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By J. W. Hickman

Most of the electron diffraction studies of oxide films which form on metals and alloys have been carried out by oxidizing the specimens in an auxiliary furnace, cooling down to room temperature and then inserting the sample in the camera and taking a diffraction photograph. Prior to the investigations at the Westinghouse Research Laboratories, no systematic study of the oxidation of any metal or alloy had been made over a wide temperature range with photographs taken at elevated temperatures except the investigation of iron by Jackson and Quarrell.' In order to interpret the electron diffraction patterns of the oxides which may form on alloys, it seemed advisable to make a comprehensive study of the oxidation of the purest metals available in the bulk form. Thus far studies have been completed on iron,2 cobalt,~ nickel,= chromium,= copper,z tungsten,s molybdenum,3 beryllium,' uranium,' thorium,' titanium6 and zirconium6 while investigations are in progress on tantalum and columbium. The next step in the study is concerned with the investigation of the oxides which form on binary alloys. Some of the alloys consist of a single phase while others contain more than one phase. The identification of the oxides on the surface of a binary alloy may be more difficult than on the metals since oxides containing both metals as well as those of each metal separately may form. Furthermore, it is possible that solid solutions of the various oxides may occur. In these cases the electron diffraction method may not be able to identify the oxidation products unequivocally. Examples of solid solutions which may present difficulties are MOO* and WOp, Fe304 and FeO.CrnOa since the diffraction patterns are so similar. Since electron diffraction can determine only the structure of the oxide, the chemical composition must be inferred from the diffraction data based upon X ray diffraction investigations of specimens of known composition. It is possible in some cases to decide whether a given solid phase reaction can occur on the surface of an alloy by a study of available thermodynamic data. Table I lists the equations for the formation of most of the oxides from the elements together with values of loglo Kg for the several temperatures. AF"B = -RT In KR AF°R and KR are the free energy and equilibrium constant of the reaction. Calculations may be made using the the given in I 1 to determine whether a given solid phase reaction is possible thermodynamically. For example, a solid phase reaction should occur between aluminum and chromium oxide to form

Jan 1, 1949

By M. H. Kline

The Great Gossan Lead in Carroll County, Va., is one of the largest undeveloped sulfide ore bodies known in the eastern United States. It extends for 16.7 miles along the western slope of the Blue Ridge Mountains (fig. 1). The various known segments of the deposit, extending from the southwest end to the northeast, are: The Great Outburst or Iron Ridge segment, Chestnut Creek, Copperas Hill, Sarah Ellen, Wild Cat, Cranberry, Dalton Hill and offset segment to the south of the Cranberry, Little Reed Island, Little Vine, and the Betty Baker at the northeast end. All of these segments have been explored or mined to various extents in the past for the iron gossan and secondary copper ore. The Great Outburst or Iron Ridge segment is now being mined by the General Chemical Division of the Allied Chemical & Dye Corp. for the sulfur and iron content of the primary ore. These deposits are becoming increasingly of Interest as a. large potential source of iron and sulfur owing to their proximity to Birmingham, where the burned cinder sells at a premium, and to the acid markets of the region.

Jan 1, 1949

By Norma Golumbic

The primary purpose of the Bergius (hydrogenation of coal) and Fischer-Tropsch (hydrogenation of carbon monoxide) processes is the production of synthetic liquid fuels. This objective is of importance in insuring an adequate supply of motor fuels and lubricating oils in the United States. In the urgency of the basic research and process development work on synthetic liquid fuels, the possibilities for the production of synthetic chemicals inherent in these processes have hitherto received little attention in this country. However, the by-products, as well as the primary products, from the Bergius and Fischer-Tropsch processes are rich source materials for organic chemicals. The overhead oil from liquid-phase hydrogenation of coal, for example, contains benzene, toluene, xylene, cyclohexane, methylcyclohexane, aromatic solvents, about 20 percent tar acids (largely phenol, cresols, and xylenols), and 3 percent nitrogen bases. Wax, alcohols, and acids are by--products of the Fischer-Tropsch synthesis. In addition, techniques have been developed which make possible the production of aliphatic hydrocarbons, alcohols, acids, aldehydes, and other oxygenated organic compounds. These chemicals are more valuable on a unit basis than gasoline. Because of continued rapid expansion of the plastic, resin, lacquer, and solvent industries, larger amounts of many of these chemicals will be needed in the near future.

Jan 1, 1949

By Rethel L. Hubbard

Fourteen straight-run asphalts were prepared in the laboratory from bitumens obtained from three sources: (1) native bitumen from Rozel Point, Utah, (2). bitumen extracted from Athabaska bituminous sandstone at Canada, and (3) bitumen extracted from Edna bituminous sandstone outcropping in San Luis Obispo County, to seven asphalts with penetrations ranging from 19 to 287 at 77 F. were prepared from each of the bitumens. The yields of the prepared asphalts ranged from 74.5 percent for a 27-penetration asphalt from the Athabaska bitumen to 99.5 percent for a 271-penetration asphalt from the Rozel Point bitumen.

Jan 1, 1949

By Peter Grandone

Bureau of Mines engineers engaged in studying stimulative methods of recovering oil have been making a series of tests on the effectiveness' of methods that may be applied in water flooding oil-bearing sandstones. The report gives the test procedures and results of a study of the rates and pressures used for injecting water into several sandstone formations in the Mid-Continent fields for the purpose of learning more about the mechanics and efficiency of the flooding process and to provide useful information for operators of water floods in this area.

Jan 1, 1949

By Donald F. Reed

In its investigation of old, abandoned, lead-zinc mines at which records of operations are not available, in 1914 the Bureau of Mines dug surface trenches anti', in 1947 It diamond-drilled three holes at the Albright Farm deposit in Sinking Valley. Some good lead-zinc ore had been extracted from veins in dolomitic limestone during the time of the American Revolution and as late as 1870. Since that time the only activity was sporadic prospecting and developing. Thu Bureau of Mines disclosed two additional veins by surface trenching, but diamond drilling failed to find significant lead-zinc mineralization.

Jan 1, 1949

By R. J. Burgess

During World War II the shortage of ore revived interest in eastern iron deposits, among which -!2..c "Ile Massachusetts and Connecticut limonites. The Cheever mine, in the Richmond-Salisbury area of Massachusetts, was formerly a large producer of limonite ere. The Bureau of Mines investigated the lateral and downward extensions of the Cheever ore body, which was mined from about 1850 to 1892, by ap open cut 1,000 feet long and also by underground workings. even holes aggregating 1,723 feet, were drilled by the Bureau during the winter of 1943-44. They comprised three diamond-core drill holes, two churn-drill holes, and two rotary-drill holes. A geophysical survey of the Cheever mine area and adjoining ground was made in conjunction with the drilling program. Although this survey did not locate the limonite ore beds, the data were of considerable assistance in locating the limestone contact which forms the footwall of the ore beds. Drilling disclosed two beds of limonite with a heavy overburden of glacial till.

Jan 1, 1949

By M. F. Boos

The Portland beryl-mica district, Middlesex County, Conn., comprises three deposits investigated by the Bureau of Mines in 1943. The Gotta-Walden deposit is in a pegmatite dike 4 to 20 feet thick, which cuts gneiss and schist. In general, the hanging wall is rich in mica and beryl with some feldspar, quartz, and garnet. The central core is usually high in quartz and feldspar, with relatively little mica and beryl. The footwall comprises quartz and feldspar, with varying amounts of mica and some beryl. The beryl crystals range in color from green to almost golden and have a maximum diameter of inches. Results of surface trenches indicate a beryl content of 0.81 percent for the pegmatite. A small production of beryl, feldspar, and scrap mica has been made from the deposit.

Jan 1, 1949

By G. W. Jones

Explosion hazards that may exist when air becomes polluted with combustible gases and vapors are extremely dangerous, particularly if the volume of gaseous atmosphere is large, and an explosion under such circumstances could do tremendous damage to persons and property. The hazard is even greater if explosive mixtures are confined under high pressure, as the pressure could increase to tremendous proportions just before the container would rupture. Because of its interest in safety in the mining and allied industries, the Federal Bureau of Mines has investigated the flammability (explosibility) of various types of combustible atmospheres and published its findings. The explosibility of natural gas has been studied, and the limits of flammability have been determined and published. Other investigations have shown how explosions of natural gas-air mixtures may be prevented by the addition of nitrogen and carbon dioxide.

Jan 1, 1949

By Leon W. Dupuy

Marquette's first reported the existence of iron In Missouri in 1673. Recorded production wan begun in 1815, increasing in size and importance until 1888, when the low price of iron resulting from Minnesota's production of high-grade ore caused most of the operators to close down. Missouri's iron production came from three types of ore: (l) Brown ores, including the deposits of primary and secondary limonites in southeast and southwest Missouri, (2) hematites of the filled sinks, including the ores of Central Ozark district, and (3) specular ores in porphyry, including the deposits of the St. Francois Mountains.

Jan 1, 1949

By Haskiel R. Shell

Methods of chemical analysis of clays for the following constituents are presented: moisture, ignition loss Fe2O3, TiO2, P2O5, CaO, MgO, Na2O, K2O, total. carbon, carbonate carbon total sulfur, soluble salts, and soluble sulfate. In these procedures the attainment of accuracy has been the primary consideration sample was taken to insure accuracy, with ordinary precautions. The procedures may therefore be somewhat somewhat and will not be suited for routine work on samples for which the approximate analysis is already known and in which the need for accuracy is not very exacting. However, the method shod be as a set of detailed directions, that have been tested and shown to yield accurate results with clays and other aluminum silicate minerals. Among these minerals are clays of all types, bentonite bauxite, shale, brick; soil, calcined refractory, and sand. Although some of the methods are Unusual, no particular claim is laid to originality. The material was drawn frail many sources, put together and tested.

Jan 1, 1949

By H. G. Doll

A new logging method, called induction logging, is described; it measures the conductivity, or resistivity, of the strata traversed by a bore hole. The apparatus, which is briefly described, comprises a coil system coupled with the ground by induction, so that there is no need for direct contact with the mud, or with the formations. For that reason, the method is particularly useful in oil base mud, and it was first applied to that case. A discussion concerning the respective contribution of each region of ground in the vicinity of the coil system is given. Through the concept of a geometrical factor, it is demonstrated that the total signal, which measures the apparent conductivity, is the summation of the partial products — geometrical factor by conductivity — for the different regions of the ground under consideration. It is thus possible to establish, for each type of coil arangement, investigation characteristic as well as departure curves and correction charts for beds of various thicknesses. This should greatly facilitate the quantative interpretation of the field logs, even in cases where such interpretation would have been difficult on electric logs taken with electrodes. It is also shown that focussing combinations of coils can be used, which give, directly on the recorded log, a value close to the true conductivity, even for fairly thin beds, thus eliminating in most cases the need for corrections. These focussing systems also give a sharper definition of the boundaries between successive strain.

Jan 1, 1949

The Physiographical Features of the Region The Middleback; Range proper, from the Iron Duke in the south to the Iron Prince in the north, extends in a meridional direction for 21 miles, but may well be taken to embrace also the Iron Knob and Iron Monarch prominences so that the total length of the Range is 37 miles.Although no great altitudes are reached, the slopes of the high country are steep and the Range stands out prominently above the peneplaned surface of upper Eyre Peninsula. The Range is built up of sub-parallel ridges at some places, and its continuity is interrupted by transverse breaks or gaps resulting from normal stream erosion and corrosion during earlier periods when precipitation was heavier and streams were more active. Traces of high-level gravels remain on the flanks of Kimba Gap. A former mature stream on the western side of the Range has had its lower reaches blocked by sand and the old stream channel has been converted into an eiongated basin of internal drainage. The sand dunes in this area appear to be practically stationary at present, being fixed by mallee vegetation. Their trend is west-northwest.The relief of the Range is regarded as having been determined primarily by meridional strike faulting and selective silification of some of the beds. Dip faulting on the Iron Duchess leases has produced subsidiary features only.The Rocks of the Region: In order that some of the points made in the discussion of the genesis of the ore bodies may be appreciated it is necessary to consider the stratigraphical succession and the igneous types represented. This classification may be...

Jan 1, 1949

By Frank J. Wiebelt

Work on the Abbott-quicksilver property was part of the general program of th~ Bureau of Mines in its investigation of domestic mineral resources, which are essential to national defense or industry and of which our present or probable future supplies are inadequate. The mine was discovered in 1862, and the intermittent production up to 1947 has totaled around 37,500 flasks of quicksilver. Output has come from ore shoots formed in the vicinity of fault intersections in a narrow zone composed of lenses of silicified serpentine breccia interbedded with shale. Work by the Bureau included the drilling of six diamond-drill holes aggregating 2,845 feet. Several possible ore zones were intersected by the drill holes. Field work was begun in April 1948 and concluded in October of the same year. This report gives detailed results of the diamond drilling and a brief account of the history and description of the ore deposits.

Jan 1, 1949

Previous published papers by Fraser (1), Hey (2), and Stillwell (3), have given respectively, details of:-1. The practice in the pilot plant operated at Zeehan for the treatment of ores from the Rosebery field.2. The design, based largely on the experience gained at Zeehan, of the concentrator built at Rosebery.3. The nature of the orebodies of the zinc-lead lode at Rosebery.Changes and developments, at the Rosebery concentrator, since operations commenced, are now described with particular reference to recent practice.Three concentrates are produced, viz.: a copper, a lead, and a zinc concentrate. The current flow-sheet is shown in Fig. 1. Typical concentrate assays are...THE OREThe ore treated is derived from the Rosebery and Hercules Mines and is, milled in the ratio of, approximately, two parts of the former to one of the latter. The ores from the two mines may be considered as being similar in general character, although the Rosebery ore contains more pyrite. It is from this mine that any increased tonnage is expected. The ore is a mass of fine-grained, intimately associated sulphides, with practically no coarse...

Jan 1, 1949

By Frank K. McIntosh

Bauxite was first discovered in Tennessee, at Chattanooga, in 1906, during the construction of' the McCallie Street tunnel through Missionary Ridge. Several years later, bauxite was found in sinking a well on the Perry or Isabella Stewart property. These and other deposits furnished a substantial tonnage for the abrasive and chemical industries during the years 1906 to, 1920. The search for domestic sources of war material prompted by World War II brought the Tennessee bauxite deposits to the attention of the Bureau of Mines. During the summer of 1942, James S. Cullison and E. Godwin, geologists of the United states Geological Survey, made a survey of the bauxite deposits of the area. In August 1942, Harold B. Ewoldt, a Bureau of Mines engineer, accompanied by the Geological Survey party visited the area and a drilling program was prepared. Drilling was started in November 1942 and continued until March 1943. A total of 2,519.5 feet in 38 holes was drilled on three properties.

Jan 1, 1949

By Robert H. Bedford

The Rogan-Mallery tin property is in the foothills on the south slope of the Tehachapi Mountains, Kern County, Calif. It was first visited by the senior author in August 1942, and exploration by means of trenching and diamond drilling began in May 1944 and was concluded in August of the same year. Cassiterite, associated with iron-rich gossan, occurs in a limestone roof pendant at places near or at its contact with the underlying granitic rocks. The cassiterite grain sizes range from 20 mesh to 150 mesh. Surface and diamond-drill samples showed tin ranging from traces up to 122.6 pounds per ton. Exploration by the Bureau of Mines included 2,100 cubic yards of trenching and the drilling of 11 diamond drill holes totaling 1,000 feet. Dana Hogan, president of the Rogan Petroleum Co. of Los Angeles, Calif.) brought these projects to the attention of the Bureau of Mines in July 1942, and the following month a Bureau engineer made a preliminary examination in company with Hillard Mallery, of 408 Ruby Street, Redondo Beach, Calif., the man who discovered them.

Jan 1, 1949

By J. L. Tokich, A. R. Troiano

Since 1921, when Hull1 discovered that cobalt can exist in the face-centered cubic and hexagonal close-packed modifications, the transitions that occur in cobalt have been extensively studied. It is generally agreed that on heating the hexagonal lattice changes to the cubic structure at ternperatures ranging from 400° to 500°C although considerable doubt exists as to the exact temperature. Data concerning the temperature of the transformation on cooling are much less concordant and their interpretation has not been satisfactory. The study is further complicated by the fact that many investigators have reported the existence of a high temperature allo-tropic change in the range 850 to 1020°C, at which the cubic lattice reverts to the hexagonal modification. The transition on cooling, which has been reported as Occurring at various temperatures from approximately 400 to 100°C, is of particular interest. Troiano and Greninger2 have recently suggested and considered the possibility Of allotropic transformations occurring in pure metals by a shear-type, diffusionless (martensite) transformation. The case of cobalt was specifically discussed and certain observations of previous investigators evaluated in terms Of this type of Of Table 1 briefly outlines the methods and results Of previous investigators Of the transformation temperatures of cobalt. Materials and Methods The major portion of this investigatioll was performed with cobalt sheet containing a total of 0.2 pet impurities with carbon present to the extent of o,I pct. After melting in an induction furnace under an atmosphere of hydrogen, the carbon con. tent analyzed 0.03 pct. Some observations were repeated with hydrogen reduced cobalt compresses analyzing 99.9 pet pure. No significant variations in results were observed employing the as-received sheet, the remelted stock, or the cobalt compresses. Filings for X ray diffraction analysis were sealed in evacuated glass ampoules. Pyrex glass tubing was used for temperatures below (600°C and for higher temperatures clear fused quartz was satisfactory. After appropriate heat treatment at various ternperatures, the specimen ampoules were furnace cooled, air cooled or quenched by crushing under distilled water. This allowed a range of cooling velocities from less than one degree C per set to greater than 1,0oo°C per sec. X ray diffraction patterns were taken with a Debye camera and filtered characteristic cobalt K-alpha radiation. The of of the existing phases was roughly approximated by visual examina-

Jan 1, 1949

By E. J. Matson

The Bureau of Mines has been investigating deposits of critical and essential minerals in the United States since 1939. The Rush Creek lead-zinc deposit, Mono County, Calif. (fig. 1), was examined by W. T. Benson in July 1944 and again in September 1945 by D. W. Butner, engineers of the Bureau of Mines. From the results of these preliminary examinations, a core-drilling program (fig. 2) was started in August 1946 and continued until November 1946, when work was stopped on account of inclement weather. Field work was again started in May 1947 and completed in June 1947. The drilling program was laid out to develop the horizontal .and vertical extensions of showings exposed in surface pits.

Jan 1, 1949

By Charles E. McCarthy

Part 1 of this report is concerned with the electric-furnace production of calcium aluminate and iron alloy from a variety of siliceous ferruginous ores of aluminum. The furnacing research was directed, first, to determine the extent of the field in the CaO-Al2O3-SiO2 system, in which calcium aluminates with the optimum leaching characteristics are obtained; second, to produce suitable quantities of these aluminate mixtures for pilot-plant leaching tests; third, to investigate the physical chemistry of the reduction reactions during furnacing; and, fourth, to study the economics of the process. The third and fourth steps were not completed. Part 2 comprises another phase of the work and will appear as a second Report of Investigations. It deals with the extraction of metallurgical-grade alumina from the calcium aluminate slag produced in the electric furnace and includes the following steps: leaching, desilicating, precipitating, dewatering, filtering, and washing of the aluminum hydrate. No claim is made that the data are complete, nor has the chronological order of obtaining data been followed. Rather, it is emphasized that additional work is necessary if the full possibilities of the process are to be evaluated. and made available.

Jan 1, 1949