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By A. Drouin, D. Lemieux, C. Chouinard

"A gold bearing pyrite concentrate was treated at the demonstration scale (15 t/d) for the extraction of gold using a cyanide-free process. The pyrite was depressed in the flotation circuit in order to promote the flotation of copper and to achieve a sufficient copper grade to meet the copper smelter criteria. However, the recoveries of copper were 80% and only about 50% for the gold was found in the copper concentrate. The balance of the gold (50%) and copper (20%) contained in the pyrite concentrate as a reject from an overall flotation circuit. The gold grade in the pyrite concentrate is 5.40 g Au/t and copper about 0.77%. About 170 tons of pyrite concentrate were processed in the DST demonstration plant. The concentrate was first oxidized using a fluid bed to produce a calcine. Copper was then extracted as copper sulphate using diluted sulphuric acid. The residual solid was submitted to the DST chlorination process for gold extraction. Thereafter, the gold was recovered from the pregnant brine by precipitation over silica using DST proprietary process. The maximum gold recovery by chlorination was 90%. The average gold recovery by cyanidation of these calcines was 71%.IntroductionDundee Sustainable Technologies (“DST”) has developed a chlorination process as an alternative to the conventional cyanidation process for the extraction of precious metals from ores or concentrates. The technology offers viable and efficient gold recoveries and the ability to handle refractory ores and contaminated material (As, Hg, etc..). The process was successfully demonstrated on hundreds of samples provided by various mines, exploration and development projects and has evolved from laboratory experiment to demonstration at an industrial scale.DST’s chlorination process operates in a closed loop circuit, which implies that no liquid effluents are generated. The chemistry and process design allows precious metal deposits containing base metals to be treated viably. The tailings from the process are inert and non-toxic, sulphide depleted and thus non-acid generating. The efficiency of the process has demonstrated excellent gold recoveries within a fraction of the time needed for cyanidation to obtain similar results. The company completed in 2015 the construction of the first industrial demonstration plant operating with the DST technology. The plant has a capacity of 15 tons per day of mineral concentrate, and the ability to extract gold and silver utilizing DST chlorination technology.DST has tested its chlorination technology at demonstration scale on the refractory pyrite concentrate containing 5.40 g Au/t and 0.8 %copper. This auriferous pyrite concentrate, was by-product of copper concentrate respecting the copper smelter norms, is produced in a country where cyanide is prohibited and refractory to cyanidation. The pyrite concentrate was initially processed successfully (gold recoveries: > 90%) by the DST technology at laboratory (2011: 20 kg) and pilot (2014: 5 tons) scales to extract gold. About 170 tons of this pyrite concentrate were processed in the DST demonstration plant located in Thetford Mines."

Jan 1, 2017

By S. D. Graham

"The extractive metallurgy of gold is largely controlled by mineralogical factors such as the presence of refractory gold, particle size, gangue mineral associations, presence of preg-robbers, oxygen and cyanide consumers, and locking characteristics in base metal sulphides. Light microscopy and automated mineralogy techniques are regularly used to characterise the effect of these variables on gold recovery. However, despite their widespread application there are a range of limitations when grades are low. Typically, the analysis of low-grade samples requires the preparation and analysis of numerous polished blocks. This is often costly and time consuming, with complexities regarding analysing statistically representative particle quantities and problems overcoming stereological bias. This is compounded by the “nugget” effect and high tenor nature of gold mineralisation. X-ray Microscopy techniques have the potential to overcome many of these problems, in particular the statistical representivity of analysis, removing stereological bias and effectively locating phases that are present in ultra-trace proportions. In this paper we outline the potential benefits of employing X-ray Microscopy (XRM) in characterising gold losses from a typical Cu-Au porphyry project, which were illusive in 2D based analysis. The talk will also outline additional application areas of XRM within the extractive value chain."

Jan 1, 2017

By Lori A. Simpson, Linda H. Liang

A high-rise building, consisting of two tower structures occupying the entire site, is in construction in San Francisco. The North Tower will consist of 12 and 35 stories above a one-level basement. The South Tower will consist of 9 and 22 stories over one partially below-grade level of common space; a portion of the South Tower will have a three-level basement. The towers will be supported on mat foundations bearing on native very dense sand in the footprint of the threelevel basement and on ground improved with soil-cement mixed (SCM) panels that extend through loose sand and marsh deposits into very dense sand. Shoring systems for the basement excavations include cantilevered and tiedback soldier-beam-and-lagging systems and SCM cutoff walls. Subsurface conditions include loose fill and Dune Sand and loose and soft marsh deposits overlying very dense sand of the Colma formation. Groundwater is approximately 15 to 22 feet deep; the three-level basement extends below groundwater. The site is on Market Street in San Francisco, with SF Municipal Railway (MUNI) and Bay Area Rapid Transit (BART) tunnels running below Market Street approximately 45 and 36 feet north of the site, respectively. Both tunnels are 16.5 feet in diameter. The top of MUNI and BART tunnels are 25 feet and 63.5 feet below street grade, respectively. BART has stringent requirements regarding construction adjacent to their facilities, including disallowing adding pressure to their tunnel, lowering groundwater by more than two feet, and vibrations from construction activities. Design of the shoring and the foundations within the BART zone of influence were subject to their design requirements. The project was also subject to a peer review, as required by the San Francisco Department of Building Inspection. We used FLAC to evaluate stresses at the BART and MUNI tunnels and on the SCM panels. This paper will present the mitigations needed to address seismic hazards and BART restrictions and to provide adequate foundation support for a tall building with high seismic loads.

Jan 1, 2017

By H. L. Ramandi, P. Moore

"The corrosion of support bolts in underground mines has become an increasingly prevalent issue over the past two decades. With an increase of premature failures due to Stress Corrosion Cracking (SCC), it is evident that understanding the environmental factor influencing the cable bolt corrosion is critical for maintaining effective ground support hence the safety and productivity of underground spaces. Experimental testing of rock and cable bolts were accomplished in a variety of packings, including saturated clay, saturated coal, mine water and grout/cement to investigate their corrosion behaviours. Water samples were obtained and analysed for pH and electrical conductivity (EC) during the experiment. After a period of 76 days the bolts were retrieved and analysed visually. Primary factors were found to be the presence of geological materials and the aeration of the bolts, i.e. the vicinity to air and air flow, while secondary factors were observed to be pH levels and EC. It was also found that the coal/clay interfaces and the water/grout/cement interfaces are non-relevant to corrosion of rockbolts and cable bolts. The proposed framework can be applied to other reinforcement materials used in underground spaces for improved understanding of corrosion environment.INTRODUCTION Rock bolts and cable bolts are the major reinforcement elements used in mining industry to improve the rockmass properties for safe and productive mining. They are normally used to pin large beams or blocks of rock in underground mines to stabilise the rockmass in the roof (strata) against collapse. The rockbolts are typically low cost hot rolled rebar while cable bolts are composed of strands of wire, normally wound together around a central king wire (Hyett and Bawden, 1993; Vandermaat, 2014). The typical length of the bolts in underground mines is 2.4 m and 4–12 m for rockbolts and cable bolts, respectively (Vandermaat, 2014; Windsor and Thompson, 1997). Cable bolts are much more flexible and usually offer a much higher load capacity than rigid rockbolts. Their increased length and flexibility allows cable bolts longer than the height of a roadway to be used in underground mines."

Jan 1, 2017

By Qi Wang, Zengzhu Kang, Jianguo Liu, Guanglei Liu

"Due to the increase of automotive vehicles, available parking spaces become a new type of limited resource in central cities of China, especially in those old districts without visionary urban planning. Additional mechanical parking in underground space is an efficient solution to provide parking spaces under the situation where the urban space is constrained. Shichahai district is an old protected zone in Beijing which is close to the Forbidden City and there are many Hutong (alleyway) and Quadrangles (courtyard house). No spaces are available for car parking on the ground and all vehicles are parking in Hutong without order currently. The local government plan to do renovation work for this district and improve the residential environment. Several innovative solutions are studied including parking in deep shafts, parking under existing buildings by under-pinned method, parking under buildings by covered excavation method, parking under roads built together with utility tunnel etc. 5000 difference types underground parking spaces are planned to be constructed in the following three years. Project examples are also introduced in this paper. INTRODUCTIONCar parking resources are very limited in central cities, especially in old districts without planning for increasing automotive vehicle volume. Traffic get worse when cars park on the side of the roads or move slowly to find parking spaces. Investigation shows the normal (parking space/ automotive vehicle volume) ratio is about 1.2 in most big cities such as New York, Tokyo and Hong Kong, while this ratio is only 0.5 in Beijing. One solution is to move cars out of central cities. But there are still huge parking requirements for the citizens living in central cities. Shichahai district is an historic protected zone in Beijing which is close to the Forbidden City and there are many Hutong and Quadrangles (refer to Figure 1 for project location). No spaces are available for car parking on ground and all vehicles are parked in Hutong without order currently. The local government had a plan to do renovation work of this district and improve the residence environment. 5000 different types of underground parking spaces are planned to be constructed in the following three years. One project designed and to be constructed by Zhongyan Technology will be introduced in this paper. Other innovative solutions will be introduced briefly as well."

Jan 1, 2017

By Tracy Brettmann, Melis Sutman, C. Guney Olgen

"The use of energy piles for geothermal heat exchange has been steadily increasing during the last decade, yet there are still pending questions on their behavior during temperature changes. This paper focuses on the thermo-mechanical response of three full-scale energy piles installed in Richmond, TX. The behavior of test piles subjected to thermo-mechanical loadings was studied in situ with the aim of quantifying the thermal influence on the performance and capacity of energy piles. An extensive field test program, including conventional pile loading tests and application of heating-cooling cycles was conducted on the test piles during a period of six weeks. For thermal load applications, the heat exchanger fluid with maximum temperature of 113°F (45°C) and minimum of 47°F (8°C) was circulated in the geothermal loops placed at the center of the test piles. Optical fiber sensors, vibrating wire strain gages, thermistors and thermal integrity profile wires were installed to monitor the strain and temperature variations along the energy piles throughout the field tests. The strain and temperature profiles during heating-cooling cycles on the test piles under static loads and without a maintained load were monitored to investigate the effect of thermo-mechanical and pure thermal loads on the energy piles, respectively. Conventional pile load tests were applied before and after the application of thermal cycles. The results of the pile load tests are compared to evaluate the effect of temperature cycles on pile capacity.IntroductionEnergy piles are deep foundation elements designed to access and exploit the relatively constant temperature of the ground and its heat storage capacity for efficient heating and cooling of buildings. The deep foundation elements that are already in place for structural support are integrated with adsorber pipes to perform as heat exchangers connected to ground source heat pump (GSHP) systems. With the use of energy piles, the heat energy is fed into and withdrawn from the ground for cooling in the summer and heating in the winter, respectively.Energy piles present an innovative way to harvest near-surface geothermal energy and to provide lower carbon emissions, however, there are still pending question on their performance. During heating-cooling cycles, energy piles experience temperature changes, which result in expansion or contraction of the piles."

Jan 1, 2017

By M. B. Kime, E. K. Kanowa

"Heap leaching of low-grade copper-cobalt oxidized ore and solvent extraction of copper, cobalt, manganese, and zinc were investigated. Heap-leaching parameters were optimized using agitated and tray batch leaching tests, capped by tests on a pilot semicontinuous heap-leach plant. The optimum pregnant leach solution yielded 2,350 mg/L Cu, 3,800 mg/L Co, 3,600 mg/L Fe, 130 mg/L Mn, 25 mg/L Zn, and 0.58 g/L solids in suspension, with pH and acidity of 1.27 and 3.66 g/L, respectively. Copper, cobalt, and impurities (Mn and Zn) were extracted using (v/v) 30% CP-150, 20% IONQUEST® 290, and 20% D2EHPA, respectively; overall recoveries of copper, cobalt, and impurities were 98, 99, and 70%, respectively.RÉSUMÉ La lixiviation en tas des minerais oxydés de cuivre et de cobalt et l’extraction par solvant du cuivre, du cobalt, du manganèse et du zinc ont été étudiés. Les paramètres de lixiviation en tas ont été optimisés à l’aide d’essais de lixiviation en discontinu sur un plateau, complétés par des essais relatifs à une usine pilote de lixiviation en tas en semi-continu. La liqueur-mère optimale a produit 2 350 mg/L de Cu, 3 800 mg/L de Co, 3 600 mg/L de Fe, 130 mg/L de Mn, 25 mg/L de Zn et 0,58 g/L de solides en suspension, avec un pH et une acidité respectifs de 1,27 et 3,66 g/L. Le cuivre, le cobalt et les impuretés (Mn et Zn) ont été extraits avec un pourcentage volumique (v/v) de 30 % de CP-150, de 20 % d’IONQUEST ® 290 et de 20 % de D2EHPA, respectivement. Les récupérations totales de cuivre, de cobalt et d’impuretés étaient de 98 %, 99 % et 70 % respectivement.INTRODUCTIONBoss Mining S.P.R.L. is a privately owned hydrometallurgical plant located in southeastern Democratic Republic of Congo. It treats oxidized ores of copper and cobalt that are recovered by sulphuric acid heap leaching (Trujillo, Cisternas, Gálvez, & Mellado, 2014; Kime, Kanowa, Mulaba- Bafubiandi, & Diyambi, 2016) and solvent extraction processes (Crane, Urbani, Dudley, Horner, & Virnig, 2009; Fisher, 2011; Kime et al., 2016). The ore to the plant is primarily sourced from the Luita and Mukondo mines. Geological prospecting work by Gecamines and Boss Mining showed that the Mukondo mine contains a very large cobalt reserve not yet exploited, but with grades as low as 0.2%.Currently, Boss Mining is focusing on the production of copper, but is investigating methods to efficiently produce both copper and cobalt. A challenge in the production of cobalt from this ore is its presence in the third oxidation state. This requires the addition of reducing agents, which increases the overall operating cost (Kime & Makgoale, 2016). Cobalt solvent extraction is also very sensitive to impurities such as nickel, zinc, manganese, and aluminum, which are often co-extracted (Swartz, Donegan, & Amos, 2009). This sensitivity to impurities requires the optimization of operational parameters to lower impurity levels as much as possible in the electrolyte."

Jan 1, 2017

By William (Bill) H. Walton

"I arrived in Chicago in 1993 with Dr. Ralph Peck’s University of Illinois bulletin titled Engineering Properties of Chicago Subsoils (Bulletin 429), which he published in 1954 with William Reed. Being an outsider, I wanted to learn from Chicago geotechnical practice leaders that included Clyde Baker, Jr., John Gnaedinger, Charles Pfingsten, Dr. Safdar Gill, Robert Lukas and Dr. Jorj Osterberg, who have influenced foundation designs for the structures that make up the contemporary Chicago skyline. One of my immediate goals was to get the Illinois Structural Engineering license to be on par with the likes of Eli Cohen, Mike Tylk, Stan Korista, Bob Halverson, Joe Burns, Ron Johnson, Bill Baker, Bob Sinn, Chuck Anderson and Dave Eckmann, who have led their structural firms in the design of the skeletal core and frames of many of Chicago’s iconic buildings (and for many other buildings around the world). From my time with GEI Consultants (GEI), then on with STS Consultants (STS, and now AECOM), and now back with GEI, I have had the opportunity to analyze and design foundations and, with the help of many skilled foundations and building constructors, to verify that predicted foundation performance matches actual movement data. The theme of Chicago’s foundation design practice is to assume and verify. In 1948, Peck published the History of Building Foundations in Chicago (Bulletin 373) that was updated in 1998 by Baker, Pfingsten and Gnaedinger, who meticulously documented hundreds of Chicago’s foundations, and have shown the value of advanced analyses and testing to advance the deep foundation design practice that includes a variety of high-capacity driven and drilled deep foundations. Mehmet Uyanik, Peck and Baker have made Chicago’s subsurface into a full-scale foundation test laboratory. They confirmed soil mechanics principles like Terzaghi’s 1-D consolidation theory when early foundations bearing on sand-clay crust over soft to medium silty clays (e.g., Auditorium, Masonic Temple, Monadnock Block and Old Board of Trade buildings) took 40 to 60 years to consolidate clay 1 to 2 ft (0.3 to 0.6 m). They also confirmed proven increases in bearing pressures based on measured performance of deep foundations bearing on the glacially derived hardpan clay till and in solid dolomite that underlies Chicago."

Jan 1, 2017

By J. Herbst, J. Groppo, A. Noble, R. Q. Honaker

"Coal and coal byproducts produced annually contain enough rare earth elements (REEs) to meet current U.S. demand. The REEs exist in the form of minerals, ion-exchanged elements associated with clays and chemically bonded elements within the organic coal matrix. Researchers at three universities have collaborated to evaluate the effectiveness of existing physical and chemical concentration processes for the recovery of the REEs. The efforts have found that physical separation processes can increase the total REE content in the thickener underflow material collected from a Central Appalachian coal cleaning facility from around 300 ppm to values greater than 17,500 ppm on an ash basis. On the other hand, leaching was effective in recovering REEs from coarse middlings materials collected from multiple coal basins as indicated by recovery values exceeding 80%. Based on material characterization data and process evaluations conducted for several potential feed coal sources, economic recovery of the REEs will require byproduct production of both clean coal and REE concentrate using a process flowsheet that is unique for each source. INTRODUCTION Recent studies initiated by NETL showed that U.S. coals contain significant amounts of rare earth elements (REEs), suggesting that rare earth minerals (REMs) and/or REEs can be produced as byproducts [1]. According to the report, the richest source of REEs is the Central Appalachian coal. At present, there are 208 coal preparation plants located in the region (WV, KY, PA, VA, AL, TN) with a capacity of 166,495 tons/hr or more than 1 billion tons annually [2]. If only a portion of these plants are retrofitted with advanced separation processes, the U.S. coal industry can become a significant producer of RE minerals as byproducts. An inherent advantage of becoming a byproduct producer of REEs is that no mining cost needs to be part of the product cost. Other researchers have also shown that coal can be a significant source of REEs. The average sum of the rare earth plus yttrium (REY) concentration of the world coal is approximately 68.5 ppm, which is lower than the corresponding upper crustal concentration (UCC) (168.4 ppm). However, the average REY content of the mineral matter in the world (404 ppm) and U.S. coals (517 ppm) are 3 times higher than the average UCC. Some of the mineral matter in Russian and Chinese coals have REY concentrations in the range of 0.68 to 2.03% and contain a better source of higher value REYs than many primary rare earth deposits [3]."

Jan 1, 2017

By M. Savella

The Runruno Gold Project is located on the island of Luzon, approximately 200 km north of Manilla in the Philippines. The mine is a surface mine operation and use the proven BIOX® and carbon in leach processes to recover gold, and the ASTER™ process for detoxification of the CIL residue prior to discharge to the Residue Storage Impoundment (RSI). Work to date has defined a mineral resource of 1.39 million ounces of gold, and the operation will produce 96,700 ounces of gold per annum over a mine life of 10.4 years. The BIOX® circuit is designed to treat 140,000 tpa of concentrate with a design capacity of 404 tpd of concentrate at a design sulphide sulphur grade of 17% S2-. The Runruno project is the first BIOX® plant to implement the Generation III BIOX® design principles. As part of the Generation III BIOX® program Outotec supplied a turnkey, containerised metallurgical laboratory to facilitate the first four stages of the BIOX® and ASTER™ inoculum build up requirements. BIOX® inoculum build-up was started during early January 2015 with 5 litres of stock cultures shipped from South Africa. The BIOX® culture was successfully adapted to concentrate produced from the mini plant during March 2015. The ASTER™ inoculum build-up commenced during early August 2015 utilising 27 litres of ASTER™ bacterial inoculum already adapted to similar process conditions expected during commercial operation. This paper will detail the various stages of inoculum build-up through to commissioning and ramp-up of the BIOX® and ASTER™ Processes at the Runruno Gold Project. The paper will highlight some of the factors affecting the commissioning process as well as the improvements seen through the introduction of the Generation III BIOX® design principles.

Jan 1, 2017

By Amauri Garcia, Rodrigo Valenzuela Reyes, Noé Cheung, José Eduardo Spinelli, Leonardo Fernandes Gomes, Rafael Kakitani

"The present research work deals with directional solidification (DS) of both Al-15wt.%Si and Al-15wt.%Si-1.5wt.%Mg alloys and further characterization of the related microstructures. The growth of refined primary Si and refined eutectic is well-known as positive in order to improve mechanical properties of the Al-Si based alloys. Alloying is also an effective method to strengthen the Al-Si based alloys, in which Mg is considered an important alloying element. However, lack of investigation regarding the effects of Mg on microstructure of these alloys is noted. So, in the present research work emphasis is given on both dendritic and eutectic growth being affected by solidification kinetics (V-growth rate and G-thermal gradient) during transient directional solidification. Experimental evolutions of microstructural spacing of both alloys have been determined which becomes possible to understand the effects of Mg coupled with the effects of growth rate on the final microstructural arrangements. A direct comparison of the tensile mechanical properties obtained for the alloys is also performed. It is shown by these correlations that the addition of Mg generally improves the tensile mechanical resistance with a minor decrease in ductility. Furthermore, the Scheil solidification path of the ternary Al-Si-Mg alloy was determined using the computational thermodynamics software Thermo-Calc, resulting in the following sequence of precipitation: Liquid-Si-a (Al)+Si- a(Al)+Si+Mg2Si. This sequence is compared with the experimental microstructure findings.INTRODUCTION Al-Si alloys containing from 4wt.% to 22wt.% Si comprise more than 90% of all Al-based castings. Parts manufactured with these alloys have a wide range of industrial applications due to their excellent castability, crack resistance, good corrosion resistance, good weldability, low density and high strength (Bray, 1976; Zolotorevsky, 2007; Reyes, 2017). Hypereutectic Al-Si alloys are widely used and researched in the automotive and aerospace sectors due to the low coefficient of thermal expansion, resistance at high temperatures, good wear resistance and high strength (Reyes, 2017; Tebib, 2013). Above the equilibrium eutectic composition (~12.5wt.%Si) the amount of primary Si particles becomes significant (Lasa, 2003). In the place of conventional hypoeutectic Al–Si, there is growing interest in hypereutectic Al–Si alloys as a candidate material for the high-quality engines because a higher volume fraction of silicon may bring about superior properties (Matsuura, 2003)"

Jan 1, 2017

"Mineral separation by exploiting the differences in mineral or metal specific gravities (sg) has been used since antiquity. In the modern era, this is most commonly seen in the recovery of gold by the use of centrifugal concentrators and the separation of coal (low sg) from waste rock (high sg) using heavy media cyclones and jigs. Other metals, notably oxides of tin and tungsten, are successfully recovered using some combination of jigs, spirals and shaking tables. However, many conventional gravity separation systems are limited to fairly coarse (>1 mm) to medium (>100 micron) particle separations due to the limitations of the gravitational separation forces in conventional equipment.Many of the high specific gravity minerals of interest are friable (e.g. cassiterite, wolframite, etc.) and excessive fines are generated in the grinding/comminution circuits which cannot be recovered with conventional equipment and may be lost directly to the tailings stream. Recent developments in centrifugal gravity separation equipment specifically designed for fine or ultra-fine particle separation and recovery have resulted in heavy mineral particle recoveries as fine as 10-20 microns. Ongoing research work has also identified the benefit of closed-circuit, multi-stage gravity recovery circuits using some combination of centrifugal concentrators and conventional equipment (tables, spirals, flotation, etc.) which can substantially increase overall plant recovery and final concentrate grade.This paper will provide details of the evolution of non-fluidized bed gravity concentrators for high sg mineral recoveries, correlate laboratory scale development work with plant results to confirm scale-up, and show how recent flowsheet developments have contributed to significantly improved plant performance.IntroductionGravity concentration is one of the oldest and most cost effective metal and/or mineral recovery systems, ranging from the classic hand panning of alluvial gold, through to the large scale production of a wide range of metals and minerals, including gold, silver, PGMs, black sands, coal and iron oxides. Conventional gravity recovery systems, comprised of some combination of sluices, spirals, jigs and shaking tables have limited application in fine particle (i.e. <100 microns) recovery, or where there are limited differences in particle specific gravities (sg), e.g. the separation of high sg, high value metal oxides (e.g. those of tin, tantalum or tungsten), from medium sg, lower value metal sulfides such as pyrite and pyrrhotite. These unit operations tend to have limited capacity, and while double and triple turn spirals and multi-deck tables have been developed, extensive floor space is often required in order to process the tonnages incorporated in the modern mineral processing plant."

Jan 1, 2017

By Vidyaranya Bandi, Madhav Madhira, Kota Vijay Kiran

"Using hyperbolic relationships for the non-linear responses of shaft and base resistances, a method is proposed for estimating initial shaft and base stiffnesses and ultimate shaft and base resistances of a pile from pile load test results. An iterative procedure is used to arrive at the values of shaft-soil and base stiffnesses and the ultimate shaft and base resistances. The method is applied to load - displacement data available from pile load test results to illustrate its efficacy.INTRODUCTIONA pile foundation is the most effective and economical solution in transferring large vertical loads to deeper depths. As the pile is subjected to axial load, the soil mass surrounding the pile is vital in providing vertical support for the pile. The nature of pile–soil interaction is three dimensional and to complicate the problem further, response of soil is nonlinear. Finding a closed form solution to such problem is extremely difficult. Several methods were developed to study and predict the response of the composite pile–soil system. Faruque and Desai (1982) implemented both numerical and geometric non-linearities in their three dimensional finite element model. Rajashree and Sitharam (2001) developed a nonlinear finite element model of batter piles under lateral loading using a hyperbolic relation for static load condition and modified hyperbolic relation, including degradation and gap for cyclic load condition.The ultimate capacity of the pile is estimated considering the strengths and unit weights of soil layers with depth, overburden pressure and other relevant parameters. The estimated capacities always need to be validated by conducting initial maintained load test. The estimated capacity may differ with the actual at site since the values of strength, stiffness, interface resistance between pile and soil, lateral earth pressure coefficient with depth and soil stratification, etc., differ from the design parameters considered for estimating the ultimate capacity of pile. The estimation of axial capacity of piles involves considerable uncertainties in selection of appropriate design parameters and the design rules are not always consistent with the installation procedures/processes involved."

Jan 1, 2017

By Pingchao Ke, Zhihong Liu

"To overcome the problem that scoroditeis not stable in neutral and alkaline solutions, we proposed and investigated a synthesis method of scorodite coated in-situ with hydrated ferric oxide in the Fe(II)-As(V)-H2O system at the initial Fe(III)/As(V) molar ratios larger than 1.0.The synthesis was carried out at 90?,pH 1.5 under atmospheric pressure. During the synthesis, oxygen gas was conducted and bubbled into the system to oxidize Fe(II) ions into Fe(III)ions, and Na2CO3aqueous solution as neutralizing agent was added controllably into the system for keeping the pH constant at 1.5. In this study, three samples of scorodite were synthesized at the controlled initial Fe(II)/As(V) molar ratios of 1.0, 2.0 and 3.0, respectively. The characterizations of the samples by HRTEM, TEM/EDX, and chemical composition indicated that the particle surfaces of scorodite synthesized at the initial Fe(II)/As(V) molar ratio of 2.0 and 3.0 were coated in situ by a film of hydrated ferric oxide with the thickness of several nanometers, while the sample synthesized at the initial Fe(II)/As(V) molar ratio of 1.0 was uncoated scorodite. The TCLP and long-term leaching for the toxicity characteristic of the samples showed that scorodite coated in situ with hydrated ferric oxide was stable in a wide pH range from 3.0 to 10.0, with the arsenic concentrations in the leaching solutions less than 1.0mg/L. Nevertheless, uncoated scorodite was unstable under the conditions from weak acidity to alkalinity, with the arsenic concentrations in the leaching solutions larger than 5.0 mg/L.INTRODUCTIONArsenic pollution is a challenge for environment and health and has been an important issue for scientists (Hopkin, 1989).Arsenicis commonly associated with ores or concentrates of nonferrous metals, mainly as independent arsenic bearing minerals such as arsenopyrite (FeAsS), tennantite(Cu12As4S13), enargite (Cu3AsS4), cobaltite (CoAsS), and gersdorffite (NiAsS), realgar (As2S2), orpiment(As2S3), etc.(Matschullat, 2000; Mandal & Suzuki, 2002; Long & Peng, 2012). In the nonferrous metallurgical processes, arsenic is enriched mainly in such arsenic bearing materials as various flue dusts, residues, and anode slimes, which results in the accumulation of arsenic in the system owing to the circulation of those arsenic-bearing materials back to the system and the pollution to the environment (Harris, et al, 2003).In addition, the utilization of arsenic is limited and has been decreasing owing to its toxicity and carcinogenicity. Therefore, arsenic has to be removed from those arsenic-bearing materials and discarded safely (Dutrizac & Jambor, 1988; Monhemius & Swash, 1999; Drahota & Fillippi, 2009).In this case, how to immobilize arsenic has become a difficult problem which must be solved. Among the methods of immobilizing arsenic which have been proposed and investigated, immobilizing arsenic into a stable mineral to fix it, has been realized as a promising method and becomes a research focus(Dutrizac et al, 1987; Dutrizac & Jambor, 1988; Demopoulos et al, 1995; Fujita et al, 2008a; 2008b).Scorodite has been known as one of the best minerals for immobilizing arsenic, owing to its high stability under weak acidic condition, the arsenic content as high as 32wt%,and good crystallinity benefiting the separation of solid to liquid(Daivid et al, 1999; Zhu & Merkel, 2001). Scorodite can be synthesized from arsenic containing solutions under both hydrothermal and atmospheric conditions, and a lot of work has been done on the synthesis of scorodite and its leaching stability characterization (Filippou & Demopoulos, 1999; Gomez et al, 2011).Two plants for the immobilization of arsenic as scorodite have been putin to operation in Chile and Japan, respectively (Filippou & Demopoulos, 1999; Amir et al, 2016)."

Jan 1, 2017

By N. Dashbold, E. Rudnik

"Waste electric and electronic equipment currently comprises the fastest-growing waste stream in the world, but at the same time it is seen as an important source of metals for the recycling industry. E-waste is usually treated pyrometallurgically, with hydrometallurgical methods used to a lesser extent. This paper reports the results of research on the selective recovery of copper from smelted low-value electronic waste. Pyrometallurgical pretreatment of the scrap allowed the removal of plastics and the increase of metal content in the material. The obtained alloy of copper, zinc, tin and silver was a multiphase solid consisting of two brass phases and inclusions rich in iron, lead and silver. Copper alloy was further anodically dissolved in ammoniacal chloride solution. It resulted in high degradation of the material and accumulation of the metals mainly in the slime. The slime was then leached in acid or ammoniacal chloride and sulfate solutions followed by selective copper electrowinning. Hydrochloric acid was the most efficient solvent for the slime, but ammoniacal solutions were more selective for copper. Copper could be leached with 96 to 100 percent and 87 percent efficiency from the slime by the chloride and sulfate solutions, respectively. Copper with 90 to 99 percent purity at current efficiency of 42 to 76 percent was obtained from the acid solutions, while copper with 98 to 99 percent purity at current efficiency of 60 to 86 percent was deposited from the ammoniacal baths. IntroductionObsolete electrical and electronic equipment makes up the fastest-growing waste stream in the world (Baldé et al., 2015), due not only to the introduction of wider ranges of new types and models of a variety of electronic products but also to the shortening of their life-spans, sometimes referred to as planned obsolescence by producers (Keeble, 2013). About 42 million tons of electronic waste, or e-waste, are estimated to have been generated globally in 2014 (Baldé et al., 2015), and it is expected that in the European Union alone the waste electrical and electronic equipment (WEEE) stream will reach more than 12 million tons by 2020 (European Commission, 2015). Accurate evaluation of e-waste generation (Wang et al., 2013) and its global transport (Breivik et al., 2014) is difficult, mainly due to a lack of high-quality data related to its market and socio-economic dynamics.Many countries introduced legislation to control e-waste flow, collection and recycling. For example, Directive 2012/19/EU on waste electrical and electronic equipment (European Parliament and the Council of the European Union, 2012) obliges all E.U. members from 2016 to maintain a minimum collection rate of 45 percent of the total weight of WEEE collected. From 2019, the minimum collection rate to be achieved annually shall be 65 percent of the average weight of electronics placed on the domestic market in the three preceding years, or alternatively 85 percent of WEEE generated in the territory of the particular member."

Jan 1, 2017

By Claude Bazin, Jalna Lamontagne

"The operators of mineral processing plants collect daily samples from strategic process streams with a view to prepare production balances to assess plant performances. The rules to minimize the risk of systematic sampling errors are known and applied in many mineral processing plants. The mass of the sample to be collected is calculated to yield a target measurement reproducibility considering the fundamental error associated to the sampling of heterogeneous material. This paper demonstrates that this practice is partly valid if one does not account for the time variation of the ore composition during the day. The concept is demonstrated using samples collected on a 30 minute basis from different streams of a gold ore concentrator. Results show that depending of the natural variability of the stream characteristics the mass of the daily samples may not be the critical variable to obtain reproducible measurements. On the other hand the number of cuts taken during the day could impact on the variance of the measurements obtained from daily samples.IntroductionMineral processing plants may treat several thousand tons of ore every day to produce concentrate or impure gold ingots. The operation and performances of these plants are monitored on a daily basis through the collection of ore samples from various streams of the processing circuit. The samples are prepared and assayed to obtain the concentrations of target elements that are subsequently used to calculate the mass flowrates in the streams of the circuit and ultimately the distribution of the target metals for the estimation of the plant performances (Morrison, 2009; Lachance and Leroux, 2016).The acquisition of representative and reproducible samples is therefore the first step in the characterization of plant performances. The term representative sample is used here to indicate an unbiased sample, i.e. a sampling procedure that does not introduce a systematic error. Rules for the collection of unbiased samples are reviewed in the literature by different authors (e.g. Morrison, 2009) and are not discussed in this paper. The term reproducible indicates the dispersion of the measurements around the average value of a characteristic of a stream meets an acceptable level of variance. The reproducibility of a measurement process (sampling and analysis) is assessed by the relative standard deviation or coefficient of variation of the measurement that is a function of the sampling and assaying errors (Morrison. 2009; Gy, 1979). Usually the focus is put on the fundamental error of sampling whose variance can be controlled by the choice of the primary sample mass or adequate particle size reduction during the preparation of secondary or tertiary samples extracted for the chemical analysis. When a sample is taken from a stream that exhibits a time varying characteristic, the obtained measurement exhibits a variability that is not only a function of the sample mass but also of the natural variability of the ore in the sampled stream. This paper examines this aspect of the sampling of a time varying process on the reproducibility of composite samples for a day of production."

Jan 1, 2017

By Pierre Gouvin, Michael Oakland

"This paper covers the rapid response methods used to monitor the emergency response to damage to an historic structure. An architectural gem, the latest incarnation of the old south Church was completed in 1875, utilizing local conglomerate (pudding stone), combined with brownstone and other materials to make an incredible showcase for priceless stained glass and other details epitomizing the height of the American Industrial Revolution. As part of required American with Disabilities retrofits to the adjacent Metropolitan Boston Transit Authority Station (MBTA), a support of excavation system was implemented with tradition sheet piles. During excavation (SOE) it was determined that Jet Grouting would need to supplement the sheeting to close openings in the SOE. During Jet Grouting, the eastern side of the structure was bisected, and lifted over 2 inches up and to the south. The movement occurred rapidly, within minutes, and subsided when Jet grouting was discontinued. The paper will describe the nature of the immediate response to get a real time monitoring program established, and the follow on monitoring program that ensued to provide the needed information to the stakeholders about this critical structure to evaluate stability, safety and to develop a long term remediation plan. The real time systems and instruments used consisted of Automated Motorized Total Stations (AMTS) and Automated Crackmeters. The Paper will describe the techniques used to control construction in safe manner.INTRODUCTIONThe Old South Church of Boston was constructed in 1875 and is one of the best examples of High Victorian Gothic Architecture in the Northeast. (Fig. 1) shows the newly constructed Old South in 1882. The Roxbury Conglomerate used to construct the church combined with large stained glass window by Clayton and Bell of London provides its unique appearance. Like most of the structures constructed in Boston’s Back Bay at that time, the church is founded on timber piles which penetrate the fill and organic soils to bear in the upper Boston Blue Clay. The churches interior includes high vaulted plaster ceilings and a 1920’s E. M. Skinner organ with exposed pipes as long as 32 ft. in length. The Church was added to the list of National Historic Landmarks in 1970 and is a featured Boston attraction."

Jan 1, 2017

By Sebastian Ernst Volkmann, Felix Lehnen

"INTRODUCTIONWhile today’s mine planning of land-based ore deposits follows methods, which are well established, mining standards for the deep-sea have not established. Having gained a basic understanding of geological settings, there is still a lack of tools and methods to assess and plan future mining projects in the deep-sea. In the framework of the “Blue Mining” research project (2014-2018) technologies and methods for the exploration and exploitation of deep-sea minerals are developed that will bring deep-sea mining a step closer. The “Blue Mining” project receives funding from the European Commission (EC; Framework Programme 7; GA No. 604500) and addresses all aspects of the value chain in the field of deep-sea mining. The project philosophy is that deep-sea mining is planned and executed in the most responsible manner: Ensuring societal benefits and profitability at acceptable resource utilization and lowest possible environmental footprint (Volkmann 2014).Inspired by the high-tech farming industry, a concept to mine seafloor manganese nodules (SMnN) was developed. Mining is considered to be similar to the potato harvest on land (Figure 1), which involves mining a field partitioned into long, narrow strips (Volkmann and Lehnen 2017). The proposed mining system composes of one mining support vessel (MSV), one or two self-propelled, crawler-type seafloor mining tools SMT(s) and different types of underwater vehicles. The MSV follows the mining route of the SMT(s), picking up the about potato-sized nodules from the seafloor. The ore is pre-processed in situ and is lifted on board of the MSV, where the ore is dewatered and loaded onto bulk carriers for transport to the purchaser. Processing and refining of ore is not subject of “Blue Mining” research."

Jan 1, 2017

By Karl A. H iggins, James P. Racine

"Displacement Cast-in-Place (DCIP) piles are not a common deep foundation type in the Washington, DC Metro Area market. As a result, less regional data is available for these foundations compared to other alternate deep foundation types. Displacement cast-in-place piles (DCIP) differ from traditional Auger Cast-In-Place (ACIP) piles in that the pile annulus is formed by pushing a partially-flighted, auger bit to depth via a large mandrel. The auger bit includes a displacing body near the bottom of the tooling. Therefore, little to no spoils are generated during installation and the soil around the annulus is largely densified in-place due to the displacing body being slightly larger than the mandrel it is attached to.Due to this densification, one would expect that the theoretical DCIP capacities (compression or tension) would be greater than an ACIP pile (assuming a pile of similar length and diameter). After 20 static load tests and the installation of over 6,000+ piles on the MGM National Harbor Casino Project, the differences in pile support characteristics between DCIP and ACIP piles of same size and depth was small. The performance of both pile types depended on the density and type of soil within the bearing stratum. In some early cases of DCIP use, the performance exceeded expectations and appeared to be more in line (or better) than typical capacities obtained from driven displacement piles. Other times, the tip elevations could not be achieved or were so difficult to achieve that installation delays occurred and/or significant additional engineering effort was required to address piles short of their requirement embedment.This paper will discuss the limitations of DCIP pile installation in dense Coastal Plain soils and will present the lessons learned during this project. The paper will also compare the DCIP pile type to both conventional ACIP and driven displacement piles utilizing regional and site-specific load test and installation data."

Jan 1, 2017

By James G. Ulinski, Sebastian Lobo-Guerrero, Vishal B. Patel

"Recently modified design equations used in the transportation industry to calculate side friction and end bearing capacity for drilled shafts are now providing more realistic estimations of capacities than did previous methods. Using multiple case studies and test results from various projects, a more realistic design approach was formulated by the Federal Highway Administration (FHWA), which resulted in greater values of ultimate capacity for side friction and end bearing and in a more efficient design overall.In 2010, the FHWA published GEC-10 – Drilled Shafts: Construction Procedures and LRFD Design Methods, which illustrates a different method of calculating side friction and end bearing resistance and results in greater values for design. In 2014, the Association of State Highway and Transportation Officials (AASHTO) adopted the method put forth by FHWA, which was included in its LRFD Bridge Design th Specifications, 7 Edition. The Pennsylvania Department of Transportation (PennDOT) recently adopted and incorporated the similar methodology as AASHTO for calculating side friction and end bearing for drilled shafts in rock, and these changes are reflected in the 2015 edition of the PennDOT Design Manual, Part 4 (DM-4). This article discusses the past and current design methodology along with a project case study with results from Osterberg Cell (O-cell) load testing, which presents a comparison between the design resistances of ultimate side friction and end bearing and the measured capacities at failure.The Old and the NewEditions of the AASHTO LRFD Bridge Design Manual from 2012 and earlier estimated ultimate side resistance, qs, in rock using the following equation (modified from Horvath and Kenney, 1979):qs=0.65aEpa(qu/pa)0.5 < 7.8pa(f ’c/pa)0.5 where: qu is the uniaxial compressive strength of the rock in ksf; pa is the atmospheric pressure in ksf; aE is the reduction factor to account for jointing in rock; and f ’c is the compressive strength of the concrete in ksi. For intact rock, previous versions of the AASHTO manual required that the ultimate end bearing resistance, qp, was calculated using the following equation: qp=2.5qu."

Jan 1, 2017