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By K. Osburn

South Deep Gold Mine, owned by Gold Fields Ltd., is situated near Westonaria in the Gauteng Province of South Africa and mines the conglomerate bands of the Upper Elsburg reefs (Mondeor Conglomerate Formation) of the Witwatersrand Supergroup and the Ventersdorp Contact Reef (VCR) of the Ventersdorp Supergroup. The stoping and underground developments are mechanized. The Upper Elsburg reefs are mined by a variety of mining methods, including mechanized drift and fill, modified drift and bench, longhole stoping, and low-profile mining. Optimal mine design and scheduling for deep-level mechanized mining are complex, and success is highly dependent on detailed, robust, and accurate geological and geostatistical models. Geological structures significantly influence the sedimentological characteristics, distribution, and preservation of the Upper Elsburg reefs and VCR. Accordingly, particular emphasis is placed on the generation of a mine-scale structural model that accommodates the relationships between the older north-trending fault systems (West Rand and Panvlakte faults) and younger east-trending dextral wrench faults. Results from underground mapping, borehole intersections, and highresolution three-dimensional seismic data have been integrated to produce coherent three-dimensional geological models. The Upper Elsburg reefs suboutcrop against the VCR and comprise an easterly diverging clastic wedge, thickening from the suboutcrop position, to approximately 130 m at the mine?s eastern boundary. The Upper Elsburg reefs are characterized by conglomerate and quartzite bands forming multiple, stacked, upward-fining unconformity-bounded couplets. Palaeocurrent directions are dominantly from west-northwest to east-southeast, indicating that the more proximal deposits are preserved close to the suboutcrop, with distal facies to the east. Sedimentological modelling is applied to individual stratigraphic units and caters for facies definition. This is achieved through channel width (CW) kriging and fitting of type sections to borehole and mapping data. Homogenous geological geozones for each stratigraphic unit are thus defined within individual structural blocks on the basis of those sedimentological parameters that have been found to have a positive spatial correlation to gold concentration. These geozones then serve as constraints to the evaluation of the orebody. This contribution presents a summary of the modelling processes that are currently applied in the development of high-confidence, timeously produced geological models that are essential input for mineral resource estimation and mechanized mine planning and scheduling.

Jan 1, 2014

By Brian Lindner, Lidia Auret, Niel Knoblauch

In this paper, a fault detection and identification framework based on feature extraction and topology extraction methods is proposed, and evaluated on a simulated base metals refinery high pressure leaching process. Feature extraction methods included linear and kernel principal component analysis, while process topology information was extracted with linear cross-correlation, partial cross-correlation and transfer entropy. Connectivity maps were constructed to identify possible fault propagation paths to aid root cause analysis. The results indicate that process topology can enhance the fault identification capability of data-based process monitoring methods. The study of the considered base metals refinery pressure leaching process is ongoing, with future work including the creation of a fault library which would lead to further critical evaluation of the proposed fault detection and identification framework.

Jan 1, 2014

By Stoyan Gaydardzhiev, Michel Shengo, Pierre Kalenga

Lab-scale flotation of copper and cobalt oxidized ore from the Luiswishi deposit in the Katanga province (DRC) has been done focusing on the influence of the degree of process water recycling on metals recovery. Results have shown that at 20 % recycling rate, the recovery of copper and cobalt in the cleaner stage have been respectively reduced to 23 % and 45 % in comparison to 53 % Cu and 63 % Co if process water has not been recycled. At 10 % recycling rate however, the system could still tolerate the effect from recycling, since Cu and Co recovery has remained respectively at acceptable levels of 52 % and 60 %. In order to explain the reasons for the observed worsening of flotation results if process water was recycled at rate higher than 20 %, electrochemical investigation of the pulp has been performed. It has been established that the chemical compounds formed in the pulp when process water was recycled, do influence the sulphidization of malachite and heterogenite and impact further collector adsorption. To confirm these assumptions, the effect from thiosulphate ions presence during the sulphidization of high purity malachite has been studied. It has been found, that thiosulphate ions depending on their concentration in water induce variations in pulp properties such as DO content, pH, Es and contribute to formation of undesirable chemical compounds on mineral surface as identified by DRIFT spectroscopy.

Jan 1, 2014

By J. Jacob, A. G. Guézennec, F. Savreux, S. Nanaa, M. Delclaud, P. d’Hugues

Mining wastes can contain base and precious metals, but also metalloids and rare earth elements that are nowadays considered as highly critical for the industrial development of the European Union. The development of alternative routes to conventional processing is still required in order to decrease the cost associated with the treatment of these resources, which are more complex in composition and with lower grades. An ecologically acceptable and yet economic alternative for processing of low-grade sulphidic primary ores as well as mining wastes is the extraction of metals using bioleaching processes. The purpose of this study was to test the potential of bioleaching procedures for the extraction of residual metals contained in sulphide-rich tailing wastes coming from a European copper mine. These wastes are mainly composed of pyrite (60%) and contain cobalt (0.06 %) and gold (0.95 g/t). Bioleaching experiments were performed in 2 L stirred reactors in batch mode and in pilot tanks (110L) in continuous mode, using the "BRGM-KCC" bacterial consortia. High metal extractions were obtained (cobalt dissolution > 90%), which confirm that bioleaching is an effective process for this tailings material. Experimental results were used to design a global treatment process scheme and to perform a preliminary economic evaluation, showing good profitability of a hypothetical industrial project.

Jan 1, 2014

By Z. D. Tan

The continuous digestion technological conditions of phosphate tailings with high magnesium content in sulfuric and phosphoric mixed acid is studied in this paper. The influences of excess coefficient of sulfuric acid, weight liquid to solid, reaction temperature and time on conversion of P2O5 and MgO are discussed. The influence of infiltration capacity of phosphogypsum by the concentration of liquid-phase SO3 is discussed too. Under the optimal technological conditions, the conversion of P2O5 is 95.56% and MgO 98.63%, the filtration rate of phosphogypsum increases with the increasing of liquid-phase concentration of SO3, the optimal apparent concentration of SO3 is 0.135~0.14g? mL-1 in liquid-phase. The filtration rate of phosphogypsum is 1473kg? m-2? h-1. N-P-Mg compound fertilizer was produced by adding magnesia powder and inflating ammonia in filtering medium.

Jan 1, 2014

By D. M. Maijer, S. L. Cockcroft, A. B. Phillion, P. Fan, C. Reilly, H. Khadivinassab

A combined experimental / numerical approach is proposed to investigate the bulk transfer of solute due to liquid metal feeding during shape casting of aluminum alloy A356 (Al-7Si-0.3Mg). A dumbbell-shaped experimental casting geometry has been developed, which promotes solute redistribution due to liquid metal feeding. The redistribution of solute in trial castings is evaluated based on the area fraction of eutectic phases. In the numerical model, silicon species segregation during solidification are calculated assuming the Scheil approximation, and are coupled with macro-scale solute transport due to Darcy flow in the mushy zone and feeding flow. The model has been implemented within the commercial CFD software, FLUENT, which simultaneously solves the thermal, fluid flow fields and species segregation on the macro-scale. The experimental and numerical results are compared and contrasted to examine the effects of liquid metal feeding in this casting.

Jan 1, 2014

By Seher Ata

This paper is concerned with the coalescence behaviour of two bubbles in dilute solutions of cetyltrimethylammonium bromide, methyl isobutyl carbonil and triton x-100. Two bubbles were produced at the tips of adjacent capillaries and the time elapsed between the first contact of the bubbles and film rupture was determined by means of a high speed camera. It was found that the amount of surfactant required to stabilise the bubbles increased in order of CTAB>TX-100>MIBC. The probability of coalescence decreased sharply with increasing surfactant concentration in CTAB and TX-100 solutions while with MIBC each bubble pairs resulted in coalescence, giving hundred per-cent coalescence probability.

Jan 1, 2014

By Josefin Lannefors, Anders Klingberg, Natalija Gorochovceva

"Development of new anionic collectors becomes more and more important. This can be explained, on the one hand, by the fact that over the years phosphate ores have become more fine grained and complex (example weathered). On the other hand, a development with a focus on sustainability (sustainable development) of new anionic surfactants is required by authorities and society. Within the sustainable development several characteristics of a collector have to be taken into an account: efficiency, selectivity, froth characteristics, environmental profile, raw materials used for the synthesis, manufacturing complexity, stability upon storage, etc.Several anionic surfactants based on ester and amide chemistry were synthesized, characterized and used as flotation agents for calcium phosphate containing ore. The surfactants were used in a formulation together with other anionics, since in a pure form, during the flotation, they did not provide right froth characteristics.A new anionic collector/formulation was developed, that fulfills all above listed requirements."

Jan 1, 2014

By Y. S. Li

The life cycle assessment method is applied to investigate the environmental impacts of cop-per-slag and copper-ore concentration process. Some environmental load data of copper production are obtained. The result indicates that damage level of human health, ecosystem quality and re-sources respectively is 0.174, 0.0203, 0.246 in the copper-slag concentration and 0.112, 0.0136, 0.299 in the copper-ore concentration. Environmental impact of copper-slag production (0.44) is more than that of copper-ore production (0.42), but can meet the environmental protect demand. With domestic copper concentrate supply gap enlarging, recovering copper from slag will lead to a significant improving of resource utilization and development of circulation economics.

Jan 1, 2014

By A. S. Macfarlane

This paper describes how knowledge of the orebody morphology and ore morphology can be used to optimize the planning, mining, and metallurgical output from an open pit copper mining operation, such as to significantly increase the stability of the whole value chain process, and increase the reliability and value of the process outputs. In the case under consideration, the orebody contains both copper and cobalt. This in itself provides a challenge, in that the two metals do not occur in consistent ratios across the orebody as a whole. Furthermore, mineralogical differences within the orebody have a significant impact on plant performance in terms of throughput rates, acid consumption, and recoveries. In order to stabilize and optimize the plant performance, it is necessary to firstly have a complete understanding of the geometallurgical factors that affect performance, and then to have a sound knowledge of how these are distributed within the orebody. These models then inform the mine planning strategy that optimizes cash flow and NPV, and also allow the development of a stockpiling strategy that not only stabilizes the plant, but also allows variations in the plant feed according to ore type and grade in volatile price scenarios. Integral to the realization of these opportunities is the establishment of an appropriate measuring, control, and reconciliation system, customized to the optimization objectives. The paper describes how all of these factors and strategies can be integrated to produce optimal value from the orebody through to final dispatched product. It also shows the significant value that can be released through such an approach.

Jan 1, 2014

By Mahdi Shevrini, Hamed Haghi

"In this research, the operation of screen classifying in silica processing circuits was investigated and modified by replacement of available trommel screens with teetered bed separator (TBS). In addition the effect of the mentioned replacement and addition of attrition scrubber on quality of final product, impurities removal, recovery and production rate were inspected. Considering screen efficiency problems to achieve certain particle size distribution, hydraulic classifying system was selected instead of trommel screens. Application of suggested plan improved quality and particle size distribution of produced silica significantly. Optimization of size classification in process circuit resulted in increase in production rate up to 21% (from 67% to 81%), silica recovery (from 68.35% up to 83.11%) and relative enhancement in removal of impurities such as Fe2O3 and TiO2. After optimization and stabilization of grinding and size classification section, industrial attrition scrubbing tests were carried out and the best solid percent and retention time were determined i.e. 70% and 6 minutes, respectively. Using sodium carbonate during attrition scrubbing, has major effect on removal of surface coating and staining especially sharp increase in clay removal; therefore 2 kg/t of sodium carbonate can be optimistic point of industrial procedure for this silica processing plant. It should be mentioned that application of attrition scrubbing which is followed by screw classifier for de-sliming were useful for better cumulating of particles in the range of appropriate liberation degree (+106-300µm) and efficient removal of metallic (iron and titanium oxides) and non-metallic (clays and feldspars) impurities."

Jan 1, 2014

By D. R. Nagaraj, Raymond Farinato

Water constitutes one of the most valuable resources employed in mineral recovery and processing. Identifying potential problems encountered in mineral processing in waters unusable for drinking or agriculture (including seawater and even hypersaline waters), understanding chemical factor interactions, and optimization of flotation reagents will greatly expand our ability to create more sustainable beneficiation technologies. The current paucity of our knowledgebase regarding high salinity effects on flotation clearly signals a need for a significant research effort. We report here results of a study designed to probe effects of pulp chemistry on metallurgical performance in the flotation of Cu and Cu-Mo ores in saline waters. The results clearly demonstrate that pH (more correctly dosage of pH modifier to target a pH set point) has the most significant effect on Mo recovery when using seawater. This is linked to the formation/precipitation of Mg(OH)2 when pH = 10.3 (in seawater). The type of pH modifier used, NaOH or Ca(OH)2, had no impact on Cu or Mo recovery, indicating that Ca2+ ions were not involved in any reduction in Mo recovery in the pH range of 9-11. Our results in tap water spiked with either Ca2+ or Mg2+ ions in the same pH range (controlled by NaOH), confirmed that Ca2+ ions had no effect on Cu or Mo recovery, but that addition of Mg2+ ions had a severe adverse effect on Mo recovery at pH = 9.5, and to a lesser extent on Cu recovery. The onset of Mg(OH)2 precipitation occurred at a higher pH, and the adverse impact of Mg(OH)2 on Cu recovery (and perhaps Mo recovery as well) was less, in sea water than in tap water spiked with Mg2+. These effects are attributed to the mitigating role of the high electrolyte concentration, notably NaCl.

Jan 1, 2014

By K. Saberyan

In this study the extraction of zirconium and hafnium has been investigated by solvent extraction using Cyanex 302 in various media such as nitric, sulfuric and hydrochloric acid has been investigated. Effect of various parameters such as type and acid concentration, extractant concentration, type of diluent, equilibrium time, various foreign ions and finally type and concentration of strip-ping agent have been studied. The results showed that nitric acid was optimum media for extraction of zirconium and hafnium. The extraction of zirconium and hafnium occurred quantitatively in the concentration of higher than 4 M nitric acid but in hydrochloric acid media, quantitative extraction obtains over 8 M HCl. In sulfuric acid media, extraction of zirconium and hafnium is negligible. Stripping studies showed that the optimum reagent for stripping was 0.5M sulfuric acid.

Jan 1, 2014

A localized nonlinear recoverable resource estimate technique has been applied using typical feasibility or new mining drilling data configurations drawn from a massive database from a mined-out area on a hydrothermal gold deposit. The results were then compared with the corresponding 8 m x 5 m grid grade-control data in order to determine the efficiency of the approach and the validity of the recoverable resource estimates for mine planning and financial forecasts.

Jan 1, 2014

By V. Yahorava

Ion exchange is considered to be an effective technology for the removal of various impurities from cobalt advance electrolytes. With the correct choice of resin, ion exchange can consistently remove the required impurities to the levels for the production of high-grade cobalt metal. Although ion exchange was in the past used primarily for nickel removal, more recently it has been also considered for the removal of copper, zinc, and cadmium. Generally, granular ion exchange products are used, but Mintek is currently evaluating ion exchange fibres for a number of applications, including the removal of copper from cobalt advance electrolytes. Fibrous ion exchangers have major advantages compared to granular resins in that they have significantly higher reaction rates, and wash water volumes could be limited. Granular and fibrous ion exchangers were evaluated and compared for the removal of copper from cobalt advance electrolyte. A synthetic electrolyte containing 50 g/L cobalt and 50 mg/L copper was used for the test work. Equilibrium isotherms, mini-column tests, and split elution tests were done. The results were used to size a full-scale operation to treat 100 m3/h of electrolyte. The potential cobalt losses or recycle requirements were estimated, and data to calculate indicative operating costs for each adsorbent was generated. This information was used for a techno-economic comparison of granular and fibrous ion exchange systems for the removal of copper from cobalt advance electrolyte.

Jan 1, 2014

By Y. Q. Qui

In the bauxite flotation process for desilication, the middling treatment mode is the important factor to raise the flotation recovery of the preparation concentrate. The middling treatment mode mainly depends on A/S and the size composition. However, similar ratio of A/S should not be the single factor of re-dressing, size composition plays an important role also. Re-dressing the middling mixed with the tailings of concentrated to the rough ground for desilication and the concentrate of scavenged to the fine ground for desilication to raise the recovery of 5.83%, when compared two flow sheet schemes.

Jan 1, 2014

By Mohammadreza Khanmohammadi, Kazem Fakharian

"AbstractIn driven piles, the gradual dissipation of excess pore water pressure and consequently the soil setup significantly contribute to increasing the pile capacity with time. The question is risen that how the scale differences affect the stress state variations around the pile shaft and at the pile tip? Would the CPT predictions better correlate with End-Of-Drive (EOD) or Beginning of Restrike (BOR) conditions? On the other hand, are the proposed a and ß parameters for clayey soils mostly predicting the EOD or BOR situation? The main objective of this paper is to back calculate the a and ß parameters from CPT profiles, pile Dynamic Load Tests (DLT) at the EOD and BOR as well as Static Load Tests (SLT) and evaluate how they compare with those suggested in literature. Four precast 400 mm square concrete piles driven in North Azadegan Oilfield in Khuzestan Province were selected for the comparisons. CPT test results were available from the extensive geotechnical investigation at the study site. DLT tests using PDA were carried out at EOD, 1 day and 14-day BOR on all the 4 piles. All the piles were SLT tested as well. The UniCone software was used to estimate the tip and shaft resistances using 4 methods including the Dutch, Eslami & Fellenius, LCPC and Schmertmann. The results indicate that the a-method based on the proposed values in literature has predicted a shaft capacity of 90% of the 14-day BOR. This is while the ß-method has predicted a shaft capacity equivalent to 1-day BOR results only. Therefore, both methods have under-predicted the shaft capacities compared to real capacities measured after the significant soil setup in the study area. Two of the CPT methods have underestimated, one has overestimated and one has matched the estimated 60-day capacity."

Jan 1, 2014

By Rui Mao, Ke-Xin Nao, Jian-Liang Zhang, Xiang-Nan Xu, Meng-Fang Wei

"In this research, fundamental characteristics of dust and sludge containing iron from the dusting system of sintering process, blast furnace, oxygen converter and rolling process in steel enterprise were studied by chemical analysis, X-ray diffraction analysis, optical microscope analysis, scanning electron microscopy analysis, particle size analysis and other analysis means. Development direction of resource utilization for dust and sludge containing iron from steel enterprise was put forward on the basis of above study.IntroductionDust and sludge containing iron for steel enterprise mainly come from the dusting system of sintering process, pelletizing process, blast furnace, oxygen converter, rolling process and other related process. Iron content of dust and sludge is between 30% and 70%, and they also contain certain content of carbon, calcium oxide, magnesium oxide and harmful elements [1-3]. Output of dust and sludge is determined by raw materials conditions, technological processes, equipment configuration and management level. Dust output in sintering process accounts for about 2% to 3% of the sinter production, while dust and sludge from iron making and steel making process respectively take up 3% to 4% of hot metal and crude steel production, and the solid waste from rolling process accounts for about 0.8% to 1.5% of the output of rolled products [4,5]. Dust and sludge contains Fe, CaO, MgO, C and other valuable resources, it will not only result in the waste of resources, but also cause serious pollution to environment ifthe dust and sludge are not recycled. China's crude steel production in 2012 is about 700 million tons and output of dust and sludge containing iron is nearly 60 million tons, so, it is of great significance to have a resource recycling for dust and sludge containing iron from steel enterprise."

Jan 1, 2014

At the exploration stage for new mining projects or for medium- and long-term areas of existing mines (typical of South African gold mines), drilling data is on a relatively large grid. This grid is normally larger than the selective mining units (SMUs). Direct estimates for the SMUs and also of much larger block units will then be smoothed due to the information effect and the high error variance. Any capital-intensive project decisions made on the basis of any of the smoothed estimates will tend to misrepresent the economic value of the project or operation, i.e. the average grade of blocks above cut-off will be underestimated and the tonnage overestimated for cut-off grades below the mean grade of the orebody. This paper presents a direct approach technique for deriving recoverable resources, referred to as localized direct conditioning (LDC), designed to correct smoothing effects and also to provide support corrections.

Jan 1, 2014

By Andrzej Wieniewski, Cezary Regula, Bozena Skorupska, Krystian Cichy

"In this paper, experiences from Polish non-ferrous metals ores enrichment plants in the copper and blende concentrates quality improvement are discussed. The blende concentrate being produced in ZGH Boleslaw S.A., with Zn content of about 54,5% is characterized by the relatively high magnesium content reaching a level of 1% resulting from the dolomite presence, while for the zinc production by electrowinning a concentrate in which magnesium content should not exceed 0,3% is required. The implemented new technology for the quality improvement of blende concentrate is based on the leaching of zinc concentrate with sulfuric acid aimed at dissolving of the contained dolomite, and then flotation of the leached concentrate. It allows to obtain a concentrate with magnesium content below 0,1% at the simultaneously increased zinc content to about 57,5%. In the paper, laboratory tests results on the development of optimal flotation flowsheet for the gypsum removal and the industrial tests results concerning the process optimization of this flotation are discussed. In turn, the copper concentrate being produced in Polish copper ore enrichment plants KGHM PM S.A., is characterized by the increased organic carbon content - above 8%. It creates problems with the smelting of this concentrate because of difficulties with the heat removal derived from the combustion of organic carbon in the flash smelting process. The implementation of segregating flotation to the industrial practice allows the effective production of two concentrates with the differentiated chemical compositions - a concentrate with increased copper content and reduced organic carbon content for the flash smelting process, and a concentrate with lower copper content and increased organic carbon content for the shaft smelting process. In the paper, conditions of the segregating flotation and the achieved results are described."

Jan 1, 2014