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By Paolo Cavalcoli, Federico Pagliacci

"As opposed to the static functional recovery of existing structures, the construction of infrastructures in an urban environment, when combined with complex geological situations, often involves building foundation structures, whether circular or rectangular in section, through rock formations or chaotic strata (sand and gravel with cobbles). Until a few years ago, these formations or strata were sometimes an insurmountable constraint on traditional foundation installation techniques. The difficulty in overcoming these geological situations is sometimes added to the increasingly frequent need to reach depths that were unimaginable just a decade ago. These are real challenges for those carrying out these works and for those manufacturing the necessary equipment. There are two main methodological approaches to these problems, that can be summed up in the rhetorical figure of ""David and Goliath"": cunning versus force. In reference to the case studies in this article: the permanent retaining walls for the Copenhagen Metro, and the structural repairs to the Arapuni Dam in New Zealand and the Wolf Creek Dam in the U.S., we will describe the foundations constructed in presence of rock using combined small-diameter direction drilling solutions, associated with their enlargement up to the project’s size, at depths exceeding 300 feet. Finally, a case study will be presented on the implementation of a large cross-section of an excavation in the rock, at depths greater than 800 feet.IntroductionAs opposed to the functional recovery of existing structures, the construction of infrastructures in an urban environment, when combined with complex geological situations, often involves building foundation structures, whether circular or rectangular in section, through rock formations or chaotic strata (sand and gravel with cobbles).Until a few years ago, these formations or strata were sometimes an insurmountable constraint on traditional foundation installation techniques. The difficulty in overcoming these geological situations is sometimes added to the increasingly frequent need to reach depths that were unimaginable just a decade ago.These are real challenges for those building these works and for those manufacturing the necessary equipment. There are two main methodological approaches to these problems, that can be summed up in the biblical figures of ""David and Goliath"": cunning versus force. In the engineering field, the force is summarized in the use of ever-larger drilling equipment in terms of installed power, weight in working conditions, winch and rotary capacity."

Jan 1, 2015

By Ross T. McGillivray, David S. Graham, Dan A. Brown, Steven D. Dapp

"The Selmon Expressway includes an elevated structure extending across several miles of weathered karstic limestone geology, and represents a challenge for design because of the high variability of the material and the difficulty in characterizing the strength. The nature of the epikarst in this region of Tampa is such that variability can be extreme within distances of only a few feet. The weathered rock includes extremely soft soil infill within solution features on and within the formation. The limestone is so weathered that coring typically does not yield useful samples for strength testing, and in-situ Standard Penetration Testing (SPT) tests often encounter refusal blow counts. Thus the challenge for foundation design includes two components of reliability risks: the uncertainty associated with the ground conditions at a given foundation location plus the uncertainty associated with the foundation performance at a given location even when the stratigraphy is determined.This paper describes the design approach that has been implemented successfully for two projects at the Lee Roy Selmon Crosstown Expressway (LRS) in Tampa, Florida: the assessment and remediation of the reversible elevated lane (REL) foundations constructed in 2004, and the elevated expressways widening project constructed in 2012. Included in this design approach is a method developed for computing axial resistance in this local geology. Design for axial loading relies primarily on the development of side resistance, which was considered less subject to performance risks than base resistance. The calculation method incorporates a statistical analysis of SPT data, tempered by engineering judgment, to characterize stratigraphy at a given location into either soil, intermediate geomaterial (IGM) or rock.IntroductionThe subsurface stratigraphy of sites underlain by weathered limestone formations can be highly variable with respect to material layer thicknesses and strengths, even over short horizontal distances. This is the case for much of Florida, and particularly the Tampa area. These conditions present a challenging environment for the design of drilled foundations because of the need for a reliable determination of subsurface conditions at each foundation location, as they relate to the expected axial performance. Contributing factors include:"

Jan 1, 2015

By Ambarish Ghosh, Chitralekha Ghatak, Tanumaya Mitra, Tarun Sengupta, Sajib Das, Sankar Kumar Nath

"Currently construction of important structures like bridges, flyovers and high rise buildings in and around Kolkata are in full swing. These structures have mostly pile or well foundations. The design methodology and construction techniques are being employed keeping in view both the safety and economy of the project. The data presented in this investigation have been taken from Geotechnical Investigation report of Component B in connection with construction of Extradosed Cable Stayed Bridge over River Hooghly in Hooghly and Nadia district of West Bengal, India. The investigation site is located within close proximity of Eocene Hinge Zone which is being taken as the principal contributor of Earthquakes in and around Kolkata. Considering the importance of the project detailed and exhaustive geotechnical investigation has been carried out and site specific response spectra have been generated for analysis and design of the bridge. This paper presents site specific response spectra, liquefaction analysis and comparison of lateral load carrying capacity of pile using Winkler approach and IS 2911 guidelines.INTRODUCTIONPile foundations are used to transfer the load of the super structure through soft soil deposit to deeper bearing stratum by means of skin friction or end bearing or both. Pile foundations are regarded as a safe alternative for supporting structures in seismic areas and have been used for this purpose in non-liquefying as well as liquefying soils. But their design in case of potentially liquefiable soil is quite different from that of non liquefiable soil. In liquefiable soil the progressive buildup of excess pore water pressure will cause stiffness degradation and loss of strength which in turn will induce additional shear force and bending moment in the pile. The mechanism of pile behavior in liquefying soil has been investigated by several investigators in the recent years based on observations of pile performance during earthquakes and studies in the centrifuge and Shake Table tests. Exhaustive geotechnical investigation has been carried out along the proposed alignment of the Extradosed Cable Stayed Bridge i.e., along Baropara, Bansberia ROB, Ishwar Gupta Bridge, Saraswati River to collect disturbed as well as undisturbed soil sample, to develop average soil profile and to determine the design parameters. The proposed project site is very close to Eocene Hinge Zone, which is basically a strike slip fault, capable of generating an earthquake of Mw 6.7. Thus it is evident that the proposed Bridge needs to be designed considering the adverse geo-hydrological condition as well as the earthquake aspects needing special attention following the state-of-the-art technology as guided by relevant codes and published literatures. Considering the soil profile of these locations ground response analysis has been carried out using equivalent linear method to determine the site amplification. Site specific response spectra have been developed for the four zones and zone factors have been determined. The computed zone factors are 0.198g, 0.195g, 0.195g and 0.20g for the four zones respectively, much higher than the zone factor 0.16g, which is for zone III, as stipulated in IS 1893:2002."

Jan 1, 2015

By William G. Ryan, David S. Graham, Dan A. Brown, Rich A. Lamb, Paul J. Axtell

"The St. Croix River Crossing project on the Minnesota-Wisconsin border has been in the process of planning and public debate for two decades, with several changes in alignment. During the course of the earlier planning process in 1995, a drilled shaft load test was performed to obtain preliminary design information. There were some difficulties in maintaining stability within the weak sandstone bearing formation, and the measured axial resistance was relatively low. Subsequent experience by the Minnesota Department of Transportation with similar weak sandstones on the I-35W project suggests that improved construction techniques using modern drilling fluids may offer opportunities for improved performance. During final design in 2012 a second load test program was performed of a full scale test shaft constructed using polymer drilling fluids. The stability of the socket excavation in the weak sandstone appeared to be greatly improved and the measured axial resistance significantly higher.This case history illustrates the excellent performance that drilled shafts can provide in even relatively weak sandstone bedrock as well as the profound influence on axial resistance associated with the construction techniques used. The improved resistance values obtained by the new load test with more recent construction technology allowed the foundation scheme to be substantially optimized with respect to the number and size of required drilled shafts, reducing the size, cost, and risk of the coffercells and footings.IntroductionThe Minnesota Department of Transportation (MnDOT) has awarded the first phase of a bridge construction project that will cross the St. Croix River between Oak Park Heights, MN and St Joseph, WI. The first phase construction contract involves building the river pier substructures including groups of drilled shafts beneath each tower leg. A general location of the bridge project is provided in Figure 1.Prior to award of the construction contract, two separate design-phase axial load tests were performed on non-production drilled shafts with rock sockets. Both tests were static, bottom-up tests using the Osterberg Cell (O-cell). The first test was performed in 1995 when final design and construction was thought to be imminent. After years of public debate and literally, an act of Congress, design of the project was finally restarted and a second load test performed in 2012. The 1995 test was conducted on the Minnesota bank approximately 900 ft southwest of the St. Croix River bank. The 2012 test was conducted in the river about 2,100 ft northeast of the1995 test location. A plan-view of the project indicating the test program locations relative to the bridge alignment is provided in Figure 2."

Jan 1, 2015

By XUEWEN WANG, Bowen Li, Mingyu Wang

A novel technology characterized by higher extraction of vanadium and recovery of valuable elements was developed to recover vanadium from stone coal. The brief flow of the novel technology mainly includes low temperature sulphation roasting, water leaching, recovering potassium, aluminum, copper and selenium, solvent extraction enrichment vanadium, precipitation of red vanadium, removal sodium from red vanadium and calcinations. The total recovery of vanadium reached 76.3%, which was higher than the current applied technology. The novel technology was environmentally-friendly and could extract vanadium from the stone coal, in which the content of V2O5 was less than 0.8%.

Jan 1, 2015

By Tobias Dubberstein, Hans-Peter Heller

The viscosity of Fe-Cr-Mn-Ni TRIP/TWIP (Transformation Induced Plasticity, Twinning Induced Plasticity) steel with varied nickel content is investigated using a vibrating finger viscometer. The viscosity of the melt is calculated from the change in power input in the field coil by an immersed finger into the liquid steel to maintain a constant peak-to-peak amplitude of the sine wave of oscillator compared to the idle state. Nickel content in steel is varied from 3 wt% to 9 wt%. The dynamic viscosity (η) at 1600 °C for 3 wt% Ni is 3.73±0.14 mPas, for 6 wt% Ni 3.50±0.03 mPas, and for 9 wt% Ni 3.93±0.09 mPas. There is a kink from low to high nickel content in viscosity values of Fe-Cr-Mn-Ni alloys. This phenomenon can be explained by a change in coordination number in the melt, as reported for Fe-Ni binary system in literature. The availability of viscosity data delivers relevant input to model free fall atomization processes of FeCrMnNi alloys.

Jan 1, 2015

By Min Chen, Lei Xu

Sintering behavior and performance of high alumina refractory based on the ternary subsystem MgAl2O4-CaAl4O7-CaAl12O19 were investigated using ZrO2 as an additive up to 8 wt.% by solid state reaction sintering. It was found that the added ZrO2 could dissolve in the CA6 grains in the form of a solid solution, which enhanced the isotropic growth of CA6 grains and then improved the sintering. As a result, the densification process was improved and areas with enrichment of ZrO2 showed a more compact structure. With further increase of ZrO2 addition, tetragonal ZrO2 were found to locate in the grain boundaries for exceeding the solid solubility limit, which enhanced the thermal shock resistance, indicating that addition of ZrO2 exhibited a positive effect on sintering behavior and performance of this refractory. In addition, it is considered that the optimal amount of ZrO2 addition was about 4% considering the performance together with the cost.

Jan 1, 2015

By Valdeci Paula Alvarenga, Sergio Luiz Costa, Itavahn Alves da Silva, Filipe Bueno Carvalho, Varadarajan Seshadri, Carlos Antonio da Silva

Use of fluorspar in steel refining operations is one of the environmental concerns and as such reduced consumption of this material or substitution of the same is one of the objectives. Industrial runs were carried out at Aperam Steel making convertor unit (Timóteo, MG, Brazil) using recycled/briquetted slag for partial or complete substitution of fluorspar. Samples were collected from the metal bath and slag after oxygen blowing to assess dephosphorization with several combinations of recycled/briquetted slag and fluorspar. The results showed that partial substitution of fluorspar by BOF slag briquettes did not affect the efficiency of dephosphorization. In general average Phosphorus content was reduced to 0.010% in the case of partial substitution compared to 0.016% in the regular refining procedure with no substitution. This replacement also resulted in 40% reduction of the fluorspar consumption in the converter

Jan 1, 2015

By Guangwei Wang, Changle Zheng, Yifan Chai, Jian Guo, Weiwei Geng, Jianliang Zhang

In this paper, characteristic and kinetics of CO2 reaction with four different kinds of coke such as top-loading coke, dry quenching tamping coke, wet quenching tamping coke and semi-coke were investigated based on isothermal method. Electric resistance reduction furnace was used to heat the sample. Volume Model (VM) and Shrinking Core Model (SCM) were used to calculate the kinetic parameters and to contrast with the experimental results. The results showed that the Volumetric Model (VM) was much suitable for the reaction of top-loading coke, dry quenching tamping coke and wet quenching tamping coke, while Shrinking Core Model (SCM) was much suitable for semi-coke.

Jan 1, 2015

By Artur R. P. Junior Sergio, Pedro A. Netto, N. Monteiro, Foluke S. de Assis, Frederico M. Margem

Synthetic fibers are being replaced gradually by natural materials such as lignocellulosic fibers. Compared to synthetic fibers, natural fibers have shown advantages in technical aspects such as environmental and economic. So there is a growing international interest in the use of those fibers. The banana fiber presents significant properties to be studied, but until now few thermal properties on banana fiber as reinforcement of polyester matrix were performed. The present work had as its objective to investigate, by photoacoustic spectroscopy and photothermal techniques the thermal properties of diffusivity, specific heat capacity and conductivity for polyester composites reinforced with banana fibers. In the polyester matrix will be added up to 30% in volume of continuous and aligned banana fibers. These values show that the incorporation of banana fibers in the polyester matrix changes its thermal properties.

Jan 1, 2015

By Jianjun Wang, Jiaqing Peng, Lingen Luo, Zhenbang li, Yinghe Lin

Copper removal from ferronickel by FeS has been exploring studied. It is found that the decopperizing agent FeS makes the copper removal in ferronickel effectively. The effects of FeS addition amount, carbon content in ferronickel and experimental temperature were investigated. The results showed that the removal rate of copper in ferronickel increased with the amount of FeS increasing. When the dosage of FeS is 20% (mass percentage)，the removal rate of copper can reach higher than 11%. The rate of copper removal rises with the amount of carbon content increasing in ferronickel. When the amount of carbon content is 1.86%, the removal ratio of copper is 41.3%. Higher experimental temperature promotes the copper removal reaction in certain extent. The flux is acidity and weak oxidative can also promote the reaction of copper removal.

Jan 1, 2015

By Larry G. Twidwell, Jannette L. Chorney, Bryce D. Ruffier, Katelyn M. Lyons, Daniel W. Gaede, Ryan J. Foy, Jerome P. Downey

The Metallurgical and Materials Engineering Department at Montana Tech is investigating various methods of extracting and refining rare earth elements from mineral ores and concentrates. As part of this research, an elevated temperature “roasting” process has been evaluated as a means of converting the rare earth elements contained in various matrices to bromides as a pretreatment step in preparation for downstream rare earth element extraction and recovery operations. Laboratory and bench-scale experiments have been performed to assess the effects of varying temperature (150 to 400° C), time (1 to 4 h), and the ammonium bromide to rare earth oxide molar ratio (6 to 24) in the roaster charge. The results show that nearly complete bromination of the rare earth oxide is achievable when the roast is performed under optimum conditions.

Jan 1, 2015

By E. O. Ávila-Davila, F. R. Barrientos-Hernández, I. A. Lira -Hernández, Miguel Pérez-Labra, M. Reyes-Pérez, J. Antonio Romero-Serrano

Slag from smelting reduction processes were characterized by chemical analysis, XRD, SEM-EDS and XRF. The results revealed Ag concentrations of 362 g/t of slag, the slag mineralogical characterization by XRD and SEM-EDS showed mineralogical species oxidized complex containing Pb, Zn, Ca, Si, Fe, As, S in its structure, silver was found in globules associated lead in the slag and the furutobeite specie. The leaching study was conducted to evaluate process variables such as NaCN concentration: from 7.8x10-3M - 1.26x10-1M, temperature: 25-50°C, particle size: +140 mesh to -400 mesh, stirring speed of 750 rpm - 900 rpm. All studies were performed with a NaOH concentration of 0.2 M. The optimal values of silver recovery encountered in conditions of 7.8x10-3M NaCN, agitation rate of 750 rpm, temperature of 35°C and with a treatment time of 240 min. We also observed that a particle size -400 mesh will have optimum recoveries compared to +140 mesh, +200, +270 and +325.

Jan 1, 2015

By Bin Zhu, Mingmei Zhu, Hong Zhou, Xiaofei Dou, Bin Xie, Yu Wang, Tiancheng Lin

In this study, the formation of 2CaO·SiO2 and 3CaO·P2O5 solid solution (nC2S-C3P) in hot metal dephosphorization process is discussed. The variations of CaO and SiO2 mass, both in nC2S-C3P solid solution phase and liquid slag phase with increasing P2O5 mass in CaO-SiO2-FetO-P2O5 slags were calculated using Factsage software. CaO-SiO2-FeOt-P2O5 slag containing up to 18 % P2O5 was melted at 1823 K then cooled to 1673 K. The contents of CaO and SiO2 both in the solid solution phase and liquid slag phase of quenched samples were observed and analyzed by SEM/EDS. Both the calculated and experimental results show that the contents of CaO and SiO2 in the solid solution phase decreased, just opposite in the liquid slag phase, with increasing P2O5 content in the slags. Formation mechanism of nC2S-C3P solid solution in the slags was derived based on the ionic structure theory of molten slag. The SiO4 4- in the nC2S-C3P solid solution can be replaced by PO4 3- in the liquid phase resulting in the increasing of free Ca2+ and SiO4 4- in liquid phase.

Jan 1, 2015

By Xiang-dong XING, Zhen-yang wang, Jian-Liang Zhang

Distribution behavior of titanium between CaO-SiO2-MgO-Al2O3-TiO2 and hot metal was studied between 1350 °C to 1600 °C. Experimental results indicate that the reaction temperature influenced the activity coefficients of titanium and resulted in the variation of equilibrium constant. Finally, the Gibbs free energy formula of titanium carbothermic reduction was fit out using the thermodynamic model of Wagner and congregated electron phase models.

Jan 1, 2015

By Zhaohui Xie, Bin Xu, Qian Li, Yongbin Yang, Tao Jiang

A high carbon low-grade gold ore, in which gold mainly occurs in carbonaceous matters, is a typical refractory gold ore whose conventional cyanide leaching extraction is only 12.9 %. In this paper, by the process of flotation-roasting-leaching, gold was effectively enriched and extracted. The flotation results showed that the enrichment ratio of gold was relevant to that of carbon, indicating that gold occurred in close association with carbon. A concentrate containing gold 7.26 g/t and carbon 12.37 % was obtained, with gold recovery 83.10 % and carbon recovery 90.24 %. Subsequently, the roasting of flotation concentrate favorably made the removal rates of carbon and sulfur reach 99.81% and 98.79%, respectively. After roasting, the gold in the roasted product was further enriched to 29.70 g/t and the optimal gold cyanide leaching extraction reached 93.66%.

Jan 1, 2015

By Junfu Chen, Jiann-Yang Hwang, Yong Zhou, Lijun Lu, Likun Lia, Jixiong Liu

The sheet-like NiS-ZnS heterostructured composites were prepared by the microwave hydrothermal. The fabrication of the heterojunctions broadened the range of light response of ZnS. The photoexcited electrons of ZnS migrated to the redox potential of NiS/Ni2S under visible light irradiation, which can facilitate the effective separation of photogenerated electrons and holes in space. The visible photocatalytic activity towards hydrogen production for NiS/ZnS nanosheet heterostructed composites without co-catalyst achieved 0.28 mmol h–1, and the quantum efficiency was up to 18.6% under the wavelength with 420 nm visible light irradiation.

Jan 1, 2015

By S. Yin, A. Bogno, H. Henein, P. Natzke

Impulse Atomization (IA) (a single fluid atomization technique) was used to rapidly solidify Al- 4.5wt%Cu and Al-4.5wt%Cu-0.4wt%Sc under argon atmosphere. In addition to the IA-generated droplets, the same technique was used to produce strips by Spray Deposition (SD) of the same alloys on a copper substrate with and without oil coating. The rapid solidification microstructures were analyzed using Scanning Electron Microscopy (SEM). From the SEM images, the amount of eutectic and the secondary dendrite arm spacing (SDAS) were measured. These SDAS results lead to the estimation of cooling rate. The eutectic fraction coupled with the metastable extension of the solidus and liquidus lines of Al-Cu (Sc) phase diagram lead to the estimation of primary and eutectic undercoolings. A comparison of the solidification path of the droplets and the strips was done as well as the analysis of the effects of scandium.

Jan 1, 2015

By Manjie Li, Mingrui Yang, Haijun Peng, Shuxing Qiu, Wei Liu, Shengfu Zhang

It is important to produce and utilize highly reactive coke in order to reduce the energy consumption and CO2 emissions through improving shaft efficiency in blast furnace. The present study aimed to investigate the transformation of iron minerals and properties of iron coke (the coke mixed iron ore fines). Along with the increase of iron ore fines, cold strength displayed a slight downtrend and the pore structure wasn’t inferred to be a major factor affected the properties of iron coke. During carbonization, the majority of mixed iron oxides were reduced to metallic iron by CO and H2 and the degree of metallization achieved to approximately 75%. Nevertheless, produced metallic iron was oxidized by pure CO2 during gasification. Iron coke reactivity index (ICRI) was obviously enhanced and the iron coke strength after reaction (ICSR) drastically decreases, which were also significantly influenced by crystal structure of carbon.

Jan 1, 2015

By Zhen Zhang, Jiang Diao, Tao Zhang, Yi Ren, Lu Jiang, Xiao-Man Yan, Bing Xie

The precipitation behavior of phosphorus enrichment phase was investigated by slag modification with Al2O3. The mineral phase of the original slag and modified slags were measured by mineral phase microscope, SEM+EDS and XRD. The mechanism of Al2O3 modification was discussed according to the thermodynamic theory analysis software (Factsage version 6.3). The results show that the high phosphorus solid solution (nˊ2CaO·SiO2-3CaO·P2O5) was generated by the continuous reaction of nC2S-C3P (nˊ＜n) solid solution and Al2O3 under 1350℃. The amount of initially precipitated solid solution (nC2S-C3P) was reduced and even disappeared with the increasing of Al2O3. If the addition of Al2O3 is enough in the slag, the high phosphorus solid solution (nˊC2S-C3P) that generated by the above mentioned reaction will continue to react with Al2O3 to produce Ca2Al2SiO7 and even C3P, which was demonstrated that the addition of Al2O3 has a positive influence on the precipitation of phosphorus enrichment phase.

Jan 1, 2015