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By David H. Yee

Because of environmental concerns, the Bureau of Mines investigated an anhydrous chlorination process for the recovery of copper from chalcopyrite, Pelletized concentrate was reacted continuously with chlorine in a vertical shaft reactor at 550° to 750° C to extract copper-iron chlorides and elemental sulfur. The resulting molten metal chlorides drained from the reactor and collected in a receiver while sulfur distilled from the top and condensed in a separate unit. The tests were conducted in a 10-cm-diam reactor constructed of glass and in l5-cm-diam reactors constructed from various refractory materials. A high-alumina ramming mix exhibited the best resistance to molten metal chlorides and elemental sulfur in chlorine atmospheres. A reactor made with this high-alumina refractory was operated for 55 hr under actual chlorinating conditions without suffering any deterioration. Tests results show that more than 96 pct of the chalcopyrite was converted to copper-iron chlorides and elemental sulfur. Good separation of the metal chloride and sulfur products was achieved. After filtration, elemental sulfur of greater than 99 pct purity was obtained.

Jan 1, 1977

By L. A. Rapoport

This paper outlines the methodology and results pertaining to the simulation of the U.S. coal industry in the context of an integrated, time-dynamic model of Long-Range Energy Developments and Supplies (LORENDAS). By way of background we will present first an overview of the overall LORENDAS model structure. We will, then, outline the characteristics of the formulation and data used for the representation of the U.S. coal industry. Finally, a series of model results will be reviewed, with particular emphasis on the long term projections of coal production and distribution under different basic economic and/or political scenarios.

Jan 1, 1977

By David Schlain

The Bureau of Mines investigated methods for electrodepositing platinum-group metals from molten cyanide baths. The preparation of thick, protective coatings on molybdenum, Inconel, graphite, stainless steel, copper, and other structural metals were studied, as well as the electroforming of platinum and iridium crucibles. Iridium, rhodium, and ruthenium can be electrodeposited under an inert atmosphere, while platinum and palladium require the presence of air. Electrolytes may be prepared by direct-current electrolysis in NaCN or mixtures of NaCN and KCN using anodes of the particular platinum-group metal. When the concentration of metal increases to about 0.3 or 0.4 percent, the deposits become bright, adherent, and coherent. Current densities may be 10 to 25 ma/cm2, and plating rates are often 0.5 mil/hr. Platinum and palladium baths deteriorate because of the oxidation of cyanide to cyanate and carbonate, and the precipitation of metal. Changes in the platinum cyanide bath are relatively slow. The protection against oxidation afforded by the platinum-group metal coatings is evaluated by testing encapsulated specimens in a thermogravimetric balance. Surface pretreatment and the use of undercoats are discussed.

Jan 1, 1977

By Martin Hertzberg

The early and reliable detection of the self-heating of combustible substances in mines is of considerable importance to the mining community. This Bureau of Mines report describes the results of a variety of studies of incipient combustion and its detection. Heated samples of coal, wood, and various polymers were used to evaluate the relative sensitivities of several types of detectors. The laboratory results indicate that submicrometer particulate detection is the most universal and sensitive method. Carbon monoxide detection was as sensitive as submicrometer particulate detection for pyrolyzing coal but was relatively insensitive to pyrolyzing wood or plastics. The conventional type of ionization smoke detector was the least sensitive for coal and of intermediate sensitivity for wood and plastics. Self-heating experiments with Pittsburgh seam coal piles of varying particle sizes gave ignition temperatures of 170° C for 4-to 7-µm dust, which increased monotonically with particle size. The measured heating rates were compared with data from an adiabatic calorimeter to obtain preexponential rate constants. The preexponential rate constants varied linearly with the surface area per unit mass of sample as would be expected for heterogeneous surface oxidation. The propagation behavior of ignition waves and the overall self-heating appears to depend critically on the magnitude of the convective flows induced, which counteract the depletion of oxygen in the void spaces of the pile. Classical theories of thermal ignition require substantial modification to be applied reliably to such cases.

Jan 1, 1977

By E. F. Nelson

The 1970s have witnessed the completion and successful start-up of several new non-ferrous metallurgical operations in the Western Hemisphere which utilize large semi-autogenous mills in the grinding circuits. These facilities' are arranged either as single-stage circuits, or in a two-stage configuration n with ball mills. Another major concentrator, designed with an autogenous mill, ball mill, crusher (ABC circuit), is presently under construction and scheduled for start-up late this year. The large primary mills employed in these circuits have high diameter-to-length ratios and are designed to accept a very coarse feed, i.e., the product of a primary gyratory crusher, or run-of-mine ore. This characteristic obviates the need for a secondary-tertiary crushing plant or, in selected cases, even a primary crusher, which is a basic requirement in feed preparation for conventional grinding mills. This paper discusses three such grinding circuits and, presents operating data for two of them: the Island Copper Mine of Utah Mines, Ltd., near Port Hardy, British-Columbia,- and the Pueblo Viejo Cyanide Leach Plant of Rosario' Dominicana, S.A. on the island of Hispaniola. The design criteria for the Cyprus Bagdad Concentrator under construction' at Bagdad, Arizona, are also included. Data pertinent to these circuits are tabulated in the Summary.

Jan 1, 1977

By Osetzky D, Hesp W. R

The treatment of a hydrobiotite containing 0·64 per cent copper with various soluHons showed that a high percentage (up to 90 per cent) of the copper can be extracted under mild conditions (1 M BCI, 85°C) or withsaline solutions (20 per cent by weight NaCI or NH4F, 400°C). The latter results suggest that the copper is incorporated in the interstratified vermiculite of a vermicuHte-biotite mica and the solutions (NaCl and NH4F) which reacted with the vermiculite without attacking the biotite gave the highest extraction yields.In general, extraction yields with saline solutions increased with the temperature (between 100 and 400°C) and duration (3 or 6 days) of the treatment but were not appreciably affected by the initial pH of solutions.The results of RCI treatment especially may have a bearing on the hydrometallurgical treatment of refractory copper ores where copper is tied to gangue silicates.

Jan 1, 1977

By Young C. Kim

Introduction and Objective of This Paper Computerized open pit mine models* are more and more used today for feasi¬bility studies as well as for long range mine planning. In fact, using these models is becoming an enforced practice due to various reasons. One main reason is its capacity to evaluate several designs in a fraction of time required by manual effort. Another reason is the necessity to evaluate several. pit designs due to ever decreasing grade of the orebody and increasing financial risk due to smaller profitability margin. In spite of today's accepted use of computer models, very little guidelines are available which the average practitioner can follow either to choose or to build the type of model best suited for his need. Consequently, the objectives of this paper are: 1. To review the current state of the art in the computerized open pit mine models. 2. To provide some suggestions for model selection. 3. To share our experiences in developing a model for a highly irregular copper ore deposit (see Appendix).

Jan 1, 1977

By E. M. Cameron

Reconnaissance radiometric and geochemical data have been obtained for an area on the western shore of Wollaston Lake that includes the Rabbit Lake uranium deposit. The study area is extensively drift cover ed. The geochemical data were obtained by analysis of center-lake sediments and surface waters for a variety of elements and other constituents. The airborne radiometric data comprise measurements of eU, eTh and K obtained with a .50,000-cc NaI (Tl) detector at a mean terrain clearance of 120 m and 5-km flight-line spacing. Uranium in lake sediments and uranium in waters are the most effective geochemical indicators of uranium mineralization; the other elements measured are not notably anomalous. A sample site density of one per 1 8 km 2 is more than adequate for identification of the mineralized area. Because many water samples contain close to or below the current analytical detection limit of 0.05 ppb U, the use of sediments is generally favoured. for broad-scale reconnaissance in the region. Uranium in these lake sediments appears to be little influenced by variations in the organic or iron and manganese content. The most effective radiometric indicator of the mineralization is the eU/eTh ratio. This parameter is less influenced by environmental variation on the ground beneath the flight line than eU alone . The eTh/K ratio is anomalous under the Athabasca Formation unconformity where, in places, the uranium mineralization is localized.

Jan 1, 1977

By Donald R. Williamson

Statistical studies at Cyprus Pima Mine indicate that samples from 22 blastholes are necessary for determining average copper grades, within a desired range of precision, for mine-model blocks by arithmetic averaging. The average number of holes in such blocks is 14. Many considerations show that more holes will not be drilled for sampling. A way to determine block grades more reliably than by" arithmetic averaging was sought. Thus far arithmetic averaging has proven to be the best procedure for the particular operation characteristics despite the small number of samples. It naturally follows that expenditure of great effort in sampling blasthole cuttings is unwise.

Jan 1, 1977

By Roy A. White

The development of a fire and rot-resistant coating treatment for mine timbers, along with the associated processing technology, is described. Included are a literature search, laboratory studies of polyimide-fungicide coatings, and leaching and fungus growth studies on coated wood blocks. Finally, an economic analysis is performed tor various levels of production.

Jan 1, 1977

By Jack E. Fraley

In this Bureau of Mines study, sealants containing mineral wool, cement, etc, were sprayed through dry-process equipment that propels dry material pneumatically to the water-adding nozzle. Advantages over slurry applications include no mixing, no extensive cleanup, and freedom from hardened cement in equipment should power be lost. Sealants with large mineral wool nodules (>l-inch) were sprayable at rates to 900 square feet per hour for 1/2-inch thickness with little dust and smooth material flow through equipment, but they were weak for mine use, Materials containing small wool nodules (1/4-inch) were stronger but tended to plug lines because the nodules were inadequately separated in the shredder. Increasing the dedusting oil also increased line plugging by holding the nodules together in larger lumps. Best results were obtained using a 3/4-inch-nodule wool with cement binder, which provided both smooth flow through the machine and adequate strength.

Jan 1, 1977

By Walter W. Kaufman

This Bureau of Mines manual for design of surface mine haulage roads covers such aspects of haulage road design as road alinement (both vertical and horizontal), construction materials, cross slope, and drainage provisions. Traffic control and design of proper lane widths to promote safe vehicle movement are included, as are suggested criteria for road and vehicle maintenance and for runaway-vehicle safety provisions. The aim of this publication is to provide those involved with surface mine haulage road design with a complete manual of recommended practices that, if implemented, will promote safer, more efficient haulage routes.

Jan 1, 1977

By M. C. Irani

This Bureau of Mines report tabulates methane emissions from U.S. bituminous coal mines with daily emission rates of at least 100,000 cfd according to States, counties, and coalbeds. Most of the methane emitted is from mines in the Appalachian States. Total daily emission in 1975 was 216.3 MMcfd, compared with 227.0 MMcfd in 1971 and 214.5 MMcfd in 1973. Thirty counties in nine States hid daily methane emissions of 1 MMcfd or more. These emitted 93 percent of the total methane. The highest emissions were from Monongalia County, W. Va., which accounted for 18.9 percent of the total. This was followed by Marion County, W. Va., 9.6 percent; Buchanan County, Va., 8.3 percent; Jefferson County, Ala., 6.1 percent; and Washington County, Pa., 5.9 percent. The Pittsburgh coalbed emitted 45.7 percent of the total methane, followed by the Pocahontas No. 3 coalbed with 12.9 percent. The report lists 196 mines, of which 60 had daily methane emissions of 1 MMcfd or more. Included in this compilation are the identification and thickness of the coalbed, methane emission, coal production and ventilation rates, number of drifts, shafts, and slopes used for ventilation purposes, shaft depth, age of mine, and gas-to-coal ratio.

Jan 1, 1977

By Guillermo V. Borquez

The economics of open pit mine design are dictated by three basic elements: cut-off grade, stripping ratio and slope angle. Although these elements are functions of a number of independent parameters, they are interrelated through their influence on the overall economics. The optimum slope angle is the most uncertain element to determine, because rock mass properties are difficult to obtain. However, for preliminary estimation, the slope angle can be determined from the relationship between the probability of failure and the safety factor. The economics of the slope selected will depend on a profit versus risk judgment. In this paper, the author will present an actual case of application of this postulate.

Jan 1, 1977

By J. F. Snyder

Minor elements determined by atomic absorption spectroscopy include: zinc, cadmium, copper, cobalt, nickel, chromium, manganese, and iron. Of these elements, only three; zinc, cadmium, and copper are found to have been introduced with the ore-forming fluids. Iron, manganese, chromium, and nickel were increased in dolo-stone lithologies when compared to limestone lithologies. The uniform distribution of cobalt suggests this element was neither increased nor decreased during ore emplacement nor during dolomitization of the rocks. Zinc increases adjacent to ore result from leakages into open spaces rather than as pervasive aureoles surrounding ore bodies.

Jan 1, 1977

By I. R. M. Chaston

Abstract. This paper puts forward the concept of 'radial' plant layout where all crushing, milling and treatment operations are preferably concentrated in one central area and these separate stages are connected by radiating conveyors to and from outside storage areas. This system is contrasted to the more customary system of 'linear' plant layout where the crushing, milling and often the treatment operations follow one after the other in separate buildings. The radial system simplifies and improves contral and supervision to a very considerable extent and can lead to a form of continuous plant operation with the separate sectors shutting down in succession for necessary maintenance while maintaining the overall plant operation. The paper is illustrated with example: from past and recent diamond treatment plant practice in South Africa which demonstrate the reduction in plant labour achieved by this system. Previous objection to this type of layout on the grounds that it inhibited plant expansion are shown to be unwarranted. Radial Layout for Increased Treatment Plant Productivity A great deal of time and trouble is spent by highly qualified and experience( metallurgists in developing the right treatment process for a given ore. This process is then often expressed in a treatment flowsheet of the type shown in Fig. 1 which shows a typical diamond plant. This flowsheet, when completed, is commonly handed over to the mechanical engineers who then design the layout of the equipment indicated on the flowsheet and produce the working drawings upon which the detailed construction of the treatment plant will be based. It is an unfortunate fact that the tedious and time-consuming juggling of equipment and inter-plant transportation is often left to hard-working draughtsmen who, however capable' in their field, lack practical experience in the day-to-day operation and maintenance of the treatment plants they design. As a result many plants have been produced which, while they satisfy the requirements of the flowsheet with minimum capital requirements, cost far more than should be necessary to op¬erate and maintain. It is often possible to change individual items of equipment which do not achieve the performance required of them, but it is usually extremely expensive to change the basic layout of the plant if this should be found to be unsatisfactory. It should therefore be recognised that great care and attention should be spent on consideration of the basic layout of any treatment plant and that the views of both designers and operators should be fully regarded before settling upon the inevitable compromise dictated by the varying requirements of process-engineering and economics. It is unfortunate that this important subject receives such scant regard in the standard ore dressing text books and hand-books, being usually dismissed in a few paragraphs.

Jan 1, 1977

By D. A. Augenstein

Operators of coal preparation plants use equipment such as large-capacity dump trucks and bulldozers to haul, spread and compact refuse material to conform to federal and state regulations governing the disposal of solid waste. For example, federal regulations require that refuse be spread and compacted in layers not more than two feet thick. If the refuse layers or piles have poor load-bearing characteristics, movement of equipment over them becomes extremely difficult. The increasing cost and limited space for the construction of settling ponds extensively used for fine refuse disposal are leading to the growing practice of dewatering the fine refuse by means of vacuum disc filters and combining the resulting filter cake with coarse refuse for waste bank disposal. However, this filter cake usually contains more than 25% moisture. Therefore, when it is combined with coarse refuse, the moisture level of the total refuse may become high enough to impair the load-bearing strength of the refuse. Precisely this problem and the attendant difficulties of moving heavy equipment arose when vacuum disc filters were installed at a preparation plant in West Virginia. Combining the moist filter cake with the coarse refuse generally results in a 12% moisture level for the total refuse at this plant. At this moisture level, the refuse can still be handled with some difficulty by the equipment. However, the problem has frequently been compouned after rains.

Jan 1, 1977

By Gordon R. Sima

This contract is concerned with the construction of a Time Resolved Audio Dosimeter System consisting of one readout unit and several dosimeter units. The Time Resolved Audio Dosimeter System was designed and developed by the Bureau of Mines with the purpose of this contract aimed at obtaining additional units for further field testing and evaluation. All construction was in accordance with the Bureau of Mines design and/or Bureau approved drawings produced during the course of this contract. This report contains a summary of the construction efforts, problems encountered, recommendations and all drawings produced under this contract.

Jan 1, 1977

By Arne Landsberg

The Bureau of Mines measured the vapor pressure of FeC12 , FeBr2, FeI2, Sb, Bi, Cd, Mg, Pb, FeC13 , and VCl2 using the Knudsen-and torsion-effusion methods, and on FeC13 -NaC1 mixtures, Au2Cl6, and MgNi2 using only the Knudsen method. Apparent vapor pressures calculated from the experimental data vary with orifice size and method of determination. Reaction with residual oxygen in the instruments was noted to have an effect on the iron halide data. Vapor pressure curves plotted as log P versus 1/T (where P is pressure and T is absolute temperature) for one substance using several orifice sizes tended to converge at a single point when extrapolated beyond the experimental region. All of the data, except those of VC12, agree with previously published results. The importance of comparing effusion measurements with those obtained by other methods and the variations encountered with various orifice sizes are discussed.

Jan 1, 1977

It is a great honour to address our Institute as President, but the choice of a suitable subject was not an easy one. In the past when the presidential address was given at an annual conference the subject usually related to the conference or industry concerned; more recently the subjects have been more philosophical and this is a distinct advantage to me.I appreciate that I am addressing an informed audience and I am sure' that you are well advised in many of the points that I hope to leave with you. Unlike the specialist who gets to know more and more about less and less and eventually knows everything about nothing, I am one of the group who gets to know less and less about more and more and eventually knows nothing about everything.I hope you will appreciate this point whilst you are listening to me.In recent years I have been closely associated with the problem that troubles most governments of our time: the competition of many groups of differing backgrounds for the land that is available to the nation.This is of particular interest to the industry with which we are concerned as it is of critical importance to the discovery and development of future reserves of minerals and metals. Part of my daily task is involved with the administration of legislation for mining operations and the conditions under which such operations may be undertaken, in implementing government policies relating to mining, and in designing and administering legislationdirected to safety and health in mines.Most of our members are involved in exploration or in day-to-day problems associated with the production of minerals or the management of companies in these pursuits and would be aware of many of the conflicting viewpoints on priorities.F. F. Espie in his presidential address of 1975 'On being a minority', made the point that our Institute found that the mining industry had a great communication 'Problem with the Australian people.I believe that this is one of our major problems.

Jan 1, 1977