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By S. Castro

The aim of the present paper is to review the current technologies for arsenic removal in the copper metallurgical industry, and to show the progress made with some promising emerging strategies, involving the pre-treatment of copper-arsenic concentrates by selective flotation or by alkaline leaching with Na2S-NaOH solutions. The advantages of alkaline leaching are the selective dissolution of arsenic and antimony, the high extraction yield, and the practically nil loss of copper, which remains in the clean copper concentrate as a CuS residue. Alkaline ?cured? ? a procedure similar to ?acid-cured? in conventional leaching ? improves arsenic extraction and reagent consumption, making this an interesting technology for the treatment of high As-Sb concentrates. In light of recent advances on the selective flotation of enargite and tennantite, the importance of redox conditions to control the flotation/depression of enargite-tennantite from copper sulfides has been well established. However, problems of selectivity must still be solved. Additionally, the limitation imposed in some cases by the need to recover the molybdenum by-product must be considered. The application of selective flotation to obtain a high-arsenic or ?dirty? concentrate and its sub-sequent treatment by the alkaline leaching process is suggested.

Jan 1, 2014

By Zhihe Dou, Yu Fang, Zimu Zhang, Yan Liu, Xiaoli Jiang Dianhua Zhang, Guanting Liu

"With the idea of “waste control by waste itself”, we come up with the crafts of using waste calcium carbide to mineralize CO2 in electrolytic aluminum waste gas, design and make out “Venturi gas-liquid-solid three stage reactor”, do experiments under the system of CO2-Ca(OH)2, investigate the influence on gas absorption by pH meter; investigate the influence on diameter distribution , rise velocity of bubble and local gas hold-up by dual conductivity probes; investigated the absorption of CO2 in every stage reactor under different initial proportion of CO2 by intelligent gas measurement system. The results showed that the reactor can fully absorb the CO2 in waste gas, and it has largely shorten the time of absorption and improve the CO2 utilization compared with the single stage reactor.The residual proportion of CO2 in the gas is below 0.08% through the absorption of three stage reactor,which show that absorption is extremely improved.IntroductionCarbide slag is a kind of polluting hydrolysis reaction byproducts in producing carbide in wet reactor, and it is mainly comprised by Ca(OH)2, It's estimated that there are about million tons carbide slag are piled up per year. Carbide slag is a kind of industrial wastes that hard to deal with ,which are treated by land filled in the past. It would not only occupy a lot of land, but also lead to secondary pollution [1].CO2 is the main greenhouse gas by now. In 2010, global CO2 emission has reached 33.5 billion tons, while China has now become the world's second largest emitter of CO2, emissions accounting for about one-seventh of the world [2].As the experts estimates, the greenhouse gas emission of whole nonferrous metal industry may over 0.6 billion tons per year, while CO2 emission of electrolytic aluminum is 0.334 billion tons per year [3]. So it is necessary and pressing to discover the reusing CO2 of electrolytic aluminum. With the idea of “waste control by waste itself”, we came up with the crafts of using carbide slag to mineralize the CO2 in electrolytic aluminum waste gas, which was experimented on the counterflow-three stage-venturi reactor,and studied the local gas holdup, residual concentration of CO2 and the volumetric transfer coefficient in the reactor."

Jan 1, 2014

By Renn Oler

Corrosion can often cause significant strength reduction and failure of steel rockbolts, thus demanding continuous rehabilitation and posing challenges to underground mines in maintaining long term ground support. The mining industry has traditionally applied galvanized and epoxy coatings for protection of ground support and reinforcement in corrosive environments due to cost considerations. However, under a harsh and corrosive groundwater condition with extreme pH levels, failure of the existing coated rockbolts often results in failure and falls of the mine roof, especially in long-term mine drifts or entries. To prevent the roof falls induced by corrosive bolt failure, DSI developed a new polymer coating, called ?Obduro AP coating,? to combat harsh and corrosive ground conditions. The new polymer coating was tested in extreme conditions to identify weaknesses and was found to be capable of handling highly corrosive mine water solutions. This paper highlights the challenges faced by underground mines with corrosive bolt failure and shows that the DSI Omega BoltTM can withstand the most corrosive ground conditions when it is coated in the new, economic Obduro AP coating.

Jan 1, 2014

By Longjiang Li, Mao Jiang, Zhihui Shen, Guizhou University, Yin Pan

This paper aims to study the influence and action mechanism of collector Y-89 on the flotation of auriferous pyrite. The measurement to identify adsorption quantity, IR and XPS spectrum analysis and flotation experiment made on the pure mineral were conducted. The research results show that when the dosage of MIBC is 20 mg/L, and pH of 8, the dosage of Y-89 over 60 mg/L, the pyrite recovery rate is greater than 80%.And when the dosage of Y-89is 60 mg/L, dosage of MIBC 20 mg/L, the pH in a wider range (pH=4~9), the recovery is greater than 75%. When the pH is above 10, the pyrite is depressed and its recovery rate is found to be dramatically dropping. Adsorption quantity measurement also shows that the strong alkaline conditions inhibit the adsorption of Y-89 on the surface of auriferous pyrite. IR measurement indicates that chemisorption of Y-89 occurs on the surface of auriferous pyrite. XPS spectrum analysis indicates that without adding Y-89, oxidation reaction occurs on the surface of pyrite. But when Y-89 is added, the chemical environment of Fe on the surface of pyrite has changed. Such findings indicate that with Y-89, chemisorption occurs on the surface of auriferous pyrite.

Jan 1, 2014

By T. Crivits

"Phase equilibria in the ‘Cu2O’-‘Fe2O3’-SiO2 system, the base slag system in copper production, were recently determined. However, the addition of MgO, commonly present in the slag, drastically changes the phase equilibria in this system. The present study focuses on the phase equilibria in the ‘Cu2O’-‘Fe2O3’-MgO-SiO2 system in equilibrium with metallic copper.Recently, an experimental procedure has been developed that resolved a number of experimental difficulties. This procedure has been successfully applied to characterise several complex industrial copper slags. It includes a high-temperature equilibration followed by rapid quenching and electron probe X-ray micro-analysis (EPMA). The methodology was adapted to the present system and used to determine the liquidus at SiO2 saturation and in contact with high-MgO phases in between 1100 and 1250 °C in Cu2Orich slags.The results indicate a maximum solubility of MgO in the system at 1200 °C of 5 wt%. The boundary line between tridymite and spinel lies 3-4 wt% closer to the SiO2 apex for every 2 wt% MgO added. These new data on the high-copper slags are important for optimisation of the direct-to blister"

Jan 1, 2014

By J. E. Sepulveda, R. Morrow

"The Linear Wear Theory provides a reliable framework for the assessment of grinding media performance at full scale. This theory can be applied for analyzing grinding media consumption rates in any given grinding operation as well as the evaluation of alternative grinding media products, based on actual operational data, correcting for conditions like ore hardness, feed and product sizes, mill power and circuit throughput; all of them unrelated to the grinding media intrinsic quality attributes. A series of Moly-Cop Tools 3.0 applications have been developed to facilitate the calculations involved. Moly-Cop Tools 3.0 is available, free of charge, to all interested parties through the corresponding author.INTRODUCTION Mineral grinding circuit operators recognize the significance of grinding media (balls) consumption on the cost structure of any full scale grinding facility. The effective cost associated with this essential consumable depends on two factors: delivered price and durability (quality) of the grinding media. When evaluating alternative grinding media varieties, there is a well accepted evaluation criterion by which a given media type is considered to be “cost-effective” when its unit application cost – normally expressed in $/ton of ore ground – is shown to be lower than that of a nominal reference condition: Grinding Media Cost = Ball Price x Ball Consumption (1) ($ /ton ground) ($/ton balls) (ton balls/ton ground) Under this criterion, an alternative, higher-price grinding media product could be “cost-effective” if its associated consumption rate is sufficiently lower than the reference media, enough to yield a lower grinding cost, as dictated by Equation 1. For the proper application of the above criterion, evaluators must rely on representative indicators of grinding media quality, ideally independent of most mill operating conditions. In each particular case, ball price is always a known component; however, it is not so evident how media performance (quality) differences amongst alternative product types could be assessed with a reasonable degree of accuracy and precision."

Jan 1, 2014

By E. Scheepers

Within a phosphorus producing submerged arc furnace it was found that the continuous fluctuation of the furnace between a flowrate-driven state (high throughput) and a thermodynamic-driven state (low throughput) caused both techniques to have similar overall, predictive abilities and resulted in a linear, ARX-type, adaptive prediction model as the model of choice. Secondly, this pre-diction model was developed, tested and then shown to have a reasonable, 8-hour-ahead predictive accuracy (R2, coefficient of determination) of 30% (±6%) on future Pslag values. This inherent relationship exists because, at the precise moment of a Pslag prediction, the furnace already contains the metallurgical memory (input variables to the linear model) needed to ensure that some predictive possibilities will always exists - all as a result of the long residence times in the furnace. Residence time, however, is not a directly adjustable variable but rather a fully dependent variable and a function of an array of interconnected and interactive variables. In fact, this applies to virtually all input variables, reemphasising the importance of innate metallurgical memory. Thirdly, predictive control possibilities were explored by simulating the set-points of two fully independent variables used by operators to control the process: the ratio of fixed carbon-to-P2O5 and the ratio of silica gravel-to-pellets. This linear, predictive control model showed only a slight improvement with an 8-hour-ahead predictive accuracy of 35% (±7%). This highlights how ineffective current adjustments are in optimally steering the process and how difficult even incremental improvements in feed-forward and predictive control can be. Finally, it is shown that fundamental design-, sampling- and process restrictions currently associated with the process will always limit the predictive and especially control accuracy or meaningfulness of any dynamic model. These restrictions include the size of the furnace resulting in long residence times, 8-hours sampling intervals, an extremely complex and interactive process and a 16% spatial analyses variation on the Pslag values ? the very value that the model is to predict. The point is made that, given the current status quo, even the perfect dynamic prediction model can not improve on an 8-hour-ahead prediction of 30% (±6%). This barrier can only be pierced with e.g. tidier and more frequent sampling regimes and other upfront capital investments, a decision that becomes a cost accounting exercise and that can only be taken by the management structure. An investment demanding ever-increasing attention is CFD software and it?s potential to shed more light on the complex interactions within the furnace.

Jan 1, 2014

By Arkady Senchenko, Yury Kulikov

"Basic theoretical grounds of the methods applied for crushing and grinding parameters determination according to international standards are given in this paper. Statistical data about crushability and grindability research are shown. The potential relationship between the values of Fred Bond Work indices and John Starkey indices (Crushing index, Ball mill index, Rod mill index and AG/SAG index) are discussed in this paper. In order to establish correlation between the crushability and grindability indices the analysis of over 2 500 tests for 165 deposits located in different parts of the world was performed. The relationships among different types of energy consumed for crushing and grinding were determined. A method for preliminary estimation of energy consumption in semiautogenous + ball mill grinding circuit is suggested for its application in preliminary technological solutions development and technical-and-economic assessment."

Jan 1, 2014

By W. J. Whiten

"Models of cone crushers and vibrating screens are described. These models have been constructed from actual plant data using a systematic model-building technique. Included in this technique is regression analysis using multi-dimensional spline functions.The models have been used to simulate complete crushing plants and hence to design and evaluate a control system for crushing plants."

Jan 1, 2014

By A. Bois-Brochu, G. Morin, G. Marin, M. C. Parr, J. Carignan

The presence of an alpha case on titanium parts produced by investment casting is problematic and has to be eliminated. The traditional techniques for the evaluation of its thickness are metallographic measurements and micro-hardness profiles. To obtain a better understanding of how the alpha case is formed with the underlying objective of limiting its depth, the present study proposes to characterize the microstructure and the chemical composition of the alpha case. Electron microprobe analyzer (EMPA) linescans were used to quantify the oxygen and substitutional elements that come from the mould and promote the alpha case formation. The chemical profiles were correlated with metallographic and microhardness measurements. For microstructure, optical microscopy (etched and polarized light analysis) was used. For phase analysis, samples were mechanically polished step by step and analysed using X-ray diffraction and optical microscopy. Furthermore, surface analysis techniques such as XPS and Auger Microscopy were evaluated but results were found to be inconclusive because the formation of the oxide layer was faster than its ablation and the matrix could thus not be analysed. The alpha case was observed on a Ti-6Al-4V step block casting.

Jan 1, 2014

By T. Holmes, D. C. Russell, G. Jolly

"The AMEC Oakville office is involved in the design and construction of an iron ore concentrator located in Liberia. Currently, the site ships Direct Shipped Ore (DSO) to overseas customers. The DSO mine-site and port can experience heavy annual rainfalls. The IMSBC Code requires that cargoes are only accepted for loading when the moisture content of the cargo is less than its Transportable Moisture Limit (TML). The moisture content of the DSO has, on occasions, risen to near or above its TML. AMEC was asked to advise whether the concentrate produced from the new concentrator would or would not have the same problems with moisture content and ship loading as the DSO.INTRODUCTION Liberia was, at one time, the world’s sixth largest exporter of iron ore and used some of the most modern mining operations of their time. However, the country has not produced iron ore over the past seventeen years because of civil unrest. The return of stability to the country has allowed the redevelopment of the iron ore industry. ArcelorMittal Liberia (AML) obtained a concession for mining in the Nimba County area of Liberia (Figure 1) in December, 2004 and has studied the known iron ore deposits and former mining operations in this area. It began phase 1 operations in June 2011 with the direct shipping of high grade ore at a rate of up to 4Mtpa. The processing of the lower grade ore in phase 2 of the project requires additional processing capability to produce at the design rate of 15Mtpa. DSO and Concentrate The DSO in the first phase is selectively mined at an average grade of 60% Fe, and then crushed and screened to -10 mm with no washing or concentration. Testing of samples has indicated a size distribution that is finer than typical sinter feed material, although critical material below 0.10 mm is low in most cases, and overall the ore is coarser than typical concentrates or ultrafine products (Feasibility study report, 2011). The phase 1 DSO facility will cease operation after the phase 2 concentrator comes into operation."

Jan 1, 2014

By Y. P. Huang

Experiment results and operation practice on reutilizing old tailings dumped at SCIM (Shang-chang Iron Mine) of KISCO (Kunming Iron and Steel Corp.) are presented. In a production period over 30 years SCIM dumped about 8 million tons of iron ore tailings. For improving resources utilization instead of wasting, experiments on processing for reutilization of the old tailings are con-ducted. These tailings are fine size fractions of weathered iluvial ores rejected out by classification- des-liming in ore washing and dressing processes, containing TFe 21%~22% in hematite mainly and limonite occasionally. Their particle size distribution, in average, is of 72.26% minus 0.037mm and 30.88% minus 0.005mm. Existence of plenty of micro-fine particles makes the tailings refractory to process, resulting in poor metallurgy. The whole sample of the old tailings without size-classification is fed into experimental process. Slon-100 type high grads WHIMS (wet high intensity magnetic separator) with cyc-pulsing is adopted, which magnetism-focusing rod?s diameter is changed from 3mm into 2mm. Operational conditions of optimizing rougher separation tests are strengthened. An iron concentrate assaying 52.21% Fe at quantity rate of 18.39% and iron recovery of 44.40% is obtained. Operational practice shows that metallurgy and economy of the old tailings treatment are close to what achieved at experiments. It is estimated, therefore, that some 1.4 million tons of this iron concentrate may be recovered from the old tailings. This means that KISCO has moved its key one-step in re-mining and reutilizing the secondary resources, which would be a good demonstration in this industry. This is also of social and economic significance in response to China government?s request on reducing consumption of resources and establishing society with economy for achieving sustainable development.

Jan 1, 2014

By S. J. Liu

The conventional collector for bauxite mineral is oleic acid, which is highly insoluble and must be used in high dosage in bauxite flotation operations, that is the great drawback of oleic acid in use. A series of hydroxamic acid were synthesized, and their collecting ability to certain minerals in bauxite: diaspore, kaolinite were studied. The collecting power of various reagents to diaspore in an incremental sequence were shown as follows: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<oleic acid<octylic hydroxamic acid; while the incremental sequence of the collecting power to kaolinite was like this: benzyl hydroxamic acid<amylic hydroxamic ac-id<heptylic hydroxamic acid<octylic hydroxamic acid<oleic acid. It could be seen that octylic hydroxamic acid had the capability of high collectivity and good selectivity, and octylic hydroxamic acid was chosen to use in the following experiments. Reduced zeta potential showed the adsorption of the anionic collector on the mineral. By the adsorptive capability and IR tests, the adsorption of octylic hydroxamic acid on diaspore was determined to be chemical absorption, which was greater than that of oleic acid, as it was physical absorption. Results of floatation experiments on manually mixed minerals indicated that the collectivity and selectivity of octylic hydroxamic acid were better than oleic acid.

Jan 1, 2014

By Y. M. Fu

In order to evaluate the flotation process, the process flow sheet was investigated. The process mineralogy of main products was studied. Through chemical mineralogical and screening analysis as well as surveying using a microscope and scanning electro-microscope, the oxidation degree and mineral composition of main-products the liberation of main minerals, the occurrence of elements such as Pb, Zn were revealed. It is pointed that to determine the flotation process, the type of prod-ucts optimum grind of original ore and middling was provided on the basis of liberation of main minerals is reliable. As correct finer ground original ore, first high-grade lead-concentrates and zinc-concentrates fast was floated from a great part of free of the galena and sphalerite of liberated. Then for finely re-ground middling of locked mineral grains of difficult liberation, mixing lead-zinc-concentrates second was floated. The four products was best in contact with characteristic of ore of Fan Kou. Therefore be obtained certain to successful economic effect.

Jan 1, 2014

By Dale Preece, Ayman Tawadrous

This paper presents a number of examples of three-dimensional blast modeling in both surface and underground environments that include time-delay explosive decking. These examples include: 1) quarry blasting, 2) coal seam protection blasting, 3) mineral mine blasting with high energy time delayed decks, and, 4) underground single-level/single-shot drawbell blasting.

Jan 1, 2014

By Nick Hazen

Many successful actions are required to bring a profitable extractive metallurgical operation into production. Competent process development performed within the project development schedule increases the chances of obtaining project financing and decreases the risk of engineering design errors being built into the commercial plant. The general sequence of steps in process development is well known: technology review, desktop studies, scoping studies, prefeasibility, and so on, with an increasing requirement for experimental evidence as the studies advance. This paper suggests principles for guiding process development work so that the efforts stay on track toward a smooth startup and a profitable commercial operation. It emphasizes closely aligning the research with the corporate goals of the mining company management, understanding the mineralogy and variability in the deposit, and guiding by flowsheet and material balance. Examples of hydrometallurgical process development leading to the early use of solvent extraction in the mining industry are given.

Jan 1, 2014

By T. Krumins, L. Zunti, R. Frischmuth

Mercury is known to occur in sulphide-bearing refractory gold deposits in the form of sulphide minerals or elemental inclusions. These deposits typically require an oxidative pre-treatment process, such as pressure oxidation or roasting, to achieve economic gold recovery. However, these processes also have the potential to liberate mercury, a portion of which may then be released to the environment through gaseous emissions. Mercury emissions from mine processing operations have been of particular interest in recent years, as governments impose lower emission targets and organizations adopt better industry practices to reduce the environmental and health aspects of releasing mercury into the environment. This paper describes various mercury removal technologies with respect to pressure oxidation gas handling circuits, with a focus on key design variables and technology selection criteria.

Jan 1, 2014

By Ernst-Ulrich Reuther, Alexander Donmen

Mine ventilation in the German coal mining industry is concerned mainly with problems of thermal environment arising from greater depths and with increasing emission of methane gas. The development of computer techniques over the past ten years for solving these and ancillary problems is reviewed. The emphasis from a planning and control point of view falls mainly on ventilation network calculations, temperature predictions and advance estimates of methane emission.

Jan 1, 2014

By Scott Martin

This paper will discuss the challenges currently facing the mining industry. By sharing experiences gained in the CIM Leading in Mining Course, I will highlight what’s working, what’s not, what are the challenges, what are the concerns, what are the opportunities, what needs to happen. Specifically, I will discuss what is currently happening with leadership and leadership development in members’ own organizations, what skill sets are important to develop in different hierarchical groups and how comprehensive leadership courses like the leading in Mining course can help improve leadership within individuals and the industry. Leadership development is a process not an event.

Jan 1, 2014

By L. W. Luo

Zeolite in some regions or countries of the world have been the subjects of materials for environmental remediation involving the use of removal to heavy metal ions and some organic pollutant as a sorbent because of its capacious ions exchange and huge surface area. This article addresses the equilibrium and kinetics for manganese adsorption using zeolite modified by hexadecyl trimethyl ammonium bromide (HTMAB) as a sorbent material over a range of pH between 3.4~7.2 with eight different Mn(?) solution concentrations. PHzpc (pH of zero point charge) of the sorbent was examined according to the method proposed by Tripathy and Kanungo, and a value of 6.91 was obtained. The experimental data fit langmuir?s model for the majority of pH and Mn(?) solution concentrations tested (0.92<R2<0.97). The maximal adsorption capacity, qm ascending with pH between 3.4~7.2, rise from 15.01mg?g-1 at 3.4 to 19.46 mg?g-1 at 7.2. Besides, the constant of Freundlich Kf have the same trend with qm, increases with pH ascending. And the sorption intensity, represented by parameter 1/n in Freundlich?s model, is favorable in entire range of metal ions concentration studied. Finally, kinetics data accurately fit to pseudo-second order which indicate that there must be sorption of Mn(?) behavior occurring on inner-sphere of the sorbent.

Jan 1, 2014