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By I. Ruiz Bustinza, L. F. Verdeja, Daniel Sbarbaro, R. Parra, J. Mochón

The oxidation of sulfides is a complex process involving gaseous products and intermediate species given rise to emission and absorption spectra which carry out important information about the reaction process. This information could be used for on line monitoring of pyrometallurgical reactor if the appropriate sensors were available. We present in this paper an analysis of the concept that has been successfully applied in iron and steel making industry, as well on fuel combustion control, where the spectra measurement gives the possibility for online monitoring and automatic control of high temperature processes. This concept has not been widely applied in the nonferrous pyrometallurgical primary production. The design of new sensors is discussed from the analysis of spectra measurements during flash combustion of copper concentrates at laboratory scale.

Jan 1, 2015

By Viraj Parekh, Kinnor Chattopadhyay, Sina Mostaghel, Xiao Zhang

Electric arc furnace steelmaking is a dominant approach in North America and controlling EAF emissions is a key issue today because of stringent permit limits imposed by various regulatory bodies. In the present study, an attempt has been made to mathematically model EAF emissions, and use the models as a predictive tool for fine tuning the process. CFD modelling has been used to model various fume release scenarios, and optimize the exhaust conditions for maximum capture. Thermodynamic calculations have been used to analyze various chemical reactions which lead to the emissions of hazardous air pollutants with special emphasis on Zinc, Lead and Manganese.

Jan 1, 2015

This paper presents a case study where Cenozoic age detritals and an ancient buried landslide have been modelled in the final walls of an iron ore pit. Orebody 25 is located in Western Australia’s Pilbara region and is an operating pit where a redesign of the final wall cutback was required. The existing slope design utilised a simplistic geological model of mixed conglomeratic, calcretic and clay –dominated detritals overlying deformed bedrock sequences. This simplicity resulted in a conservative design that was not reflective of the slopes performance to that point. Further field investigation was carried out with the results assessed in conjunction with historic drilling, mapping and laboratory testing. A detailed geotechnical model was developed including three conglomerate and two clay dominated units and laterstage calcrete overprinting. The clay units were of significant importance to the stability assessment and resulting slope design due to the thickness and poor strength conditions indicated by the laboratory and field testing. However, the drilling investigation shed only limited understanding as to the origin of the clays and thereby how they should be treated as a component in the stability analysis. A comparison of the ratio of various geochemical elements measured by assay was made between the clays and 1) shale bedrock and 2) clays of known detrital origin from other nearby sites. This indicated the clays had a strong affinity with weathered bedrock. This and other textural features resulted in the interpretation that the clay units were relic debris preserved following ancient landslides in bedrock shale. Using laboratory testing data and calibration of results for a landslide origin, stability analyses were run, resulting in a steeper slope design being implemented. Excavation of the final cutback is now in progress with the model confirmed as appropriate.

Jan 1, 2015

By Jocelyn Bouchard, Claude Bazin, Sami Makni, Rolando Quispe

"Finely disseminated minerals in ores require intensive size reduction to achieve sufficient liberation for the subsequent concentration process. The use of small grinding media in conventional ball mills as a replacement for the usual 2.5 to 3.8 cm balls (1.0 to 1.5 in) produces a finer size distribution at a lower power drawn by the mill motor. However, the conditions ensuring a successful application of using small media for fine grinding are still not fully understood and some plants faced issues to keep the newly introduced steel charge inside the mill during industrial trials. The retention conditions of small media are investigated in this paper using a continuously operated 40 x 40 cm laboratory grinding mill. The tests assess the effect of the steel charge level, the slurry solids concentration and the feed rate on the rate of ejection of the grinding media. The dominant variable is found to be the filling of the mill with the grinding media, followed by the mill feed rate. Results show that increasing the slurry solids concentration within a grinding mill may be favorable for the retention of the media inside the mill.IntroductionProcessing of complex ores often requires the use of fine grinding to liberate finely disseminated minerals. Grinding requirements for a P80 of less than 0.02 mm are not uncommon, and different grinding mills are available for such application (Leonida, 2014; Pease et al., 2006; Davey, 2006; Orford et al., 2006; Nesset et al., 2006). Even conventional horizontal ball mills charged with of 2.5 cm or larger grinding media can be used for fine grinding. However, simulation (Orford and al., 2006) and plant observations (Alves and L-Bouchet, 2005; Brisette, 2010; Brisette and Roman, 2012) demonstrated the advantages of using smaller grinding media in terms of size reduction and energy consumption."

Jan 1, 2015

By M. B. Dusseault, A. Pirayehgar

"There is concern that hydraulic fracturing (HF) near an existing critically stressed fault could trigger slip and generate a seismic event of significance. To this end, a mathematical discontinuum model representing a naturally fractured rock (NFR) mass containing a fault is created, and fault slip response to fluid injection is studied. UDECTM is used as a Discrete Element Method (DEM) approach to define the seismic moment, and also to assess the influence of injection and slip on further shear slip propagation. In most of the simulations, slip and dilation take place along a number of oriented fracture surfaces, so it is reasonable to assume that in a real case, microseimic emissions would accompany each slip “event”. The moment magnitude scale (Mw) is used to measure the size of the microseismic event in terms of the energy released. Seismic moment is a measure of the total energy (work) released during a seismic event and is used to measure its size. From another aspect, the injection energy is calculated as the total energy required for achieving the hydraulic fracturing; this is viewed as energy to open fractures against the ambient stress field and much of it is potential stored energy that can be released and create discontinuities (work of fracture), deformations (W=F·d), heat and radiated seismic energy. A small amount of the total released energy is transformed to radiated seismic energy and another small amount results in tensile fractures. Fracture energy is used to calculate the work required to create fracture surfaces. Comparing the energy release by fracturing or seismic events indicates their contribution to the total amount of released energy or total work. The amount of energy associated with the stick-slip event is small compared with the overall work done to generate the distortions (i.e. increases in aperture by forcing them open) in the rock mass, and much of the energy in slip is lost as heat from the plastic deformation, rather than as radiated seismic energy.Microseismic monitoring shows the spatial distribution and magnitude of seismicity associated with slip of bedding planes and natural and incipient fractures. Work calculations have been undertaken to look at the various sources of energy storage (elastic strain energy) or dissipation (slip), and likely the energy losses from viscous dissipation could be addressed as well, helping to clarify HF processes in NFRs."

Jan 1, 2015

By Jorge Flores, Dean Nichols

Some view quantitative risk assessment (QRA) as difficult to understand and complicated to use. They are comfortable with the proven reliability of quantity distance (QD) and question the benefits of applying QRA principles to explosive safety. In response to such questions, a review of the history of the American Table of Distances (ATD) provides insight to the strengths and weaknesses of the concepts behind QD tables. Additionally, a closer look at QRA features that are available today will reveal stunning capabilities and improved user friendliness not available previously. This paper looks at the early days of explosive safety, the use and limitations of QD, the meaning of risk in the context of QRA and discusses recent developments that knock down barriers previously hindering acceptance of QRA among regulatory agencies.

Jan 1, 2015

By E. Poiate, P. R. Cabral, A. V. N. Santos, P. V. M. Costa, C. S. Amaral, A. M. Costa

This paper discusses the design of underground salt caverns, opened by solution mining, for the production of brine and storage of natural gas under high pressures. The caverns are located in the salt basin in Maceio City, Alagoas State, at the northeast region of Brazil. Special attention is given to the geomechanical structural design of the caverns using computer codes specially developed for the simulation of excavations in salt rock formations, considering validated constitutive creep laws under different initial stress states and temperatures. The behavior of sedimentary rocks intercalations presented in the salt layer is simulated using elastic-plastic models. The excavation of the caverns by solution mining is also simulated starting from a geostatic initial equilibrium state of stresses, with a unique formulation only implemented in these computer codes, without the need of the application of boundary stresses to the model in order to develop the initial state of stresses. These computer codes have being used in the design of several clusters of caverns for brine production used as raw material of Poly Vinyl Chloride (PVC) of the Chemical Industryin Brazil. These computer codes and methodology were also applied to the design of the underground conventional potash mine in the state of Sergipe, overlying tachyhydrite and carnallite with very high creep strain rate. They have also been used in the design of the pre-salt oil wells through thick layers of stratified salt rock in Santos Basin, for the exploration and production of the pre-salt reservoirs in Brazil. The constitutive creep equations implemented in the codes are based on a double mechanism creep law. The creep constants adopted in the simulation are taken from a previous investigation carried out on an experimental panel of the potash mine, considering the stratified geology with different salt rocks of the basin where the mine is located. These constants were also obtained by lab tests under different confined and differential stresses and temperatures.

Jan 1, 2015

By M. El Tokhi, H. Arman, B. M. Amin

"This paper aims to overview some mechanical and physical features of the gabbroic rocks. The study has two phases: filed study/in-situ measurements and laboratory work. During the field studies, rock block samples were collected from different locations of the study area to represent the different types of the gabbroic rocks. Either core or rock samples for various tests were prepared from rock samples taken to the laboratory. The unconfined compressive strength (UCS), indirect tensile strength (ITS), point load index (PLI), Schmidth hammer rebound value (SHV), slake durability index (SDI), sonic velocity (SV) and unit weight (UW) test were carried out either on the selected rock block samples or core samples.INTRODUCTIONThe geology of the United Arab Emirates (UAE) has been divided into three major rock units (Lippard et al., 1986); an autochthonous succession, allochthonous units composed mainly of Mesozoic rocks and include the Sumeini Group (concomittent slope sediments), Hawasina Complex (basinal sediments) and the Semail ophiolite nappe (massive slice of former oceanic crust), that were emplaced as a series of thrust nappe in the Late Cretaceous and Neo-autochthonous sequence of Maastrichtian and Lower Tertiary sediments.The Semail Ophiolite (600 km long and up to 150 km wide) is thought by some authors (Glennie et al., 1990) to have been generated along a subduction related back-arc spreading axis during the Cenomanian-Turonian and was obducted onto the Arabian continental margin during the Campanian. Others, however, consider it to represent a primitive arc-spreading center related to oblique subduction Lippard et al., 1986). The Ophiolitic rocks in the study area comprise mantle and crustal sequences. The mantle peridotite and crustal gabbros are the dominant rock types of the exposed Semail Ophiolite north of the Hatta zone. This paper is only concentrated on the gabbroic rocks."

Jan 1, 2015

By D. K. Chibwe, P. Taskinen

"This investigation consists of a numerical and physical modelling exercise on flow patterns, mixing, solid-liquid mass transfer, and slag-matte phase distribution in a 0.2-scale cold model of an industrial Peirce-Smith converter (PSC). Water, kerosene, air, and sintered benzoic acid compacts were used to simulate matte, slag, injected gas, and solid additions into the PSC. The 2D and 3D numerical simulations were carried out using volume of fluid (VOF) and realizable k-e (RKE) turbulence models to account for the multiphase and turbulence nature of the flow respectively. These models were implemented using the commercial computational fluid dynamics numerical code FLUENT.Numerical and physical simulations were able to predict, in agreement, the mixing and dispersion characteristics of the system in relation to various blowing conditions. Measurement of mass transfer indicated that fluid flow in the PSC is stratified. Blowing configurations and slag volume both had significant effects on mixing propagation, wave formation, and splashing.As a potential process alternative to increase conversion efficiency, we propose a combined blowing configuration using top lance and lateral nozzles. The numerical simulations were conducted on combined as well as lateral blowing conditions, and the results of the combined concept are encouraging."

Jan 1, 2015

By D. F. Malan

"This document highlights some of the topical problems associated with the design and support of deep tabular excavations in hard rock. The displacement discontinuity boundary element method has been used for at least five decades to analyse stress and displacement distributions around narrow width excavations with complex plan outlines. The assumption is made in most cases that the rock mass surrounding the excavation is perfectly elastic. Although this approach works well to minimise stress concentrations in practice, it has limitations as important parameters, such as the effect of mining rate, cannot be investigated. Recently, a limit equilibrium model has been studied as a means to enhance standard layout design exercises by including an interactive on-reef damage model. This approach can include explicit energy release dissipation computations. A second problem faced by engineers in the mining industry is the evaluation of pillar and remnant stress. The paper highlights two aspects namely the effect of element size in displacement discontinuity modeling on pillar stress and the difficulty to estimate the effect of total closure on the regeneration of stress in old mining areas. Regarding the support of the tabular excavations, current efforts are focussed on providing improved aerial coverage using hangingwall bolting and temporary nets. An unresolved issue is the installation of permanent mesh in low stoping width areas. INTRODUCTIONSince 1886, more than 50 000 tons of gold has been mined in the Witwatersrand Basin of South Africa (Hartnady, 2009). The nearby platinum mines also saw significant growth in recent years and more than 80% of the world’s platinum group metal reserves are contained in the Bushveld Complex of South Africa (Nell, 2004). Apart from the economic aspects, the mines served as an outstanding rock engineering “laboratory” for many decades owing to the deep, tabular nature of the excavations. The period from 1960 to 1980 was especially lucrative in terms of research and world-renowned researchers investigated the support and rockburst problems (e.g. see Cook et al., 1966; Salamon, 1968; Bienawski, 1973; Wagner, 1984). Many of the rock-related problems nevertheless persist up to the present day and this paper explores some of these problems and recent progress. The production of gold declined substantially in recent years (Hartnady, 2009) and well-directed rock engineering research can play a meaningful role to slow this trend. The objective of the document is to highlight critical areas requiring additional research and not to discuss the topics in detail. The reader is referred to the many references for additional information. The paper only focuses on three areas namely numerical modelling, pillar stress estimation and aerial support. Although these are diverse topics, it is included in one paper to illustrate the many unsolved and practical problems associated with deep tabular excavations."

Jan 1, 2015

By A. Tylczak, C. Norman, C. Shook, S. Loif

"There are a lot of good reasons to manage energy use at mining operations. Optimizing process energy use reduces operating costs. Tracking energy use can help identify unplanned process changes or malfunctioning equipment early, which allows problems to be corrected promptly.Sacré-Davey Engineering in Vancouver has performed over 50 Energy Management studies for various industries including: mining, pulp and paper, oil and gas, etc. Energy Management programs can be used to identify energy reduction opportunities, assess project feasibility, complete equipment selection trade-offs, as well as to monitor and manage energy costs. Benefits of energy management programs are reduced energy costs, reduced maintenance, and increased plant automation. Additionally, energy management can provide access to utility incentive funding and quantify savings which can greatly improve the return on investment of potential projects.Energy management studies are funded by many Utility programs across Canada. There are various programs available for existing plants energy audits, project feasibility studies, new plant design reviews and energy monitoring and targeting, etc. There are capital incentives available which can significantly reduce payback period.This paper discusses how energy management can be used to support mill/mine operations groups, maintenance programs, as well as expansion or green field projects. This paper will also provide an overview of Canadian Utility companies programs and how they can assist mining companies.IntroductionThere are a lot of good reasons to manage energy use at mining operations. Optimizing process energy use reduces operating costs. Tracking energy use can help identify unplanned process changes and identify malfunctioning equipment early, which allows problems to be corrected promptly."

Jan 1, 2015

By Mansoor Barati, Xue Yin, Yanhui Sun, Alex McLean, Yindong Yang

The formation and evolution of inclusions in Ti-Stabilized, 17Cr Austenitic Stainless Steel produced by the ingot casting process were investigated through systematic sampling of liquid steel and rolled products. Analysis methods included total oxygen and nitrogen contents, optical microscopy, scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS). The results indicate that the composition of inclusions was strongly dependent on the types of added alloying agents. During the AOD refining process, after the addition of ferrosilicon alloy and electrolytic manganese, followed by aluminum, the composition of inclusions changed from manganese silicate-rich inclusions to Al2O3-rich inclusions. After tapping and titanium wire feeding, pure TiN particles and complex inclusions with Al2O3-MgO-TiOx cores coated with TiN were found to be the dominant inclusions when [%Ti] was 0.307 in the molten steel. These findings were confirmed by thermodynamic calculations which indicated that TiN inclusions could be formed in the liquid phase due to the high contents of [Ti] and [N] in the molten steel. From the start of casting to the rolled bar, there was no obvious change in the composition of inclusions compared to the titanium addition stage. Stringer-shaped TiN inclusions elongated along the rolling direction with lengths varying from 17 to 84µm were observed in the rolled bar, which could detrimentally impact the mechanical properties of the stainless steels.

Jan 1, 2015

By X. Q. Jiang, D. L. Chen, A. Macwan

Magnesium alloy, being the lightest structural material, is a key candidate for the weight reduction of vehicles in automotive and aerospace industries; however, its poor corrosion resistance and difficulty in deformation are limiting factors. Recently, Al/Mg/Al tri-layered clad sheets have been considered as a promising alternative to improve corrosion resistance and formability of magnesium alloys. The aim of this study was to evaluate the tensile properties and deformation behavior of Al/Mg/Al tri-layer clad sheets at different temperatures and strain rates. Yield strength (YS), ultimate tensile strength (UTS), and elongation were observed to increase with increasing strain rate. With increasing temperature from -40°C to 180°C, YS and UTS decreased and ductility increased. The strain hardening exponent evaluated via three equations of Hollomon, Swift, and Afrin et al. showed a similar increase with increasing strain rate and decreasing temperature. The fractographic analysis showed partial debonding of clad interface especially at higher strain rates and lower temperatures.

Jan 1, 2015

By A. Hashempour, D. Javani

"Selection of an optimal bit is a critical issue in drilling engineering. Specific energy (SE) and Cost per Foot (CPF) are the most common methods for evaluation of bit efficiency and optimal bit selection. The major shortfall of both methods is that they do not directly account for geological and geomechanical parameters of formations being drilling. In this paper, results of using the two foregoing methods are compared using Formation Drillability (FD) method, which directly accounts for geological and geomechanical parameters of a formation. This method combines various geological and geomechanical parameters and yields a dimensionless parameter indicating the formation drilling hardness (drillability). Results of this study show that the amount of energy, cost and time spent for drilling a unit volume / length of an identical formation may vary in different wells. This is due to the fact that geological and geomechanical characteristics of a formation may vary among wells and even within short intervals of a single well. Therefore, an optimal bit may not be appropriately selected, if drilling and economical parameters are the only factors considered and the formation geological and geomechanical specifications are ignored.INTRODUCTIONMany authors such as Bilgesu, Al-Rashidi, Aminian, and Ameri (2000) and Clegg (2006) conducted research in the evaluation of bit performance and optimum bit selection. Almost all of them tried to establish a good relationship based on geomechanical parameters. Primary examples are the research done by Ubaldi (1999), Macini, Magagni, Da Dalt, and Valente (2007)."

Jan 1, 2015

By Q. F. Wang, M. H. Lai, T. Q. Liu, G. G. Dong

Compared with the traditional pre-treatment process, biological oxidation process has many advantages including higher gold recovery, less cost, easier operation. The bio-oxidation reactor is the most important equipment for biological oxidation process. In this paper, the characteristics of biological oxidation are investigated, and the design principles are proposed based on laboratory tests. Both increasing the tank height and taking new inflation system can enhance higher dissolved oxygen. The new type of large-scale industrial bio-oxidation reactor is designed, which is 9.5 m in diameter and 10 m in height. The bio-oxidation reactor metallurgical performance has been tested by industrial-scale experiment. The slurry of flotation concentrate is divided into two parts to feed two bio-oxidation reactors. The feeding rates of two reactors are adjusted on the basis of getting the same content of S, Fe, As in overflow. The result shows that the feeding rate of the new type of 700 m3 bio-oxidation reactor is 3.72 m3 per hour, and the feed rate of the conventional 700 m3 bio-oxidation reactor was 3.23 m3 per hour. The processing capacity of the former is 15.2% higher than that of the later, which demonstrates the new type of bio-oxidation reactor has higher oxidation rate.

Jan 1, 2015

By H. Kuno, H. Kobayakawa

A borehole inclinometer with FBG optical fiber sensors has been developed to clarify very slow slope movements, and the results of its application to a real slope have been shown. The main characteristics kept in mind while developing this inclinometer are as follows. Firstly, the workability must be good so that only one cable is required for taking the measurements, because the inclinometer is composed of several FBG sensor elements constructed on an optical fiber. Secondly, the minimum interval of the distorted measurements must be close, namely, within 100 mm. Thirdly, the inclinometer must excel in thunder resistance. The measurements were executed by setting up the developed borehole inclinometer on a slope where the rate of displacement is several millimeters per year. The movement of the device was developed by comparing it with that of the results of an existing borehole inclinometer. The area of the displacement concentration, 1 m in width for 4-m sections, was confirmed by the existing borehole inclinometer. The boring core, recovered using a high-quality drilling technique, was examined. Landslide clay was not permitted at the location where the displacement had concentrated as a result of comparing the measurement results with the boring core, and the rotation of gravel by the movement of the slope’s land block was allowed. These results show the slope being caught in the stage just before a primary landslide. In addition, the feature whereby the slope behavior depends on the depth was analyzed by comparing the information on the underground displacement with precipitation and earthquake records.

Jan 1, 2015

By Hidekatsu Takeuchi, Masaru Sakakibara, Shigeo Tanabe, Kenji Harada, Akihiko Suzuki, Shoji Morihana

"Deep mixing (DM) method, one of the most commonly used solidification methods, is based on the principle of solidifying soft ground. It can be classified into two categories such as Cement Deep Mixing (CDM) method and Dry Jet Mixing (DJM) method which apply hardening agent in slurry condition and in powdery condition respectively. In recent years, DM methods have undergone changes that have evolved them from the traditional method to meet the needs of the diversifying market. Among them, the Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method is a DM method which mixes a cement-type hardening agent in slurry condition mechanically with soils in situ and incorporates the innovative technique, “atomized ejection” that has been developed to allow faster installation of larger diameter columns without sacrificing quality compared with conventional methods. At this technique, the atomized hardening agent is discharged together with compressed air through a device incorporated into the mixing blade. It also has advantages of performing the works with low-displacement of the surrounding soils in consideration of environmental friendliness and with higher penetration capability against hard ground.This paper presents the technological outline of the above-mentioned CI-CMC method, focusing on the atomized-ejection technique, followed by some construction examples, applied to the self-earth-retaining wall, to the hard ground and the area adjacent to the existing structures.INTRODUCTIONAccording to the accumulation of its case histories, Deep Mixing method has been receiving the demands of its application to more challenging conditions, such as harder ground condition, and requirement of lower displacement of the surrounding ground during its operation. In addition, to match its price against the other cheaper methods and widely receive its benefit of higher quality, the cost reduction of Deep Mixing is also one of the major challenges. For the cost reduction, higher productivity and lower consumption of the material to obtain the equivalent strength and homogeneity with the conventional method are required.The Contrivance-Innovation Clay Mixing Consolidation (CI-CMC) method has been developed to meet these demands. CI-CMC incorporates the mist ejection that has been developed to achieve faster installation of larger diameter columns without sacrificing quality compared with the existing methods. Normally, we obtain cement columns of about 1.0 m in diameter by using Deep Mixing method. To increase the productivity, it is not preferable to drastically increase the penetration and withdrawal speed of the mixing blades because of the hardness of the ground and restriction by minimum number of passage of rotating blades per a certain height of the soil cement. Instead, the expansion of diameter of the columns will simply increase the productivity. The development of the new mist ejection system, as shown in Photo 1, has enabled the diameter of soil cement columns to 2.0 m on single axis while 1.6 m on double axes. Mist ejection means that the hardening agent slurry is sprayed into the ground in mist form together with compressed air thereby achieving homogeneous mixing and reducing the resistance on rotating blades."

Jan 1, 2015

By D. Settles, R. Rose, P. L. Dunn

"A new mineral sands operation is being developed in Georgia by Southern Ionics, Inc. (SII). Prevailing mineralogy and certain design constraints required detailed testing and circuit analysis to create a robust separation processes. The floating wet concentrator plant (WCP) and mineral separation plant (MSP) flow sheets were designed based on historical testing information and recent SII test campaigns on various composite feed samples. The flow sheets were finalized through rigorous process and orebody sequence modeling.The process uses traditional physical separation equipment; however a new MT spiral, the MG12, was selected for use on board the WCP for roughing duty. The MG12 spiral is a two-stage, twelve-turn spiral that has been proven to achieve very high recoveries of heavy minerals. The floating plant includes feed desliming operations, a central MT surge bin for optimum spiral circuit feed control and ancillary operations for concentrate and tailings handling. Scrubbed heavy mineral concentrate (HMC) is then transported to the MSP for concentration of the titanium and zirconium bearing mineral fractions.The testing, flowsheet development, and plant design will be described and explained, and a brief summary of the current project status will be given.IntroductionSouthern Ionics Inc. (SII) is a privately held chemical manufacturing company, founded in 1980 by Milton Sundbeck. SII focuses primarily on the sale of specialty and intermediate inorganic chemicals. Core markets include cement and refinery catalysts, molecular sieves, zeolites, pulp and paper, pharmaceuticals, TiO2 and water treatment. SII is built on the four cornerstones of service, quality, technology and delivery with all SII facilities ISO certified and key products used in potable water treatment certified to NSF standards. SII owns and operates its own transportation fleet and is focused on being a low cost producer, committed to safety and the environment."

Jan 1, 2015

By A. Mosqueda Martinez, L. C. Trytten, R. P. Kofluk, J. J. Budac

The Corefco ammonia leach nickel refinery treats Ni-Co mixed sulphides from the high-pressure acid leaching of Moa Bay nickel laterite. Due to the low iron content of the feed, the ammonia leach process generates a leach residue with ~10% Ni+Co. Since commissioning a leach residue pressure filtration circuit in 2002, this residue has been stockpiled, dried, and sold commercially. For several years, the residue was sold to nickel smelters overseas. In 2014, re-processing of the residue in the high-pressure acid leach was tested. Lab test work was completed showing excellent extraction of the contained nickel and cobalt, and additional beneficial effects in the high-pressure acid leach circuit. A plant test in Moa confirmed the results, and preparation for shipment of the valuable leach residue for re-processing has begun. This paper outlines the test work and results, and some commercial considerations.

Jan 1, 2015

By Zhan-fang Cao, Hong Zhong, Li-feng Li, Shuai Wang, Xiao-yu Cao, Guang-yi Liu, Ming-ming Wang

"In recent years, there has been an increasing focus on the hydrometallurgical processing of molybdenite, with the decline of high-grade and easily handled molybdenum minerals. In this work, a novel method of selective extraction of complex molybdenite concentrate, which is characteristic of high-grade copper ore, has been investigated. The results show that the leaching of chalcopyrite was impacted by the pH of the electrolyte when sodium carbonate and ammonium acid carbonate were added to the electrolyte. The leaching rate of molybdenum reached 99.39%, but chalcopyrite could not be leached at all in 240 min under experimental conditions of liquid-to-solid ratio 25:1, concentration of NaCl 4 mol/L, pH=9, room temperature and agitation speed 400 rpm. The grade of copper in the residue was 21.84%, with a recovery 99.93%. The technology of selective electro-oxidation leaching of molybdenum and recovery of copper from complex molybdenite concentrate is an effective separation method. The diffusion control model can be used to describe the process of leaching of molybdenum. The activation energy of the leaching reaction was found to be approximately 9.21 kJ/mol.IntroductionWorldwide, high-grade and easy-to-handle ore is decreasing, while the proportion of low-grade and complex ore is increasing. Porphyry copper ores with associated low-grade molybdenite are very abundant in China. Molybdenum is a valuable byproduct in the processing of porphyry copper deposits where the molybdenum is present in low quantities in the form of molybdenite (MoS2). In the conventional processing of copper sulfide ores by froth flotation, most of the molybdenite in the ore floats along with the copper sulfides. In this way, a bulk copper-molybdenum concentrate is produced. Afterward, the bulk coppermolybdenum concentrate is treated by differential flotation to obtain a rougher molybdenum concentrate, which requires several successive cleaning steps to produce a final molybdenum concentrate. However, it is widely recognized that flotation alone cannot economically produce a high-grade molybdenite concentrate, i.e., with less than 0.5% Cu. Therefore, in most cases, it is necessary to use a final step of chemical purification of the molybdenite concentrate to reduce the copper content to a level suitable for the market (Antonijevic and Pacovic,1992; Gerhardt et al., 2001; Fu and Zhong, 2003; Reza et al., 2006, Rafael et al., 2013)."

Jan 1, 2015