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By Frank H. Skelding

Still the world's largest producer, consumer and importer/exporter of minerals, the United States has, in recent years, become more and more aware of the many diverse forces that increasingly affect its ability to maintain free access to and trade in minerals, both domestically and abroad. The nation's growing dependence upon foreign sources of minerals in the face of mounting competition is causing many changes, not only in the mineral industries, but in national attitudes and policies as well. This paper examines the position of the United States in the world mineral economy relative to the significant trends that have and are developing. It attempts to define and evaluate the major present and future impact of these trends and to anticipate the probable effects upon the U.S. and its mineral economy.

Jan 1, 1976

By Longworth C. R

Competing requirements for land usage sometimes make the correct all- ocation difficult. The decision can be complicated by many factors such as local resident pressure, previous government decisions, economic pres- sures and the duration or permanency of the competing land usages. This problem often confronts the extractive industries with consequent delays in granting leases and some- times considerable local dissension. A proposal to extend the high grade silica sand quarry of the Wamberal Sand Company Pty. Limited is a microcosm of these competing requirements. The sand quarry is located on the New South Wales central coast. It is an open pit operation on a near beach deposit of silica sand suitable for flint glass manufacture.

Jan 1, 1976

By John E. Kelley

Laboratory equipment, which simulates abrasive impacts between steel and minerals that might be present during pneumatic transport of coal, was used by the Bureau of Mines to characterize the potential explosion hazard of such collisions in an atmosphere of fine coal dust, air, and methane. A variety of coal mine rock materials, including sandstone, limestone, and pyrite-bearing limestone, were impacted with specimens of pipeline steel. Tests were con-ducted in atmospheres containing zero to 6.4 vol-pct methane mixed with zero to 300 mg/l coal dust. Coal dust in air alone was not ignited by abrasive impacts, but additions of as little as 1 vol-pct methane to the coal dust and air mixture resulted in ignitions. Steel impacting against sandstone caused ignitions in mixtures of coal dust, air, and methane, and the probability for ignitions increased with an increase in methane. No ignitions occurred with impacts of steel on lime-stone or pyrite-bearing limestone, even when large showers of sparks were produced. Studies of the effect of tangential collision velocity showed that no ignitions of coal dust, air, and methane occurred below 900 fpm (4.57 m/sec). Ignitions in coal-air-methane mixtures were found to be caused by a hot friction-induced smear on the impacted rock at the impact site rather than by sparks. High-speed photography was used to verify this observation.

Jan 1, 1976

The mineralogy of nickel slags from the flash smelter of Western Mining Corporation Ltd. at Kalgoorlie was studied. Residual magnesium silicates in the sulphide concentrates raise the melting point of the slag and result in the formation of magnesium-rich olivines. Addition of lime lowered the melting point, and, in slowly cooled slags, resulted in the formation of a pyroxene.Magnetite and sulphides were also present in all slags.The converter slags contained an olivine near fayalite in composition, together with wiistite, magnetite, and a little sulphide.Accretions from the hearth of the flash furnace were largely composed of magnetite with subsidiary olivine similar in composition to those of the flash furnace slags.Wall deposits, however, were largely composed of nickel ferrite and nickel-iron olivines.

Jan 1, 1976

Minerals are vital to any industrialized civilization. Annually, the United States uses more than 4 billion tons of new mineral materials, or about 40,000 pounds per person-about half being mineral fuels and the other half being metals and nonmetallics. Stable and economic domestic mining, mineral, metal, and mineral reclamation industries are essential to the economy. The value of United States energy and processed materials of mineral origin exceds $200 billion annually. Although a number of minerals are imported, especially some designated as "strategic and critical," most U.S. mineral supplies are derived from the domestic mines and processing facilities that you will be seeing, reading about, and visiting as you use this visitor guide. We hope you enjoy your experiences. This pamphlet, a guide to mining and mineral operations that may be observed or visited and some other points of interest relating to minerals, is intended to aid tourists and students who are interested in mining. Some may wish to study our Nation's romantic past; others may plan to enter the minerals industry as a career; still others may have a primary interest in conservation practices. The pamphlet is also intended to aid State and local officials, Chambers of Commerce, and mining firms in answering some of the many questions of tourists and students.

Jan 1, 1976

By F. E. Pawlek

Copper concentrates can be comminuted in an attritor within a very short time to a particle size of 1 - 0.1 um. Addition of sodium hydroxide enhances commninution. The concentrates, suspended only in water, can be completely dissolved under oxygen over pressure and temperatures ranging from 120 - 180°C (248 - 356°F), because the surface area of the concentrate has been significantly increased by the ultra fine grinding. Addi¬tion of a small amount of silver ions to leach liquor containing sulfuric acid acted as a catalyst for the dissolution of chalcopyrite, because of the formation of local elements on the surface. The addition of C1- ions was also catalytically very effective. With this method it is possible to completely dissolve the copper contained in chalcopyrite concentrates after ultra fine grinding within 30 min at 110°C (230°F) under an oxygen partial pressure of 1 atm (14 psig). Several flowsheets demonstrate the industrial feasibility.

Jan 1, 1976

By R. A. Guidotti

The Federal Bureau of Mines studied the thermal decomposition of the nitrides of the Group V A metals (CbN, Ta3N5, and VN) with the goal of preparing high-purity metals. Solid-state purification and arc and electron-beam melting were examined. Electron-beam melting proved to be the most efficient means of nitrogen and oxygen removal. Columbium and tantalum of 99.9-pct purity were prepared by this technique; in the case of vanadium, however, nitrogen could not be reduced below the solid-solution level.

Jan 1, 1976

By Wilson R. G

Mining conditions imposed by a coal seam roof can be analysed according to natural causes, before consideration of strata control. All types of roof behaviour can be explained by considering only three independent variables. They are roof rock types, rock stresses and discontinuities. Roof rock types encountered in the Sc.ithern Coalfield of New South Wales (NSW) are sandstone, shale, mudstone, laminite and coal. Each rock has its own mode of failure. Lithological stability of the sediments varies from one type to another. Regional stresses upon a coal seam roof will vary in magnitude according to the proportion of gravitational stress, which is related to depth of cover, and residual stress, which is related to the maximum depth of burial and may be gauged by coal rank. Local stresses will vary according to tectonic deformation, related to irregularities in seam structure.

Jan 1, 1976

By John C. Franklin

A radon survey was made at five different locations in the Twilight mine near Uravan, Colo., to determine chances in radon concentrations in an inactive mine. Data were taken with a continuous monitor set for 1-minute count periods and readings were taken 24 hours a day for 9 days. The 12 readings per station each hour accurately showed how t w radon concentration varied during the day. From the data collected from the intake portal to station 4, the average radon emanation rate was estimated at 18 picocuries per second per square foot (pCi/sec/ft3). A daily cycle in radon concentration was detected that apparently was related to barometric pressure change.

Jan 1, 1976

To provide a faster means to open and close permissible electrical enclosures. Approach: An inspection and repair port with a multiple start thread which provides a permissible joint has been developed and tested. How It Works: The inspection port screw thread has a large pitch, which allows the port cover to be rotated from fully closed 10 fully open, in less than one revolution. See Figure 1. When the cover is screwed back in. it be-gins engagement within one eighth turn because the screw design has eight separate threads. To prevent Its unauthorized opening, the port cover has a bolt guarded by ears which accept a padlock. The threads are designed to tolerate a reasonable amount of grit without binding, although wipe-off cleanness is necessary during reassembly. Enclosures of two different sizes each fitted with the quick-access port, were

Jan 1, 1976

By James H. Allen

The air lift method of pumping water is discussed. A review of several large diameter hole drilling projects that used reverse circulation air lift techniques is presented. Proposals are made for reverse circulation flow rates for slow rates of bit penetration (5 fph) as well as reverse circulation flow rates for faster rates of bit penetration (10 fph). The Ingersoll- Rand air lift equations are modified for rotary drilling operations. By establishing minimum reverse circulation flow rates and utilizing the modified air lift equations, the establishment of minimum circulation equipment sizes and a more definitive requirement for improved bit body design should result.

Jan 1, 1976

By Peter N. Blakey

The Kidd Creek orebody is a massive, base metal deposit with widths up to 600 feet and a strike length of 2,200 feet. The orebody dips eastwards at 70° to 80° and is amenable to sub-level open stoping. Five distinct zones (Fig.1) based on structural wall rocks and ore type parameters occur within the orebody. These zones are: Zone 1 - Mainly copper stringer ore Zone 2 - Massive pyrite ore Zone 3 - Massive sphalerite and chalcopyrite Zones 4 and 5 - Are banded and variable in nature Compressive strengths vary from zone to zone with an average of 22,000 p.s.i. and highs of 40,000 p.s.i. The mine is developed from a ramp extending from surface to the 1600 foot level and a 24 foot diameter, 3050 foot vertical shaft with main levels at 400 foot intervals. Sub-levels at 100 foot vertical intervals are driven from the ramp. transverse and longitudinal pillars to support the crown pillar left under the open pit. The layout allows an opportunity to enlarge or reduce pillar sizes and also to introduce fill on any horizon should conditions warrant. It also offers a large number of operating stopes spread through the various ore zones giving good ore blending characteristics. All ore from the stopes is handled through drawpoints using Wagner ST8 scooptrams with an average one way haul length of 650 feet.

Jan 1, 1976

By B. N. Church, J. J. Barakso, A. F. Bowman

"An evaluation of mineralization in the Goosly- Owen Lake area of central British Columbia is the result of a comprehensive geochemical study of rock samples obtained from a regional geological survey. The dispersion of metals in country rocks about a line of Tertiary intrusions suggests that these igneous bodies may be genetically related to known sulphide replacements, disseminations and vein deposits. The geochemical investigation is based on the determination of 12 elements from samples gathered from more than 800 scattered field stations. To assist processing and interpretation, the data are subjected to a variety of statistical procedures, including correlation of the elements, factor analysis, clustm• analysis and computer contouring of the elements. Some practical applications of rock geochemistry in regional exploration are indicated."

Jan 1, 1976

By Sheridan J. Rodgers

The quantity and behavior of gases in metal and nonmetal mines were monitored to provide background information on feasibility of incipient fire detection systems. Monitoring was conducted during working and nonworking periods at intake air, return air and working places. Gases generated during diesel operations and shot firing were of particular interest. Gases which were monitored were CU, C02, N0, N02 and S02: submicron particulate concentrations were monitored also. Commercially available instruments were used and included nondispersive infrared, electrochemical and chemiluminescent types. The ratios of the various gases generated during diesel operations and shot firing were similar to those expected from an incipient fire, with the exception of the C02/NOx ratio, which is sufficiently different to be considered for early fire warning. Samples taken near leaking bulkheads showed high C02 levels and low C0 levels, the reverse of anticipated behavior in coal mines.

Jan 1, 1976

By B. S. Ignasiak, Dennis Carson

"Laboratory study of the behaviour• of binary coal blends shows that coke strength is more closely dependent on the distribution of ""reactive"" oxygen in the parent coals than on their proximate, elemental or petrographic compositions, and it also appears possible to qualitatively predict coke strength from information about reactive oxygen. Proceeding from this recognition, experiments were carried out to test the possibility of preparing metallurgical cokes from binary blends in which non-caking hvb coal was substantially freed of reactive oxygen by prior heat t1•eatment under controlled conditions. The results indicate that such blends can yield surprisingly strong cokes and that coke strength may be amenable to further improvements by modifying the size distribution of the pre-heated component and the rate at which it is charred."

Jan 1, 1976

By B. J. Moore

This publication contains analyses and related source data for 234 natural gas samples from wells and pipelines in 21 States and 1 foreign country. All of the samples were obtained and analyzed during calendar year 1975 as a part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted in the United States by the Bureau of Mines since 1917. In late 1965, the survey was expanded to include foreign gasfields. The analyses published herein were made by mass spectrometer and n special helium analysis apparatus, which are described in Bureau of Mines Bulletins 4862 and 576.3 The results of the investigation of the occurrences of helium are published annually to make the information available as soon as possible to the gas industry and the public in general. Seventeen previous publications have presented the results of 10,831 gas analyses prior to 1975. The first 3, Bulletins 486,4 576,5 and 617,6 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960. The other 14

Jan 1, 1976

By H. D. Strain

Potash is a generic term used to describe a number of compounds containing the element potassium (K), which is one of the three major plant nutrients. Potash content of these compounds is commonly expressed as percentage potassium oxide (K20), and the market value of the products is usually dependent on contained K20. Most of the potash produced (approximately 95%) is used in agriculture as fertilizer. Potash products today are shipped by producing countries all over the world to meet the need for increased food production. WORLD POTASH RESERVES Apparent world potash reserves are shown in Table 15.2B.1 and total some 96 billion mt of recoverable potassium oxide. The Canadian reserves account for approximately one-half the known world reserves. The reserves shown represent the potassium oxide content of a variety of potash-bearing ores. The major ore is sylvinite (a mechanical mixture of KC1 and NaCl) from which KC1 or sylvite is recovered (63.2% K20 equivalent). Other ores, such as langbeinite (potassium, magnesium sulfate-22.7% K20) and carnallite (potassuim magnesuim chloride-17.0% K20) are also mined in various parts of the world, mainly for the potassium content. Theoretically, potassium is available in almost unlimited qualities from brines and saline waters. To date, the cost of recovery from salt brines has been greater than the costs by mining operations, but new technology could make brines and seawater an increasingly important source. POTASH PRODUCTION Potash production dates back to the 1860s in Germany, which was the only recorded producing country until 1912. By 1912 Germany was producing approximately 1 million tpy of K2O equivalent. Production began in France in 1913 and in the United States in 1915. World potash production and consumption are shown in Table 15.2B.2 for the years 1950-51 through 1967-68. In 1967 and 1968 the major potash-pro¬ducing countries in order of importance were those listed in Table 15.2B.3. By 1972 Canadian production had outstripped U.S. production. WORLD CONSUMPTION World consumption of potash for the years 1950-51 through 1967-68 is shown in Table 15.2B.2. Table 15.2B.4 shows total world consumption of potassium materials in 1967-68 by country. More than 70% of the world's potash is

Jan 1, 1976

By Thomas A. Phillips

The Bureau of dines present, an economic evaluation of its process for the ferric chloride leaching of chalcopyrite concentrate. In this process, chalcopyrite concentrate is leached with ferric chloride solution to extract copper, which is precipitated from the solution by electrolysis while leaving sulfur in the residue. Spent liquor from electrolysis is treated with oxygen to regenerate the ferric chloride leach solution and the sulfur-laden residue is processed to recover the sulfur. A cost estimate was prepared for a plant capable of processing 600 tons of chalcopyrite concentrate per day, 330 days per year. The fixed capital cost, on an early 1.975 basis is $27,831,600 and the estimated operating cost is 9.9 cents, per pound of copper product. In comparison, the estimated operating cost of a smelter equipped with a citrate process plant to recover sulfur is about 13.6 cents per pound of copper product. No charge for chalcopyrite concentrate or credit for recovered byproducts has been included in either operating cost. The ferric chloride leach process, therefore, appears to be economically attractive.

Jan 1, 1976

By Leonard P. Vitt

This report details the work done to provide the U.S. Bureau of Mines with a customized Wireless Ground Monitor Wireless Ground Monitor was modified as follows: 1. A voltage regulator was added to prevent false trips with line voltage variations. 2. A Ground Wire Trap was designed to eliminate problems with parallel paths and provide spark suppression. 3. A three phase filter was designed to reduce 60 Hz leakage current. 4. A portable tester was designed to permit complete test of installed systems. 5. The design was modified to insure trip with an open ground wire in the event of a failure of any one semi-conductor component.

Jan 1, 1976

By W. Jack Wilkes, Gilbert L. Butler

TRANSPORTATION TUNNELING The use of tunnels for transportation, namely rapid rail transit systems and highways is on the increase. How much that increase might be through the 1980's is the question that is discussed in this paper. In 1975, there were 218 route miles of subway tunnels for rapid rail transit and 154 lane-miles of highway tunnel. From the viewpoint of many transportation planners and designers, the tunnel is one of the tools which may be used to by-pass many types of obstacles: a mountain, a body of water, or a Central Business District (CBD). Therefore, the transportation tunnel is a rural as well as an urban solution with major emphasis on the latter because of the current transportation needs of our cities. In the case of rural locations, tunnels are usually constructed through mountains in order to eliminate miles of steep grades and dangerous curves, such as the Eisenhower Tunnel which cuts through the Continental Divide in Colorado along 1-70 and saves 10 miles and 40 minutes of driving time. Tunnels also provide an excellent transportation link across bodies of water in order not to interfere with shipping lanes. The Chesapeake Bay Tunnel and Bay Tubes of the BART system are excellent examples of this type of tunnel.

Jan 1, 1976