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By Oliver Bowles

The Bureau of Mines issued three Information Circulars on marble many years ago (5), (6), (7).2/ They have long been out of print; furthermore, conditions have changed considerably in the industry in succeeding years. A presentation of current data is therefore desirable. This report furnishes general information on marble, including its properties, distribution of domestic and foreign deposits, methods and equipment used in quarrying and milling, economic and marketing problems, and recent advances in marble technology. INTRODUCTION Most marbles are crystallized limestone. The term "marble" is derived from a Greek word meaning to sparkle or flash, because the calcite crystals in marble sparkle as they reflect light. The word "marble" is employed frequently to mean a small ball used in the game of marbles with which nearly every child is familiar. Although the little spheres were originally of marble, few of those made in recent years contain that material; nevertheless, the expression "playing marbles" has persisted.

Jan 1, 1958

By Frank L. Wideman

This information circular describes methods used in mining inclined beds of phosphate rock in mines operated by San Francisco Chemical Co. in Rich County, Utah. The mines are on the western flank of the Crawford Mountains, a short, narrow range in northern Utah near the Idaho-Wyoming corner (fig. 1). The western front of the range is a conspicuous wall of folded and faulted sedimentary rocks that rises abruptly 300 to 600 feet above the floor of the adjacent Bear River Valley. Rex Peak, highest point in the range, is approximately 8,000 feet above sea level. The area surrounding the mines is sparsely populated. Randolph, the county seat of Rich County, has a population of 650. It is 10 miles southwest of the mines by road and the only town in their vicinity.

Jan 1, 1958

By James Westfield

A brief résumé follows of recent activities of the Division of Coal-Mine Inspection that have had a favorable effect on health, safety, and the reduction of injuries at coal mines: 1. The Federal Mine Safety Code for Bituminous Coal and Lignite Mines of the United States was issued originally by the Director of the Bureau of Mines on July 24, 1946, after consulting with management and labor representatives of the coal-mining industry. The code has been used by Federal coal-mine inspectors while inspecting bituminous-coal and lignite mines as a basis for determining the existence of unhealthful and unsafe conditions and practices in these mines. A revised code was issued by the Secretary of the Interior on October 8, 1953, after further consultations with representatives of management and mine workers and was incorporated by reference in the 1952 and subsequent bituminous-coal wage agreements. The agreement of May 29, 1946, between the Secretary of the Interior, acting as Coal Mines Administrator under authority of Executive Order 9728, and the United Mine Workers of America, covering bituminous-coal and lignite mines in Government possession, charged Federal coal-mine inspectors with the responsibility of making periodic investigations of the mines and reporting to the Coal Mines Administrator any violations of the Federal Mine Safety Code. Federal coal-mine inspectors also had temporary authority to close mines found to be imminently dangerous, but such authority (under Executive Order 9728) was removed on June 30, 1947, when Government control of the mines was terminated.

Jan 1, 1958

By Woodcock J. T

When an aqueous suspension of pyrite and manganese ore reacts with oxygen, manganese is dissolved by the ferrous sulphate and sulphuric acid produced by the oxidation of pyrite. The kinetics of certain steps in the overall reaction were studied. A rate equation for the oxidation of ferrous sulphate by gaseous oxygen was derived for the temperature range from 1000 to 200° C. An exact rate equation for the production of ferrous ion from pyrite could not be established but it was shown that the temperature, oxygen pressure, pyrite surface area, and the reduction of ferric ion by pyrite are important. A rate equation was derived for the reaction of manganese dioxide with ferrous sulphate. A major facfor controlling the rate was whether or not ferric oxide was formed by hydrolysis at the manganese dioxide surface.It was shown that if hydrolysis was prevented the factor cpntrolling the rate of the overall reaction ,was the rate of production of ferrous ion, and little ferrous ion was oxidised by oxygen. When hydrolysis of iron did occur, the overall rate was not a simplefunction of anyone factor and much ferrous ion was wasted by oxidation with oxygen.INTRODUCTIONIn another paper (Cornelius and Woodcock, 1958) the results of the reaction of an aqueous suspension of a manganese ore and pyrite with oxygen are reported. It is shown that the ferrous ion and sulphuric acid generated in situ by the oxidation of pyrite, dissolves manganese as manganous sulphate. To obtain a better understanding of the process as a whole, the kinetics of certain steps in the overall reaction were studied.When an aqueous suspension of a manganese ore and pyrite reacts with oxygen, the overall reaction may be conventionally represented by equation (1) (Cornelius and Woodcock, 1958).2Mn02 + 2FeSz + 6i02 + 2HzO= 2MnS04 + 2H2S04+ F'ez03 ... , .. (1)

Jan 1, 1958

By C. E. Henning

The total number of petroleum refineries in the United States on January 1, 1958, was 318 and their total crude-oil throughput capacity was 9,407,707 barrels per day, according to the Bureau of Mines annual survey. During 1957, 3 new refineries began operating while 4 refineries were retired. Although there was 1 less refinery, the total crude-oil throughput capacity at the beginning of 1958 was 284,033 barrels per day, or 3 percent, more than the January 1, 1957, level. During 1957 all refinery districts showed increases in capacity. The largest increase, 27 percent, occurred in the West Coast district followed by the Indiana-Illinois-Kentucky district with 14-percent increase and the Texas Gulf Coast district with 13-percent increase. The national increase in capacity had the effect of raising the capacity of the average refinery from 28,601 to 29,584 barrels per day. New crude-oil capacity under construction on January 1, 1958, totaled 185,265 barrels, and an additional 297,885 barrels capacity was reported building as replacement for existing facilities. Included in total new construction were 2 new refineries, 1 in Washington and another in Texas, with planned processing capacities of 45,000 barrels and 8,550 barrels per day, respectively.

Jan 1, 1958

By J. F. Davis

Pegmatite dykes containing lithium minerals and beryl occur dose to the borders of intrusive masses of granitic rock in the Winnipeg River area of Manitoba. Both vertical and flat-lying dykes are present. Most of the pegmatites consist of zones, containing characteristic mineral assemblages, arranged more or Jess parallel to the borders of the dykes. Five important lithium minerals are present; each occurs in a separate zone, but all the lithium-bearing zones are situated toward the centres of the pegmatites. Spodumene is the most abundant and widespread of the lithium minerals and occurs as small crystals intimately intergrown with quartz. Beryl is not an important constituent of the lithium pegmatites, but when .present, occurs outside the lithium zones, toward the margins of the -dykes. Beryl is most common in dykes containing few or no lithium minerals. The mineral assemblage in the beryl zone of the lithium dykes is the same as that of the beryl dykes. The attitude and internal structure, particularly zoning, of the pegmatite dykes, and the texture and assemblages of the constituent minerals, have an important bearing on exploration, development, and mining of these pegmatites, and on the extraction of various mineral products from them.

Jan 1, 1958

By W. Vickers

SALKOVITZ1 has given a number of useful angles between planes for use with the Laue method in determining the orientation of bismuth single crystals. Bismuth is usually considered as having a face-centered-rhombohedra1 structure with its axial angle 87°34', Fig. 1. A similar figure given by Sal-kovitz appears to be in error in that the angle there marked as 87°34' should be 92°26. The primitive cell is a single rhombohedron of axial angle 570 14. The structure is almost face-centered-cubic and hence high accuracy in measurements is essential if there is to be no confusion in indexing poles or zone axes. It is easier to get this accuracy if zone axes are plotted on the stereogram because they will lie near the basic circle where the net has a more open scale. The zone axes can be read from the film, using a Greninger chart, and can be plotted more accurately than poles. Also, the angles between points near the basic circle can be read more accurately than those between poles near the center. In order to use the zone axes the angles between directions have been calculated from a formula given by Niggli,2 and are given in Table I. Miller indices

Jan 1, 1958

By Ervin E. Underwood

IT has been recognized for many years that dis-persed particles have great value in raising the creep resistance of metallic alloys. In fact, some of the most successful high-temperature alloys owe their superiority to this factor above all others. A recent observation by Glen1," indicates that even better high-temperature resistance to deformation results in alloys capable of two successive precipitation reactions. The ramifications of this finding are of great interest. Unfortunately, our understanding of the reasons for such notable improvements has not kept pace with technical developments. In an effort to uncover some of the basic facts governing strengthening by particles, a program was initiated at the Battelle Memorial Institute with the primary goal of comparing creep strengths in single-phase and two-phase (precipitating) alloys. The effects of precipitation from solid solution on the creep properties of alloys are generally such that the resistance to creep is increased. However, if alloys are heat treated to different degrees of hardness before creep testing, it is often found that those possessing the maximum hardness initially do not necessarily have the maximum creep resistance. Depending on the stresses and temperatures involved other structures may prove more desirable. Considerations of the above nature indicate the importance of defining the initial state of the alloy. Here, it was decided to start with quenched single- phase alloys in which precipitation and creep deformation proceed concurrently. Equipment and Experimental Procedures Preparation of the Specimens—Four 25 lb ingots were prepared from 99.999 pct Cu and 99.996 pct Al to compositions of 1, 2, 3, and 4 wt pct Cu. Spec-trographic and chemical analyses are listed in Table I. After heat treatments and intermediate reductions, the alloys were cold rolled to 1/8 in. thick sheet. The final cold reductions amounted to 50, 40, 20, and 10 pct for the 1, 2, 3, and 4 pct Cu alloys, respectively. The specimens for creep testing were machined into tensile flats 7 in. long, 3/4 in. wide (at the shoulders), and 1/8 in. thick. The reduced sections were 1/4 in. wide and 21/2 in. long. After heat treatments at 540°C to an ASTM grain size of 1 1, the specimens were quenched into water at room temperature, then electropolished in a glacial acetic acid and perchloric acid solution. The gage marks were Knoop impressions placed 2 in. apart on the reduced sections. Blanks of 1 x 1 in, were cut from the same sheets for the age hardening runs and were given the same grain size heat treatments. The specimens and blanks were stored in a refrigerator at —40°C until needed for testing. Creep Measurements—Creep tests were conducted in a constant temperature room which was maintained at 26° ±1°C. A split-type, hinged, vertical-tube furnace was mounted on a horizontal track so that the specimen could be enclosed suddenly. Thus, it took about 15 min for the specimen to come within 5°C of the test temperature. The temperature variation along the specimen was controlled to about

Jan 1, 1958

By R. J. Grace

Carbon in the form of coke is used as a reactant in various chemical and metallurgical processes, The high cost of by-product coke along with its periodic lack of availability and high investment necessary for additional by-product recovery facilities indicate the need for a low-cost production unit based on a new procedure for coke manufacture, Traveling-grate coking-stokers were developed by Shawinigan Chemicals Ltd. to produce coke required for carbide manufacture, They were adapted to kilns so that the hot volatile gases could be used for lime burning, Their operation has been described in various patent disclosures (1, 2, 3), and their application to rotary lime burning kilns has been described by Andersen (4). Details of the process and plants have also been published by Kurt Baum (5,6).

Jan 1, 1958

By R. H. Storch

The work described in this report was part of a Bureau of Mines program to appraise the titanium-mineral resources of Idaho. Part of the program included churn drilling of alluvial deposits that previous preliminary testing, primarily for rare minerals, had indicated to be potential sources of titanium minerals. The first spot churn drilling began in the Deadwood placer area, Valley County, Idaho, in July 1956 to determine both the amount and grade of the ilmenite, FeTi03. Ten holes, ranging in depth from 6 to 40 feet and aggregating 251 feet, were drilled; 54 samples were taken. The samples were sent to the Spokane field laboratory for concentration and visual estimation of the amounts of the more common minerals in the heavy sand concentrates. For specific determinations samples from each drill hole were composited and shipped to the Bureau of Mines laboratory in Albany, Oreg., where petrographic, quantitative X-ray spectrographic, and chemical analyses were made.

Jan 1, 1958

By P. C. Van Natter

Numerous mine fires have resulted in high death tolls and considerable finan¬cial loss during the history of coal mining. In most instances the death toll and financial loss were greater because of inadequate fire-fighting facilities. The information in this report is presented in the hope it may serves as a guide in the selection, placement, and care of fire-protection systems in similar coal mines. The adequacy of fire protection varies according to size of operation, employment, and production. When fires occur on the surface or underground, measures must be applied quickly to prevent incipient fires from spreading. The record of coal-mine fires shows that, in many instances, facilities for combating fires were very meager or were absent. It would be virtually impossible to establish and maintain all the necessary facili¬ties that may be needed to extinguish widespread mine fires, but it is believed that the coal industry can ill afford less than the minimum required by other industries where the time element and avenues of escape are much more favorable.

Jan 1, 1958

By E. P. Klier, V. Weiss

IN studies of the X-ray diffraction line geometry of iron with chromium radiation using techniques aimed at minimizing the background intensity, Kp and Ka emission satellites* were resolved with three techniques. These satellite lines are present with sufficient intensity to lead potentially to erroneous structure analysis, if not properly interpreted. The techniques used were: 1) film technique with un-filtered radiation and polycrystalline specimen, 2) film technique with unfiltered radiation and single crystal, and 3) counter technique with unfiltered radiation and single crystal. An example of results obtained with technique 1 is given in Fig. 1.

Jan 1, 1958

By T. W. Wlodek

In this paper the relative merits of shot peening, induction surface hardening, spiral-rolling, and the combination of these surface treatments, are evaluated on the basis of their capacity to increase the fatigue strength of drill steel. The S-N relations for plain car-bon steel (SAE 1080) and Ni-Cr-Mo drill steels in the as-rolled condition were determined previously, using the new Canadian method of testing drill steel introduced at the annual meeting of the Institute in Toronto in 1950 (19). S-N curves have now been determined by this method for these two drill steels in the following conditions: shot-peened and drawn, induction hardened, induction hardened and shot-peened, and spiral-rolled. ( S.R.) . The ratios of the fatigue strengths of these steels after surface treatment, to their fatigue strengths in the as-rolled condition, are compared and the most beneficial treatments are thereby pointed out. The expected range of stresses and their distribution during actual drilling operations are estimated from data available, and the mechanism of failure of drill steel in the as-rolled and surface-treated conditions is analyzed. The magnitude of the surface compression stresses and their effect on ?fatigue strength are discussed.

Jan 1, 1958

By Sidney Katell

This report is the fourth in the series, Bibliography of Investment and Operating Costs for Chemical and Petroleum Plants. The initial work, Bureau of Mines In- formation Circular 7516, was published in October 1949 in conjunction with the synthetic liquid fuels program authorized by Public Law 290, 78th Congress. It included references to and abstracts of publications appearing from 1930 to September 1948 on all processes in general use in the petroleum refining and chemical industries. A supplemental bibliography, Bureau of Mines Information Circular 7705, was published in January 1955 to cover the period September 1948 through June 1952; and Supplement 2, Information Circular 7751, published in September 1956, covered the period June 1952 through June 1954. The present supplement covers the period July 1954 through December 1956.21 The information in this paper was obtained from the following sources: 1. Bureau of Mines Information Circulars. 2. Bureau of Mines Reports of Investigations. 3. Chemical Engineering. 4. Chemical Engineering Progress. 5. Chemical Engineering Costs Quarterly (Cost Engineering).

Jan 1, 1958

By R. H. Winn

In this paper a heterogeneous carbonate reservoir is considered as a succession of layers of formations of radically different porosities, permeabilities, water saturations, and rock matrix types; i.e., the heterogeneity is vertical rather than radial to the wellbore. Presumably each layer is more or less homogeneous. To determine the "net oil in place" in this reservoir it is desirable to know the porosity and water saturation of each layer. In addition, the section must be subdivided into that which will produce oil, that which will produce water, and that which will produce little or nothing. In numerous wells drilled in these reservoirs radioactivity surveys, guard electrode surveys, and caliper surveys have been made. These logs have been compared with core analysis data, when available, and the analysis of the surveys compared with production data. This study, still in progress, is intended to provide improved analytical techniques if such are possible. This paper is a progress report on the work. DETERMINATION OF POROSITY The neutron-gamma log has long been recognized as a measure of hydrogen concentration.1,2,3 In reservoirs that are free of clay, shale, or other hydrogen containing matrices, it has been accepted as a measure of porosity.4,5 Empirical methods to relate relative neu-tron-gamma intensity to porosity are often employed." To provide a more precise determination of porosity from the neutron-gamma log each instrument is calibrated immediately prior to each survey by a method which refers all tools to a hydrogenous cylinder. To insure stability a calibration check is made after each survey. These calibration records are printed as an integral part of the log that is recorded in standard counts per second. A detailed description of the calibration procedure is available in the literature.' The procedure employed insures that each Survey is numerically reproducible within the limits of statistical variation. To relate the standard neutron counts per second to porosity and hole size, records were made in test wells constructed of blocks of limestone. The porosities of the blocks were accurately measured and the blocks completely saturated with fresh water. Fig. 1 presents some of the results obtained in these test wells.' The lines shown in Fig. 1 were obtained by deriving an empirical equation relating the 11 points shown so that the relationship may be projected to larger and smaller hole sizes. A detailed description of the tool is available in the literature.' Field tests indicate that the tool is adjacent to the wall of the hole most of the time when the surveys are made in uncased holes drilled with saline muds. In this circumstance porosity may be calculated from Fig. 1 if the hole size is known. When fresh muds that form thick mud cakes are employed, the centralizing effect of the mud cake must be considered and the porosity determination is less reliable. In cased holes the combined effect of variations in hole diameter and the unknown eccentricity of the casing in the hole may make porosity determinations extremely unreliable. In any event, an accurate knowledge of hole size is essen-

Jan 1, 1958

By Luis Jimenez Borja

El presente artículo describe la situación del plomo y los problemas que enfrenta nivel mundial. El plomo tiene una serie de características físicas y químicas que lo hacen deseable para muchos usos industriales; es blando, maleable, y puede mezclarse fácilmente para formar aleaciones. Es a partir de 1956 donde el consumo de plomo en los Estados Unidos aumentó a 40% en el uso de la industria automovilística. Posteriormente, entre 1950 y 1956 esta industria decrece y los siguientes 30 años mostraron a los Estados Unidos como un gran productor de plomo. Sin embargo, la situación ha ido cambiando y dicho país de autosuficiente, ha pasado a ser dependiente de la producción foránea. La principal causa de esta declinación es que con el incremento del consumo, su industria minera no ha podido mantener el paso y aún más ha decrecido, así como los costos de producción y la disminución de sus reservas. Por ello, las medidas que se tomaron fueron la inclusión de fondos, que eran disponibles para sus compras de plomo y zinc, de forma que los mineros americanos obtengan una especie de subsidio que les permita seguir operando.

Jan 1, 1958

President Robert M. von Storch called the meeting to order at 9:00 A.M., and introduced the first speaker of the MANUFACTURERS' HOUR. D. M. Stromquist, Technical Representative, Coal Chemical Sales Division, United States Steel Corporation, Salt Lake City, Utah, presented a paper, "Ammonium Nitrate and Its Use as a Blasting Agent," which was illustrated with a number of slides. (See Index.) President von Storch introduced Kenneth J. MacLeod, Socony Mobil Oil Company, Denver, Colorado, who gave a short paper on "New Greases." Following are excerpts from Mr. MacLeod's talk: The recent advances in machinery, and their continuing development present a never ending challenge to the oil companies to develop new and better oils. Over the years, industry's machinery has been pressed to meet higher production rates, which has subjected the machinery to increased speeds, temperatures and pressures. Lubrications have had to be designed for a wider range of use. The entire industry has attempted to produce a good product for this extra-duty need. Most greases have contained lead in the past, and especially the food industry has had to be most careful in the use of this around food products.

Jan 1, 1958

By W. G. Mine

In September, 1953, seismographs were installed in the Crowsnest Pass area of Alberta and British Columbia to study the 'bumps' which were occurring in the coal mines at Fernie and Coleman, and to investigate the possibility that they might be related to minor earthquakes in the area. During the initial phase of the work, three seismographs were operated at widely separated stations, two in the region of coal mines at Coal Creek and Coleman and one at Turner Valley, distant from any mining operations. Some earthquakes were recorded at all three stations and, in addition, many small disturbances were recorded by the seismographs located near the mines, especially -by the instrument at Goal Greek. A closer network of radio-linked seismographs was then in-stalled near Fernie, the records of which definitely established that the small disturbances were occurring in the mine workings, both active and inactive. No relationship was established between bumps and local earth-quakes in the area. This work was initiated as a -co-operative effort with the Fuels Di-vision of the Mines Branch, Department of Mines and Technical Surveys, which has undertaken a study into the phenomena of ground stress relief in underground mine workings.

Jan 1, 1958

By J. P. Powell

This report provides information on the techniques and results obtained on representative waterflooding projects in Cowley County, Kans. Records show that waterflooding was begun as early as 1935, but not until 1948 was the method expanded. The greater depths to the oil-producing formations in this area compared to those in eastern Kansas undoubtedly delayed the widespread use of secondary-recovery methods. This report presents a discussion of four waterflooding projects in Cowley County, Kans. The locations of these projects are shown in figure 1. The projects have been in operation from 1 to 7 years and have produced more than 1 million barrels of additional oil by injecting 11.5 million barrels of water. The projects are designed to take advantage of elevation and height of the separator tank to collect by gravity flow the produced brine at the respective treating or storage tanks. The closed-type water system is used on three of the projects and an open-type water conditioning system on the fourth. On one of the projects, which was drilled along a narrow shoestring formation, alternate well, were converted to input wells. However, most of the input wells for flooding converted producing wells.

Jan 1, 1958

By Eugene T. Sheridan

The 23d annual survey of the peat industry by the Bureau of Mines, United States Department of the Interior, revealed that 75 producers in 17 States re-ported commercial production of peat in 1956. Forty-seven producers reported humus production, 19 reported reed-sedge peat, 17 reported moss peat, and 1 reported muck. This total exceeds the number of active operations, but several producers reported recovering more than one type of peat. Fifty-five percent of the total production was reported as peat humus, 30 percent as reed-sedge peat, and 15 percent as moss peat. A negligible amount was reported as other types. More than one-fourth of the total output was raw peat with no preparation, other than having been air-dried. The remainder consisted of processed peat prepared for use by cultivation, shredding, or kiln drying.

Jan 1, 1958