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By I. A. Mwamba

Plain and alloyed titanium aluminides of composition Ti-47.5 at.% Al were prepared by melting commercial-purity titanium and aluminium with additions of 1 at.% precious metal. The as-cast alloys were subjected to potentiodynamic scans in 5, 15, and 25 wt% HCl aqueous solutions at room temperature and compared for their abilities to spontaneously passivate. Addition of precious metals resulted in a general improvement of corrosion resistance by increasing the open circuit potential to more noble values. Addition of 1 at.% gold or silver to titanium aluminide did not significantly increase the corrosion potential (Ecorr) above that of the plain titanium aluminide alloy, indicating that gold and silver are not sufficient cathodic modifiers to improve the corrosion resistance of titanium aluminide in all the solutions tested. However, platinum, palladium, and iridium additions shifted the corrosion potentials to the position of the passive region of plain TiAl for all solution concentrations. This indicated that TiAl alloyed with these platinum group metals would passivate spontaneously by cathodic modification. TiAl alloyed with palladium performed the best in 5 wt% HCl solution with the most positive corrosion potential. In 15 wt% HCl solution, alloys with platinum exhibited the most positive corrosion potentials, while alloying with iridium or palladium revealed more negative corrosion potentials. Thus, palladium alloying led to the best cathodic modification of titanium aluminide in low-concentration HCl solution, whereas platinum and iridium alloying additions resulted in the best cathodic modification of titanium aluminide in high-concentration HCl solutions.

Jan 1, 2013

By Rohan Stevens, Katsuhiro Kameyama, Osamu Iwata, Jinming Liao

In densely populated cities such as Hong Kong, where unoccupied space is becoming more valuable as the population grows, city planners are more often looking to underground space to meet the increasing need for transportation and services. Given the dense population of people, amenities and high-rise buildings above or near such underground space, it is essential to minimise any disturbance and potential damage during construction. Hence, the excavation of hard rock to develop such underground space can be highly restricted, expensive and time consuming. This is the case for many of the tunnels currently being excavated by drill and blast directly underneath Hong Kong’s busiest business districts and most popular residential areas.

Jan 1, 2013

By C. Kunze

ABSTRACT Although closure sureties cover works that are carried out during the existence of a mining company, certain liabilities are not known when the surety is established and become apparent only in a late stage of the closure phase, or even after the site has been relinquished. This paper supports the concept that these financial risks lend themselves to insurance solutions. Making insurance for unknown liabilities mandatory while defining unambiguous legal conditions could create a viable market for insurance products, provide a sufficient statistical basis for the calculation of premiums, and reduce costs.

Jan 1, 2013

By Perry Sisk

In order to protect nearby structures during a blasting project, a peak particle velocity limit is often stipulated by a government agency or the owner of a particular structure. At the start of a blasting project, a preliminary estimate for the minimum scaled distance is often determined using a vibration prediction equation before any site-specific data have been obtained. Reasonably conservative assumptions are typically made for the unknown input variables in the vibration prediction equation until site-specific blasting data have been obtained and evaluated. Although this approach is prudent, it provides no assurance that the peak particle velocity values generated during the initial phase of the project will be below the specified limit.

Jan 1, 2013

By Mike Muchard

STATNAMIC load testing augmented with embedded instrumentation has been successfully used to obtain structural and geotechnical design information on large diameter spun cast concrete cylinder piles on many large marine construction projects. The paper focuses on one particularly interesting large marine project involving a new bridge to St. George Island, Florida where instrumentation and STATNAMIC load testing was used in conjunction with static load testing on high capacity piles. The information presented includes embedded instrumentation measurements taken during pile fabrication (post-tensioning), during pile driving, during static load testing, and STATNAMIC load testing. As much of this data is the first of its kind on concrete cylinder piles, it is exciting to present the foundation industry with this additional insight as to the behavior of this pile type and the accuracy of the methods used to test them.

Jan 1, 2013

By P. J. Petit

Changing mining conditions, legislative issues, rising costs, and the constrained supply of skills and electricity in South Africa, have been some of the criteria forcing mine operators and engineers to review the traditional use of compressed air to power underground hand-held drilling operations in narrow-stope, hard-rock mines. In answering the question, 'What is the best way to power this mine?', they have resorted to trade-off studies with results of limited usefulness, because they are site-specific, and use only a few comparative parameters, based on a small data set. This paper aims to provide definitive, objective, and quantitative decision-making approaches to evaluating alternative energy-delivery systems for stoping in narrow-reef hard rock mines, based on primary and relevant criteria. These include quantifiable criteria such as capital expenditure, operating costs, resulting financial returns, energy and water usage, production performance, life-of-mine, etc. Other important criteria with qualitative aspects are integrated. These are safety, health, and environmental concerns, legislative requirements, business risk, technology change, etc. The paper begins with a review of decision-making processes available, and proposes the use of the analytical hierarchy process (AHP) method as a multiple-criteria decision-making tool and the decision tree based on milestone-driven uncertainties, to validate the selection of the energy delivery system. The results of a multiple-criteria questionnaire completed by a variety of industry experts and professionals, such as production and operation managers, consultants, suppliers, and techno-financial analysts, are discussed. The evaluation indicates the potential for hydropower to be the best solution for narrow-reef hard rock mines, based on current information, mine design layout and production.

Jan 1, 2013

By R. Boom, B. Kraaijveld, H. Kuntzel, Y. Meteleva-Fischer

"Alloying refining with rare earth elements followed by acid leaching was examined for the potential of upgrading of metallurgical grade silicon. Microstructure study of silicon alloyed with small additions of rare earths showed behavior relatively similar to the influence of calcium addition. After alloying with neodymium the phosphorus content was detected in various intermetallic silicides containing neodymium and iron. The content of lanthanum and neodymium in refined silicon was by several times lower than that of aluminium and calcium. Alloying with lanthanum and neodymium at smaller additions than calcium reduced the phosphorus content down to the same level. The efficiency of lanthanum and neodymium in removal of boron and phosphorus at the 1-2 wt% of their additions and their low solubility in silicon make the alloying with these metals followed by acid leaching an attractive option for the refining route of metallurgical grade silicon up to solar grade.IntroductionA striving for a cheap ""green"" energy directs the research interests in silicon solar cells towards new efficient refining routes for metallurgical grade silicon (MG-Si, -98% purity). The silicon price determines up to high extent the solar module's price, so that cheap and efficient metallurgical process is awaited. The research challenge is to fulfil the purity requirements of solar grade silicon (SoG-Si, 6N) by competing with the energy-consuming and environmentally unfriendly Siemens process. Most difficult impurities to remove are boron and phosphorus, so technologies dedicated to their efficient removal attract an attention of industry and academia.Alloying refining (also known as solvent refining) is one of the most promising refining options, which is based on a principle of solid-liquid extraction using limited solubility of impurity elements in solid silicon [ 1]. Various elements were proposed for alloying refining: aluminium [2], calcium [3], tin [4], iron [5], copper [6] etc. The attractiveness of the alloying refining is in decreasing a melting point of the metal mixture and an affinity of the alloying element to the most harmful impurities, especially to boron and phosphorus. However, the difficulties are still faced due to self-solubility of the alloying elements, their low affinity to boron and/or phosphorus, silicon losses and necessity of removal of the silicide impurity phases in an additional step, using acid leaching [7], fractional melting [ 8] etc."

Jan 1, 2013

By D. Wolfe, R. Cleminson

"The Aurora North mine has been operating for more than ten years, and is the source of over half of Syncrude’s bitumen production. The slurry systems at Aurora experience high rates of wear, and mission lengths on current slurry pumps are nominally 1500-2000 hours. Recent work has enabled a better understanding of the significant adverse effect of large particle impingement damage to impeller vane leading edges - which is the known life determining issue for Aurora hydrotransport pumps. A new pump design has been developed with a larger diameter impeller and increased vane lengths, and is expected to triple Aurora’s mission length for hydrotransport pumps.INTRODUCTIONSlurry Pumps are Critical Equipment at SyncrudeSlurry pumps are a critical component in Syncrude’s operations. In a typical Aurora application, each pump stage helps move over 8000 dry tonnes per hour of oil sand, plus an equal volume of process water that has been added to create the slurry. The average impeller life in oil sand hydrotransport service at Aurora has been nominally 1500-2000 hours, or 12-16 million tonnes of oil sand pumped. Generally, the slurry pump application at Aurora has proven very difficult to improve due to the unique combination of high sand abrasivity, 125 mm (5”) large particle top size (lumps), and high flow rate relative to basic pump size; a factor that results in higher than optimal impeller vane speeds for the service conditions.PROJECT BASISSlurry Pumps are the Reliability Bottleneck at AuroraSlurry pumps are currently the shortest-lived components that determine the overall system run length at Aurora, in Hydrotransport, Extraction and Tailings. Vibrating screens and piping had been previous bottlenecks, but their reliability has been improved through upgrades in equipment design and wear materials. Both vibrating screens and piping can now achieve 4000 hour mission lengths."

Jan 1, 2013

By Filippo Leoni, Wesley Schmutzler

"The LPV-111 East Back Levee Improvement Project lies along the Gulf Intracoastal Waterway (GIWW) in Orleans Parish of New Orleans, La., and is an essential component of the New Orleans Hurricane Protection System. The Hurricane Protection Office of the U.S. Army Corps of Engineers (USACE) attributed failure of the New Orleans East levees system to overtopping, erosion and subsequent breaching of LPV-111 along the GIWW, as well as other sections of flood protection during Hurricane Katrina in 2005. The existing levee suffered extensive damages from Hurricane Katrina, such that the USACE elected to provide earth stabilization and to rebuild the levee sections. Due to the adverse geotechnical properties of the foundation soils, the Corps deemed ground improvement necessary to stabilize the new levee and to limit its footprint. Wet Deep Mixing Method (DMM) was selected as the most suitable technology for this task.ChallengesDesign: This reach specifically protects East New Orleans and the Bayou Savage National Wildlife Refuge, the largest urban wildlife refuge in the U.S. and home to several threatened or endangered species of birds as well as many reptiles, amphibians and small mammals. The Corps chose DMM due to the sensitivity of the protected marshlands and because the method limits the footprint of the raised levees. The increase in the load bearing capacity of the treated soil significantly decreases the footprint necessary to attain the required height increase. This limitation required the new levee to have steep slopes, drastically increasing the surcharge on foundation soils characterized by overall poor geotechnical properties (soft clays and peats). The design also considered the increased horizontal stresses on the levees due to the extreme storm surges during a hurricane.The design of the 1.6 m diameter (5.25 ft) DMM elements called for overlapping them to form a double auger element that formed buttresses perpendicular to the levee alignment. The contractor installed the buttresses at a maximum on center spacing of 4.7 m (15.5 ft). One additional double auger DMM element was midway between consecutive buttresses at the centerline of the levee to further help prevent settlement (Figure 1)."

Jan 1, 2013

By M. Rakoma

Following the blasting fatality on 17 December 2009, Landau Colliery was forced to change from the blasting practices that had been utilized since the start-up of the mine. Since then, attempts have been made to optimize blasting results. The challenge is rooted to the mining environment - during the early life of the mine, mining took place in virgin areas, whereas currently mining is taking place in areas overlying old underground bord and pillar workings. The underground bord and pillar workings aggravate phenomena such as spontaneous combustion, hot holes, and sinkholes. The 2009 fatality was attributed to hot holes causing premature detonation. Landau has been struggling with poor results from their overburden and coal blasts; leading to poor fragmentation of overburden and the PI parting that lies between the No.1 and No.2 coal seams. An extensive literature survey was completed in order to identify possible alternative solutions that could be evaluated for this unique mining environment, which demands a high degree of caution during mining to ensure factors such as dragline stability and personnel safety. The literature survey confirmed that the previous blasting technique, which was mainly characterized by air decking, was indeed the more efficient, although it was deemed unsafe because of the possibility of hot holes and the high sensitivity of detonators. Potential modifications to the blasting technique were modelled in a Microsoft Excel simulation that was available from the mine, and pit visits were conducted in order to determine whether implementation would be a problem. From the model it is evident that results can be improved by changing the current burden and spacing ratio. Visiting the pit revealed that the tie-in pattern and drilling inaccuracies are contributing to problem areas.

Jan 1, 2013

By S. Gopalan, J. D. Milshtein, S. N. Basu

Production of syngas is proposed utilizing the W/W03 redox system and employing a solarpowered two-step thermochemical cycle. Three chemical reactions occur in two chambers. Assisted by a solar concentrator, a high temperature reaction reduces W03 powder to metallic tungsten in both chambers. Subsequently, the temperature in one of the chambers is lowered and H2(g) is produced via re-oxidation of the tungsten powder using steam. The temperature in the other chamber is simultaneously lowered to an intermediate temperature and CO(g) is produced via oxidation of the tungsten powder using C02(g)· The gas streams coming out of the two chambers result in the syngas production. A complete thermodynamic analysis of the system is described. The W/W03 redox cycle offers greater gravimetric fuel productivity compared to previously proposed systems, and the entire cycle can be operated below 1273K.

Jan 1, 2013

By Mike Lovitt

New Gold Inc. had commissioned Orica to assist with the design of the drawbell blasting at New Afton Underground copper/gold block cave at Kamloops, British Columbia, Canada. Orica have had much success in developing the single-shot drawbell method at Freeport Indonesia in 2001 in the Deep Ore Zone and they will be using it exclusively in their new Grasberg Underground Operation. RioTinto Northparkes have also used the single shot drawbell blasting in their Second Lift E26 Project and even in the E48 orebody which is a post undercut block cave, realising the safety and operational benefits of this blasting method.

Jan 1, 2013

By Richard E. Sylwester

Evaluating surface and subsurface conditions for marine foundations (bridges, causeways, terminals, etc.) is often done with a limited amount of data. Subsurface information for these projects is primarily acquired using traditional methods, such as boreholes, test pits or divers, which tend to be expensive and limited in the area of coverage. A number of geophysical methods, including precision bathymetry, sidescan sonar, and seismic reflection or subbottom profiling are extremely cost-effective and obtain significantly more data than can be acquired using traditional intrusive methods. These geophysical methods provide detailed surface images and continuous profiles of the subsurface stratigraphy. This information can be invaluable for selecting the best location for geotechnical boreholes and to map potential geohazards such as submarine slides and filled or open scour holes. Offshore investigations conducted for a proposed highway bridge (Knik Arm Bridge, Cook Inlet, AK), the retrofit of two existing bridge (Antioch and Dumbarton Bridges, CA) and a proposed cruise ship terminal (Ketchikan, AK) used a combination of geophysical methods to map water depth, detect and map debris on the seabed, map the thickness of unconsolidated sediment, determine the depth to bedrock and identify potential geohazards such as scour holes. The results of the geophysical investigations will be used to select locations for obtaining geotechnical borings, to extrapolate geologic information between existing or proposed boreholes, evaluate the potential depth of scour and design a pile support pier. Geotechnical engineers, offshore contractors and bridge designers are realizing the importance of the early use of offshore geophysics for (i) site characterization, (ii) to reduce the uncertainty of geotechnical conditions thus avoiding designs that may be overly conservative and thus more expensive and (iii) to assist in selecting locations for geotechnical borings.

Jan 1, 2013

By Andrew P. Gize

The analytical approaches used to solve a specific problem are dependent upon the information required, coupled with limitations imposed by available facilities, costs, and time. The organic matter associated with ore deposits has the potential to yield information for two problems. Information can be obtained to provide guidelines for prospecting, and, secondly, to solve genetic problems. A major potential of organic matter in providing prospecting guides lies in the high thermal sensitivity of organic matter in sediments which are metamorphosed at grades lower than greenschist facies. The organic matter can then be used to map thermal anomalies potentially associated with mineralization. The analytical approach is to determine the thermal maturity of the total organic matter, or of specific fractions, using techniques which are relatively quick and inexpensive. Consideration of genetic models (for example, reduction, complexing, involvement of oil field brines) generally requires more specific information than the overall thermal maturity of the organic matter, necessitating infor¬mation on molecular composition and structure. The facilities, time, and cost of this information are greater than for mapping thermal anomalies. The analytical techniques discussed include elemental analyses, spectroscopy (infra-red, visible and ultra-violet), Fourier Transform infra-red, nuclear magnetic resonance, extraction, pyrolysis techniques, chromatography and mass spectrometry.

Jan 1, 2013

By Guo Chen, Yifeng Shi, Xiaobiao Shang, Nanshang Shen, Bangqi Zhang, Jinhui Peng, Junruo Chen

"The energy is introduced directly into the volume of the honeycomb ceramic regenerator due to the complex interaction of microwaves with minerals in microwave gas heating system. A three-dimensional numerical model is developed to simulate the electromagnetic field by solving Maxwell's equations using finite-difference time-domain method. Computational result is presented for the microwave power absorption of the regenerator. Effects of the dielectric constant and the effective loss factor on the microwave power absorption in the regenerator are studied as well. Numerical results show that the heating pattern strongly depends on the dielectric property of the regenerator. The demonstration of the model of electromagnetic field distribution can be applied effectively and efficiently to optimize the fundamental parameters in the microwave heating processing.IntroductionIn recent years, microwave energy has been utilized in many fields, such as food processing, chemical engineering and mineral processing [l]. In contrast to conventional heating, where heat is transferred from a surface to the interior, microwave energy is introduced directly into the volume of minerals due to the complex interaction of the microwave with the mineral. Based on volumetric heating effects, microwave heating has several advantages such as pollution free, rapid heating technique, internal heating, high efficiency over conventional heating [ 1-4]."

Jan 1, 2013

By Gary Cavanough, Stuart Addinell, Hector Parra

Drilling deep, straight, accurate holes in hard rock to achieve efficient blasting is a challenge for the mining/quarrying industries with short holes normally drilled using “top hole hammer” (THH) and deep holes using “down the hole Hammer” (DTH).

Jan 1, 2013

By Jack Eloranta

The winning of metals often requires fine grinding of very hard ore. The US Bureau of mines measured compressive strengths exceeding 100,000 PSI (700 MPa) in Minnesota taconites. Grinding down to 300 mesh (50 µ) is required for some fine-grained taconites. While other metal ores may not be as strong, significant grinding costs are the rule rather than the exception. One author recently reported that a 7% drop in grinding costs would fully offset a doubling of the drill and blast budget. Another author found that drill and blast costs were 13% of the costs of producing iron ore concentrate while fine crushing and grinding were over 60% of the cost of producing concentrate.

Jan 1, 2013

By M. Nduna

Surface properties of metal sulphides have a great significance in various areas of engineering and science, such as acid mine drainage, contaminant sorption, and metal separation. In various attempts at producing metal sulphide particles from synthetic solutions, prodigious quantities of nuclei that grow only to colloidal dimensions have been frequently reported. This copious nucleation is promoted by the high levels of supersaturation that characterize most precipitation reactions. Colloidal particle formation in precipi¬tation-based separation processes results in sub-optimal solid-liquid separation, which is alleviated by the production of more highly crystalline particles or agglomerates. The current work approaches this challenge from an electrochemistry perspective, by measuring surface charge potential of precipitant particles during metal sulphide precipitation with respect to the concentration of metal sulphide lattice ions in solution. Electrophoresis was used to measure the metal sulphide particle zeta potential and the settling properties were obtained by performing settleability measurements using an Imhoff settling cone. A suspension of copper sulphide particles was precipitated from synthetic solutions of copper and sulphide ions at equimolar concentrations. Immediately after precipitation the copper sulphide particles had a zeta potential of -50 mV and a settleability of about 7 ml.l-1. With the addition of copper ions the settleability increased by a factor of nearly three times and the zeta potential also increased to a maximum of -40 mV. A decrease in zeta potential to a minimum of -60 mV was observed after the addition of sulphide ions and this was associated with a settleability of 0 ml.l-1.

Jan 1, 2013

By Marcio Toshio Tanaka, Marcelo Breda Mourao, Cyro Takano, Cesar Yuji Narita

"The concerns in questions related to the environmental impact in the steelmaking industries caused mainly on the gas emissions such as the dioxide carbon are due to its raw material such as the coal, a fossil and non renewable resource. The purpose of this paper is to replace from 10% to 50% of the coal used in cokemaking by mixing it with a renewable source (wood charcoal). The powder (- 325 mesh) from both raw materials (coal and wood charcoal) were mixed in order to obtain a briquette that was then heat treated at 1100°C to obtain the biocoke. Results of usual analysis (coke reactivity index, coke strength after reaction and cold crushing strength test) were employed to compare to regular coke briquettes. It was found that biocoke with different amounts of wood charcoal present features enabling it to be used in some ore reductionprocesses.1. IntroductionThe iron and steelmaking industry is a heavy emitter of carbon dioxide; according to the World Steel Association, 6.5% of global emissions of this greenhouse gas is due to the production of ferrous materials [ 1]. This is due to the fact that the fuel and reductant employed in the blast furnace is metallurgical coke, obtained from fossil coal. There are some projects aiming to reduce or even eliminate the emission of fossil GHG in the iron and steelmaking process [2]. Most of them propose the capture and storage of the gas (CCS) [3], a technology not yet proven. Other studies point out that the coke consumption in the blast furnace could be reduced by using high reactivity coke; this could lead to lower temperatures in the thermal reserve zone of the blast furnace and consequently less fuel rate in the furnace.The use of biomass in the iron ore reduction process is known as an environmentally accepted solution, as biomass does not release already fossilized carbon."

Jan 1, 2013

By G. W. Sparkes

The use of CR-39 plastic polymer as a solid state nuclear track detector in the textural analysis of radioactive minerals in geological samples was first described by I.R Basham in 1981. CR-39 autoradiographs provide a detailed, high-resolution image of the in situ distribution of the radioactive minerals within geological samples on both the macroscopic and microscopic scales. This technique is an inexpensive and effective means of obtaining detailed textural information that provides insight into the style of mineralization, its relationship to primary and secondary structures in the host rock, and its association with particular geological features or mineral phases. Although this technique does not provide any information on the identity of the minerals responsible for the radioactivity, the resultant autoradiographs can be used to select regions for further detailed analysis such as petrography, microprobe analysis, or SEM imaging. This paper summarizes the procedure and outlines the appropriate time and materials required for both the exposure and etching of the CR-39 with respect to the intensity of the radioactivity emitted by the geological samples.

Jan 1, 2013