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By Aaron Noble, Mahmud Esad Uluer

Respirable coal mine dust (RCMD) is one of the biggest occupational health hazards for underground coal miners. Dusty mining environments can cause long-term health problems, including pneumoconiosis and progressive massive fibrosis. The Mine Safety and Health Administration (MSHA) has recently revised regulations promoting enhanced dust mitigation technologies, which have sparked renewed interest in the development of dust mitigation technologies. The flooded bed dust scrubber (FBS) is one of the most widely used technologies; however, it is limited by technical challenges, the most notable being the potential to clog. Recent studies have shown that applying vibration to filter mesh can improve the overall efficiency of the scrubber and that the system can be readily integrated to existing continuous mining equipment using an energy harvesting approach. In this follow-up study, the impact of mesh design and surface modification on system efficiency was examined using different vibrating liquid-coated stainless-steel mesh panels in a laboratory-scale FBS. Based on the two-way interaction data from a multi-factor experimental design, the results show that the performance of the system can be optimized by using hydrophilic 20- or 30-layer filters and by excitation frequencies between 67 and 134 Hz. This laboratory study suggests that a 20-layer mesh screen with hydrophilic surface applications and optimized vibration parameters can perform similar to that of a 30-layer static mesh, which is typically used in industrial units.

May 23, 2024

By Chenxi Ding, Chenglong Xiao, Guoli Shi, Zhiwei Zhao

This study investigates the directional blasting of a 90° slit charge structure using laboratory experiments and field tests. A 90° slit charge suitable for the corner of roadway is proposed. After the slit charge blasting, two long main cracks along the slit, and several short secondary cracks in other directions. The slit charge not only significantly reduces damage to the surrounding rock, but also improves the quality of the roadway contour. In addition, a comprehensive damage evaluation system of the roadway contour and the surrounding rock is constructed using digital image analysis, borehole televiewer, and CT scanning.

May 23, 2024

By Danu Putra, Budi Sulistianto, Tri Karian, Mohammad Nur Heriawan

Stope layout optimization is an important feature of underground mining that maximizes the economic value of the project while taking mining limits into account. The large number of parameters and constraints makes it difficult to obtain the optimum condition. Several algorithms have been created to address these problems using a variety of methods. However, the circulating method has not explicitly included stope dimension stability analysis, resulting in a solution that is not stability-proven, which can result in a suboptimal solution. This study integrates the Mathews stability graph into the stope optimization algorithm so that the optimized stope layout considers stability conditions directly through an assessment of the available geomechanical data within the block model. The proposed algorithm is validated through a case study of a synthetic block model created by considering variations in grade and the geomechanical conditions of the rock. Furthermore, several scenarios are created to compare the performance of the algorithm that applies variations in stope sizes with the common case study of stope sizes that remain fixed. A more detailed assessment is also conducted on each final stope layout wall to ensure the successful application of stability analysis in the proposed algorithm through back analysis on the Mathews stability graph. The optimization results show that all walls in the final stope layout fall into the stable condition. Also, the proposed algorithm is also capable of maintaining the project’s economic value. Ultimately, the proposed algorithm can be deemed applicable and suitable for use in the initial stages of mining as a comprehensive assessment of the optimal stope layout, taking into account the stability conditions of the stope.

May 22, 2024

By Giovanni Rubinich Moraes, Giorgio de Tomi, Irfan Ullah

The study examines productive and unproductive hours in four underground mine shifts: 6 h, 8 h, 10 h, and 12 h. Moreover, two sub-scenarios of single or two blasts examined the effect on mine utilization regarding effective working hours in underground mines. Cuiabá Mine data, the Brazilian’s largest and deepest underground gold mine, was used in both sub-scenarios. Under the first sub-scenario, which assumes two blasts per day, the 6-h shift had an effective work time (EWT) of 13 h and 30 min or 56.3% of the day. The EWT was 15 h and 20 min, 63.9% of the day, in the 8-h shift scenario. The 15-h, 30-min EWT took 64.6% of the day in both 10/12-h shifts. The 6-h scenario had an EWT of 16 h and 15 min (67.7%) in the second sub-scenario with a single blast daily. The 8-h scenario boosted EWT to 18 h and 25 min (76.7%) daily. An EWT of 18 h and 35 min daily (77.4%) was found in 10/12-h shifts. Comparisons of both sub-scenarios show that EWT positively correlates with shift length. Sub-scenario 1 has a 7.6% incremental step from 6 to 8 h, while sub-scenario 2 has 9%. EWT increases from 8-h to 10/12-h shifts by 0.7% for single and two blasts daily. Compared to the two sub-scenarios, halting operations for blasting once daily improves the EWT average by 12.5%. Reducing blasting and changing underground mining shift duration might boost economic viability.

May 21, 2024

By Li Yuab Chi, Rikard Mäki, Riika M. Ylitalo, Pekka Bergström, Zong‑Xian Zhang, Sunniva Haugen, Anders Sand

The effect of detonator placement on rock fragmentation by blasting was studied in the Kevitsa open-pit mine. Considering rock mass properties, explosives properties, and blast parameters, a comprehensive analysis of 37 production blasts confirms that the middle detonator yields finer fragmentation than the bottom detonator in the full range of investigated sizes. Meanwhile, using the LS-DYNA code, a bench model with a single blasthole was built in a three-dimensional setting. A single detonator placed at two different positions—the middle and bottom—of the explosive column was analyzed in this study. By analyzing principal stress states on the plane through the blasthole axial and vertical to the bench face, the numerical results show that the middle detonator creates a stress concentration area near the bench face characterized by triaxial tension, while the bottom detonator does not. Furthermore, the middle detonator generates a larger stress concentration area with biaxial tension near the bench face than the bottom detonator. Considering that triaxial and biaxial tensions are more favorable to fragmentation than uniaxial tension, it can be concluded from simulation results that these areas with triaxial tension and biaxial tension in the middle detonator are a significant factor contributing to achieving better fragmentation, compared to the bottom detonator. The middle detonator position has replaced the bottom detonator position in the Kevitsa mine.

May 20, 2024

By Emily Sarver, August Greth, Cigdem Keles, Setareh Ghaychi Afrouz

The characterization of respirable dust on the basis of constituent fractions and particle sizes is increasingly of concern for evaluating exposure hazards. For high-resolution particle analysis, scanning electron microscopy with energy dispersive X-ray (SEM-EDX) can be an effective tool. However, it requires particles to be deposited on a smooth, uniform substrate such as a polycarbonate (PC) filter for optimal results. While direct sampling onto PC is possible, this is not the standard approach in many situations. For example, in coal mines, respirable dust samples have typically been collected onto polyvinyl chloride (PVC) filters because they are intended for gravimetric and/or infrared spectroscopy analysis. Such fibrous substrates are not ideal for SEM-EDX (or other microscopy), but an effective method to recover and redeposit the dust particles could render such samples suitable for the additional analysis. Here, we present a simple method and compare SEM-EDX results for paired samples analyzed directly on PC and following recovery from PVC and redeposition on PC. Both laboratorygenerated dust samples (n = 10 pairs) and field samples of respirable coal mine dust (n = 44 pairs) are included in this study. Although some changes in particle size distributions were observed between samples analyzed directly and those that were recovered and redeposited prior to analysis, the results indicate the dust recovery method generally yields a representative sample in terms of mineral constituents. That said, results also highlighted the effects of high particle loading density on individual particle analysis. Considering all sample pairs, those with similar loading density between the directly analyzed and recovered sample tended to exhibit similar mineralogy distributions. This was generally the case for the lab-generated sample pairs, and the Freeman-Halton exact test of independence indicated that the samples in just three (of 10) pairs were in disagreement in terms of their mineralogy distributions. On the other hand, for the field samples, the directly analyzed sample often had higher loading density than the recovered sample; and the Freeman-Halton test showed that 25 (of 44) pairs were in disagreement. However, the effect of possible particle agglomeration on the directly analyzed samples cannot be ruled out—and exploration of this factor was beyond the scope of the current study.

May 17, 2024

By Shankar Kumar, Arvind Kumar Mishra, Chitranjan Prasad Singh

Formulating a predictive model for blast-induced ground vibration (BIGV) has always been challenging due to the complex non-linear relationship between the BIGV and its influencing factors. Researchers have used empirical, artificial intelligence methods and numerical modelling methods to predict BIGV. In a dragline bench blasting, a massive quantity of explosives is used compared to other loading machinery, and the height of the bench depends on the size of the dragline. For effective utilization of explosives energy, decking is used to reduce the hazardous effects of blasting. In this paper, an attempt has been made for effective prediction of BIGV, and its mitigation on dragline bench blasting considering a deck length, stiffness ratio, hole spacing to burden ratio, hole depth to burden ratio, the distance of monitoring PPV from blasting site, Schmidt hammer rebound number of the bench to be blasted, and maximum charge per hole to total charge per blast. So artificial neural network (ANN) model and random forest (RF) model have been developed considering the parameters mentioned above. For the statistical performance of the predictive model, the coefficient of determination (R2) value is 0.8895, MSE is 22.84 for the ANN model, and the random forest (RF) model whose R2 is 0.8165 and MSE is 27.18. The sensitivity analysis results show that stiffness ratio, deck length, and Schmidt hammer rebound number are more influential parameters out of the selected parameters. The reduction of ground vibration with the introduction of decking led to a 3 to 15% reduction in ground vibration.

May 15, 2024

By C. Allen, H. Zhang, L. Falk

Shock loss occurs when there is a change in the area of a drift or airflow direction. These shock losses accumulate throughout the ventilation system and will increase the mine resistance as underground development deepens or becomes more complex. Hence, shock losses should be carefully considered when establishing the resistance through a series of branches as they can be a significant contributor to the estimated mine resistance. Using computer software to simulate a ventilation system is common but applying reasonable shock loss factors in the software is not a simple or direct process. Determining shock loss values includes the consideration of historical measurements, application of factors and formulas from literature based on the geometry and complexity of junctions, and the geometry variation at different locations. For example, the shock loss at the bottom of a ventilation raise can be comprised of a 90° bend and a sudden area change. This paper presents an approach for estimating shock loss factors near raise junctions using computational fluid dynamics. Current and future work will also be compared with field measurements. Results from this approach are compared with software defaults as well as classical techniques in published literature and standards.

May 14, 2024

By Taghi Sherizadeh, Samuel Nowak, Kutay Karadeniz, Paul Brooks, Alper Kirmaci, Mina Esmaeelpour, Dogukan Guner, Gunnar Wurst

As mines continue to deepen and become more expansive, active monitoring of larger volumes of rock mass will become more critical to calibrate numerical simulations and to ensure the safety of underground workers. Monitoring larger volumes of rock mass requires low-cost sensors which are simple in construction and installation. In this study, a novel hybrid optical fiber cable (HOFC) designed for use in distributed optical fiber sensing (DOFS) via grouted boreholes was employed to monitor a bulk mining operation in an underground metal mine. The HOFC was successfully used to monitor approximately 2.7 × 103 m3 of rock mass above excavations surrounding a pillar removal area in which six large pillars were removed simultaneously. A total of six measurement boreholes (maximum depth of 22 m) were used to measure strain along the optical fiber during the pillar removal operation using the HOFC, allowing for 70 individual strain measurement points, which were constructed for under one US dollar each. Monitoring of the excavation area took place over a 44-day period after pillar removal. Extensional strains were noted in the areas closest to the removed pillars, while areas of compression were noted directly above the remaining pillar in the area. The results of the case study demonstrate that a low-cost optical fiber strain sensing network can be rapidly installed in a large excavation area and can provide highly sensitive strain measurements in a manner that would be cost-prohibitive via other methods.

May 13, 2024

By Mona M. Fawzy, Ahmed A. Eliwa, Ahmed H. Orabi, Amal E. Mubark, Ebrahim A. Gawad

During the last decades, the growing demand for rare earth elements (REEs) has led to numerous recent studies to recover these elements from various bearing ores and wastes. Therefore, the recovery of REEs from Ras Baroud polymetallic concentrate has been investigated in the current study. Physical beneficiation for the Ras Baroud pegmatite sample was carried out, yielding a concentrate for euxenite (Y), fergusonite (Y), xenotime (Y), monazite (Ce), allanite, thorite, uranothorite, and Hf-zircon, which resulted in raising the concentrations of rare earth elements, Th, Zr, U, and Ti in the sample. Fusion digestion processes with sodium hydroxide were studied using the Conceived Predictive Diagonal (CPD) technique. The three experimental digestion groups proved the dissolution of 99.9, 95.6, 99.9, 52.5, and 0.47% for REEs, Th, U, Ti, and Zr, respectively, under fusion conditions of 723 K, 120 min, 1/1.5 ore/alkali ratio, and − 100-μm particle sizes. Fusion kinetics, isotherms, and thermodynamics were investigated using several suggested models, namely, pseudo reversible first order, uptake general model, and shrinking core model which matched well with the experimental digestion results. Selective recovery of actinide content from REE content of the digested concentrate chloride solutions was accomplished using solvent extraction with di-2-ethyl hexyl phosphoric acid. About 99.9, 99.9, and 4.2% extraction efficiencies for Th, U, and REEs were performed, respectively, using 0.3 mol/L solvent concentration in kerosene as a diluent, 1/2 organic to aqueous ratio, an aqueous pH of 0.2, and 15-min contact time. Thorium and uranium ions were stripped with sulfuric acid solution 2.5 mol/L with 94 and 98% stripping efficiency, respectively. A highly purified REE precipitate was obtained from the raffinate solutions. Zircon mineralization tailings were obtained as a by-product through the alkaline digestion process.

May 4, 2024

By Tahereh Rostami, Behnam Khoshandam

In the present paper, the recovery of mixed spent cathodes is evaluated and performed through a hydrogen reduction process. Firstly, the lithium is isolated by the hydrogen reduction process as LiOH at 600 ◦C for 15 min with 10% H2 with a flow rate of 350 ml/min. In the second step, 98.37% Li is recovered through water-leaching of hydrogen reduction products at 100 ◦C for 90 min with 50 ml/g. The filtration residual is reduced by using a carbothermic reduction process and a hydrogen reduction method. The first one is performed under an Ar atmosphere at 900 ◦C for 210 min and the second one is conducted at 800 ◦C for 150 min. The purer products are achieved using the hydrogen reduction method at lower temperatures and shorter holding times compared to a carbothermic reduction process with recovery percentages of 100%, 99.06%, and 70% for Ni, Co, and Mn, respectively. Given the importance of reducing the emission of toxic gases, the hydrogen reduction process is also a promising method for metal recycling. The obtained results also demonstrated that Li, Co, Ni, and Mn can be effectively separated from the mixed cathode material through the hydrogen reduction process as a sustainable and environmentally friendly recycling process. This study provides an impressive understanding of the hydrogen reduction process and valuable guidance for a larger-scale hydrogen reduction process.

May 3, 2024

By Ebrahim F. Salmi, Tan Phan, Ewan J. Sellers, Thomas R. Stacey

Extension of ore pass length has become increasingly critical for optimising energy-efficient underground mining operations. Long and ultra-long ore passes, spanning from 300 to 700 m, can significantly improve the functionality and viability of underground mass mining operations though suboptimal performance has an extremely adverse impact on production. The public domain lacks substantial information regarding the primary engineering, geological, and geotechnical risks and challenges associated with the design, implementation, operation, and maintenance of such long ore passes. Therefore, the aggregation of past experiences and the insights of experts assume paramount significance. An innovative methodology is introduced to address this evident data deficiency and to establish comprehensive guidelines for the resilient design of such lengthy ore passes — combining gap analysis with expert elicitation techniques. This equips design engineers with the necessary tools to formulate and adapt strategies for assessing the numerous challenges and uncertainties that invariably accompany their projects. Expert elicitation techniques are summarised, and a gap analysis is conducted with subject matter experts, from various countries, collating their extensive ore pass design experience, to create a comprehensive list of effective parameters and key risks that must be considered. Quantitative analysis of the survey results enabled the identification and ranking of the numerous factors affecting the design, operation, and maintenance of long and ultra-long ore passes and highlights the complex technical challenges (substantial damage from rock particle impact, increased dynamic mining stresses leading to failure, air-blasts and back blasts, dust, preferential flow, turbulent and dynamic material flow) that are uncommon in shorter ore passes. Additionally, increasing length heightens the probability of intersecting weak rock or discontinuities, leading to a higher risk of structural failure and instabilities. Faulting, folding, and large-scale structures are also critical geological factors to be considered in the design of such structures. The key geotechnical factor is also the rock type surrounding the pass. Experts highlighted the lack of clear guidelines for decision-making, resilient design, and construction so this work suggests future investigations to determine the complex interaction between the effective parameters, using approaches like the rock engineering system, discovery of cascading hazards, and optimal controls.

May 3, 2024

By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

By Yuqi Zhao, Zhiyong Lin, Leiting Shen, Hongyang Wang

Gibbsite-type bauxite is the main material for alumina extraction by Bayer process globally, while the iron in red mud is difficult to use for the high alumina content. Therefore, the efficient separation of iron and alumina is the premise for the resource utilization of red mud. In this work, the separation of iron and alumina in red mud containing 47.45% Fe and 11.58% Al2O3 was studied through reduction roasting followed by magnetic separation. The analysis methods of XRD, VSM, SEM, and EDS were used to investigate the phase transformation of red mud during reduction roasting. Results show that hematite can be firstly reduced into magnetite, and alumogoethite into magnetite and alumina. Then, the magnetite reduction undergoes the process of Fe3O4→FeO→Fe, while alumina can react with FeO to form hercynite. The hercynite is ultimately reduced into metallic iron and alumina at elevated temperature. The specific saturation magnetization of reduced product is closely related to its main minerals, that is, the specific saturation magnetization of magnetite and metallic iron is higher than that of wustite and hercynite. The mass ratio of Fe to Al2O3 in magnetic concentrate increases with roasting temperature, from 4.55 at 600 °C to 10.27 at 1200 °C. Therefore, efficient separation of iron and alumina in red mud could be achieved through deep reduction-magnetic separation.

May 2, 2024

By Brendan Donnelly, Jung-Hoon Sul, Lasitha Piyathilaka, Sanghyun Jeong, Benjamin Probyn

The chains of armored face conveyor (AFCs) are constantly in contact with water and wet coal, which results in a significant proportion of unplanned downtime experienced on longwall equipment due to corrosion. While reverse osmosis (RO) is one of the most prevalent water treatment methods for reducing salinity and dissolved solids in coal mining, its impact on the corrosion of the AFC chains has not been well studied. This work studies the direct effects of RO water on the corrosion of AFC chains. Immersion tests followed by surface micromorphology analysis and corrosion indices indicate that the RO water increased the corrosion rate of the AFC chains due to the reduced tendency of preventive films on the chains.

May 1, 2024

By Arif Emre Dursun

The aim of this study is to present hazard classifications of location, type and causes of accidents in the Turkish coal-extracting industry using the analytic hierarchy process (AHP). In this study, fatal mine accidents were analyzed by pairwise comparison and weighting, and the most important hazards were identified by determining the effective main and sub-criteria among location, type and causes of accidents. For this purpose, first-, second- and third-level hazards consisting of location, type and causes of accident were determined by using the data of fatal mine accidents in underground and openpit coal mining in Turkey between 2010 and 2020.

May 1, 2024

By Mustafa Kumral, Mehmet Balci

Strategic mine planning centers on solving cut-off grade selection, capacity planning, and block sequencing. Even though significant knowledge has been accumulated on mine planning over the last decades, there is still potential to add value to mineral sourcing by addressing various aspects. To this end, this paper addresses two issues. The effects of (1) grade/metal distribution within a mineral deposit and (2) the economies of scale (EoS) are explored in cut-off grade selection and capacity planning. In doing so, the interdependency between cut-off grade selection and capacity planning is also considered. A case study is implemented on a metallic deposit whose grade distribution exhibits lognormal distribution to detect if grade/ metal distribution influences cut-off grade selection. Also, based on the same ore tonnage and metal quantity, six different datasets are generated with different shape and scale factors. The research outcomes indicate that deposits with lower shape and scale factors of lognormal distribution are more sensitive to metal price and discount rate changes because slight cut-off grade variations significantly change net present value (NPV). While the NPV of the deposit with the largest shape factor is $3,208,112,841 with a cut-off grade of 0.058 oz/tonne, the NPV of the deposit with the smallest shape factor is $93,617,240 with a cut-off grade of 0.027 oz/tonne. Furthermore, the case study is directed to investigate the effect of EoS on a project’s value, with a specific emphasis on the ratio of variable cost to total cost (capacity factor). Two different regression analyses are conducted based on the proposed model for optimal capacity planning and cut-off grade selection, respectively. In the first one, the absolute standardized beta values for EoS of mining and mineral processing costs are 0.736 and 0.425, meaning that capacity planning is highly sensitive to the EoS of mining and mineral processing operating costs. Meanwhile, the absolute standardized beta value for grade variability is 0.054 which means that the effects of grade variability and metal distribution are almost negligible for capacity planning. However, EoS is the most critical variable for capacity optimization. In the second regression analysis, the standardized beta values for grade variability and EoS of mineral processing operating cost are 0.573 and 0.522, so their effects on cut-off grade selection become vital.

Apr 29, 2024

By Shanxi Wu, Jialong Li, Haoyu Hu, Jiqing He, Zhaohui Wang, Bochao An, Shenyi Zhang

There are a large number of thick alluvium and thin bedrock deposits at depth in the Henan coal base. The degree of surface mining is high, and the surface environment is seriously damaged. Using indoor experiments, numerical simulation, and field measurement, it is studied the influence of the mechanical properties of thick alluvium on the surface subsidence characteristics of thick alluvium thin bedrock deposits at depth, taking Zhaogu No. 2 coal mine as the research background. The results show that the compressive strength and elastic modulus of the alluvial layer are linearly negatively correlated with the alluvial layer particle size, linearly positively correlated with the confining pressure, and nonlinearly positively correlated with the loading rate. The thickness of the alluvial layer has the greatest influence on the displacement of surface subsidence and the range of surface subsidence. The advancing mining rate of the working face has the greatest influence on the surface horizontal displacement. The mechanical properties of the alluvial layer affect the evolution characteristics of the caving arch and towering roof beam. The influence range of the 11012 working face is about 550 m, β is about 55.5°, and the maximum subsidence rate of the surface is 12 mm/day. The mining process and separation grouting can be adjusted to control the overburden displacement to reduce surface disturbance and protect the surface ecological environment. The research results of this paper can provide a research basis for the study of surface subsidence under similar geological conditions.

Apr 28, 2024

By Sidi Deng, Sharon Pedraza, Aaron Noble, Subodh Das, Bin Ji, Wencai Zhang, Michael Van Brunt

In this study, a MSWI bottom ash sample was assessed to evaluate the feasibility of various physical beneficiation processes in concentrating valuable elements prior to chemical leaching. The raw sample was initially assayed to determine the content and economic value of various metals present in the material. The potential recoverable value (PRV) of the sample was calculated, and the result showed that the total PRV of the sample was 483 $/ton, with Ti, Sc, Fe, Cu, and Zn being the most valuable metals. Next, various physical separation processes, including size fractionation, froth flotation, magnetic separation, and gravity separation, were conducted to determine the extent to which the valuable elements can be concentrated. The results were compiled into an element-by-beneficiation enrichment ratio (er) matrix that was used to develop suitable beneficiation flowsheets for further consideration. The result clearly show delineation of four products, including a Fe-rich product that can be isolated by magnetic separation (er = 5.0), a Cu/Zn-rich product that can be isolated by flotation (er = 5.3 to 9.4), a Sc-rich product that can be isolated by gravity separation (er = 0.6), and a Ti–rich product that is produced in the residue. Lastly, the leachability of valuable elements from the bottom ash sample was determined by acid leaching tests. The results indicated that it is viable to employ hydrometallurgical methods to recover and purify the valuable metals. This work provides a reference for the recovery of valuable metals from MSWI bottom ash from both the technical and economic aspects.

Apr 27, 2024

By Chun Yu, Jiarui Min, Xuemin Ding, Rongdong Deng, Bao Guo, Yu Miao

Pb2+ plays a modifying role in the flotation behavior of various sulfide and oxide minerals. However, there is currently no consensus on the use of lead salts as modifiers in mineral flotation. Based on previous research, this article provides a comprehensive review of the activation effect of Pb2+ on common oxide and sulfide minerals flotation from the perspective of interfacial reactions. A theoretical model for Pb2+ activation has been proposed in this article. When the pH is less than 7, Pb2+ replaces the metal atoms in the lattice of sulfide minerals or adsorbs on the mineral surface to form PbS. When pH is in the range of 7 ~ 10, chemical adsorption of Pb(OH)+ occurs on the mineral surface, leading to the formation of Me-O-Pb+. When pH = 10 ~ 11, Pb(OH)2 precipitates on the mineral surface. Under this condition, it activates the flotation of quartz but inhibits the flotation of sulfide minerals.

Apr 25, 2024