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By Salvatore Fancello, Ferruccio Cribari, Amerigo Tanzi, Mauro D’Angelo, Massimo Lodico, Alessandro Bertero, Eliano Romani, Tommaso Gondolini, Fabio Giannelli

"The new metro line “C” entails the construction and rehabilitation of 24 stations and 21,5 km of metro line, 13 of which carried out underground; the new metro line will improve the transportation system of a congested city such as Rome.The new line “C” of San Giovanni metro station will be constructed adjacent to the existing line “A” of San Giovanni station; the new metro line “C” is deeper than line “A” and will underpass the existing station. The underpass project envisages an Artificial Ground Freezing in order to excavate two new tunnels, while keeping trains running in the safest possible condition.In order to allow trains to regularly run to and from the existing station’s line “A”, a temporary structure for rail support, during excavation of the under-crossing tunnels, was installed and a real-time monitoring system was devised in order to control both soil temperature during freezing activities and the existing station’s behavior. The monitoring system has been one of the key to the success of the project.The excavation of tunnels under the water table, with a hydraulic head of over 10 m in not homogeneous soils having different mechanical properties and permeability and below existing sensitive structures, involves special ground freezing sequences and methods, as well as peculiar drilling systems and operations, such as TDDT (Trevi Directional Drilling Technology).THE NEW “C” LINE OF ROME’S METROThe world’s most complex and extraordinary Metro System is currently being built in the heart of Rome. Its underground route stretches underneath the most important monuments, churches and historical buildings.Rome’s Metro Line C is the longest urban underground railway in Italy and it is the first line in Rome to extend further east to the Great Ring Road, thus bridging the gap between the farthest suburbs and the Historical Centre. It is an original project, carried out mostly underground at a depth of 25/30 metres below road level."

Jan 1, 2016

By William Hawker, James Vaughan, Jeff Chen, Antony van der Ent

"Nickel agromining utilizes hyperaccumulator plants (“metal crops”) to extract nickel from low-grade soils, a process that yields high-grade nickel bio-ore. This feedstock is further processed into a range of nickel products. The bio-ore is relatively free of impurities that complicate the traditional processing of laterite nickel ores. In this paper, current primary nickel processing routes and proposed nickel bio-ore processing options are summarised. A novel pyro-hydrometallurgical route demonstrated at the laboratory scale is described. This process produces a precipitated nickel hydroxide product and takes advantage of the water-soluble basic compounds in the ash to minimise reagent requirements, thereby making it suitable for small-scale implementation in close proximity to the nickel farm. In this process, nickel is precipitated from the leach solution using the basic ash wash liquor. Leaching nickel from ash generated from open air burning requires strong acid and long residence times to obtain high recoveries due to its complex nature and distribution of nickel in multiple phases. This process can be improved by optimising the ashing process with respect to nickel leachability.INTRODUCTIONHyperaccumulator plants have the unique capacity to ‘biopurify’ and concentrate certain trace elements (e.g. nickel) from the soil into their biomass (Reeves 2003; van der Ent et al., 2015). Cultivating these plants as ‘metal crops’ by periodically harvesting and incinerating their biomass generates a high-grade bio-ore (Chaney et al. 1998; Li et al. 2003). This process is called phytomining or ‘agromining’ which is an emerging technology for extracting nickel from sub-economic resources (van der Ent et al., 2015). Potential near-term applications of the technology include implementation on land ahead of processing of the underlying ore-body (Willis 2015), as a mine-site rehabilitation strategy or as an alternative crop for farmers on land that is not suitable for normal food crops. In the longer term, nickel agromining could provide a significant supplement to the nickel supply chain. Critical to the success of agromining is effective bio-ore processing. Due to the unique chemical composition of this feedstock material, existing processes are not very efficient. Our current research efforts aim to develop new process options that overcome limitations of previously trialled routes. In this paper we summarise conventional nickel process routes and proposed new options for producing agromined nickel."

Jan 1, 2016

By Jens Classen, Martino Gatti

"GENERAL PROJECT DATAThe Sparvo Tunnel is part of the “Variante di Valico” project, a new 65km (40mi) highway link between Bologna and Florence, designed to renew the existing A1 route which connects Bologna and Florence. It is composed of 2 x 2,5km (1,55mi) twin tunnels excavated inside a complex geological context, characterized by the presence of a series of surface landslides and methane gas.The inclination is 2,6 % and the minimum radius is 1.400m (4.600ft). The two tunnel tubes were excavated by a 15,6m (51ft) diameter EPB-TBM from summer 2011 to summer 2013. The internal diameter of the concrete lining is 13,6m (44,5ft), made up of precast concrete segments 2m (6,5ft) long and 70cm (28”) thick, being the largest and heaviest segments ever produced. Excavation went smooth apart from initial problems concerning clogging problems and a main bearing damage of the TBM, which are discussed in a further paper during the congress. No structural damage was observed until the end of the TBM drives.SITE OBSERVATIONS DURING THE POST-EXCAVATION PHASEThe first evidence of the stress state of the segmental lining appeared on November 20, 2013 inside the northern tube (1st drive). Ring No. 884 showed obvious signs of overstress, resulting in spalling and crushing of the concrete, and the subsequent bending of the reinforcement, as visible in figure 1.At this time the tunnel invert was already partially backfilled, and construction traffic was running through the tunnel. First safety measures included closing of the tunnel, and initial measurements of the displacements."

Jan 1, 2016

By Lisa R. Papandrea, David Chen, Walter E. Kaeck

"Construction of the University at Buffalo’s new School of Medicine and Biomedical Sciences (UB-SMBS) required excavation in variable ground to a depth of more than 40 ft adjacent to the NFTA Metro subway and Allen Street Station. Complicating the building design and construction, the new medical facility incorporates the at grade Station entrance building, requiring a combination of temporary and permanent excavation support structures, a complex sequence of ground support installation, and a mix of shallow and deep foundations to accommodate the large floor spans and concentrated column loads introduced by building over and adjacent to the Station entrance. Excavation and foundation construction was challenged by a stratified soil profile with interlayered and sensitive sands, silts and clays and complicated groundwater regime with perched and regional water tables. Efficient construction required ongoing coordination between the design team and contractor, careful field observation, and construction monitoring in several facets of below grade construction. This paper describes the design and construction of excavation support structures and foundations to manage the variable ground, congested site conditions, and complications of building adjacent and above an active subway station. Use of site instrumentation and monitoring data to provide guidance in construction when unanticipated field conditions arise is illustrated. Lessons learned in installation and sequencing of excavation support, groundwater control and foundation construction are also discussed.INTRODUCTIONUniversity at Buffalo President Satish K. Tripathi heralded the new School of Medicine and Biomedical Sciences (UB-SMBS) as a future linchpin of UB’s downtown campus that will revitalize the area and enhance western New York’s emerging bio-sciences corridor. The $375 Million, 628,000 square foot, eight story building with two basements is expected to house 2,000 faculty, student and staff allowing UB to increase class size from 140 to 180 students. It will be constructed above the Niagara Frontier Transportation Authority’s (NFTA) Allen Street Station, creating a direct connection to Buffalo’s light rail system. The 200 ft x 400 ft site is bounded by Main Street, High Street, Washington Street and the Roosevelt Apartments and adjoining parking lot at the west, north, east and south respectively, as shown in Figure 2. Groundbreaking for the new building was in October 2013 with the facility scheduled to open in early 2017."

Jan 1, 2016

By Bartho J. Admiraal

"As part of the Schiphol-Amsterdam-Almere project, the largest aqueduct in Europe is being built in order for the A1 motorway to cross the Vecht River. The A1 consists of 12 lanes and the total width of the aqueduct will be 65 m (213 ft). The total length of the structure will be 620 m (2035 ft). Speed of construction is essential for the DBFM-contract, which forms the primary reason for choosing a building method with a horizontal water retaining barrier created by low pressure grouting. After final checks on the water tightness of the silica based layer (softgel), excavation to a depth of approximately 12 m (40 ft) below the water table could be started in order to build the aqueduct.This paper presents a new approach for the calculation of the required grout volumes needed to ensure a “softgel” layer without gaps or holes. The approach applies measurement of deviations due to execution aspects in a probabilistic model. With this model, one is able to study the effects in a field application, i.e. multiple rows of grouted spheres. The results are visualized in order to analyze the risk of holes more easily. It is evident that the existence of a hole means a major leakage. By completing multiple runs, the strategy for grout volumes can be adjusted to minimize this risk.INTRODUCTIONThe Dutch Department of Waterways and Public Works invests over € 4 billion between 2012-2020 to increase the capacity of 63 km (41 mi) motorways of one of Holland’s major corridors. The A1/A6 will be transformed over a distance of 20 kilometers (13 mi). Near Muiden, the current drawbridge on the A1 for crossing the Vecht river will be replaced by a new aqueduct to be located slightly south of the existing bridge."

Jan 1, 2016

By Mohamed Elgouhary, Carol L. Tasillo, Daniel Koziol

"The Bolivar Dam, located near the Village of Bolivar, Ohio is one of a system of dams designed to provide flood control and water conservation in the Muskingum Watershed. The Bolivar Dam is a “dry dam” that only impounds water during flood events. In order to address problematic seepage, which negatively affects the structural stability of the dam, the U.S. Army Corps of Engineers (USACE) designed a partial-depth and partial-length Seepage Barrier Wall (SBW) through the upstream slope of the dam. For this project, TREVIICOS constructed a 36 in (914 mm) positive SBW by plastic concrete panel wall method and excavated using hydromill and clamshell equipment. The plastic concrete was manufactured on-site, which allowed for enhanced quality control and prompt service. This required the installation, commissioning and operation of a concrete batch plant on-site. This paper presents the challenging aspects of the design, manufacture and placement of the plastic concrete for the SBW in order to meet contract strength and permeability requirements as well as workability requirements necessary for tremie concrete placement.Project General InformationBolivar Dam is located in Northeast Ohio (Fig. 1). It is one of a system of sixteen dam projects designed to provide flood control and water conservation in the Muskingum Basin, which covers 20 percent of the State of Ohio (Fig. 2). Bolivar Dam is on Sandy Creek, a tributary of the Tuscarawas River.The Dam has been constructed, operated and maintained by the USACE, for the Muskingum Watershed Conservancy District. Its construction was completed in 1937 and it has been in operation for flood control since 1939.Bolivar Dam is a rolled earth fill dam, with a typical embankment section made of a central impervious core flanked upstream and downstream by a pervious outer shell with downstream rock toe. The embankment has a maximum height of 87 ft (26.5 m) and a crest length of 6,300 ft (1,920 m), and is comprised of the main embankment starting on the left abutment of about 1,500 ft (457 m) heading to the Northeast, followed by the terrace embankment of 4,800 ft (1,463 m) heading to the North. An upstream impervious blanket extends up to 500 ft (152 m) upstream of the dam along the majority of its length. The outlet works are to the left of the embankment, and consist of an intake structure with six gates, followed by two outlet conduits that finish in a stilling basin. To the left of the outlet works is the uncontrolled emergency spillway, which was doubled in width to 540 ft (165 m) in 1989, and excavated material utilized for construction of a stability berm against the upstream face of the main embankment. A concrete parapet wall was also installed along the upstream side of the crest during this work. In 1982, a toe drain, downstream filter berm and line of 35 relief wells were installed. The filter berm was recently extended an additional 200 ft (61.0 m) downstream and granular filters were placed over an approximate 2000 linear ft (610 m) reach of the lower terrace slope. (Fig. 3)."

Jan 1, 2016

By Ben M. Lewis, Yogesh Prashar

"The East Bay Municipal Utility District (EBMUD) is a major water utility service providing water to over 1.3 million people in the eastern San Francisco Bay Area. EBMUD manages 28 dams at 5 terminal and 23 open-cut reservoirs within a 331-square-mile customer service area. As part of a 2012 update on EBMUD’s Infrastructure Rehabilitation Plan for Distribution Reservoirs, EBMUD has decided to replace Central Reservoir, a 152.8 milliongallon open cut reservoir, with optimally sized tanks. This paper presents the results of an analytical comparison of various foundation reinforcement solutions for the proposed tanks including: Cement Deep Soil Mixed (CDSM) columns, vibro stone columns, rammed aggregate piers, and lightweight cellular concrete fill. The computational program GeoMat (www.ensoftinc.com) was used to perform simplified soil structure interaction analyses. Settlement estimates were developed for each alternative with the proposed loading and compared to an allowable differential settlement criterion established at 0.3-inches over a 50 foot length. The authors wish to present the importance of considering mat and soil interaction along with various settlement mitigation methods considered for this challenging project.INTRODUCTIONProject BackgroundCentral Reservoir is an operational open-cut reservoir located north of the intersection of 25th Avenue and East 29th Street in Oakland, California. The reservoir is bound by 23rd Avenue to the west, Sheffield Avenue to the east and Interstate Highway 580 to the north. Originally, the Central Reservoir site was a drainage swale incising into weathered bedrock formed from Pleistocene alluvial deposits. The reservoir was first constructed in 1910 by excavating a basin below grade and constructing an embankment dam on the south and cutting/filling the bedrock and alluvial deposits from the drainage swale. The main dam at the Central Reservoir site is also a DSOD (Department of Safety of Dams) jurisdictional dam and as such is regularly monitored by the EBMUD Materials Engineering Section and the California DSOD.In a 2012 update to EBMUD’s Infrastructure Rehabilitation Plan for Distribution Reservoirs, Central Reservoir was identified as a critical facility that has reached the end of its useful life and must be replaced due to: a failing panel craft lining which contains polychlorinated biphenyls in the interior coating, a roof that does not meet the current seismic code, and reduced operating levels due to potential leakage in the upper portions of the panel craft lining. Furthermore, Central Reservoir is about three times larger than required and is located at a lower elevation than other regional reservoirs in the pressure zone resulting in increased labor-intensive operational challenges and water quality operations.This project presents some challenging geotechnical demands – the site is founded on weakly consolidated Holocene Alluvium overlying weathered bedrock, the proposed structural loads are large, and the new Central Reservoir is to be placed on a pad at an elevation of 182 feet, required placement of up to 30 feet of fill over the current basin. Additionally, the project aims for a long-term foundation solution that will outlive the new replacement tanks and accommodate future site upgrades. In order to meet this goal, the differential settlement criterion for the tanks was ¼ inch over 50 feet length. Lastly, the project also aims to address EBMUD’s increasing trench spoil stockpiles by recycling discarded trench spoils as fill for the proposed tank pad."

Jan 1, 2016

By Dan Mahrt

"In June of 2009, a slope failure occurred along River Road in Bismarck, North Dakota. The slope failure affected approximately 300 feet of River Road with vertical displacements up to 3 feet, resulting in closure of the road. River Road travels along the Missouri River in Bismarck in a geologic area riddled with historic slope failures of varying sizes. River Road is a city roadway which travels along the Missouri River. The toe of the failure extended into the Missouri River, therefore methods to repair the slope needed to be constructed within United States Army Corps of Engineers (USACE) requirements, and be acceptable to the City of Bismarck. As this is a scenic area along the river, the stakeholders desired to maintain the scenic landscape along the roadway as a part of the slope stabilization.Due to the magnitude movement of the failure mass, the geometry of the failure was relatively easy to evaluate. In evaluating remediation options and collaborating with the USACE, the team determined that the scarp was situated primarily within the navigable portion of the Missouri River. This required USACE approval for any repair or remedial work downslope of the roadway. The City of Bismarck wished to reopen the roadway as soon as possible, therefore stabilization options were limited to working within the road right-of-way to avoid permitting for working within the navigable waterway.The remediation solution for this project involved a combination of driven H-pile and placement of lightweight fill to re-construct the roadway at the original grades, and avoid impacting the navigable portions of the Missouri River. This paper discusses the unique project constraints and the innovative solution using multiple technologies to successfully stabilize the slope.BackgroundIn June 2009, Bismarck, North Dakota experienced two consecutive days of significant rain resulting in over 5 inches of precipitation in a 36-hour period. Shortly after these rain events, a slope failure was noted on River Road, a city street along the Missouri River in Bismarck. Initial findings noted the slope failure affected about a 300-foot long portion of the roadway, with vertical displacements of about 2 feet. The city of Bismarck closed the roadway and began evaluating repair solutions for the road."

Jan 1, 2016

By Dianyuan Dang, Guihong Han, Wenjuan Wang, Tao Jiang, Yanfang Huang

In this study reduction kinetics and swelling behaviors in "two-step process” were investigated by weight-loss technique and visualizing physical changes of pellet. Results showed that reduction degree (r) increased with increasing temperature and time. According to the dynamic calculation, when reduction temperature was lower than 1000°C the reduction process was controlled by chemical reaction with apparent activation energy of 72.27 kJ/mol. When reduction temperature was higher than 1000 , the equation of t/[1-(1-r)1/3] against [1+2(1-r)-3(1-r)2/3]/[1-(1-r)1/3] followed straight lines, demonstrating that reduction was mixed-controlled. Swelling experiments indicated that the maximum swelling index increased with the increase of reduction temperature and CO content.

Jan 1, 2016

By Bo Jiang, Jiusan Xiao, Hongmin Zhu, Kai Huang, Shuqiang Jiao

Carbothermal selective reduction of simulative titanium slag and various titanium raw materials were presented and SiO2 was found to be partially reduced, forming a series of Fe-Si alloys during the process. Thermodynamic analysis of the selective reduction between TiO2 and SiO2 was performed using HSC 6.0 software, then a series of equilibrium experiments were designed and presented. The activity of Si reduced from SiO2 was affected by the presence of Fe reduced from FeOx and the generation of Fe-Si alloys, promoting the reduction of SiO2 in the whole process. The results of experiment are in great accordance with the calculated data obtained from thermodynamic analysis.

Jan 1, 2016

By Guo Chen, Xuefeng Liao, Tu Hu, Shengzhou Zhang, Hongying Xia, Jinhui Peng, Libo Zhang

Pine nut shell is as raw material for preparation of high surface area activated carbon (HSAAC) by microwave induced KOH activation. The effects of microwave power, activation duration and KOH/C mass rate (R) on the iodine adsorption capability and activated carbon yield were investigated. Additionally the surface characteristics of HSAAC were characterized by nitrogen adsorption isotherms and SEM. The operating variables were optimized utilizing the response surface methodology and were identified microwave power 738W, activation duration 17 min, and R 4, corresponding to a yield of 46.28 % and an iodine number of 2154 mg/g. The key pore structure parameters of HSAAC such as the Brunauer–Emmett–Teller (BET) surface area and total pore volume were estimated to be 3819 m2/g and 2.09 mL/g, respectively. The findings strongly support the feasibility of microwave heating for preparation of HSAAC from spent pine nut shell by microwave induced KOH activation.

Jan 1, 2016

By Sedef Pinar Basag, Onuralp Yucel, Ahmet Turan

Niederschlag process is commonly used to produce metallic antimony. The process is a metallothermic process which is conducted in one step for metallic antimony production. Using this method Sb2S3 is mixed with coal and metallic iron and subjected to reduction. During heating, antimony sulfide is decomposed and sulphur combines with iron to form the matte phase. Metallic antimony is collected at the bottom of the crucible. In this study, evaluation of Sb2S3 concentrate, extracted and obtained from West Anatolian Region of Turkey was investigated by using Niederschlag process. The reductant stoichiometry, reduction temperature and duration were carried out in the experiments. Chemical analysis methods by using atomic absorption spectrometry (AAS) and X-ray diffraction spectrometry (XRD) techniques were used for the characterization of the concentrate, metallic nuggets and matte phases.

Jan 1, 2016

By Yuanbo Zhang, Ruijun Wang, Qian Li, Zhao Jing, Guanghui Li, Zhengwei Yu, Chen Liu

The high content of sodium and potassium in sinter is harmful for blast furnace ironmaking. Reductive sintering technology can remove more alkali metals than conventional sintering process. In order to improve the removal ratios of Na and K, reductive sintering with both CO-containing flue gas circulation and carbon-bearing pellet was conducted in this study. Experimental results show that all indexes except the VSV and P were improved in reductive sintering with CO circulation. Flue gas circulation technique combined with carbon-bearing pellets were beneficial to reductive sintering, because it could maintain good sintering indexes and enhance the removal of Na, K. The best removal ratios of Na, K and reduction degree of iron oxides were 20.37%, 63.73% and 23.76%. In reductive finished sinter, silicate mineral becomes the important binder phase, and main iron mineral phases are wustite (FexO) and magnetite (Fe3O4).

Jan 1, 2016

By Linfeng Zhou, Rong Sun, Guanghui Li, Zhiwei Peng, Tao Jiang

The effects of microwave roasting on separation of rhenium (Re) and molybdenum (Mo) from a molybdenite concentrate have been investigated based on evaluation of the heating characteristics of the concentrate in the microwave field. The results show that a variety of operating variables, namely microwave power, sample weight, sample geometry, roasting temperature, roasting time and atmosphere significantly impact on the volatilization rates of Re and Mo. The optimum conditions for Re-Mo separation are microwave power 1300 W, sample weight 20 g, sample geometry pellets, temperature 600 oC, time 1.5 h, and atmosphere 20%O2. Under these experimental conditions, the volatilization rate of Re reaches 88.12%, while that of Mo is just 5.15%. Microwave-assisted roasting provides an alternative route to separating Re and Mo from molybdenite concentrate.

Jan 1, 2016

By Pengcheng Li, Wei-Tong Du, Yu Wang, Gang Wen

Carbon dioxide could be utilized as a weak oxidant and a kind of coolant to oxidize elements, meanwhile, helping control the temperature during the converter vanadium extraction process. However, the optimum content of CO2 and the cooling effect of CO2 at low content have not been reported. In this study, experimental research based on the influence of different CO2 contents from 0% to 25% injected to the vanadium-containing hot metal was carried out, as well as contrast experiments of O2-N2 mixed blowing. The results indicated that the optimum content of CO2 was 15%. Under the optimum condition, the oxidation of [C] was the lowest and the oxidation rate of [V] was 96.9%, while the temperature was also lower than the O2-N2 mixed blowing. This paper provide a potential property for utilizing CO2 during the converter vanadium extraction process.

Jan 1, 2016

By Jintao Gao, Zhancheng Guo, Chong Li

A new approach to enrich MFe and RO phase from the converter slag by super gravity was investigated. The samples obtained by the gravity coefficient G=600 and cooling rate V=5K/min from 1623K to 1373K appeared significant stratification and the MFe gathered at the bottom of sample. With the help of metallographic microscopy and X-ray diffraction, it is found that large quantity of white RO phase gathered at the lower part of the sample as the concentrate, with volume fraction appearing gradient distribution along the direction of super gravity, while the upper part was mainly composed of dicalcium silicate as the tailing. The mass fractions of the FeO, MgO and MnO in the concentrate are up to 40.46%, 6.9% and 3.91%, while that in the tailing are just 11.65%, 2.15% and 1.55%. The recovery ratios of FeO, MgO and MnO in the concentrate are 60.35%, 58.45% and 72.24%, respectively.

Jan 1, 2016

By Guangliang Wu, Dongchang Huang, Xinbin Liu

Oxidation Kinetics of SPHC was analyzed by TGA, and the curve of oxidation weight gain with different temperature was acquired. It is found that, when the oxidation temperature is between 500 and 600 , all the curves are linear; when the oxidation temperature is above 700 , the curves are close to parabolic. At the temperature of 900 , the oxidation weight gain increases dramatically. The TGA results indicate that the activation energy of SPHC steel is 146.19 kJ/mol at the temperature of 500 900 , and an oxidation kinetic model was set up for variable temperature. Based on the temperature change during rolling process, numerical simulation of oxide scales evolution was carried out for SPHC steel, and the simulation result agreed well with measured ones. It can provide a basis for estimating the scale growth and controlling the temperature on site.

Jan 1, 2016

By Hans Jürgen Maier, Gregory Gerstein, Florian Nürnberger

Microstructural analysis to support the development of material models provides valuable information to design complex forming operations. Damage models such as e.g. by Gurson consider spherical voids only. However, investigations of bcc steels by scanning electron microscopy reveal that voids exhibit an ellipsoidal shape with progressing deformation. The material’s weakening in the Gurson model is taken into account by the void volume fraction. Therefore, a three-dimensional characterization of the void shape offers important data for modelling. Thus, information on the anisotropy of the process of void evolution and accordingly, about the anisotropy of the deformation process is provided. Application of the information regarding the void shape anisotropy within the Gurson model is discussed.

Jan 1, 2016

By Jiang Diao, Yong Qiao, Xuan Liu, Tao Zhang, Bing Xie

Adding CaO into the vanadium extraction converter is an effective way to decrease the dephosphorization burden in subsequent steelmaking process. The crystallisation process of spinel is one of the most decisive factors in the subsequent extraction. The theoretical calculation results show that the temperature of the peak total crystallization rate will decrease 5K with basicity increasing 0.1. The relation between cooling conditions and grain size of spinels is also discussed. It is found that low cooling rate and high basicity benefit spinel crystal growth. And the non-isothermal crystallization kinetics results indicated that the restriction factors of spinel growth is that solid crystals accept new components from liquid-solid interfacial. While the sample was cooled down to 1250 (1523K) at cooling rate of 5K/min, the crystal growth is consistent with Ostwald coarsening grew up law, and controlled by diffusion of particle.

Jan 1, 2016

By Yuanbo Zhang, Huanpeng Mi, Guanghui Li, Binjun Liang, Zhiwei Peng, Tao Jiang

Ludwigite ore has not yet been utilized on an industrial scale due to its complex mineralogy and fine mineral dissemination. In this study, sodium salts were employed to enhance the separation of iron and boron by reductive roasting-magnetic separation. It was found that the separation of iron and boron as well as the iron grade and recovery were significantly improved b y the addition of Na2SO4 or Na2CO3. Under the reduction temperature of 1050 °C, reduction time of 60 min and magnetic intensity of 0.1T. Compared with the inexistence of sodium salts, the iron grade and recovery of the magnetic concentrate increased from 83.3% and 88.6% to 93.2% and 95.1%, respectively, by adding 6% Na2CO3. The XRD and microstructure analyses indicated that the iron oxides were transformed into metallic iron and the average metallic iron grains were grown to over 40μm which was beneficial for separation of metallic iron from gangue.

Jan 1, 2016