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By E. J. Haas, K. A. Rost

"This study sought to identify changes in continuous mining machine (CMM) operators’ risk perception and risk behaviors as a result of adding a proximity detection system (PDS) into their environment. To accomplish this research task, 9 CMM operators from 5 locations were interviewed. Interviews were thematically analyzed for constructs including patterns in risk perception and behavior before and after PDS integration and the process of adapting to the PDS. Operators discussed standing in the red zone less than they did before using the PDS; however, they also discussed other risky decisions they made while learning how to operate their CMM with the PDS technology such as “cheating” the technology and working faster to meet production goals. The process of relearning job tasks with technology and unintended behaviors as a result of that relearning process need to be taken into account when introducing new technology into the mine environment. The study results show an in-depth view of mine workers’ perspectives and how their job tasks and environment could be or are affected when learning how to use new technology that are relevant to companies and mine operators when introducing new technology into the mine environment. INTRODUCTION Established “red zones” can help prevent striking and pinning incidents by providing guidance to continuous mining machine (CMM) operators about where they should stand and not stand while operating a CMM. Although red zones influence operator placement positions, these guidelines are not foolproof safety mechanisms. Depending on the job task and circumstances of the mine environment, a CMM operator may unintentionally or intentionally stand in a red zone. For example, CMM operators may work in close proximity to their CMM for better visual attention cues and the ability to work at a higher rate of production [1-3]. To further enhance protection and prevent collisions between vehicles and mine workers, a proximity detection system (PDS) was developed for the industry. The PDS determines an individual’s position relative to a specific piece of machinery, issues visual and/or audible warnings to the mine worker to change positions, and, if necessary, disables machine motion [4]. The introduction of new technology within other sectors has been identified as a factor that influences work decisions. Specifically, previous research demonstrates that when technology debuts there can be an initial intrinsic risk perceived among users about how the technology will interact with their current environment and behaviors; however, these ambiguities, including the possible risks and benefits, are seldom studied [5]. Some research suggests that the constant presence of technology can disrupt situation awareness and decision-making capabilities by increasing worker responsibilities and worker cognitive demands [6-8]. Further, if workers’ perceived risks both with and without technology are misjudged, unsafe decisions that result in human error and injury may be more likely [9-11]. Although these statements are provided within a broad contextual framework, they support the need to study how technology is perceived among end users in their own environment. Because research about technological impact on worker behaviors has suggested both positive and negative consequences of technology, this issue is worth addressing in the mining industry. Specifically, research has not determined whether CMM operators view their placement choices in the red zone as safe or risky and what effect PDS technology has, if any, on risk perception and subsequent risk behavior."

Jan 1, 2015

By F. Cihangir, A. Kesimal, K. Karaman, B. Ercikdi

Uniaxial compressive strength (UCS) and shear strength parameters(cohesion and angle of internal friction, Cand F) of rocks are important parameters needed for various engineering projects such as tunnelling and slope stability. However, direct determination of these parameters is difficult and requires high-quality core samples for tests. Therefore, this study aimed to explore the applicability of the Brazilian test (BT) - a simple, less sophisticated and inexpensive method for both specimen preparation and testing - to estimate the UCS and shear strength parameters of rocks. Thirty-seven rock types were sampled and tested, 24of which were volcanic, 8 were metamorphic, and 5 were sedimentary. Statistical equations were derived to estimate the UCS and shear strength parameters of rocks using the BT. The validity of the statistically derived equations was confirmed using predictive analytics software (PASW Statistics 18). A strong linear relation was found between BT and UCS values. BT and UCS values exhibited prominent linear correlations withthe cohesion values of rocks. The Mohr envelope was also used to determine the cohesion and friction angle of rocks using BT and UCS values. It is deduced from the current study that the BT values can be used to estimate the UCS and cohesion. However, no relation was observed between the angle of internal friction values and the UCS and BT for all rock types. Therefore, different approaches are suggested for the estimation of the internal angle of friction for application in the preliminary design of projects.

Jan 1, 2015

By P. K. Kaiser, C. D. Martin, F. Amann

"This article focuses on the uniaxial compressive strength (UCS) of homogeneous and heterogeneous rocks. Critical factors impacting the UCS of rocks are reviewed and then separate assessments of UCS data from homogeneous and heterogeneous rocks are presented. The variability (coefficient of variation) of UCS test results for homogeneous rocks is found to be generally <25% while for heterogeneous rocks the variability is >35%. Failure mode variation is found to be the cause of the variability of UCS test results in heterogeneous rocks. Empirical engineering design methods that use UCS as an input parameter are discussed and suggestions are provided for selecting appropriate UCS values.INTRODUCTIONThe UCS is one of the most commonly used rock engineering parameters whether for rock mass classification or for strength determination. The mean UCS and its variability are often assumed to represent a reliable rock material property. For the reasons discussed in this article, UCS is rarely representative of the intact rock UCS. The UCS test simply records the collapse load during uniaxial loading of a cylindrical specimen. As suggested by many, the UCS is an index rather than a unique engineering parameter. The UCS is thus a proxy for rock strength which depends on the loading rate (e.g., Bieniawski 1967), specimen geometry (e.g., Hudson et al., 1971), specimen size (e.g., Bieniawski 1968), and many other factors. Furthermore, the UCS is not the same as the Hoek-Brown strength criterion parameter sci.There are differences in opinion on what is commonly considered to be ‘intact rock’. When sampling ‘intact’ pieces of core from drillholes crossing blocks of rock bound by block forming discontinuities, samples will be ‘intact’ but some samples will be veined, others will be damaged, and others will be neither. According to Hoek (1983), intact rock pieces are “the unfractured blocks occurring between structural discontinuities in a typical rock mass” and the sci parameter for intact rock is determined using the fitting procedure proposed by Hoek and Brown (1997) based on the data requirements outlined by Hoek (1983). Studies (e.g., Bewick and Kaiser 2014; Kaiser and Kim 2014) have shown that independently determined UCS and sci values for the same rock type are not equivalent. Thus, UCS data cannot be used as a replacement for sci."

Jan 1, 2015

By X. X. Wu, Q. Zhang, R. H. Fan, Y. J. Feng, J. D. Liu, P. Z. Zhao

In the present study, AA6016 automotive sheets with different grain size were fabricated through changing fabricating parameters, and the effects of grain size on the bendability were studied by bending test and optical microscopy. The results showed that the sheet with coarse grains exhibited poor bendability, and some micro-cracks were revealed at the surface of the bending samples. While the sheet with fine grains exhibited good bendability, and the bending samples showed smooth surface. Shear bands on the cross section of bending samples were observed. It was found that samples with coarse grains had more shear bands. These shear bands distributed in bundles, which facilitated the formation of continuous neckings and micro-cracks. However samples with fine grains had less shear bands, which distributed uniformly. The decrease of grain size could not only hinder the formation of shear bands, but also improve the homogeneity of its distribution during bending. On the other hand, refining grains could increase the amount of grain boundaries, which impede the propagation of shear bands. Hence the decrease of grain size could hinder the formation of continuous neckings and micro-cracks during bending, resulting in the significant improvement of the bendability.

Jan 1, 2015

By A. Koster, V. Maurel, S. Dezecot, Szmytka. F.

The aim of this work is to clarify the role of microstructure heterogeneity in the initiation and growth of cracks in a lost foam cast A319 for low cycle fatigue (LCF) loading condition. Because 2D analysis fail to establish the scenario of damage events, this study is based on 3D in situ analysis using synchrotron X-ray tomography during LCF test performed at 200°C. If X-ray tomography is now an established technique to study damage development in 3D, its application for relatively high temperature cyclic tests has never been done so far. Initial 3D observations of damage show that the cracks that lead to fracture initiate near large pores and propagate into the hard particles 3D network of the eutectic regions.

Jan 1, 2015

By Mark S. Greenleaf, Alec D. Smith, Mary Vittoria-Bertrand, Heather B. Scranton, Jean Louis Z. Locsin

"Rhode Island’s new $163.7 million, 2,265 ft (690 m) long, four-lane Sakonnet River Bridge sits just south of the existing bridge in Portsmouth/Tiverton. The bridge, a critical transportation system link between Massachusetts and Rhode Island, has a steel I-girder main span and concrete New England Bulb Tee approach spans. The foundation work was done between October 2009 and July 2010, and the bridge was completed in February 2014.Foundation design and construction challenges make the project noteworthy. There were thick layers of silty glacial soils with bedrock as deep as 400 ft (122 m) below the waterline, coupled with high foundation capacity demands at the river piers in 50 ft (15 m) of water. The Sakonnet was one of the first major bridge projects in the country to incorporate AASHTO Load and Resistance Factor Design (LRFD) guidelines for foundation design and construction. Because of these and other challenges, the engineers conducted two design-phase load test programs on several foundation elements. These programs were successful and allowed the engineers to adjust the final foundation design prior to the start of construction. During construction, the contractors drove thirty 6 ft (1.8 m) diameter steel pipe piles, each with a novel recessed steel plate insert, to depths of 130 to 200 ft (40 to 61 m) at the three river piers. The insert provided increased resistance of the steel pipe piles and saved about $9 million. Also, 457 14x117 en bearing or friction H-section piles were driven to between 50 and 190 ft (15 to 58 m) at five land piers. All piles were driven relatively close to the existing bridge, which remained in service during construction, due to the project team’s precautionary use of instrumentation and the installation of a jacking system.Area GeologyThe Sakonnet River is up to 60 ft (18 m) deep along the bridge alignment and is underlain by a deep bedrock valley. The bedrock valley is buried by at least 350 ft (107 m) of soil, which includes a complex sequence of interbedded glacial soils (glacial till, glaciolacustrine deposits and glaciofluvial deposits), overlain by geologically recent estuarine deposits. The soils having the greatest impact on the foundation resistance are the glaciolacustrine (fine sandy silt or silt) and glaciofluvial (silty sand with gravel, cobbles, and occasional boulders less than about 2.5 ft [0.8 m] in size). The soil overburden decreases toward the east and west banks of the river, as the bedrock surface rises."

Jan 1, 2015

By E. Ghali, W. Zhang, G. Gabra, N. Sorour, G. Houlachi

The additives polyacrylamide, 1-Butyl-3-methylimidazolium chloride, Tetra-butylammonium bromide, Benzalkonium chloride and chitin are evaluated during zinc electrolysis from synthetic acidic sulphate electrolyte containing Mn2+ ions, in absence and in presence of 0.0055 mg dm-3 of Sb3+ ions. Galvanostatic polarization tests for 2 hours at 50 mA cm-2 and 38oC were carried out to determine the cathodic and anodic potentials, and current efficiency of the deposited zinc. Potentiodynamic polarization and cyclic voltammetry tests have also been employed to study the electrochemical behavior of each additive on the zinc deposit on aluminum electrode. Results showed that, in presence of Sb3+, adding 1 to 3 mg of 1-Butyl-3-methylimidazolium chloride increases the cell voltage by ˜0-7 mV. Current efficiency is increased by ˜4.90-6.40%; power consumption is reduced by ˜147-173 kWh t-1 by adding 1-3 mg, respectively. However, in absence of Sb3+, cell voltage is decreased by ˜7-28 mV, current efficiency is increased by ˜0.70-1.50%; power consumption is reduced by ˜41-47 kWh t-1 by adding 1-3 mg. The effect of the other additives on cell voltage, current efficiency, lead content and morphology of zinc deposit has also been examined. Surface morphology and crystallographic orientation of the deposit was studied using scanning electron microscopic (SEM) and X-ray diffraction (XRD), respectively. The content of lead in the deposit has also been measured using inductively coupled plasma spectroscopy (ICP).

Jan 1, 2015

By R. R. Song, Q. Li, H. Xing, X. C. Wei

Geomechanical modelling of fault stability is an important part of CO2 capture and storage (CCS) research program to ensure its viability and long-term safety. Storage of CO2 in deep subsurface reservoirs requires estimates of sustainable fluid pressures that will not induce fracturing or fault reactivation which could cause fault slip. More importantly, fault slip gives rise to seismic waves, which inflict severe damage to the cap rock of the reservoirs and may result in leakage pathways for the buoyant plume and thus compromise the integrity of seal formations. In this study, we generated a numerical model tuned towards conditions usually encountered in the Shenhua CCS demonstration project in Ordos basin. In particular, with the purpose of evaluating the sensitivity of the parameters as well as their relationships with the moment magnitude of the seismicity, a variance-based sensitivity analysis was adopted for importance ranking of the uncertain input parameters of the given model. However, such flow models could involve one or several spatial inputs, for instance, fault dip, distance between fault and the injection well, friction angle of fault, permeability of fault, Young's Modulus of fault, injecting pore pressure and the stress field. Studying the sensitivity to each of these spatial inputs motivated the present work. The results led to the following conclusions: fault depth and fault dip significantly affect the behavior of the fault and the fault slip becomes violent with the fault depth increasing and fault dip decreasing. Furthermore, the results indicate that slip time increases with the fault dip decreasing and decreases with permeability of fault increasing. In addition, the calculation of seismic moment and moment magnitude of an earthquake demonstrates that it rises significantly with the decrease of fault dip and the increase of fault depth, and it decreases with the rising stress field. The results show that variations of the only controllable parameter injection pressure do not show great influence to the fault behavior compared with other geological factors, which imply site selection is extremely important for the CCS projects.

Jan 1, 2015

By T. Ivankina, T. Lokajícek, H. Kern, T. Svitek

The knowledge of 3D velocity distribution of P- and S-waves in rocks is very important parameter for interpretation and understanding the nature of seismic anisotropy observed in the earth’s crust and upper mantle. A new high-pressure measuring head was designed and constructed to enable ultrasonic sounding of spherical rock samples in 132 independent directions under up to 60 MPa of acting hydrostatic pressure by means of simultaneous longitudinal and transversal sounding. New measuring system enables ultrasonic sounding of spherical rock samples by using a pair of P-wave sensors and two pairs of perpendicularly polarized S-wave sensors (TV and TH) see Fig.1. Shear wave sensors polarization is oriented according to rotation axis of the sample. Special shear wave gel was used to transfer shear waves between the sample and sensors under acting hydrostatic pressure. An isotropic glass sphere was used to check and calibrate the new measuring setup. A spherical sample of a biotite gneiss from the Outokumpu scientific drill hole was used for testing measurement. There is shown that both, P- and S-wave velocities, can be measured simultaneously up to 70 MPa, respectively. We report data of the 3D velocity distribution of P- and Swaves measured for the first time on a sample sphere of biotite gneiss. We rely, in particular, on the directional dependence of compressional and shear wave propagation and their relationship to the crystallographic (CPO) and shape preferred orientation (SPO) of major rock-forming minerals. The 3D seismic measurements revealed a strong foliation-related directional dependence (anisotropy) of P- and Swave velocities. Ultrasonic measurements were compared with 3D velocity calculations based on neutron diffraction measurements of crystallographic preferred orientation (CPO) of major minerals. Comparison of 3-D velocity distribution (P, S1, S2 and S1-S2) determined by two completely different methods ultrasonic sounding and neutron diffraction is presented. Measurements showed that the intrinsic bulk anisotropy is basically caused by the CPO of biotite constituting about 23 vol.% of the rock.

Jan 1, 2015

By J. F. Liu, L. Chen, C. P. Wang

"Calcite-cemented joints abound in the rock masses of Beishan area, which is the most potential area for the high-level radioactive waste (HLW) disposal of China. The mechanical properties of Beishan granite containing a calcite-cemented joint with a dip angle of 82° was investigated under uniaxial compression and the acoustic emission (AE) characteristics were also studied in this paper. Compared to intact granite, the calcite-cemented joint caused a decrease more than 50% in uniaxial compressive strength and a decrease more than 90% in shear strength. The Young’s modulus was also decreased, while the circumferential deformation of jointed granite was sharply increased. The AE monitoring system successfully recorded the process of micro-crack development and the results indicated that the risk of rock-burst could be reduced due to the appearance of calcite-cemented joint.INTRODUCTIONThe properties of jointed rocks differ considerably from that of intact rock. Due to the difficulties in specimen preparation, analogue experiments with artificially prefabricated fractures are often used to study the mechanical behavior of jointed rock (Chen et al. 2012; Kulatilake et al. 2001; Singh et al. 2001). However, natural joints are not quite similar to the artificial fractures and it is necessary to investigate the mechanical behavior of jointed rocks. Xie et al. 2011 studied the mechanical properties of marbles with natural joints by uniaxial compression tests and found that the uniaxial compressive strength of jointed rock is greatly decreased. With the unaxial compression tests, Jacobsson 2005, 2007 tested the intact and jointed granites, which were taken from the potential site for high-level radioactive waste (HLW) disposal of Sweden. However, no significant difference in strength or modulus was found. The above research results are inconsistent and it indicates the complexity of the mechanical properties of natural joints."

Jan 1, 2015

By Hang Zhao, Xinping Li, Pingan Wu, Yi Luo

"The deep-buried rock surrounding the Jinping II Hydro-power Station was taken as the engineering background. Using model specimens of classified rock materials to simulate fractured rock mass under high in-situ stress conditions, the test about acoustic propagation law on single fracture model of specimen under different pressures and different angles were carried out. The variation of p-wave velocity in fractured rock mass and axial stress-strain relationship in the whole test procedure was also studied. Based on damage mechanics principle and the acoustic wave propagation in cracked rock mass, comparative study on damage constitutive relation of fractured rock mass under high in-situ stress in consideration of equivalent strain and equivalent energy was performed. As the results showed, with the change of axial stress level under constant confining pressure, the change in wave velocity can be divided into three stages: slow increase (small variation in amplitude), rapid reduce (large variation in amplitude ) and accelerate reduction. When the confining pressure is constant, the maximum p-wave velocity and the peak strength of specimens increases with the decrease of the crack angle.When the crack angle is constant, the maximum p-wave velocity and the peak strength of specimens increases with the increase of confining pressure.It is identified that the theoretical calculation results of constitutive relation about elasto-plastic damage model containing variable wave velocity in the fractured rock mass is consistent with the model test results.Therefore,the constitutive relation can provide reasonable suggestions for engineering practice. INTRODUCTIONThere are a lot of joints and fractures in surrounding rock mass of deep-lying in the Jinping-II hydropower station, which has a great influence on the physical and mechanical properties of rocks and effects the acoustic wave propagation and attenuation law in rock. Many previous research and project examples has proved that sound propagation parameters are closely related to crack and stress condition. Thus, it has certain theoretical significance and practical application value to carry out researches on sound propagation characteristics and establish damage constitutive model of fractured rock mass which is related to sound propagation parameters."

Jan 1, 2015

By S. Mohanan, C. R. Kumar, S. K. Bhoja, T. Venugopalan

"A pressing issue that has often been the topic of discussion in iron-making operations in India is the high content of alumina in the country’s iron ore deposits. The presence of alumina has hampered production by affecting slag fluidity, and thereby the hot metal quality. Iron ores from Indian mines are generally rich in hematite, with traces or small amounts of goethite/limonite, kaolinite, gibbsite and quartz reported from time to time. In day-to-day production, emphasis is placed on checking the chemical analysis of product samples, but the true solution to the alumina problem lies in estimating the mineralogy of the ore samples. We developed a mathematical model, based on singular value decomposition, to predict mineralogy from classical chemical analysis. We then used X-ray diffraction patterns, scanning electron microscope analysis, and grain counting with an optical microscope to determine actual mineral compositions and to test the values predicted by the model. The results indicate that with regular calibration, the model can be used as a simple, fast and effective tool to predict on a regular basis the mineralogy of multiple samples.IntroductionIndian blast furnaces use high-grade iron ores (as lumps or as sinter) and coke (obtained from the destructive distillation of coal) as raw materials for the production of high-quality hot metal to be converted into different steel products through the Linz- Donawitz process. The iron ores are mainly sourced from the Singhbhum region of Odisha and Jharkhand states, the Bailadialla region of Chattisgarh state and the Bellary region of Karnataka and Goa states, and are mainly classified based on size as (1) lump ore (fed directly into blast furnaces), (2) fines (converted into sinter/pellets and fed to blast furnaces) and (3) slimes (< 0.15 mm; currently dumped in huge slime ponds). Any variation in the quality of the ores supplied results in variations in the production trends of hot metal."

Jan 1, 2015

By F. Awotwe-Appiah, P. Koshy, J. Dankwah, J. R. Dankwah

This research investigates the generation of an effective carbonaceous material from waste ‘pure water sachets’ and their subsequent utilisation as reductants for the reduction of the Opon Mansi iron ore. Composite pellets of Opon Mansi iron ore and pulverised carbonaceous material generated from waste pure water sachets were heated from room temperature to 1200 °C in a gas fired furnace for seventy minutes. The reduced pellet was analysed chemically for its oxygen and carbon content using a LECO Oxygen/Nitrogen and LECO Carbon/Sulphur analysers, respectively. It was observed that nuggets of metallic iron were readily produced with the carbonaceous materials acting as an effective reductant and source of chemical energy. XRD analysis of waste ‘pure water sachets’ revealed that the polymer was semi-crystalline with peaks that were identical to those of high density polyethylene (HDPE). Gas emission behaviour of the iron ore-PWS pellet was studied in a horizontal tube furnace at 1200 °C using an infrared gas analyser; the results revealed an exhaust gas rich in the reducing gases CO and CH4 along with CO2.

Jan 1, 2015

By Xing-Liang Sun, Xian-Min Han, Zheng-Guo Zhu

The study on the material properties of frozen soils in China was being developed quickly in the past decades of years, because of the increase of the engineering constructed in frozen soil regions on the Qinghai–Tibet Plateau, and numerous research results were achieved mainly about strength and deformation behaviour and constitutive models of frozen soils. Studies have shown that the deformation procedure of frozen soils is irreversible; therefore, it is more appropriate to research mechanical properties of frozen soils by means of damage mechanics theory. In this paper, an elasto-viscoplastic anisotropic damage model is presented by introduction of Perzyna viscoplastic equation into analyzing the deformation of frozen soil. In addition, an anisotropic damage evolution equation is obtained by means of extending non-viscous damage to viscous damage. Triaxial tests at different strain rates are chosen to illustrate the application of this model, and good agreement between experimental data and numerically simulated results is obtained. The calculated results indicate that, under the same conditions, the damage at higher strain rate is less than that at low one. So the phenomena are explained from damage mechanics that the frozen soil has larger elastic modulus and shear strength at higher strain rates, and explained from mechanism that the emergence and development of micro-cracks in the body of frozen soil can be to some extent retarded at higher strain rates.

Jan 1, 2015

By Guojun Wang, Zejun Chen, Wenchang Liu

Al/Mg/Ti laminated metal composite sheet (LMCS) can combine the merits of each of metal components, and obtain excellent performances. It incorporates the advantages of high strength, light weight, easy melt and atomization, and good space adaptability to substitute for the bumper Al sheet of Whipple shield structure for space debris shield. The Al/Mg/Ti LMCS was fabricated by hot roll bonding technology in a certain sequence. The manufacturing process and parameters were analyzed and studied, including the first rolling reduction, roll boding temperature and stacking structure of each metal. The microstructure of dissimilar metals and bonding interface were characterized and analyzed. The optimized manufacturing procedures and parameters were presented based on the microstructure and mechanical properties of LMCS. The research results offer some guides and references for controlling the shape of bonding interface, optimizing the annealing process, improving the mechanical properties of Al/Mg/Ti LMCS.

Jan 1, 2015

By L. A. Ayres da Silva, J. P. G. Negri, A. L. M. Ayres da Silva

"Rock hardness is dependent on the type and quantity of the various mineral constituents of the rock and the bond strength that exists between the mineral grains. As the book “The Complete ISRM Suggested Methods For Rock Characterization, Testing and Monitoring:1974-2006” explains, hardness is a concept of material property. As such, the quantitative measure of hardness depends on the type of the test employed.Among the three types of tests that have been used to measure the hardness of rocks and minerals: 1) indentation tests; 2) dynamic and rebound tests; 3) scratch tests, the authors of this paper chose indentation tests, more specifically the Vickers test, and complementary verified the correlation between the results of the Schmidt sclerometer tests (rebound tests) and the Vickers microhardness tests in a set of the same 9 (nine) granite rocks.The objective of this research was to verif y the correlation of one created index, based on the Vickers test that can be able to represent the rock material hardness. We know that Vickers tests determine the microhardness of individual rock minerals. A pyramidal shaped diamond is applied to the surface with a specified force. The area of the permanent residual deformation divided by the applied force is a measure of the hardness. Using the relative participation of the mineral components of the rock, we established a hardness index denominated EVM (Equivalent Vickers Microhardness).The correlation of the EVM with others strength properties and application parameters like UCS (Uniaxial Compressive Strength) to study sawability of granite blocks have presented very good results. The association of equivalent microhardness with others strength parameters, allowed to find powerful algorithms for analyzes of the rock materials behavior under diversified circumstances, as the sawability of granite blocks, as we can see in Fig. 1.Other very interesting correlations were found as the EVM values and that were obtained by the use of the Schmidt impact hammer for the superficial hardness determination."

Jan 1, 2015

By Z. Z. Öztürk, N. Sarica, A. H. Üçisik, C. Bindal

"Titanium oxide films were fabricated on commercially pure titanium surfaces via anodization procedure. Anodization parameters, anodization time and voltage were altered, whereas temperature and chemical composition of anodization bath were kept constant. The main idea in this study is to obtain rough titanium-oxide surfaces. The type and feature of titanium oxide formed were observed via SEM and EDX analyses. What was revealed from SEM and EDX analyses were combined with Ti-O phase diagram in order to make judgment on the type of phases obtained, e.g. solid solution and/or compounds. Studies on the different regions of each sample showed that surfaces consist of different titanium oxide compounds with various O/Ti ratios in nano level and solid solutions varying in terms of chemistry on the same sample. Thus together rough surfaces and inhomogeneous distribution of "titanium oxides" were obtained. It was also found that when anodization time and voltage were increased, more granular surface with higher O/Ti atomic ratio was obtained."

Jan 1, 2015

By Y. Q. Li, X. H. Long

In this work, structural and electronic properties of smithsonite (ZnCO3) and cerussite (PbCO3) as the typical lead-zinc oxide minerals is simulated by means of DFT. The calculated results could be concluded as: (1) The density of states (DOS) of Zn atom in ZnCO3 is nearer to the Fermi level than that of Pb atom in PbCO3, suggesting that the Zn atom of ZnCO3 is more active and easier to interact with water molecules and hydroxyl ions. Smithsonite, therefore, could be more readily depressed in the flotation process. (2) The bond population value of Zn-O (0.23) and C-O (0.92) in ZnCO3 is obviously larger than that of Pb-O (-0.01) and C-O (0.85) in PbCO3, indicating that the covalent characteristic of ZnCO3 is stronger than that of PbCO3. (3) It is shown that the charge of Pb (+1.32e) in PbCO3 is more positive than that of Zn (+1.22e) in ZnCO3, suggesting that cerussite is easier to interacting with HS- compared with smithsonite in the flotation process. In summary, the structural and electronic property of smithsonite is completely different with cerussite, leading to the difference of their flotation behaviour.

Jan 1, 2015

By T. Sugawara, S. Hara, Y. Mitsui

Surfaces of rock slopes in cold regions often become frozen in winter. Therefore, understanding time-dependent behavior of frozen rock, as well as that of unfrozen rock, is important for long-term stability assessment of rock slopes. In this study, a series of uniaxial compression tests and creep tests were carried out on Shikotsu welded tuff under dry and water-saturated conditions at -20 °C to clarify timedependent strength and deformation of the frozen rock. The influence of water content on them also was investigated. It was found that the amount of deformation of the water-saturated specimen was much greater than that of the dry specimen. It also was found that the creep behavior of the water-saturated specimen was similar to that of polycrystalline ice. These show that deformation of the water-saturated specimen is strongly affected by pore ice. The UCS of the water-saturated specimen was approximately equal to that of the dry specimen at a strain rate below 4.2×10-6/s, and its value was about 17 MPa. However, the former increased up to 26 MPa at 4.2×10-4/s with loading rate, whereas there was little increase in the latter. This means that the UCS of the water-saturated specimen was always greater than that of the dry specimen at higher strain rates. The creep life of water-saturated specimens was longer than that of the dry specimens at stress level greater than 15 MPa. These results of UCS and creep life show that inclusion effect due to presence of pore ice plays an important role on strength of the water-saturated specimen. Creep life of the non-failure specimen that was loaded for more than three days was estimated by the relationship between creep life and axial strain rate at 10 s on failure specimens. It was found that creep life of the water-saturated specimens was shorter than that of the dry specimen at stress levels less than 14 MPa. This suggests that estimation of creep life of frozen rock under water-saturated condition is important for the stability assessment of frozen rock slopes. It was clear that the loading-rate dependency of UCS was related to the stress-level dependency of creep life in both dry and wet conditions. This indicates that there are common fracture mechanism in creep and uniaxial compression tests. It also indicates that the creep life can be estimated by the relationship between the UCS and the loading rate. The time dependencies of the water-saturated specimen were in good agreement with those of polycrystalline ice. This confirms that pore ice strongly affects the strength of the water-saturated specimens as, well as the deformation behavior.

Jan 1, 2015

By P. Semberg, B. Bjorkman, C. Andersson

"In this study, the interaction between magnetite and the additive olivine was studied after oxidation as well as after isothermal reduction at temperatures in the 500º-1,300º C range. In the olivine sample, the forsteritic olivine particles react partly during the oxidation pretreatment to form magnesioferrite and vitreous silica along the particle corona. This breakdown of the olivine particles during oxidation liberates magnesium from the particles, which do not react until temperatures of above 1,150° C in reducing atmosphere. When the hematite in the sample is reduced, and when the temperature is high enough to allow solid-state diffusion at ~800º C, the magnesium of the magnesioferrite redistributes, so that the magnesium concentration approaches the same level throughout the iron oxide structure. For magnetite, this did not occur until 800° C. At 1,000° C, this magnesium reacts further with the silica in the glassy slag phase, which crystallizes into fayalitic olivine. At this temperature, the magnesium has diffused over distances of more than 600 µm from large olivine particles after 2 hrs reduction. From this point, the primary slag phase in the pellet, until melting, is solid fayalite. Upon reduction to metal, the metallization front concentrates the MgO in the remaining wustite, which can lead to MgO levels of up to 10 mole% locally. The melting point of the fayalite is raised from 1,145º C to a melting range of 1,238-1,264º C due to the MgO increase, as estimated based on phase diagrams, which were adapted to the pellets tested. Much of the olivine that remained unaltered in the oxidation process will be encapsulated by iron before the particles begin to dissolve in reducing conditions and, therefore, plays no role in the reduction before final melting of the particles occurs.IntroductionEnvironmental concerns have placed increasing pressure on the CO2-intensive iron and steel industries to further optimize operation toward higher productivity and more efficient use of reducing agents. At the same time, high demand for iron ore has caused new iron ores with lower grades and more complex chemistries to be taken into production. In Scandinavia, the main iron-bearing material is magnetite-based pellets with olivine, which allow operation with very low slag volumes and, hence, lower fuel rate ( Slagnes and Sundqvist Ökvist, 2008; Hallin et al., 1994). Both the MgO and SiO2 of the olivine, as well as the elements of the gangue of the ore, i.e., Si, Mg, Ca, Al and alkali, interact with the iron oxides to give the finished pellet product its final properties in the blast furnace. Tailoring the additive mix to be used for a certain iron ore for optimal product properties, therefore, requires detailed knowledge of the mechanisms by which these elements dissolve and react in the pellet."

Jan 1, 2015