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By Y. Nakamura, T. H. Okabe, S. A. Sunkar, K. Nose

Ruthenium (Ru) is known as a platinum group element with a very small production volume. In fact, the worldwide annual production of primary Ru metal is only about 20-30 tons, and it depends on the amount of Pt produced, since Ru is a byproduct from Pt smelting. The primary uses of Ru are as a material for resistors, as a catalyst for electrode materials, and as a sputtering target for hard disk memory storage. In order to recover Ru from the spent sand-blasting abrasive media generated during the cleaning of the apparatus used for Ru sputtering, a hydrometallurgical recovery process using hypochlorite solution has been investigated. In this study, various types of recycling processes that are presently under development are also introduced, and their features and differences are discussed. The advantages and disadvantages of the new recycling processes are evaluated, and the possibility of establishing new recycling processes in the future is discussed from a multilateral perspective.

Jan 1, 2014

By G. Jenny

The particle size distribution of ground minerals is of decisive importance for downstream processes like floatation, separation, drying or others. In order to optimize the process efficiency on one hand and the final product quality on the other hand an early control of the grinding or classification stage is essential. The ultrasound based particle size analyser OPUS is capable of performing on-line particle size distribution (PSD) and solid content measurement of mineral slurries such as iron ore, copper ore, fluorspar, or quartz sand and alumina directly in heavy and rough process environment. The instrument provides a PSD of 31 size classes and can be applied for particles from nanometer range up to several millimetres. Arbitrary interpolations in between the 31 measured points are available. Typical residue values show an excellent agreement to off-line particle size analysis methods such as e.g. sieve analyses or laser diffraction. OPUS is designed as rugged in-line probe made from stainless steel. The applied technique is independent of product flow dynamics, contamination, optical properties, vibrations, pressures or changes in solid concentrations. The instrument provides all data on the system?s PC or on the process control system by a variety of interfaces.

Jan 1, 2014

By N. Aslin, R. Clark, G. Heferen

The methods of harvesting copper from stainless steel mother plates has been investigated from fundamental and operational experience perspectives. At least five different harvesting techniques have been identified that have different effects on product quality, current efficiency, current distribution, growth morphology and ease of stripping. Each method is examined from fundamental principles to understand what occurs during the harvesting process and why the particular effects are manifested. Experience from plants operating the harvesting method is provided to show that the fundamental understanding is relevant. Best practice harvesting method and harvesting management are described.

Jan 1, 2014

By Yuanyuan Wang, Yuhao Ding, Hao Bai, Kang Zhou, Guangwei Du

"In this paper, the list analysis of GHG emissions of aluminum industry was conducted based on the data from typical electrolytic aluminum plants of a China’s northwest province. The results show that under the conditions of average anode effect coefficient as 0.16 times/(cell• day) and anode duration as 5 minutes per day, equivalent emissions of CO2 reached 1.23 ton per ton of aluminum, in which PFC emissions accounted for about 71%. Compared with foreign advanced level, which is 0.87 ton per ton of aluminum under the conditions of average anode effect coefficient as 0.01 times/(cell•day) and anode duration as 0.46 minutes per day, there is much room for China’s aluminum industry to reduce GHG emissions. Since anode effect plays an important role on PFCs generation in electrolytic aluminum process, how to control anode effect strictly becomes the key factor for remarkable reduction of GHG emissions in China’s aluminum industry.IntroductionTechnology of aluminum electrolysis is a mature and efficient process of aluminum production. Due to the huge demand on aluminum worldwide, so resource consumption, energy consumption and pollutant emissions in the process of aluminum production are still large. The global output of aluminum reached 45193 kt in 2012. A large amount of CO2 and PFCs are produced in the process of aluminum production, and the greenhouse effect and environmental pollution caused by emissions of them is a concern. PFCs belong to a powerful greenhouse gas, thus emission reduction of PFCs is very important for aluminum electrolysis industry. At present, China's aluminum production accounts for about 33% of the world's aluminum production, and controlling PFCs emission has become the key point of pollution control of aluminum electrolysis industry in China [1].Taking the case of a typical electrolytic aluminum plant of a China’s northwest province, this paper studies the list analysis of GHG emissions of aluminum industry in China. GHG emissions of a China’s northwest province were calculated through investigating existing situation of aluminum electrolysis industry in the province, knowing capacity, output, main production technology and equipment level of aluminum electrolysis industry, and using the calculation framework and methods of GHG emissions of aluminum electrolysis industry, which were put forward by the intergovernmental panel on climate change (IPCC), the international aluminum association and other organizations at home and abroad. The list analysis of GHG emissions of aluminum electrolysis industry will offer useful information in promoting emission reduction of GHG in aluminum electrolysis industry, improve the efficiency of energy utilization."

Jan 1, 2014

By Andy L. Shaffer

A novel liquid settlement system (LSS) was installed in advance of mining at a western United States (U.S.) longwall mine to measure total roof sag from the time of cutting to days after mining during gate road development. The system was used to compare differences in roof sag between conventional place-change mining using a Joy continuous miner and a Fletcher roof bolter and mining using a miner-bolter. The LSS was installed with an intrinsically safe, miniature data acquisition system (MIDAS) to record roof response at four locations in the same gate road. The system utilized pressure transducers to measure roof sag by the principle of falling head (fluid pressure) in fluid-filletubes installed in the immediate roof. Details of the LSS design, installation, data collection, post-processing, and future applications are discussed.

Jan 1, 2014

By N. Nehoroshev, P. Solozhenkin, N. Voyloshnikova, A. Pshennikov

"Molecular modeling of clusters of major bismuth minerals, Bi2S3, was carried out whereby molecular models of minerals and reagents clusters were created. Their HOMO and LUMO energy levels were calculated and using known modelling equations, the absolute hardness ?, eV and electronegativity were calculated. The charges of separate atoms of clusters and the change of properties of the minerals were determined which allowed predictions of the flotation properties of raw ores containing rare bismuth minerals. Modeled complexes containing the clusters of minerals and various collectors were constructed, consisting of atoms and bonds within clusters of minerals. Major physical and chemical parameters were determined for the complexes created, including the total and electronic energy. Based on the energy calculations, predictions of the collector efficiency were proposed. The efficiency of collector was established for various thiolic reagents, the compounds of phosphorus (III) and mixtures of reagents. Theoretical results were checked and confirmed against laboratory ore flotation tests. A gold-bismuth-magnetite ore type was studied where gold, bismuth and iron (magnetite) are of industrial interest. The ore contains 2.8 g/t Au, 1.0 g/t Ag, 0.26% Bi, 45% Fe and 1.25% As. Sulphide mineralization can be mainly found in the form of pyrrhotite, pyrite and arsenopyrite. Bismuth can be mainly found in the form of bismuthite and native bismuth. Gold is fine. A flow sheet for Zhelezny Kryazh ore treatment was proposed. This flow sheet consists of grinding to 95-98% -74 µm, sulfide flotation with two cleaner with xanthate addition, cyanidation of flotation concentrate and flotation tailings included treatment with with CaO (6 kg, 6 hours), cyanidation (8 hours) and CIL (8+24 hours). Saleable products are gold doré, bismuth and iron concentrate."

Jan 1, 2014

By Zhihe Dou, Yan Li, Qiuyue Zhao, Guozhi Lv, Yan Liu, Hongliang Zhao

"Abstract: How to reduce carbon dioxide emissions has become a vexing problem, meanwhile, there exist high energy consumption and low efficiency problems in the existing CO2 capture and storage technologies. For CO2 comprehensive Utilization, this paper researches a new technology of absorbing the CO2 emission with high alkaline calcium or high alkaline wastewater sludge mineralization of calcium and invent a core device for multi-level jet carbonation. The industrial test has been carried out in China Xinyu slag Engineering Co., Ltd. The wastewater flow is 150m3/h in the pilot scale. The prepared calcium carbonate has a whiteness greater than 90%, particle size less than 150nm. The mineralization of aluminum exhaust with waste carbide indicates that the CO2 absorption rate is greater than 99.0%, CO2 concentration in the exhaust gas is lower than 0.08%, the purity of mineralized calcium carbonate is greater than 99.0% and particle size is less than 100 nm.InstructionAccording to the statistic data from IEA (2009), the carbon dioxide discharge from fossil fuel consumption in China has exceeded it in the US by the year of 2007, China, has become the largest emitter of carbon dioxide all over the world. Meanwhile, the economic scale is still on an increasing trend in the next 50-100 years, leading to a continuous increment in carbon dioxide discharge. According to the international energy agency forecasts, the energy-relative CO2 discharge in China will rise to 11,615 million tons, 91.3% higher than it in 2007. In the year of 2012, the CO2 gross discharge has reached 10,000 million tons, obviously higher than the predicted value. It is a tremendous task to reduce the emission. Non-ferrous metals industry is one of the largest emitters of carbon dioxide among the industrial circle, the whole industry might discharge a huge amount of carbon dioxide (over 600 million tons), in which the electrolytic aluminum industry is the largest energy consuming industry and CO2 emitter. At present, the CO2 discharge has focused by the whole world due to the environmental problems it causes; meanwhile, supplement of new carbon source is needed due to the exhausting oil and coal resources, so that various countries in the world are attaching importance of the recycle and purification of CO2. Many countries are studying on the cyclic utilization of carbon dioxide. Gas CO2 is mainly applied in chemical, pharmaceutical raw materials, beverage filling agent, refrigerant, inert medium, solvents, pressure source, the welding protective gas, antioxidant and fire extinguishing agent, etc. Solid CO2 is mainly applied in penicillin production, fish, cream, ice cream and other food storage and transportation at low temperature, etc. nowadays, such methods as absorption method, membrane separation, adsorption, etc. are widely used to recycle CO2, with such problems as high investment cost and technical constraints etc."

Jan 1, 2014

By Y. B. Zhu

Soil reconstruction and improvement trials and vegetation experiment is carried out at Shuilong-shan acid rock waste dumps at Dexing Copper Mine in China. pH value, Cu2+, Pb2+, Zn2+, etc. concentration in acid rock drainage (ARD) is also monitored every month since 2005. The results of experiment show that: Lime and topsoil stripped from open-pit is appropriated soil improvement material. Full cover soil improvement method is suitable for flat area, contour soil improvement method and hole soil improvement method is appropriate for slope area. The optimal plant species is ligustrum lucidum Ait,Lespedeza bicolor, Paspalum notatum, Veti-veria zizanioides, Eragrostis pilos and Neyraudia reynaudian. It is the best for Arbor, shrub and grass to be arranged in pairs or groups in order to remold optimal landscape. Pilot sites, covering 3ha, is established. Vegetation coverage reaches 90% in platform area, 40% in slope area. pH value in ARD increased slightly, Cu2+, Pb2+ concentration in ARD decreased, Zn2+ concentration in ARD decreased and varied slightly.

Jan 1, 2014

By Ibrahim Alp, Ersin Yazici, Oktay Celep, Haci Deveci

Low extractions (<80%) in cyanide leaching impose the application of physical and chemical pre-treatment methods (e.g., ultra-fine grinding, roasting, alkaline leaching) prior to cyanide leaching to achieve acceptable recoveries. The effectiveness of the selected pre-treatment method is linked intimately with inherent mineralogical properties of ore. In this study, a refractory silver ore assaying 145 g/t Ag was subjected to various pretreatment tests in an attempt to eliminate its refractoriness. Direct cyanidation of the ground ore (d80: 65 µm) produced a low silver extraction of only 29.5% over 24 h indicating its high refractoriness. Previous studies have shown that silver occurs mainly as Sb/As containing sulfide minerals such as pyrargyrite (Ag3SbS3), tetrahedrite (Cu12Sb4S13) and proustite (Ag3AsS3), which do not respond well to cyanide leaching. Also, silver-containing minerals are closely associated with and/or encapsulated in other mineral phases that can restrict the contact of cyanide with silver. Therefore, alkaline leaching (using 3 M of Na2S, NaOH or KOH solution) and ultra-fine grinding as pre-treatment methods were tested to improve the extraction of silver. All the alkaline leaching tests were carried out for 3 h at800C. Neither NaOH nor KOH leaching produced the desired effect on the extraction of silver (i.e., ~30%). Even, a sharp decrease in the extraction of silver (i.e., 10%) was observed in Na2S leaching. On the other hand, ultra-fine grinding (UFG) (d80: 3 µm) substantially improved the extraction of silver in cyanide leaching (95% Ag at 24 h after UFG). It can be inferred from these findings that the refractoriness of the ore is essentially physical in character (i.e. the encapsulation of silver presumably in non-sulphide minerals such as barite and quartz).

Jan 1, 2014

By R. T. Dec

Current industrial compacting and briquetting practices are largely based on trial-and-error techniques. This paper introduces a two-dimensional finite element model of briquetting process in the roller press. Compared with other modeling techniques used in the past, finite element method offers the most versatile approach because it incorporates adequate information about powder behavior, geometry and frictional conditions and offers predictions for the density distribution, the velocity field, the stress distribution, roll force and torque. More over, when the model includes elasticity, it offers predictions on the internal stress state in the briquette after its exit from the roll. This enables to perform realistic computer experiments which are helpful for establishing the forming cavity geometry and process conditions necessary to produce briquettes with the desired properties. Three forming cavity profiles are analyzed. Results from model are verified on experimental roller press and best cavity profile is recommended for briquetting of sub bituminous coal fines.

Jan 1, 2014

By R. Raghavaraju

Estimation of the dynamic stress field in terms of its amplitude and decay around a blast hole is a key input parameter in all numerical modeling and blast prediction exercises. However, there is very limited information available in literature on these critical parameters, which would be considered essential in any blast modeling exercise. A laboratory-scale experimental study has been carried out in two different rock types to study at very close range the stress wave decay from a blast hole at distances ranging from 3 to 10 borehole radii. The single–hole blasting experiments employed a centrally located detonating cord (5.3 g/m) in 6 mm(1/4 inch) and 10 mm (3/8 inch) boreholes. The coupling medium employed was air and water, in addition to using a thin-walled copper tube in intimate contact with borehole wall to prevent of penetration of explosion gases into the emerging cracks. The paper describes the nature (amplitude and decay) of the transmitted shock pressure and their evolution in the two rock types for these various experimental conditions, which are present to varying degrees in all blasting operations.

Jan 1, 2014

By X. Tan

In this paper, the application of the metallurgical residue produced from oceanic cobalt-rich crusts leaching process is studied in the area of wastewater treatment. The modification of the sulfuric acid leached residue and the adsorption behavior behaviour of heavy metal ions such as (Pb(II), Cu(II), Zn(II), Cd(II), Ni(II), Mn(II), Co(II), As(III)) in the waste-water on the surface of the residue are investigated. The rate of adsorption efficiency of heavy metal ions in the wastewater on the modified sulfuric acid leached residue is investigated. It is showed that when the initial pH value of wastewater containing heavy metal ions including Pb(II), Cu(II), Co(II), Ni(II), Mn(II), Zn(II), Cd(II) and As(III) range from 1.4 to 1.9, with the use of the modified leached residue, As(III) ion can be selectively separated from wastewater, and the separation efficiency can reach 90%~100%. The adsorption efficiency is affected by pH, reaction time, amount of adsorbent and the initial concentration of heavy metal ions in wastewater. The results showed that the optimum pH was natural pH value and the absorption equilibrium time was 2 hours. The adsorption efficiency of heavy metal ions increases with the addition of adsorbent and de- creases with the increase of the initial concentrations of heavy metal ions in wastewater. The heavy metal ions polluted wastewater, of which concentration is about 22.5~793.6 mg/L, can meet the national disposal standard for industrial wastewaters in China very well, after 2 hours treated by 3.75~7.50 g/L modified adsorbent at room temperature. Standard methods were used to investaged investigate the absorption behaviour between abosorbentabsorbent and metal ions in the wastewater. It is concluded that the adsorption behaviour of Co(II), Mn(II) and As(III) ion fits Freundlich iso-therm, while the adsorption behaviour of Pb(II), Cu(II), Zn(II), Cd(II) and Ni(II) ions fits Langmuir isotherm, and the saturated adsorption amount of the modified adsorbent is about 54.0~336.7mg metal/g?adsorbentabsorbent. It is suggested that the modified sulfuric acid leached residue produced from oceanic cobalt-rich crusts is environmentally attractive and meaningful as absorbent used in heavy metal ions polluted wastewater.

Jan 1, 2014

By Rong Fan, Roger Smart, Ning Xu

As part of an Australian Research Council project with Newmont and Newcrest mining companies studying the influence of clay minerals on rheology, hydrodynamics and flotation response, the cryo-SEM technique has been used to capture and image the clay (low crystallinity kaolinite Q38) aggregate structures in the flotation pulp immediately after collector and before frother addition. Samples were also collected from the earliest froth phase and the froth overflow corresponding to early and later concentrates. In this technique, a copper tube is filled with the sample during operation of the cell. The tube is immediately plunged into liquid nitrogen vitrifying the water phase before it can crystallise as ice thereby retaining the structures without volume or other physical change. After sublimation of the vitrified water surface, the aggregate structures are revealed and can be compared between pulp and froth phases from clays in different feeds and flotation conditions. The images from both low-clay ore and ore with clay content reveal various levels of aggregation as predominantly edge-edge connected aggregates similar to those found in our previous studies of high-clay tailings. For the samples from the ore with clay content, more extensive edge-edge clay strings are found in the early froth phase as compared to exiting froth overflow and the pulp phase with short edge-edge connected strings. It is suggested that the strings of clay particles result from edge-edge aggregation in the Plateau borders of the bubbles before breakage during sampling and the more extensive edge-edge aggregation in early froth phase is induced by crowding in the bubble borders. The clay strings collected into the overflow concentrate are almost all broken up compared with the Froth before drop-back. The implications for entrainment and entrapment mechanisms of gangue capture in froth will be discussed.

Jan 1, 2014

By R Zavadil, S Kuyucak, F Fazeli

Proton exchange membrane (PEM) fuel cells generate electricity by reacting hydrogen and oxygen. A thin, bipolar electrode material provides a medium for electron exchange with the electrolyte, alternately serving as anode at the hydrogen-rich side and cathode at the oxygen-rich side. Stainless steels have sufficient corrosion resistance to qualify as bipolar plate materials. However, the protective chromite layer increases the contact resistance, the battery’s internal resistance; and thus, decreases the electrical efficiency of the fuel cell. A heat-treatment is proposed and investigated via simulation by ThermoCalc / Dictra and experimentally, to generate a sufficient quantity of conducting surface carbides that breach the protective layer. Once carbide growth is arrested, a subsequent heat-treatment is also needed at a higher temperature to restore the corrosion resistance by filling-in the Cr-depleted layer (sensitization) around the carbide particles.

Jan 1, 2014

By F. Bello, J. Engels

"During 2012 and 2013, Minera Esperanza conducted a series of thickening and deposition trials to identify design and operational parameters associated with increased thickening of its tailings. These trials focused on benchmarking the current solids concentration of tailings (62 - 64%) in anticipation of an increase to 67% solids once two new 45 m diameter deep-cone paste thickeners are commissioned in 2014. These trials studied the sedimentation and rheological characteristics of the existing tailings and performed deposition modelling to assist with developing short- and long-term designs for the tailings storage facility. To verify and optimise these models, Minera Esperanza considered a series of laboratory, pilot, and industrial-scale deposition trials. This paper provides a review of the trials conducted in the laboratory and at industrial-scale and considers the results and optimisations for the short- and long-term design of Minera Esperanza’s tailings storage facility."

Jan 1, 2014

By S. Y. Chen

A new process comprising metallizing reduction, magnetic separation, and electroheat melting separation is proposed with the aim of achieving high recoveries of iron, vanadium, and titanium from vanadium titanomagnetite. The effects of magnetic intensity, reduction temperature, reduction time, carbon ratio, and coal particle size on the efficiency of reductionmagnetic separation were investigated, the reaction mechanisms elucidated by SEM and EDS analysis, and the optimal process parameters established. Recoveries of up to 80.08% for titanium, 95.07% for iron, and 71.60% for vanadium were achieved. The reduction sequence is shown to be: Fe2O3 ? Fe3O4 ? FeO ? Fe; Fe2TiO5 ? Fe2TiO4 + TiO2 ? Fe + FeTiO3 ? Fe + FeTi2O5 ? Fe + TiO2.

Jan 1, 2014

By M. Saghaeian, R. Hejazi, L. Hosseini, M. Zare

Difference between plant feed specifications in practice and design feed is a problem that most of processing plants face during operating and commissioning. This topic has led to inappropriate operating and necessitates repeating the basic tests on new feed. Gol-E-Gohar fourth concentrate line with a capacity of 2 MTPY, located in Kerman province, is the first iron concentrate plant in Iran in which High Pressure Grinding Roll (HPGR) technology has been applied. Plant&apos;s feed consists of 30% AG mills pebbles of lines 1-3 and 70% run of mine crushed ore whose Fe=51%, Fe/FeO=2.5, S=1.7% and work index=15 kWh/t. Desired concentrate has Fe>68% and S<0.7%. After the plant construction and operation commencement, providing design feed was not possible due to the crushing unit`s not being complete, therefore the plant was fed by AG mills pebbles. For predicting optimal conditions of the plant and investigating the possibility of improving the current concentrate specifications, sampling from the new feed and laboratory and pilot tests was performed again. Studies showed that new feed has Fe=41%, Fe/FeO=3.5, work index=17 kWh/t. Results of laboratory tests with Davis tube device and pilot tests run using magnetic separators with simulating the plant`s circuit showed that with current feed, achievable recovery in industrial scale would be 75.52% which compared to plant&apos;s recovery in studied period (75.94%) shows that plant operated in optimal conditions. To improve the current concentrate specifications (Fe=66%, S=1.03%, Ferec=75.94%) and for achieving desired concentrate, samples were reground to four fractions with k100= 300, 212, 100, 45 and Davis tube tests were performed on each of the samples separately. Results showed that the fraction whose k100=212 µm or k80=200 µm has respective Fe and S grades of 68.27% and 0.681% which are consistent with the desired concentrate.

Jan 1, 2014

By I. L. Grigorova

As a result of the main processes of the limestone treatment ? sawing, buffing and polishing, a technological waste is usually obtained. These final tailings consist of a water suspension with highly variable solid phase content and granulometric composition. Since the waste is conducted to a tailing pool or another place, this leads to environment pollution. In this work the slurry waste generated during the limestone processing in a Bulgarian limestone manufacturing company was characterized. The chemical composition, particle size distribution, solid phase content, whiteness, yellowness, abrasion, specific surface and density were determined. The possibility of obtaining building/construction materials from limestone processing waste was studied in a laboratory scale. The technological tests included thickening, filtration and drying of waste products. Continuous operation laboratory thickener was used. Coagulant Accepta® 8302 (aluminum sulphate solution) and anionic flocculant Magnafloc® 155 were found to be the most effective in the sedimentation of the products. Filtration tests were performed using a laboratory pressure filter. Drying tests were carried out in laboratory facilities using the direct heating method. On the basis of the laboratory results a technology for limestone treatment waste was developed. A production line for building materials from limestone slurry was set up. As a result the manufacturing company has a possibility to use circulating water.

Jan 1, 2014

By Shuji Owada, Shinya Suzuki, Chiharu Tokoro, Daisuke Haraguchi, Sayaka Izawa

"Coprecipitation with ferrihydrite has been one of the major treatment method for As(V) removal from wastewater such as acid mine drainage. We already confirmed coprecipitation of As(V) with ferrihydrite consists of two kinds of mechanism; one is two dimensional As(V) uptake to the surface of ferrihydrite by surface complexation and another is three dimensional As(V) uptake into ferrihydrite by surface precipitation. We also already confirmed As(V) adsorption process by ferrihydrite could be quantitatively evaluated by original surface complexation model with parameter values reported by Dzombak and Morel. However, As(V) coprecipitation process couldn’t quantitatively be represented by only the original model. In this study, construction and calculation using surface precipitation model were attempted for As(V) coprecipitation treatment with ferrihydrite. In the surface precipitation model, precipitation was described by the formation of solid compound between ferrihydrite and ferric arsenate. Activity of these precipitates was determined by surface precipitation ratio of FeAsO4(s) obtained experimentally from XANES analyses. Solubility products of surface precipitation of FeAsO4(s) (Ksp_FeAsO4(suf.)) were determined by fitting to sorption densities and surface precipitation ratio in each condition. The values of Ksp_FeAsO4(suf.) were determined 10-7.7 at pH5 and 10-10.2 at pH7, respectively. Based on the obtained Ksp_FeAsO4(suf.) value, As(V) removal and isotherm were calculated for As(V) co-precipitation treatment using surface precipitation model. Good agreement between experimental and calculated values was observed. These results were suggested that the quantitative prediction of As(V) co-precipitation treatment was possible if Ksp_FeAsO4(suf.) value was estimated experimentally."

Jan 1, 2014

By M. Kargar Razi

According to the unique properties and many applications of nano silver powder, it was prepared from acid leaching tail solution. The low value residual gold and silver ions were occurred with fellow heavy metals as pollutants (Fe2+, Cu 2+and Zn2+) in acid leaching tail solution in Mouteh gold mine in Iran. Preparation of nano silver particles was achieved in two steps: first, by addition of ammonia as separation step and second by using different reagents as precipitation and extraction steps. Different controlled parameters were including pH, residence time and temperature, mixing time, and reducing reagents to metals molar ratio. Acid leaching process was carried out with sulphuric and nitric acid via suitable reductants. In order to remove copper, zinc, and silver ions from solution, all of the conditions were controlled. The optimum conditions for preparation of nano silver powder with less than 90 nm were pH 10.5, hydrazine/methanol to silver molar ratio of 3 to 4, and reduction time of 5 min in 45 °C. The results were evaluated via SEM, A.A and UV- Vis spectroscopy analytical methods.

Jan 1, 2014