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By M. de Beer

The conversion of carbon-containing feedstock into liquid fuels can proceed via the Fischer-Tropsch synthesis, which is catalysed using supported cobalt catalysts. These catalysts contain noble metals to facilitate the reduction of oxidic cobalt species in the catalyst precursor to metallic cobalt, which is the catalytically active species for the Fischer-Tropsch synthesis. This is thought to occur via hydrogen spillover, i.e. the diffusion of atomic hydrogen over the support from the noble metal to the oxidic cobalt moieties. Noble metals may also affectthe dispersion of cobalt in the active Fischer-Tropsch catalyst. The economic aspect of the addition of noble metals to the Fischer-Tropsch catalyst is discussed.

Jan 1, 2014

By W. Y. Gao

Diaojuntai Concentrator adopts a process of low intensity and high intensity magnetic separation and anionic reverse flotation, with all the concentrate from magnetic separation being treated by re-verse flotation to obtain a qualified final concentrate. The high reagent cost and energy consumption of the reverse flotation have led to a high concentrate cost. The test research on reducing the feed to the reverse flotation was therefore carried out. Based on the study of the properties of the ore sample, the concentrate of low intensity magnetic separation was screened at 0.076 mm and the undersize fraction was concentrated by concentrator with gravity and magnetic field. The results show that a qualified concentrate can be obtained at various rising current rate, pulsating current and power-on style, with the operation rate over 85%. The extraction of some part of qualified concentrate from the concentrate of low intensity magnetic separation by magnetic separation can reduce the feed to the reverse flotation by about 35% so as to reduce the production cost of concentrate.

Jan 1, 2014

By Lorenzo Reyes-Bozo, Ronaldo Herrera-Urbina, Pablo Higueras, Alex Godoy-Faúndez

"The copper mining industry in Chile and perhaps in other countries as well is faced with the challenge to implement the best practices in order to achieve a sustainable and more environment-friendly growth. Relationships between mining industry and society have been historically complex due to its environmental impacts. Whereas the ore grade has declined continuously, this has involved an intensive energy and water consumption thus increasing operational costs at different stages of the concentration process. In the case of copper sulphide ore concentration, froth flotation is the main technology used worldwide. The amount of the different chemical reagents used in flotation plants (i.e., collectors, depressants, frothers and modifiers) affects significantly production costs and has a negative effect on the environment as well. The objective of this research work was to evaluate the use of biosolids and their main components (i.e., glucose, proteins and humic substances) as more environment-friendly flotation collectors for chalcopyrite and molybdenite. For this purpose, microflotation tests were conducted in a modified Hallimond tube. In addition, FTIR and zeta potential experiments were performed to investigate the interaction of biosolids with these sulphide minerals. Biosolids and their main components may interact through physical and chemical ways due to different affinities with such sulphide minerals as chalcopyrite, pyrite and molybdenite, which are present in copper sulphide ores. In alkaline pHs, biosolids and their main components make the zeta potential of the sulphide minerals investigated more negative. These results may provide important information concerning the behavior of the main sulphide minerals in the concentration of copper sulphide ores at industrial scale, wherein mill processes could affect their surfaces properties. Therefore, biosolids and their main components may open an opportunity to be used in copper sulphide flotation plants to partially replace conventional reagents, which are more hazardous and less environment-friendly."

Jan 1, 2014

By Z. He

Based on full investigation of the characteristic of sphalerite in the residue obtained from cyanidation leaching process and the study of the mechanism of the interaction between flotation reagents and sphalerite with the aid of electrochemical analysis, the reagent named YO was developed for eliminating the depression effect of CN- on sphalerite and reducing the dosage of CuSO4. The achievements have been used in commercial production for the treatment of the cyanidation residue to recover the zinc minerals, obtaining a zinc concentrate with grade of 56.49% Zn and recovery of 86.63% Zn.

Jan 1, 2014

By Agnieszka Surowiak, Tomasz Niedoba

The paper presents a way of determining relations between ash content in coal, particle size and particle density by means of regression, multidimensional Morgenstern distribution functions and kernel approximation. The three-dimensional random vector (D, ?, ?), where D is a random variable describing particle size, ? - random variable describing particle density and ? - random variable describing ash content, where function ?=?(d, ?) is obtained by means of regressive function. The multidimensional Morgenstern distribution functions and kernel estimators with the use of Gauss function were applied to approximate the functions f(d, ?, ?) and f1(d, ?). This approach is a new way of multidimensional description of grained materials such as coal and it also allows to evaluate material features more properly than the classical statistical approach. The results were verified statistically.

Jan 1, 2014

By J. Y. Hascoet, M. Marya, S. Marya

Additive manufacturing (AM) brings disruptive changes over the ways parts and products are designed, tested, qualified, assembled, inspected and marketed. With these changes come real technical challenges, therefore, concerns that mainly stem from the maturity and diversity of today’s AM processes, the feedstock materials, and the interactions between the numerous process parameters. Additive manufacturing is somewhat similar to laser and electron-beam conduction-mode welding and involves a multitude of dynamic physical events between projected feedstock and moving heat source that influence process robustness, thus deposit properties. For this paper, a simple air vent, selected for its size, thin-wall, hollow geometry and materials (specifically 316L) was made using a laser-based powder blown technology (Construction Laser Additive Direct or CLAD) and systematically inspected by optical microscopy, microhardness indentations, and electron-back-scattering diffraction (EBSD). This exemplary part is first analyzed to broadly discuss metallurgical phenomena in additive manufacturing, particularly solidification and texture development. The paper then expands to other alloys and continues correlating metallurgical observations to process parameters and part properties, also borrowing from past experience with the same 3D printing CLAD system.

Jan 1, 2014

By M. Chettibi

The interaction and galena flotation with xanthenes and dexanthogen regularities have been de-fined. So, using thermodynamic method of analysis, the thermodynamic stability of [galena - xanthenes - water] system and the behavior of lead xanthenes surface state in solution were devised. Thus, results of cared out calculations and experimental investigation completely coincide with-out depending on witch product of sulfur oxidation is formed in the solution. In additional, was obtained quantitative physico-chemical models for the necessary xanthenes concentration of lead sul-fide complete flotation in the tuning fork of: at ?? values from 7.0 up to 9.0 (or at the formation of lead carbonate PbCO3 ) and at ?? values from 9.0 up to 12 (or at the formation of lead hydro carbonate Pb3(OH)2(CO3)2 Physico-chemical models derived can be used as the criteria for functional units of automation systems to control and regulate the flotation process in mineral processing plants.

Jan 1, 2014

By Pierre Roy, Claude Gosselin, Maryam Sadeghi, Michel Bourassa, Christian Rochefort, Claude Bazin, Gautier Mahieu, François Lavoie, Marilène Renaud, David Cataford

"Spirals are gravity concentrators used for the concentration of iron oxide minerals from ores. This paper presents the mineral size recovery curves observed for spirals operating in two Canadian iron ore processing plants. The size recovery curves are presented for rougher, cleaner and re-cleaner spirals. The partition curves observed for the spirals are significantly different than those observed for typical gravity concentration devices such as hydrocyclones or hydraulic classifiers. The size recovery curves show the complex behaviour of the minerals as they flow down a spiral and are analysed with a view toward process modelling and simulation. Initial simulation results show that gains in the iron recovery can be achieved by increasing the recovery of coarse iron oxide particles in the rougher spirals.INTRODUCTION Spiral concentrators are gravity based separation devices used for the preparation of coal, iron and different heavy minerals ores (Wills, 1992). The classification of the particles in spirals is based on the combination of gravity, centrifuge, drag, lift and Bagnold forces (Atasoy and Spottiswood, 1995; Burt, 1984; Bouchard, 2001). Several papers are dedicated to the analysis of the forces acting on the particles flowing down a spiral (Das and al., 2007; Sivamohan and Forssberg, 1985; Holland-Batt and Holtham, 1991; Holtham , 1992). Most of these papers aim at the development of a general model for the simulation of the classification of the particles for coal ore processing. Few papers deal with the operation of spirals for processing iron ores (Hyma and Meech, 1989; Srivastava, 2001; Dallaire et al., 1978) and fewer papers present results for spirals used as cleaners following a rougher stage. Since the classification in spiral classifiers is dependent on the particle size and specific gravity a partition or performance curve commonly applied to classifiers (Mai Manga et al., 2012) is used here to analyse spiral operation. Few papers were found to describe the operation of spirals in terms of partition curves (Atasoy and Spottiswood, 1995; Holland-Batt and Holtham, 1991; Richards et al., 2000). Most of the investigations presented the application of a model to simulate the position of coal particles of various sizes and specific gravities along the trough of a spiral (Kapur et al., 1996; Holland-Batt and Holtham, 1991). In addition most of the available literature on spirals deals with one stage of concentration by spirals (Dallaire et al., 1978; Das and al., 2007; Sivamohan and Forssberg, 1985) while industrial circuits usually consist of rougher and cleaner spirals."

Jan 1, 2014

By Miguel Becerra, Daniel Jordán, Jorge Soto, Luis Torres

"Most SAG grinding operations currently use ball sizes between 5.5 and 6 inch maximum size. However, in most cases the use of this ball sizes hasn’t been justified by a phenomenological analysis of the real effect on the grinding process, but rather by trial and error. The analysis of the influence of ball sizes in SAG grinding hasn’t been developed in detail by considering the effect on process parameters inside the mill, grinding efficiency or internal classification. Historically a conventional grinding reference has been made on the empirical procedure developed by Azzaroni (1980). Further to Azzaroni’s methodology, Sepulveda (Sepúlveda, 2007) developed the SPEC methodology, incorporating the ball size effect on the grinding efficiency parameters using a population balance model included on Molycop tools spreadsheets.This paper demonstrates a detailed analysis at pilot scale of the ball size employed in SAG grinding and scaling that exists between the different levels. This analysis includes assessing the effect of balls sizes on parameters associated with grinding efficiency and its effect on the total fill level, product size distribution and specific energy consumption, among others. In a complementary way it develops a technical - economical evaluation from industrial data comparing two different ball sizes and its effect on the grinding process analysed integrally."

Jan 1, 2014

By Mathew Janes

"Sheet piles remain an economic solution to many shoring problems. However, installation of sheet piling suffers high noise and vibration with conventional impact or vibratory methods or low production and high expense with push techniques. Many projects simply will not allow sheet piling due to vibration concerns.Installing sheet piles with a tunable, high frequency Resonant vibrator provides high production with imperceptible ground vibrations. Recent projects in Canada have proven the technique on production projects where vibration sensitive structures are present immediately adjacent to the sheet piling. A project in Whitehorse, Yukon required a Waterloo style impervious sheet pile barrier be driven immediately adjacent to a sensitive, large diameter sewer line. The 1800 m2 Waterloo barrier was driven to prevent hydrocarbon leachate from entering the Yukon River. Proposed driving of the sheet raised concerned as the sewer serviced downtown Whitehorse. Monitoring of the sewer during Resonant driving proved the ground vibrations to be imperceptible. Use of the Resonant Driver prevented all concern over ground borne vibration of the sewer and allowed the contractor to progress at conventional, high production while maintaining low cost to the owner.Subsequent projects continue to prove that Resonant driving of sheet piles achieves high production while eliminating ground vibration.IntroductionA complex environmental clean-up problem required a unique solution. A historic oil and fuel transfer station in Whitehorse, Yukon is located on the Yukon River. The facility has been in use since the Second World War and witnessed much careless activity. The sand and gravel site provided ease of transmission of hydrocarbon leachates directly into the Yukon River. Continued use of the site required a barrier wall be constructed to prevent hydrocarbon from leaching into the Yukon River. A short construction season and restrictive fisheries window made for a compressed schedule. Along the shoreline of the property and within the required clean up zone a large diameter sanitary sewer collector line was present that serviced the majority of downtown Whitehorse. The design called for a barrier wall to be constructed along the waterfront adjacent to the sewer with cofferdams constructed out into the Yukon River to recover contaminated riverbed soils. The coarse sands and gravels meant high hydraulic conductivity into any kind of excavation, including slurried or drilled shafts that may have been used to construct a low vibration shoring system. Conventional hammer or vibrator technology would result in high ground vibrations that risked damaging the sewer. The Resonant Driver method was selected for its ability to drive sheet piles with high production and zero ground borne vibrations."

Jan 1, 2014

By K. Yamaguchi, Sekimoto. H.

"Platinum Group Metals (PGMs) used as catalyst which reduces toxic substances in emission gas exhausted from an automobile should extensively be recycled because they are rare metals produced only at the limited regions. The recycling process is to smelt an alumina honeycomb, in which PGM is built, in molten iron with flux such as lime and silica to separate them. PGMs are concentrated in molten iron while alumina in slag.The objective of this study is to understand the factor to concentrate PGMs in liquid iron as much as possible. Fundamental research of the distribution of the PGMs between the slag and liquid iron was carried out to recover the value metals of platinum, palladium and rhodium from the three-way auto catalyst. The distribution ratios of platinum, palladium and rhodium between the Al2O3-CaO-SiO2 slag and liquid iron are from 10-6 to 10-5, and these are concentrated in comparison with slag phase by about 1 million times to the liquid iron at 1873 K. The distribution ratios of platinum between the FexO-CaO-SiO2 slag and liquid iron decrease from 0.1 to 2?10-4 with increasing the CaO content in the slag. The CaO addition to the FexO unary slag is effective in concentrating platinum in molten iron.Based on the distribution ratios obtained in this work, recovery of PGMs was determined. The recovery of platinum, palladium and rhodium increase with increasing the mass ratio, Mmetal/Mslag. In the case of the conditions of Mmetal/Mslag = 0.04, the recoveries of PGMs showed more than 99.97%. The use of liquid iron and carbon saturated liquid iron as the collector metal is advantageous for the PGM recycling of the three-way auto catalyst. We found that PGMs are enriched to the molten iron or the carbon saturated iron and the slag loss of PGMs is negligible small."

Jan 1, 2014

By M. J. Raffaldi, K. W. Harris, K. A. Perry

"Highwall miners have been widely used to extract additional coal reserves from existing surface operations, particularly on contour operations in the Appalachian coalfields. Using a continuous miner cutting head, coal may be extracted from significant depths (such as 150 m), leaving behind an array of web and barrier pillars with the purpose of maintaining highwall stability. This method inherently involves elevated risks to both equipment and personnel due to proximity to and increased exposure time near highwalls. As a result, modern operations should actively design web and barrier pillars to maximize extraction while providing adequate stability. The ARMPS-HWM software, an empirical-based program created for the design of web and barrier pillars at highwall mining operations, is one such approach. The calculated stability factor is compared with empirically established guidelines produced from examining case histories.The ARMPS-HWM program is a handy tool for initial design, but understanding the site’s structurally significant geologic features and geomechanical behavior is important and may potentially increase extraction. We created a two-dimensional numerical model using FLAC3D and calibrated it to ensure pillar strength, closely following the Mark- Bieniawski formula for a typical range of pillar geometries and overburden properties. The development of pillar stresses along a highwall panel was then numerically investigated as mining progressed, and the stress distribution between barrier pillars was found to be asymmetric, which can result in an over-design of the closeout web pillars if tributary area loading is assumed. Finally, the importance of adequate barrier pillar stability is highlighted."

Jan 1, 2014

By Massimiliano Zanin, William Skinner, Keith Quast

With the scarcity of fresh potable water on mining sites, particularly those in arid and remote regions, the use of sea water is being contemplated and actually used at a number of mineral concentrators worldwide. The use of sea water, with its associated high dissolved solids content and ionic strength will affect all aspects of processing (e.g. frothing and froth stability, buffering capacity for pH control, solubility of minerals and corrosion of media and equipment). Selective depression of pyrite is more difficult in sea water due to the increased lime addition to achieve a high pH. This results in a reduction in molybdenite recovery. The use of grinding media with various chromium contents and its effect on subsequent Cu and Mo flotation has been investigated in the current study, with both grinding and flotation testing conducted in artificial sea water. Pulp chemistry (pH, Eh and DO) have been logged during grinding, and flotation testing was conducted on subsequent slurries. The flotation results show that the system is remarkably robust and able to cope with wide ranges of pulp chemistry parameters. The effects of artificial sea water on the surfaces of minerals during grinding have been examined using X-Ray Photoelectron Spectroscopy

Jan 1, 2014

Calaverite is a gold telluride found in the Kalgoorlie region, Fiji, Cripple Creek Colorado and numerous other locations. It is known that a high pH is necessary for calaverite cyanidation, with the leach rate increasing substantially above pH 12 due to the hydroxide ion concentration. In most circumstances lime is used to achieve high pH, however lime saturates at approximately pH 12, limiting the maximum pH obtainable in a critical region for calaverite leaching. Plant observations, laboratory experiments and thermodynamic modelling show that the maxi-mum hydroxide ion concentration that can be achieved with lime (CaO) is strongly dependent on common ions. The presence of calcium, as commonly found in saline waters, substantially diminishes the maximum pH that can be obtained with lime. Conversely the presence of sulfate ions, as generated through oxidation of sulfides, substantially increases the maximum pH that can be achieved with lime. Sulfide oxidation during cyanide leaching of complex ores may generate acid and sulfate ions, making overdosing with lime at the front of the circuit, or staged addition down the leach train, important to maintaining the maximum hydroxide concentration.

Jan 1, 2014

By S. Tshikhudo

This paper outlines an investigation into the recovery of saleable fractions of coal from ?as-arising? South Export Plant effluent streams, using Baleen microscreening technology. South Export Plant, a subdivision of BHP Billiton Energy Coal SA (BECSA) Coal Processing, is a two-module plant treating 2000 t/h. The nominally -150 µm coal is untreated and is therefore passed from classifying cyclones to the thickeners for process water recovery. The thickened underflow is pumped into a series of slurry cells for further settling and recovery of supernatant water. The marginal quality, moisture content, and handlebility of this settled material renders it unsuitable for inclusion into saleable products and it is thus stockpiled and trucked to designated pits for disposal. Over the years, stockpiling and trucking has become an overly expensive exercise. In an effort to recover some of this cost, a task team was assigned to investigate less costly options to process slurry across BECSA plants. Various technologies such as froth flotation, sieve bends, and Reflux Classifier were considered, although the results were generally not beneficial ? this could be attributed to weathered/oxidized coal. A decision was made to pursue an alternative approach by testing the suitability of the new ?Baleen Filter?. The concept is to screen out the higher-grade fraction (+50 µm) as saleable product and reject the finer fractions to the slurry ponds. The Baleen Filter was found to effectively screen at an acceptable efficiency between 94% and 99.99%, with a very sharp cut-point (d50 and Ep). The actual yields from the screening results were better than the predicted yields in terms of both mass and energy as predicted from feedstock analysis.

Jan 1, 2014

By Michael Karmis

"In December 2011, the U.S. Attorney’s Office for the Southern District of West Virginia, the U.S. Department of Justice, Alpha Natural Resources (ANR) and Alpha Appalachia Holdings entered into a nonprosecution agreement related to the explosion at the Upper Big Branch Mine (UBB) that killed 29 miners. This coal operation was owned by Performance Coal Co., an affiliate of Massey Energy Co., which was acquired by ANR in June 2011, more than a year after the UBB explosion. Pursuant to the agreement, ANR agreed to:• Establish a trust within 120 days.• Pay a total of US$48 million into the trust to be used solely to fund and administer research and development (R&D) projects to improve mine health and safety.• Administer the trust by three highly qualified individuals with academic and/or professional backgrounds in mine health and safety.In April 2012, the Alpha Foundation for the Improvement of Mine Safety and Health was created. The three directors - Michael Karmis, president; David Wegman, vice presidenttreasurer, and Keith Heasley, vice presidentsecretary - approved a plan to expend both the interest and principal of the trust, aiming at an 8-10 year research horizon. The foundation also appointed David Belden, an experienced manager of nonprofits and professional associations, as the first executive director of the foundation. The IRS approved the foundation’s tax-exempt application, as described in Section 501c(3) of the Internal Revenue Code, on Dec. 18, 2012. The board established guiding principles of the foundation, which are as follows:• Mission: to improve mine health and safety through funding R&D projects to qualified academic institutions and other not-for-profit organizations.• Vision: to enable miners in the future to be free of work related injury or disease by the implementation of the results of the projects funded by the foundation and undertaken by the best researchers from any discipline that can contribute. The foundation is now approaching its third year and regularly posts updates, including semi-annual reports, to its website (www.http.alpha-foundation.org/), which serves as the main medium for communication with the broader stakeholder community"

Jan 1, 2014

By Kozlov Andrey, Matveeva Tamara

"The results of mineralogical and technological studies of platiniferous dunites from Svetloborsky zonal massif (Urals platinum belt) are presented and the basic typomorphic signs of productive mineral assemblages are substantiated. The characteristic features of platinum ore mineralization are revealed: a wide range of iron-platinum alloys, enrichment of ore-formed system by the elements Os, Ir, Rh and activity of the S and As in it, intrusion of Fe-Ni sulfides in platinum and its fusion with magnetite. More than 80% of PGM mineral grains has size less than 100 microns, that determines the possibility of significant losses of platinum in the process of gravity separation and the need for additional recovery processes for small and fine fractions of platinum tailings and sludge products. Summarized results of laboratory tests of small-volume sample processing of platiniferous dunites are presented and the processing flow sheet is developed and tested. The flow sheet incorporates several stages, including stage-wise grinding and gravity separation of ore using the centrifugal concentrator Knelson KS-MD for differently sized material and flotation treatment of tailing products using new classes of reagents for additional recovery of PGM fines."

Jan 1, 2014

By Fangtian Wang

The fully mechanized longwall mining was employed in a shallow coal seam that was under the gobs of room and pillar mining and overlain by thin bedrock and thick loose sands. Operational practices have demonstrated that severe accidents would occur including roof structure instability, roof steps, damages of shield supports, and face bumps triggered by the large area roof weighting, resulting in serious threats to the safety of underground miners and equipment. This paper uses Shigetai Mine, located in the Ordos area, Inner Mongolia, as the study site. It fully considers the geological conditions of 3-1-2 coal seam and employs theoretical analysis, 3DEC numerical simulation, and field measurements to analyze the overlying strata movement for the shallow seams under an abandoned room and pillar mine without pillar extraction. The research results serve as an excellent guide to mining in similar geological and mining conditions.

Jan 1, 2014

By Luis Bergh, Iván Rojas, Juan Yianatos, Luis Vinnett

"At present, flotation rate characterization follows standard measurements to identify the overall flotation performance looking at the feed, tailings and concentrate in flotation cells or banks. This classical approach does not take into account the evolution of the true collection rate down the flotation banks explicitly. The potential for identifying the impact of the mineral characteristics (size and liberation) as well as the effect of different manipulated variables (reagents, froth depth, gas dispersion) on the true flotation process remains hindered. Top-of-froth (TOF) measurements, which consist of sampling the first layer on the froth surface, have been used to characterize the mineral collected by true flotation in rougher banks. The information provided by TOF samples allows evaluating the floatable mineral evolution (grade, particle size, liberation) down the bank. In this work, an indirect approach to estimate the flotation rate along rougher flotation banks is proposed. The new approach is based on the decreasing of collected mineral grades (on top of froth) and the feed characteristics. Flotation rates per liberation classes were used to reconstruct the TOF grades from the feed information. This approach requires a simple froth surface sampling, without constraints typically observed during mass balance surveys and uncertainties on the mineral recovery estimation. The proposed methodology was successfully applied at industrial scale using TOF measurements together with QEMSCAN information."

Jan 1, 2014

By Peter Scales, Ricardo Jeldres, Fernando Concha, Pedro Toledo, Shane Usher, Anthony Stickland

The impact of several electrolytes present in seawater on the rheological properties of flocculated mineral suspensions was assessed using the creep test. Flocculated suspensions were obtained by adding polymer flocculant to a cylinder of mineral suspension and aggregating the suspension using the plunger method. The suspension was allowed to sediment and the supernatant liquid decanted prior to tests for the viscoelastic properties of the resulting sediment. The solid used was alumina AKP-30 both, below and above the isoelectric point. The polymer used was AN934SH, an anionic flocculant with high molecular weight. Salts analyzed were MgCl2, CaCl2 and NaCl, known as water structure makers, and KI and KCl, known as water structure breakers. A high salt concentration of 0.5 M was used to approach the ionic strength of seawater. For both pH’s studied, the sediments demonstrated a viscoelastic non-linear behavior observed as a non-linear relationship between yield strain and applied stress. In the absence of flocculant, it was observed that the viscosity and yield stress of a suspension increase in the presence of structure maker salts for the case of both silica suspensions and alumina suspensions. These results were explained using hypernetted chain statistical mechanics models describing the interaction of ions with solvated surfaces. In contrast, with the presence of flocculant, the shear yield strain of alumina suspensions increases with the breaker character of the salts, however, this result has been explained by an extension of the results from the models. The work has significant implications for the flocculation of mineral suspensions in the presence of seawater.

Jan 1, 2014