentals of this new technology and presents data from Kanawha Eagle in addition to other industrialscale installations.INTRODUCTIONOver the past decade, column flotation has continued to gain acceptance as an alternative method for recovering fine coal due to superior metallurgical performance as compared to mechanical flotation cells. This point has been proven on numerous occasions by comparison of plant flotation data with the release analysis separation curve (Dell et al., 1972). Data from a release analysis test approximates the ultimate flotation response of a coal sample. In North America, a number of investigations have been published that document bottom-line improvements achieved using column cells (Luttrell et al., 1999; Kohmuench et al., 2004; Baumgarth et al., 2005). According to these reports, the benefits are derived from an overall increase in plant yield that can be achieved due to the improved product grade in the flotation circuit. In particular, the application of wash water to a deep froth utilized in column flotation minimizes the nonselective recovery of high-ash ultrafines that are hydraulically entrained in the froth by conventional flotation machines."

Jan 1, 2013

By A. Azizi, P. Blatter, A. Bouajila

ABSTRACT In-situ monitoring of gold dissolution by means of a rotating electrochemical quartzcrystal microbalance unveiled dramatic decreases in gold leaching from sulphide-rich ore after 360 minutes in an actual cyanidation circuit. Pre-oxidation was effective in enhancing gold extraction by preventing a passive film from forming on gold surfaces. This work aims to highlight efforts undertaken to determine (1) how gold cyanidation is limited by passivation, (2) what reactions and mechanisms are involved during sulphide-rich ore cyanidation, and (3) how peroxidation efficiency of an industrial sulphide ore is controlled by galvanic associations between its sulphide constituents.

Jan 1, 2013

By Jun Li, Lin Chen, Tian-zu Yang, Wei-feng Liu, Wan-da Bin

"The Chinese bismuth production accounts for more than 80% all over the world in 2011. The main raw materials of bismuth smelting are bismuth concentrate and by-products of Cu or Pb smelting process. Many traditional methods of bismuth smelting in china was reviewed in this paper, such as reverberating furnace smelting, blast furnace smelting, fire-refining, ferric chloride leaching-hydrolysis, slurry electrolysis, and so on. But all the traditional pyrometallurgy or hydrometallurgy process have such shortages of low recovery, poor environment, and high cost. Therefore new technologies are introduced into the smelting process of bismuth concentrate, such as low-temperature alkaline smelting and side-blown bath smelting with oxygen-enrichment. These technologies have got great progress on energy saving, emission reduction, and friendly environment. Finally the development direction of new technology on bismuth smelting was prospected.IntroductionAs a green metal, bismuth has a wider applications, just extending from the traditional medicine, metallurgical-chemical engineering, low-melting alloys, solders, catalyst, and electronics to cosmetics, flame retardant, storage battery, semiconductor, supper conductor and nuclear energy etc[1,2,3,4,5,6,7]. This will increase the production of bismuth and promote the development and progress of bismuth smelting technology. At present, The major bismuth-product countries are China, Mexico, Peru, KZ, Bolivia and Canada etc, and China are dominating. A survey from the USGS[8] showed that Chinese bismuth production were 12,500 tonnes and got 80% of the world's in 2011. Thus the technology of Chinese bismuth smelting have a great representativeness."

Jan 1, 2013

By Zhihao Yue, Honglie Shen, Yahui Teng, Ye Jiang

"In this paper, manganous nitrate [Mn(NO3)z] was used to assist the etching of silicon wafer in hydrofluoric acid (HF) for the antireflective application, and alumina (Al2O3) layer was deposited on the surface of the etched sample by atomic layer deposition method for further antireflection. The surface morphological and compositional studies of these samples were performed by scanning electron microscopy attached with an energy-dispersive X-ray spectrometer. The surface reflectance measurements were carried out using UV-Vis-NIR spectrophotometer. Binary structures of pyramids and nanopores were obtained by etching the alkaline textured monocrystalline silicon wafer in HF and Mn(NO3)z mixed solution for not more than 15 min. But excessive increase of etching time of up to 30 min resulted in the whole destruction of pyramids. The average reflectances of the 5-min-etched sample before and after being coated with 75-nm-thick Al2O3 layer are 4.62% and 3.47% in the range of 200-1000 nm, respectively.1. IntroductionAs we know, the reflectance of silicon wafer after being sliced is so high that the maximal photoelectric conversion efficiency of silicon based solar cells is limited. Therefore, alkaline texturization process was used for silicon solar cell in industrial production. But the reflectance of this alkaline textured wafer is still greater than 10% and this process can only be used for monocrystalline silicon solar cell."

Jan 1, 2013

By R. Ordóñez Olivares

This manuscript focuses on the design and development of steels for the railroad industry and methods of testing them. Here are summarized the results of research focusing on alloy development and design, with particular focus on advanced rails and wheels. The high-performance steels are characterized for their mechanical and service characteristics. The relationship between properties and cleanliness is discussed and compared to the regular railroad steel. Some of the tests presented are standard tests that are complemented with the nonstandard test recommended by the Association of American Railroads (AAR) and recommended modifications of this. The paper presents the results of metallurgical analysis, mechanical, and residual stress tests. The laboratory methods include microstructure, residual stresses, tensile, hardness, fracture toughness, and microcleanliness tests.

Jan 1, 2013

By B. Hart, J. Marois

"Scanning electron microscopy coupled with energy dispersive X-ray spectroscopy (SEM–EDX), and Time of flight secondary ion mass spectroscopy (TOF-SIMS)were used to analyze pyrochlore grains from Niobec froth flotation plant. Samples from the mill feed, pyrochlore rougher feed, pyrochlore rougher concentrate, and tail were analyzed in order to identify a potential relationship between pyrochlore matrix composition and selective separation. SEM-EDX analyses indicate that pyrochlore grains with high Fe content appear to be less recoverable than those with a lower Fe content and that the flotation response is related to matrix Fe rather than Fe occurring as inclusions. TOF-SIMS was used to analyse the surface of high Fe and low Fe pyrochlore, in order to identify a potential relationship between pyrochlore matrix composition and the related effect on cationic collector adsorption (tallow diamine). Surface analyses of pyrochlore from a conditioning test show that species indicative of the collector favour the surface of Fe poor pyrochlore relative to the Fe rich variety. The results from the conditioning test illustrate a negative relationship between collector loading and the presence of Fe and related oxidation species. This study identifies the link between pyrochlore matrix Fe content and, the presence of surface oxidation products, to collector loading. Poor Fe rich pyrochlore recovery noted in the Niobec froth flotation plant may be partially explained by this mechanism.INTRODUCTIONPyrochlore, the most abundant niobium containing mineral (Perrault and Manker, 1981) is economically recovered in Brazil, China, and Canada (Niobec) (Kouptsidis et al., 2008). Since 1974 Niobec has been extracting niobium from the St-Honorécarbonatite deposit. Niobec is the only operating Nb extraction facility in North American and one of the three major world producers of ferroniobium (Dufresne and Goyette, 2004; Belzile, 2009).Flotation is the preferred and most cost-effective method for pyrochlore recovery (Burks, 1958; Shapolov and Polkin, 1958; Zakharov et al., 1967; Razvozzhaev and Nikiforov, 1972; Bogdanov et al., 1973; Abeidu, 1974; Raby and Desrochers, 1975; Wilson, 1979; Biss and Nadeau, 1982; Biss, 1985). With the aim of optimising the flotation process for the Niobec ore, numerous experiments were performed on the influence of surfactants and type of water to optimise pyrochlore recovery and grade during flotation (Gomez et al., 1987; Rao et al., 1988; Dufresne and Goyette, 2004; Belzile, 2009)."

Jan 1, 2013

By Xie Zhang, Jiang Diao, Xin Qiu, Lu Jiang, Bing Xie, Hong-Yi Li

"Duplex converter process, in which the first converter is used for removing phosphorus from hot metal (De-P), is an important way to produce low P-content and ultra-low P-content steels. In order to improve phosphorization removal and formation of slag with high basicity at relatively low temperature during dephosphorization converter process, effects of temperature, silicon content in hot metal and varied compositions of the De-P converter slag on phosphorus distribution between the slag and hot metal were investigated with thermodynamic calculations and by laboratory scale experiments in present work. Results showed that phosphorus distribution ratio between slag and metal was varied in 10.6~26.6 when basicity of the slag was in the range of 1.5~2.1 at 1370, and the distribution ratio was increased with increasing basicity and Fe10 content in the slag.IntroductionIt is known that phosphorus exists in steel in the form of solid solution, which can significantly improve strength and hardness of steel at room temperature. However, the plasticity and toughness of steel, especially the low temperature plasticity is sharply reduced and leads to high ductile-brittle transition temperature. This phenomenon is commonly known as cold brittleness of steel [1~3]. Hence, phosphorus should be removed as much as possible in the steelmaking process, because it is generally harmful to the iron and steel products."

Jan 1, 2013

By Naixiang Feng, Shaohu Tao, Zhihui Wang, Yuezhong Di

"A novel vacuum aluminothermic reduction lithium process was developed in present work which used lithium carbonate, alumina and calcium oxide as raw material. The process mainly contained three steps. The first step is that LiA102 clinker is prepared in ambient environment, then metal lithium is vacuum extracted from LiAl02 clinker with aluminum power as reducing agent, and the last step is that alumina is leached from the reduction residue with a mixture of sodium hydroxide and sodium carbonate. The results show that the lithium reduction ratio can be over 95% under the conditions of reduction temperature 1423K, reduction time 3h, and aluminum excess 20%. The main components of reduction residue are CaO· Al203 and 12Ca0·7Alz03. The alumina leaching rate of calcium aluminate in residue is over 80%. High-whiteness aluminum hydroxide can be obtained by carbonation precipitation of the reduction slag leaching solution.IntroductionWith a density about half of water, lithium is with the lowest density of all solids, mere 0.5 g/cm3 at 20 °C [l]. Lithium is widely used in aerospace, aviation, nuclear-generated power and electric battery industry. Nowadays, over 90 % of the world's primary lithium is produced by molten salt electrolysis [2-4]. But the development of molten salt electrolysis will be effected by some factors: cost, environment, and so on. Vacuum thermal reduction may be used extensively in future because of its low-energy consumption, high-purity and short-cycle."

Jan 1, 2013

By Louise Corriveau, Bronwyn Azar, Valerie A. Jackson, Luke Ootes, Jeff Harris

We use the results of new bedrock mapping, combined with geochemical point data and airborne radiometric data (in particular equivalent uranium concentrations) to help determine which geological units in the Paleoproterozoic Great Bear magmatic zone (GBmz) contain elevated uranium. The data collectively indicate that the highest primary uranium concentrations are in equigranular granites and subvolcanic/volcanic porphyries. Notably, these rocks host the majority of known uranium-bearing deposits and/or prospects in the GBmz. We speculate that the uranium in these deposits/prospects was derived from nearby, uranium-enriched rocks and was mobilized by much younger, circulating hydrothermal fluids. Sedimentary rocks of the Thelon and Dismal Lakes groups unconformably overlie the GBmz and are known to host unconformity-type and sandstone-hosted uranium prospects. Most likely, the uraniumenriched rocks of the GBmz acted as a uranium donor to these overlying sedimentary basins. The method of investigation employed in this study may be applicable to other ‘granitic’ terrains in order to identify regions with favourable rocks for uranium exploration.

Jan 1, 2013

By Donghai Li, Cheng Pan, Xuewei Lv, Mei Liu, Enguang Guo

"Phosphorite is the main raw material for the production of phosphorus in chemical industry. More attentions have been drawn to the phosphorite concentrate beneficiated from low-grade phosphorite due to the decrease of high-grade phosphorite. For another, the agglomeration process is necessary for the phosphorite concentrate after beneficiation process. The mineralogy and sintering process of the phosphorite from Leshan, China were studied in this work. The result shows that the main phases in the phosphorite are fluorapatite (Ca3(P04)3F), hydroxylapatite (Cas(P04)3(0H)), quartz (Si02) and dolomite (CaMg(C03)2). The yield of the sinter increases with increasing the carbon dosage to 7%, and then decreases when it continuously increases. Similar regularities were found for the strength and the content of P20s of the sinter. The best strength of the sinter as well as its P205 content were discovered when the carbon dosage is 7%. Fluorapatite ((Ca5(P04)3)F) is the main phase in the sinter while fuggerite (Ca2MgSiz01) is the main binder phase.IntroductionPhosphorus is an important foundation industrial raw material of national defense industry, food industry and chemical industry, where it is used to produce red phosphorus, phosphonium hydroxide, phosphorus pentasulfide and phosphoric anhydride[l-2]."

Jan 1, 2013

By S. du Plessis

Nationalization is high on the policy agenda in South Africa. This paper considers the case for nationalizing the local mining sector from an evidence-based perspective, which is derived from theoretical considerations and related to the known features of the South African mining sector and economy. A strong case against nationalization emerges, which can be summarized as follows. The mining sector is competitive and therefore a poor candidate for public ownership. Furthermore, the resources sector does not dominate the South African economy nor does it create the risk of a decrease in the competitiveness of the industrial sector via the unintended adverse impact of an appreciating real exchange rate due to a commodity boom (Dutch Disease). Nationalizing the mining sector will cost the government more than it receives. This is not only a bad idea in itself, but it will limit the scope for distributive policies on the national budget. The contemporary international experience demonstrates the risks of fiscal imprudence. Finally, nationalizing the resources sector will undermine support for those very market-based institutions required to achieve a higher long-run growth trajectory.

Jan 1, 2013

By Robert E. McIvor

"“Classification System Efficiency (CSE)” is a powerful, emerging tool that can be used to increase grinding circuit efficiency. It is defined as the percentage of the ball mill energy being used to grind target, oversize particles. The discovery, validation and current use of CSE, including how it was manipulated, are described through seven plant case studies. These resulted in efficiency improvements ranging from 3 to 30 percent, along with major reductions in over-grinding. The achievable CSE for any given circuit is described. This paper demonstrates both how, and how much, every plant can benefit from increasing grinding circuit CSE.DEFINITIONS: BALL MILL CIRCUIT “CLASSIFICATION SYSTEM EFFICIENCY (CSE)”, “EFFECTIVE MILL GRINDING POWER”: “WASTED/OVER-GRINDING MILL POWER”The closed ball mill circuit is shown in Figure 1. The extreme importance of the circulating load ratio in determining circuit productivity was demonstrated by Davis (1925) and re-published by Guadin (1939), as shown in Figure 2. The circuit production rate increases with increased circulating load ratio, rapidly so at first and continuing to increase more gradually with higher and higher values of circulating load ratio.The underlying cause of this relationship was seen when comparing the ball mill feed and product size distributions from two different ball mill circuits, one with a low circulating load ratio, and one with a high circulating load ratio (Figure 3). While the F80’s and P80’s of these two circuits were close to the same, the mill feed and discharge size distributions were quite different. The ball mill in the circuit with the higher circulating load ratio contained a substantially greater fraction of material coarser than the target P80, as indicated by the respective mill feed and discharge size distributions. This fraction represents the fraction of the mill power being expended on “coarse” (in this case, plus P80 size) material, or the circuit “classification system efficiency.” The “effective mill grinding power” is the total mill power multiplied by the CSE. The compliment of CSE, the remaining fraction of “fines” in the mill, is the fraction of the mill power being wasted, and spent on over-grinding of material already finer than the circuit target product size. This is the “wasted/over-grinding mill power”"

Jan 1, 2013

By J. Paraszczak

ABSTRACT Diesel-powered loaders are a pillar of modern underground metal mining. As these mines are getting deeper and hotter and the emission regulations stricter, ventilation costs are soaring, affecting production cost. Also, the cost of diesel fuel is expected to rise. These may make the use of diesel engines more problematic. Electric load-haul-dump machines (LHDs) are an interesting alternative. This paper compares features and performance of diesel and electric, cable-powered LHDs. It overviews equipment offerings, and compares, analyzes and discusses technical parameters, operational problems and cost issues. The paper gives some conclusions about electric LHD applicability and performance, indicates possible applications, and suggests further research work.

Jan 1, 2013

By Patrick E. Durnal

A joint venture of Ben C. Gerwick Inc., Sverdrup (now Jacobs) and DMJM (now DMJM Harris) designed the $779 mill seismic upgrade of the Richmond - San Rafael Bridge over the San Pablo Bay in the San Francisco Bay Area and provided construction support to Caltrans. Construction of the marine foundation retrofit was completed by a joint venture of Tudor Saliba/Tidewater/Koch-Skanska and their subcontractors: Pomeroy Precast Construction, AGRA Foundations, Dutra Construction and Vortex Divers. Construction management and inspection was performed by Caltrans with support of various consultants.

Jan 1, 2013

By Tyler Acorn, Paul Worsey, Nathan Rouse

The effect of the hole diameter on vibration attenuation has not been incorporated in most vibration models in the blasting industry. In current vibration models, the charge weight and the distance from the blast are the two primary variables that are addressed. Charge weight is a function of explosive density, charge length, and charge diameter. This geometry-weight can complicate the isolation of the charge diameter variable.

Jan 1, 2013

By Qing-Yun Huang, Xiao-Yi Zeng, Bing Xie, Hong-Yi Li, Jia-Rong Yan

"In order to utilize vanadium resource in vanadium-titanium magnetite ore efficiently, vanadium distribution ratio between hot metal and slag should be improved during BF process, meanwhile the precipitating of Ti(C,N) in slag must be minimized. Effects of temperature, Ti02 content in the slag and basicity on vanadium distribution between slag and hot metal were investigated by experiment and thermodynamic calculation. The results indicated that high temperature, low Ti02 content and high binary basicity of slag were beneficial to increase the vanadium distribution ratio. The effects of temperature and Ti02 content in slag on vanadium distribution were stronger than that of slag basicity.IntroductionVanadium is an important element that is widely used in industrial fields. Most of vanadium resource is hosted in vanadium bearing titanomagnetite [l]. Vanadium bearing titanomagnetite is thus one of the domainate raw materials to produce the vanadium products. In other words, the comprehensive utilization of vanadium bearing titanomagnetite is beneficial for vanadium resource utilization. Vanadium bearing titanomagnetite sources are abundant in Pan Xi of China [4]."

Jan 1, 2013

By S. Yalcin, S. Chang, M. Oliazadeh

"Present day ferrochrome demand is on the rise, as more steel products require this material as an alloying element. It is projected that the stainless steel demands will grow by about 6% per year to 2020; as such, the supply and demand for ferrochrome appears promising. Chromite is the only economical source of chromium, which is commonly upgraded by gravity techniques and used to produce ferrochrome. The gravity separation methods are not able to treat particles finer than 0.1 mm efficiently. Therefore, in processing chromite ore, a large quantity of fine tailings; some 25% of the mineral values have been reported as lost in slimes during processing. The chromite content of these tailings is typically 10-20% Cr2O3 and accumulates into a large stockpile/pond. A chromite concentrator project in Canada, considers a cut-off grade of 20% Cr2O3. This indicates further processing might be required to recover chromite from low-grade stockpile when the high-grade deposits are depleted. Low-grade ores normally indicates disseminated chromite ores with low liberation and consequently fine comminution. This paper reviews the techniques for treating chromite from fine material and provides some examples of successful operations in fine chromite recovery. Beneficiation techniques for fine particles include gravity separation, magnetic separation, and flotation. Several case studies are presented here that used one of the aforementioned methods or a combination of them.INTRODUCTIONChromium is one of the essential element and important material for production of ferrochrome alloys and special steel. Chromium occurs as chromium spinel, a complex mineral with chemical composition of (Fe, Mg) O (Cr, Al, Fe)2 . Chromite ore is exclusively found in ultramafic igneous rocks. Major associated gangue minerals are talc, quartz, serpentine and iron oxides.Chromite is a heavy mineral, with a specific gravity in the range of 4-5, relative to associated gangue minerals in a chromite ore, which makes gravity concentration a suitable process. This is generally true for coarse particles, ranging from 1 mm to 100 mm. Typically, the ore is prepared by crushing (and grinding if necessary) to a suitable size and the material is sized for the appropriate beneficiation techniques. It is common to use heavy medium separation (e.g. dense media drums, dense media cyclones, or Dyna Whirlpool) to treat coarse size and intermediate size particles (1 – 100 mm). Intermediate and fine particles (20 – 0.1 mm) could be treated by jigs. Spirals, shaking table, sluices, and Reichert cones can upgrade fine particles. Figure 1 shows a typical chromite beneficiation process flowsheet. As can be seen, it consists of three major sections: feed preparation (crushing, screening), de-sliming, and concentration. Beneficiation recoveries range from 80 to 85%, although the ratio of upgrading is only 2 to 3."

Jan 1, 2013

By Simon St. John Tose

We have had a long history in supporting the development of training material to ensure “safe” blasting. This has been provided as both significant technical guidance to the industry and input into the development of the new industry surface rockbreakers or shotfirers qualification in South Africa (RSA). The learning material supplied to the industry is based on both a classroom knowledge component and an assessment on the practical application of the learning by the trainee blaster on the job under the supervision of the appointed blaster. This training includes all blasting applications which can often extend beyond the “normal” mining environment of open pits, underground and quarries into civil applications such as trenches, blasting close to private buildings, public roads, pipelines, power lines, swimming pools and the removal of concrete structures and building demolitions etc.

Jan 1, 2013

By Tex M. Kubacki

On August 6, 2007, the Crandall Canyon Mine experienced a collapse which trapped six mine-workers. An MW 4.1 seismic event was recorded in conjunction with this collapse. An additional 54 seismic events were detected and located in the vicinity via routine processing techniques during the month of the collapse. Waveformbased cross-correlation detection techniques have been used to uncover 1,328 small, previously undetected seismic events which occurred near the collapse area between July 26 and August 9, 2007. This work has resulted in lowering the magnitude threshold of completeness from ML 1.6 to ML -0.5, a 2.1 order-of-magnitude improvement over standard processing techniques. Event locations have been computed using a double-difference inversion. The spatial pattern of events ultimately helps to delineate the extent of the collapsed area. It is shown that many of the large catalogued events (>ML1.6) tend to be closely followed by numerous (often 20 or more) smaller aftershocks. Cluster analysis of the known catalog reinforces prior work indicating the existence of seismic clustering on the east and west sides of the collapse. Research now demonstrates that it is possible to differentiate events related to the main collapse from those related to the rescue attempt following the collapse. The cross-correlation techniques described herein greatly improve the ability to detect small mining-induced seismic events. These methods may lead to improvements in assessing seismic hazards for conditions similar to those observed at Crandall Canyon preceding the collapse.

Jan 1, 2013

By Peter W. Lipman

Structural and topographic relief in the Sangre de Cristo Mountains of northern New Mexico provides a remarkable cross section through the recently recognized 23-26 m.y.-old Questa caldera and cogenetic volcanic and plutonic rocks. Although largely eroded, remnants of an ash-flow sheet of silicic-alkalic rhyolite and associated more mafic lavas of the Latir volcanic field are preserved as far as 45 km beyond the source caldera. Within the caldera, the tuff ponded to a thickness of 2-3 km and enclosed chaotic megabreccia fragments which slumped from the caldera walls. At the time of ash-flow eruption, the volcanic field was severely deformed along northwest-trending faults related to the Miocene Rio Grande rift, with most intense deformation occurring within the caldera. Strata were steeply tilted and locally overturned along presumably listric faults. Ash- flow tuffs locally underwent secondary flowage over concurrently developing fault scarps and accumulated within structural basins as rheoignimbritic lava flows. Cogenetic batholithic granitic rocks, exposed over an area of 20 x 35 km, range from mesozonal quartz monzonite to epizonal porphyritic granite and aplite, with the shallower and more silicic phases most abundant within the caldera. Compositionally and texturally distinct granitic phases define a highly evolved resurgent intrusion within the caldera, an incomplete ring dike along its southern margin, and a large mass of less fractionated quartz monzonite south of the caldera. A negative Bouguer gravity anomaly is closely confined to the area of ex- posed granitic rocks; it also reflects boundaries of the Questa caldera. The gravity anomaly is interpreted as defining the extent of the underlying batholith, emplaced into lower parts of the volcanic sequence and underlying Precambrian rocks. Paleomagnetic determinations indicate that the granitic rocks were above Curie temperatures at the time of caldera formation and regional listric faulting, yet most are little different in radiometric age from the intensely deformed volcanic rocks. These relations indicate that the batholithic complex represents the source magma body for the volcanic rocks, into which the Questa caldera collapsed, and was largely liquid at the time of regional tectonic disruption. Compositions of the volcanic and plutonic phases changed from early calc-alkaline metaluminous rocks, to weakly peralkaline silicic rhyolite and equivalent afredsonite-acmite granite at the time of the caldera formation, then back to post- caldera calc-riebeckite granitic rocks. Maximum concentrations of alkalis and minor elements such as Rb, Th, U, Nb, Zr, and Y were reached at the time the caldera formed about 25-26 m.y. ago, but the major molybdenum mineralization of the Questa district took place when the late calc-alkaline granitic ring intrusions were emplaced about 23 m.y. ago, along the south margin of the caldera.

Jan 1, 2013