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By D. E. Hirsch

The Bureau of Mines, as a part of American Petroleum Institute Research Project 60, Characterization of the Heavy Ends of Petroleum, has made extensive use of gel permeation chromatography (GPC). Data developed in this study were used to develop several correlations that greatly expanded the usefulness of GPC and the data have been used as an aid in the interpretation of mass spectra (MS). GPC retention volume data on pure compounds were used with molecular structure to develop correlations that can be used to accurately predict retention volumes, molecular volumes, densities, chain lengths, and ring numbers of many components of petroleum without resorting to further laboratory experimentation. Conversely, the correlation can be used to select or reject some compounds from several possible compounds that are indicated on the basis of MS analysis. The utility of these correlations in compound type characterization is demonstrated by showing their application to 330° to 550° C fractions from a low-sulfur and a high-sulfur crude oil.

Jan 1, 1974

By Mohamed Yusuff

Modern transportation systems are one of the most important achievements of our civilization and provide us with tools for broadening individual and social freedom of choice. The transportation system initiated today is handed dawn to the next generation, probably with little choice because of the enormous expenditure of monies involved, and influence their way of life as to where they should live and where they should work. The ever increasing antagonism between the citizens and the planners of the transportation systems necessitates a careful review of the entire planning process. The planning process can be broadly classified into: the goal formulation and decision making process; the plan development process; and the plan implementation process. THE GOAL FORMULATION AND DECISION MAKING PROCESS Goal formulation and decision making is one of the vital phases of the planning process and is primarily based upon social values. In measuring social values, the planner must employ an appropriate scale of measurement since in the absence of this yardstick, these values tend to became vague and abstract ideals. The need for major social programs and concerns (poverty, etc.) of the urban areas should be analyzed to determine the type of transportation system which would contribute to the solution.

Jan 1, 1974

By L. E. Schultze

[The Bureau of Mines conducted bench-scale studies to develop techniques for stripping tetravalent cerium from tri-n-butyl phosphate solutions. Experiments were conducted in a constant-temperature bath using beakers and mechanical stirring. Ninety-five pct of the cerium was stripped from a 50-pct tri-n-butyl phosphate 50-pct kerosene solution containing 0.18 M cerium in 15 minutes at 50° C using 0.11 M aqueous formaldehyde.]

Jan 1, 1974

This report, the fourth in an annual series, outlines recent trends and developments in the minerals industry. Discussed are new methods, equipment, techniques, and systems used to more effectively extract and process mineral products. Environmental considerations, health and safety standards, price controls, inflation, material shortages, and more dependence on foreign imports were problems faced by the minerals industry. Although productivity increased for most mineral commodities, the annual rate of increase has slowed in recent years, indicating a maturing technological situation. Growing concern for energy resulted in increased interest and research in alternative fuel sources. The primary concerns of metallurgists were pollution control and improved efficiency and performance of metallurgical processes, especially for reduction of energy consumption.

Jan 1, 1974

By Martha McJunkin, Lawrence Pietrzak

This paper describes and demonstrates the application of systems analysis and mathematical modeling techniques in the planning of actual tunnel projects and research and development to improve tunneling techniques. A recently completed tunnel project located in Utah is used as an example. Although cost estimating computer programs are used in tunnel project planning, the introduction of performance modeling, simulating the time to excavate, has added advantages that are explored here. The performance/cost tunneling model (TM) described herein mathematically simulates on a high-speed digital computer the important activities of a number of tunneling techniques accounting for activity interactions, variable external environments, mechanical failure, and other uncertainties. A cost accounting segment is included to facilitate cost-effectiveness comparisons. It is shown that, when combined with informed judgment and appreciation of limitations, the TM can be a useful tool that may help improve tunneling operations and cost estimation, for example, by achieving more balanced system designs or bounding the performance/cost implications of geologic and other uncertainties. Ultimately, this might lead to more competitive bids and greater profits. The need for systems analysis and modeling in tunneling research and development (R&D) is well recognized and documented.(1-5) In R&D one must seek broadly useful solutions to the basic problems of face fragmentation, materials handling, ground support, and environmental control. These solutions must take account of the interdependence of these elements and, for a variety of ground conditions, the limitations or constraints that any innovation in one element may impose on total system performance and cost. In this regard the structure and logic of the TM has been kept as simple and modular as possible so

Jan 1, 1974

By Dennis K. Mortensen

The warm southwestern desert of Arizona is an ideal location for ASARCO's new Sacaton Unit. The climate of this arid region played a major role in the design considerations of the Unit's crushing and concentrating facilities. Low yearly rainfall and relatively high yearly temperatures are a combination that was taken advantage of when designing the surface facilities. The plantsite, located due west of the mine pit, is in an area originally covered with sparse desert vegetation, underlain to an average depth of 125 feet by desert alluvium. The entire plantsite area slopes gently to the southwest at approximately 1%. Ground conditions at the plantsite area were not acceptable for construction due to the collapsability of the wetted soil when under loaded conditions, Overburden from the pit area was used to form the foundation for the entire plantsite. This waste material, entirely devoid of rock, was placed and compacted to an elevation approximately 20 feet above the desert floor. Elevating the plantsite by filling with waste material not only provided an adequate construction foundation but also eliminated the possibility of flooding from run-off in the surrounding desert areas.

Jan 1, 1974

By Jack L. Henry

A laboratory and a pilot-plant-scale investigation has been conducted by the Bureau of Mines to examine possible sources of nitride defects in the production of magnesium-reduced titanium sponge. The production of alpha-stabilized nitride inclusions in hot-rolled titanium plate from air contamination of sponge during its manufacture has been experimentally demonstrated. Magnesium-reduced sponge prepared from air-contaminated magnesium or when contaminated by an air leak during reduction, vacuum distillation, or inert gas sweep, shows very large variations in nitrogen content. Refractory nitrides, delta TiN and epsilon Ti2N have been identified in this sponge. The highest incidence of inclusions resulted from sponge that was reduced by air-contaminated magnesium and from sponge subjected to air contamination during the vacuum distillation cycle and during helium sweep. Air contamination of sponge during the reduction cycle was not nearly as effective in producing inclusions. Tests showed that color and texture may not be reliable criteria for locating defects during sponge inspection. Maintenance of good vacuum-tight integrity, filtration of molten magnesium prior to charging into the reduction retort, and mechanical attrition of sponge to pulverize and disperse nitrides are suggested as practices to lower inclusion incidence in commercial titanium ingots.

Jan 1, 1974

By W. H. Ryback

When a fire or explosion occurs in an underground coal mine, the atmosphere guickly becomes irrespirable. Highly irritant smoke and toxic levels of carbon monoxide and dioxide are produced, and consumption of oxygen by the fire or blast can reduce its concentration below that needed to support life. Work parties entering such a hazardous atmosphere for rescue or recovery operations are required to use, as their primary respiratory protection, a fully self-contained breathing apparatus of at least two hours duration. Apparatus used in this role has primarily been of the closed circuit rebreather type, using pressurized oxygen storage and chemical removal of expired carbon dioxide. Typically, commercial self-contained breathing devices for mine rescue have been heavy, bulky, and uncomfortable to use. The McCaa apparatus, long the industry standard, represented the best art available when it was First designed in 1926. It weighs 41 Ibs., protrudes about six inches above shoulder height, and provides breathing gas at temperatures up to 120° F. More recent designs, such as the Drager BG174A and Scott Rescue-Pak, using modern light weight materials and fabrication techniques have improved on all parameters of the McCaa to some extent. It was the intent of the Bureau of Mines, acting under the authority of the Coal Mine Health and Safety Act of 1969, to fund the development of a new self-contained breathing apparatus which would incorporate the best available technology and serve as a benchmark for future commercial designs, as the Bureau-sponsored McCaa had 45 years previously.

Jan 1, 1974

The panic bars (and associated linkages and electrical circuitry) that are defined in this document are a machine operator-actuated control for the emergency deenergization of the tram motors on self-propelled, electric and diesel face equipment: including haulage equipment such as shuttle cars. There are nine basic types of panic bars (and several variations) that arc recommended in this document, but all of the panic bars are characteristically of the "fire door" type that is frequently encountered on outside exit doors of many public and some commercial buildings. It is also the intent of the following panic bar designs that, when emergency brakes are added to the face equipment machinery for which they arc required, that they be designed and hooked up so that actuation of the panic bar will result in automatic application of the emergency brakes (immediately following the deenergization of the tram motors). The following panic bar design requirements are a restatement of the proposed requirements defined in the Federal Register, requirements cited in "Guidelines for the Design and Installation of Devices for Deenergization of Self-Propelled Electric Face Equipment/Automatic Emergency Brakes" by C. E. Lester and J. D. Greenhalgh of MESA, and Bendix recommendations that were formulated as a result of discussions with personnel al the various machine manufacturers and underground coal mines that we surveyed, discussions with G. L. Judy (our consultant), etc:

Jan 1, 1974

By Curtis D. Edgerton

Miami Oölite limestone is the only significant construction mineral in southeastern Florida. Its source area coincides with that of rapid urban expansion. Two-thirds of the existing resource is already unavailable because of development. Land-use conflicts place future availability of limestone in jeopardy. However, a sufficient limestone resource to meet demand for many years is present if its extraction is not restricted. Adverse environmental effects of quarrying Miami Oölite are not severe; land values often increase following quarrying. Future availability depends upon--(l) achieving uniformity of Federal, State, county, and municipality statutory requirements governing quarry operations; (2) setting aside specific land areas for future quarrying; and (3) cooperative planning to provide for land utilization upon completion of quarrying.

Jan 1, 1974

During the first quarter of 1973 ADL worked closely with PMSRC staff, under an extremely compressed time schedule, on all aspects of the detailed planning, organization and overall coordination and preparation of the lectures and in-mine demonstrations for the Bureau's Technology Transfer Seminar on Mine Communications given in March of 1973 to representatives of the mining industry. Our efforts centered on the detailed organization and preparation of each of the five technical seminar lectures and associated supporting material, and the coordination of tasks assigned to ADL and other seminar participants. Revised and expanded drafts of the seminar papers were prepared from rough draft versions obtained from PMSRC, Collins Radio and ADL staff. Measurements were made to gather key data on the operation and performance of each of the following systems installed in the Bruceton Safety Research Mine; call alert paging, roof bolt paging, section wireless radio, and guided wireless radio systems. These data were analyzed, manufacturer's equipment specifications utilized, and calculations made to provide performance curves and data for each of the above systems. A substantial amount of artwork was conceived and prepared for 35 m slides, system identification posters in the mine, and seminar handouts. This artwork included some forty 8-1/2" x 11" line sketches, graphs, block diagrams, circuit diagrams, coverage maps, and other line drawings; five 30" x 40" block diagram system identification posters suitable for in-mine use; a 20" x 30" detail perspective illustration of a representative coal mine layout; forty viewgraphs; and seventy 35 m slides of the artwork and word charts. Conferences, discussions and review sessions were held with conference participants to help coordinate the various efforts, obtain technical information, and make final plans regarding the lecture presentations, associated visual aids, and the communication system installations to be demonstrated in the Bruceton mine. These meetings included final systems checkouts and dry run presentations and reviews of the lectures and mine demonstrations. This phase of the seminar effort concluded with R. Lagace and R. Spencer of ADL participating in two days of seminar presentations in the lecture hall and in the Bruceton mine.

Jan 1, 1974

By J. A. Eisele

The Bureau of Hines conducted a bench-scale investigation of a concentrated H2S04 reaction for recovering and separating rare-earth elements, barium, and strontium from a bastnasite ore and byproduct. Barium and strontium were dissolved in the concentrated acid and precipitated as a mixed product by water dilution. Separation of strontium from barium was effected by reaction with Na2C03 solution, followed by a dilute acid leach of the SrC03 formed. After removing the barium and strontium from bastnäsite are, the rare-earth elements were roasted to water-soluble sulfates. The rare-earth sulfate solution was subsequently processed by solvent extraction to produce rare-earth oxides low in lead and magnesium.

Jan 1, 1974

By George A. Savanick

Coal mine roof shales fracture preferentially at slickensided surfaces because of weak or nonexistent adhesion between two slickensided rock surfaces. The purpose of this Bureau of Mines research was to characterize chemically the thin film of smooth, glossy material that makes up the slickenside. This material was analyzed by electron spectroscopy and ion scattering spectrometry while in place on the rock surface and by standard methods of quantitative chemical analysis on concentrate removed from the rock. These analyses showed that the chemistry and mineralogy of the slickensides are similar to that of the adjacent shale.

Jan 1, 1974

A symposium on the health hazards of respirable dust in the mining and milling of talc was held on May 8, 1973, in Washington, D.C. The results of medical effects on both human and animal subjects were presented. Methods for identification and classification of talc minerals were also presented. Analytical techniques discussed included X-ray diffraction, scanning electron microscope observation, electron probe, and optical microscopy.

Jan 1, 1974

By R. F. Stewart

A nuclear meter based on measurement of prompt capture gamma rays is being developed for monitoring the sulfur content of coal streams. Equipment has been built to measure sulfur rapidly, and methods have been devised to compensate for changes in moisture, ash, and bulk density of coal flowing through a bin. Pilot plant tests of the system with various additives to different coals show a precision and accuracy of 0.02 percent sulfur and 0.04 percent sulfur, respectively. Based on these results, a hardwired meter has been fabricated for testing in a commercial coal preparation plant.

Jan 1, 1974

By R. Feenstra

In the course of time, an increasing number of investigations on jet cutting all kinds of material, such as rocks1, 2, 3, metals4, 5, and wood6 have been reported to serve various applications. This paper deals with one particular application of jets, viz deep-well drilling for hydrocarbon exploration and production. A number of papers have been published on this subject 7, 8, 9, some of which refer to jets purposely containing abrasives, termed 'jetted particle drilling'7. Since such abrasives complicate fluid handling considerably and do not appear to be absolutely necessary for making hole we have restricted ourselves to conventional drilling fluids. A large part of our investigation has been performed with the aid of three laboratory-type drilling machines, which permit tests on both micro-bits (12 in) and full-scale bits (62 - 9 5/8 in). In view of the application of jets in deep wells, care has been taken to simulate hydrostatic pressures as they exist in the field on the hole bottom. These have been found to have a major effect on the bit-penetration rate for various drilling fluids. Following experiments with single nozzles, laboratory bits have been designed, improved further and developed for field use. Field runs on 9 5/8 in bits, using conventional equipment and pumps, served to verify the feasibility of the jet drilling concept. Further efforts are evidently needed to evaluate the jet drilling method. It is encouraging that one of these10, a field test programme, is supported by a number of oil companies jointly. Such a combined effort is of paramount importance to evaluate and develop this new method of drilling to its full potential in a reasonable period of time. This paper aims to contribute to that ultimate goal.

Jan 1, 1974

The purpose of this study is to develop designs to facilitate and accelerate auger rotation stoppage (and auger rotation start up so as to promote auger disengagement during auger miner repositioning) and to provide a time delay and warning signal prior to auger start up to permit any miner s near the augers to get away from the augers before they start rotating. In the underground coal mines in the U.S., there are four auger miners that are currently in use. They are the Jeffrey 100L (see Figure 1-1) and 100M (see Figure 1-2), and the Wilcox WCM and the MK20A (see Figure 1-3).

Jan 1, 1974

The development of the Moura Coal Preparation Plant is described, commencing with the first'stage of the plant commissioned in 1963. The subsequent expansion stages are traced through to October, 1973. The plant has undergone frequent stages of expansion and modification and this process is continuing. The development programme for 1974 is described as proposed in late 1973. The characteristics of the Moura and Kianga field coal seams with respect to washability are summarised and some comment is made on the blending of these coals prior to washing, to ensure production of export grade coal within specification.

Jan 1, 1974

By J. C. Franklin

The Spokane Mining Research Center of the Federal Bureau of Mines is placing major emphasis on chemical stabilization as part of the ground support program. Development of polymeric material suitable for bonding rock fractures around the mine opening is one phase of the program. Some of the problems that must be considered are viscosity, applicability, adhesion, cure times, strength, toxicity, and flammability. Epoxies and polyesters were investigated, but shrinkage in polyesters caused redirected effort toward epoxies. Test results with the latter showed that bonded fractures in mine-roof strata were stronger than the virgin rock. Further tests showed that polymeric materials have good potential for bonding, and in conjunction with polymer roof bolts, are expected to result in an economic and useful new support concept.

Jan 1, 1974

By J. W. Wilson, P. C. Graham

SUMMARY The Witwatersrand quartzites in which South African gold mining operations are moat exclusively conducted, are notoriously difficult and costly to drill. Despite this situation, however, with the high cost of developing new mines and extending existing mines, together with the rising cost of labour and mining problems resulting from the ever-increasing depths of workings, the demand for raise-boring in these formations is increasing rapidly. Not only is the demand for raises and shafts increasing, but also the length and size of these excavations. Raise-boring studies carried out in South African gold mines have indicated that increased penetration rates and possibly reduced costs could be obtained if higher thrusts were available at the reaming head. Until fairly recently there has been no raise-boring machine suitable for underground use that possessed the thrust and torque characteristics necessary to achieve high penetration rates in hard abrasive quartzite formations and the cutters available were not really developed for high loading. In response to these requirements a raise-borer, the Robbins 83R was designed and built in Seattle, U.S.A. for the Anglo American Corporation. This machine is operating in South African gold mines and is currently being used at a depth of 12 000 ft below surface in one of the. Group's mines. The initial raises bored have substantiated that increased penetration is attainable at high thrust and it is now apparent that the machine is sufficiently versatile to drill raises of up to 12 ft in diameter in quartzite formation over a length of 2 000 ft.

Jan 1, 1974