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By F. P. Haver

Primary lead is produced in the United States by the pyrometallurgical smelting of lead sulfide (galena, PbS) concentrates, which poses sulfur dioxide and lead air pollution control problems. The Federal Bureau of Mines has investigated an alternative hydrometallurgy procedure that does not generate gaseous sulfur oxides and diminishes the potential for the escape of lead into the atmosphere. The procedure involves leaching galena flotation concentrates with ferric chloride (FeC13) solution to obtain lead chloride (PbC12) and elemental sulfur as expressed by the following chemical reaction: PbS + 2FeC13 ? PbC12 + 2FeCl2 + S°. At 100° C, over 99 pct of the PbS in the concentrate is converted to PbCl2 in less than 15 min. The leach solution, composed of brine (NaCl) containing slightly more than the theoretical required amount of FeC13, dissolves the PbC12 as it is formed, leaving a residue of elemental sulfur plus gangue. High-purity PbC12 (>99.9 pct) crystallizes from the leach filtrate on cooling and is electrolyzed in a low-temperature, fused-salt cell to obtain corroding-grade metal (>99.94 pct Pb). Spent leach solution (FeC12) is regenerated for further use by reaction with the chlorine obtained in the electrolysis of lead chloride. Other values, such as Ag, Cu, Zn, and S°, are recovered by additional treatment of either the leach solution or leach residue.

Jan 1, 1976

By Edwarde R. May

The Flambeau volcanogenic massive sulfide deposit located in northwestern Wisconsin occurs within the southern lobe of the Canadian Precambrian Shield. The steeply dipping tabular body occurs in a complex pile of cyclic schistose intermediate to felsic fragmental volcanics. No chloritic alteration pipe is recognized but adjacent rocks have undergone magnesia metasomatism and subsequently were metamorphosed to the upper greenschist and lower amphibolite facies. Although modest in size the deposit is of special interest in that it has an extensive and well preserved supergene enrichment blanket. Economic minerals found within a pyritized quartz-sericite schist are chalcocite and bornite overlying primary chalcopyrite.

Jan 1, 1976

By H. C. Ko

Calorimetric determinations of low-temperature heat capacities and standard enthalpy of formation were made by the Federal Bureau of Mines for basic aluminum sulfite, A1203?2.0S02?5.3H20. The standard values of entropy (S°), enthalpy of formation (?Hf°), and calculated Gibbs energy of formation (?Gf°) at 298.15 K are 85.2±0.1 cal/deg-mole, -943.1±1.2 kcal/mole, and -820.7±1.2 kcal/mole, respectively.

Jan 1, 1976

By J. C. Gerdeen

SAP-S information on the following element types are included in this appendix: Type 1. Three-Dimensional Truss and Bolt Element Type 4. Two-Dimensional Finite Elements Type 8. Variable-Number-Nodes Thick Shell and Three-Dimensional Elements Type 9. Two-Dimensional Joint Element (to be used with Type 4 elements) Type 10. Three-Dimensional Joint Element (to be used with Type 8 elements) Additional SAP4 elements, Types 2, 3, 5, 6, 7 and 12, are also contained in SAP-S and information on these elements is readily available in any SAP4 user's manual. These elements are as follows: Type 2. Three-Dimensional Beam Elements Type 3. Plane- Stress Membrane I-r .n Elements Type 5. Three-Dimensional Solid Elements (8 Node: Brick) Type 6. Plate and Shell Elements (Quadrilateral) Type 7. Boundary Elements Type 12. Three-Dimensional Straight or Curved Pipe Elements

Jan 1, 1976

By Stephen A. Hare, O&apos

Powder metallurgy processing of commercial Raney nickel powders was examined. The typical angular particle shape, in conjuction with aluminum present in a eutectic phase, facilitated interlocking leading to excellent green strength after compaction. Density and porosity as influenced by the compacting pressure were studied over the range of 37.5 to 207 meganewton per square meter (MN/m2). Sintering in an inert atmosphere from 575° to 850° C caused a volume increase which is attributed to a solid state reaction between Al and Ni2Al3 phases. The reaction is 3Al + Ni2Al3 ? 2NiA13. A thermal pretreatment of 70 hours at 700° C was required to prevent this reaction from occurring during sintering. Density and porosity as a function of compacting pressure and sintering temperature were determined after a thermal pretreatment of the powder.

Jan 1, 1976

By Charles W. Daugherty, James P. Gould, Kenneth R. Ware

INTRODUCTION As illustrated in Figure 1, the Washington Metropolitan Area Transit Authority's (WMATA) rapid transit system (METRO) ultimately will comprise 100 miles of line divided among 10 routes. At this time about 46 per cent of the system is under construction or in operation. Planning and design of an additional 38 per cent is at an advanced stage. Of the 84 miles under development or construction, about 10.4 miles consist of soft ground tunnels, and another 1600 feet of mixed face. This paper describes most of the factors considered by designers in setting grades for such tunnels. It is hoped the paper will be a useful guide to planners and engineers in developing similar transit systems. The problems faced in Washington, including those related to geology, are not so unique that the solutions cannot be applied to other systems. The paper also may be of interest to contractors who have not perceived the logic behind the selection of a particular vertical alignment. An attempt is made to explain the background constraints that make most tunnel alignments a compromise among competing alternatives. Readers might assume that the choice of alignments is largely controlled by geological conditions. In fact this is merely one of many factors to be considered.

Jan 1, 1976

VOLUME I Volume I of this three-volume report is the result of development of a comprehensive, coordinated approach to site data-acquisition activities to produce key plans and reports during the evaluation and development of a surface coal mine. A logic diagram illustrates activities in the planning and decision-making process from exploration through post-mining monitoring. The report briefly discusses major elements, other than the site environment, which influence development of mining and reclamation plans and refers to other readily available literature for details outside the scope of this study. The essence of the rationale is shown to be the 1 employment of necessary skills at the proper time to evaluate specific data ' requirements and integrate them into a cost-effective program to produce initial and major feasibility reports, mining, and reclamation plans, and the environmental impact assessment.

Jan 1, 1976

By R. Blickensderfer

Several thin film absorber stacks with spectrally selective characteristics were developed by the Bureau of Mines. The stacks consisted of a silicon thick film or a zirconium compound thin film on a reflective thin film of silver. The zirconium absorber films, with the general formula ZrCxOyNz, were prepared by reactively sputtering zirconium or zirconium carbide in argon with small amounts of oxygen, nitrogen, or both, or by oxidizing zirconium films in air. A few similar types of films were prepared from titanium. The short-wave absorptance over the solar spectrum, a(s), and thermal emittance at 600 K, e(600 K), of the solar absorber stacks were calculated from room-temperature reflectance data. The values of a(s) ranged from 0.47 to 0.93, e(600 K) from 0.49 to 0.034, and the ratio a(s)/e(600 K) from 1.7 to 34. The specimen with the best combination of properties, a ZrNx-Ag stack, had a solar absorptance a(s) of 0.85 and a ratio, a(s)/e(600 K), of 24. The effect of film thickness and composition on spectral selectivity was determined. An emissometer for measuring normal total emittance up to 800 K and a method for determining a (s), e(T) (hemispherical), and a(s)/e(T) using simulated solar radiation are described. A calorimetric method for measuring a(s) and e(T) (hemispherical) at elevated temperature is also described. Measurements made on several specimens agreed favorably with calculated values.

Jan 1, 1976

By William J. Stone

Large reserves of coal and uranium exist in the San Juan Basin of northwestern New Mexico. The mining and development of these resources necessarily also involves depletion of area water resources and disturbance of the hydrogeologic framework. In an effort to better define the water resources and hydrogeologic framework of this region, the New Mexico Bureau of Mines and Mineral Resources, the U. S. Geological Survey, and the State Engineer's Office are presently engaged in a cooperative study of the Hydrogeology and Ground-Water Resources of Northwestern New Mexico. The purposes of this paper are to introduce our project, review tine coal and uranium resources of the San Juan Basin, and discuss the various hydrogeologic considerations recognized in their exploitation.

Jan 1, 1976

By Thomas A. Giordano

Portable communications equipment is becoming increasingly important in underground mining. Proper selection of microphones and hearing devices to be part of these communication systems is essential if the messages are to be transmitted intelligibly. In this program a thorough study of the requirements for these transducers was made with respect to intelligibility, mechanical configuration, human factors and safety. A computer analysis was made to predict how several combinations of transducers would perform at typical mining noise levels. A survey has been made of those microphones and hearing devices on the market today that might be applicable to the miner communication system. Several systems are proposed and evaluated.

Jan 1, 1976

By Lloyd A. Morley

The problems associated with the presence of organic materials and of water in explosion-proof enclosures used in high voltage, high capacity applications were examined through a literature search and theoretical reasoning. Information on volatilities is presented. The conclusion is reached that explosive pressures are significantly enhanced by inclusion of these materials.

Jan 1, 1976

The number of railroad coal cars (open top hoppers), dominated rail car orders and deliveries in 1975 according to announcements made February 11, by the Association of American Railroads and the American Railway Car Institute. Acting to keep ahead of increased coal production, the railroads installed 21,748 new coal cars in 1975, the most since 1957. The 1975 installation resulted in a net increase of 6,560 coal cars and an overall gain of 4.5 percent in the total capacity of the hopper car fleet. With most of the new coal cars going into unit train service --where car utilization is greatest --the railroads actual coal-carrying capacity was increased far more than 4.5 percent. The AAR estimated that unit train operations now move 50 percent of all rail-hauled coal compared to only 42 percent 2 years ago. COBALT - The Societe Miniere de Tenke Fungurume (SMTF) copper-cobalt project in Zaire reportedly was suspended in January for an indefenite length of time. According to officials, the deferment resulted from a number of adverse factors, one of which was exceptional increases in capital costs. The project was scheduled for completion in early 1978, with an eventual production of 14.3 million pounds of cobalt per year. Reserves of cobalt were reported to be 505 million pounds. SMTF is a consortium and includes American, British, French, Japanese, and Zairian interests.

Jan 1, 1976

At the end of August, U.S. producer posting of 99.5 percent unalloyed aluminum had been established at 48¢ per pound. At that time, dealer-quoted unalloyed ingot was reportedly at 44¢-47¢. CADMIUM: By late August, most U.S. producers had raised cadmium selling prices by 25¢ to $3 per pound. As a consequence, dealer quoting of cadmium ranged from $2.95 to $3.05 per pound. COAL: The wildcat strike, which began in southern West Virginia on July 19 and eventually spread to nine other States before ending on August 13, at its peak, idled approximately 115,000 miners and accounted for daily coal losses of an estimated 1.5 million tons at the height of the work stoppage. Concerned about the effects of the production cutbacks, the Bureau of Mines, early in the strike period, initiated its coal strike monitoring system which it had developed during the prolonged coal strike in the fall of 1974.

Jan 1, 1976

The excavation of sandstone of generally medium strength for the Liverpool Link Line by Dosco Mark 2A Roadheaders has demonstrated the versatility and good performance of road- headers in suitable rock formations. A description is given of the strata traversed by the tunnels together with descriptions of equipment and crews, excavation sequences, operating difficulties and the results achiev- ed. In addition tunnel construction is des- cribed for a difficult section where there was only O.Sm clearance between invert and a four lane vehicular tunnel below, and O.5m clearance between tunnel crown and a century old sewer above.

Jan 1, 1976

The demands of the economy require larger manufacturing facilities using greater quantit- ies of raw materials which must be mined, handl- ed, stockpiled and recovered with efficiency and dependability. All over the world, mining com- panies, steel manufacturers, power stations and process plants are not only seeking but finding methods of increasing outputs and'reducing costs in the field of materials handling. In mining bigger continuous mining machines and shovels, larger trucks and crushers are digging and processing greater quantities of differing materials which have to be handled and shipped at rates once thought to be impossible. To implement such schemes demands the blending of a lot of diverse-equipment, mining machinery, bins, feeders, reclaimers and it is here that the belt conveyor assumes a role of ever increas- ing importance. Significant developments have taken place in the seventies with respect to conveyor belt transportation; not only in the systems but also in the components which combine to make such systems work efficiently.

Jan 1, 1976

By M. K. McCarter

In 1963, a major expansion program at Kennecott's Bingham Canyon mine converted rail operation in the upper portion of the pit to truck haulage. Since that time truck-haulage capacity has increased to about 272 000 Mg (300,000 tons) per day. The majority of this production is waste material which is deposited in monolithic dumps located on the eastern slopes of the Oquirrh Mountains. The largest of these dumps, referred to as Copper Notch and Keystone, measures approximately 1830 m (6000 ft) in length, from 180 to 300 m (600 to 1000 ft) in height, and contains some 430 Tg (470 mil lion tons) of waste. The height, structure, rapid rate of growth, and anticipated leaching suggested the possibility of dump failure. In order to evaluate this possibility, an outside consulting firm was retained in 1966 to investigate the stability of the growing dumps. Their investigation indicated that, other than superficial movement, the waste dumps would be stable under static loading, and that soil distribution was not continuous enough to sustain massive foundation failure. Since this investigation, however, several failure processes have been observed. Crest settlement occurs frequently in response to compaction and over-steepening in the upper portion of the dump surface. Over-steepening results from accumulation of fines near the crest caused by natural segregation. Normally, coarse material, near the base of the dump, exhibits an angle of repose near 0.65 rad (37"). The fine material, however, stands as steep as 0.75 rad (40"). Periodic equilibrium adjustments cause stepwise settlement (Figure 1) of the dump surface and occasional sloughing of the protective berm. Routine surface preparation by dozers and graders and frequent inspections by supervisory personnel have proven adequate in preventing problems associated with this form of crest instability.

Jan 1, 1976

By Robert G. Lundquist

This report summarizes all relevant findings and conclusions regarding capabillty of high-energy projectile impact to operate effectively in an open pit mining environment and to successfully handle secondary breakage and bench scaling problems. A silenced, aimable, mobile projectile launcher was designed and fabricated, utilizing a Government-furnished smooth-bore, 90 mm cannon. The silenced launcher was tested at the contractor's test site prior to shipment to ANAMAX Mining Company's Twin Buttes Mine near Tucson, Arizona. Demonstration tests were conducted at an inactive waste dump in the mine on 39 oversize boulders to determine the relationship between boulder size and projectile energy required for secondary breakage. The high energy projectile impact method (known by the acronym REAM -Rapid Excavation and Mining) was tested on an additional 23 boulders in the working mine and on 31 areas of potentially loose rock high on the pit walls. Most of the secondary breakage tests were successful and acceptable for open-pit mining purposes without producing large amounts of fly rock. Five of the 31 scaling tests were successful with one shot, but most of the remainder required two or more shots, and a few could not be dislodged because they were not as loose as they appeared to be, based on visual examination from a distance. Cost comparisons between the REAM method and conventional methods of secondary breakage and bench scaling are discussed. A film documentary, REAM--Mining Applications of High Energy Projectile Impact, has been produced by the contractor depicting the applications of the silenced cannon.

Jan 1, 1976

By R. R. Johnson

The Hama Mining Company owns and operates The Groveland Mine near Iron Mountain, in the Upper Peninsula of Michigan. The orebody is part of the Menominee Range of the Lake Superior District. The ore (generally known as Jasper taconite) contains an average of 35% iron ranging from 28% to 39% with an overall split of 60% magnetite and 40% hematite. The variations encountered throughout the orebody require a certain amount of blending to reduce feed changes to the mill. One of the variables which affects the crushers, as well as the mill, is the range of hardness which has a low of 7.9 and a high of 24.6 as measured by the Bond Twin pendulum impact and crushing technique. Reference is made to hardness only to point out its effect on crushing and wear rate variations. Over a period of time, these variables do, of course, average out. Mining of the low grade ore started in 1959 and has operated continuously to date. Preparation of the feed for conventional rod and ball mill grinding is accomplished by three stages of crushing. Reduction of crude ore is first passed through a 54 inch gyratory crusher; then through a secondary crusher; followed by two or three tertiary crushers in closed circuit with screens as production quotas require (Figure 1). Current demand to the crushers is about 5,200,000 tons of crude ore per year.

Jan 1, 1976

By Zsuzsanna Zborovszky

Experimental study directed toward gaining improved understanding of the exact mechanisms causing ignition in the PTB breakflash. Investigation and comparison of tungsten and copper wires as to their ability to cause hot wire ignition. Evaluation of the importance of discharge duration in the ignition process. Study of the parameters influencing the duration of a discharge (minimum discharge voltage, purity of electrode materials, purity and properties of the gaseous atmosphere contaminations, deposits on the electrode surface).

Jan 1, 1976

By Russell Miller, Fun-Den Wang

High Pressure Water Jet Assisted Tunneling The high pressure water jet assisted tunneling project was conducted in a granite quarry near Skykomish, Washington, approximately 90 miles east of Seattle. A 7-ft diam tunnel boring machine was modified and equipped with high pressure water jets. The concept that tunneling rates can be improved by using high pressure water jets was validated, with an average increased advance rate of 50% to 60%. For some tests, the advance rate was more than doubled. A comprehensive economic analysis has shown that very significant savings are possible. At a 50% increase in advance rate, cost savings of 14% and 24% were projected for 10-ft and 20-ft diam tunnels respectively. These benefits were seen to be relatively insensitive to water jet equipment costs.

Jan 1, 1976