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This: symposium was sponsored by the Bureau of Mines, U.S. Department of the lnterior, in order to critically examine the state-of-the-art of sulfide flotation chemistry and to define current and emerging problems that should be emphasized in future fundamental research. The topics covered through invited papers include both reviews and recent research results in the areas of thermodynamics of reagent-mineral interactions; collector adsorption processes; the effects of solid-state point defects on flotation; activation and deactivation phenomena; the electrochemical role of oxygen in sulfide flotation; environmental problems in flotation; and selective flocculation of fines. Papers riving perspectives on flotation research in relationship to our national mineral requirements and the relationships between industrial flotation research and academics are also presented. An edited summary of the symposium follows the papers.

Jan 1, 1980

By Richard C. Moore

The U.S. Bureau of Mines contracted a study to estimate what effects the underground mining of thick coal seams in the western United Slates would have on the surrounding water resources. Potential coal fields in the western United States where this type of mining might occur were identified. The foreign literature was searched for studies of effects on hydrology from thick seam underground coal mining. Based on the limited information obtained from the foreign literature, estimates of the effects of this type of mining on the ground and surface water in the western states were made.

Jan 1, 1980

By Carl Fisher

A microseismic roof fall warning system was field tested in Western and Eastern coal mines in the United States to better define the capabilities and limitations of the microseismic method in predicting roof fall. Microseismic event and energy type data were obtained and documented for twenty-three coal mine roof falls, Field test results indicate that both the microseismic event and energy methods, as applied in this development effort, have a high probability for successful application in a commercially practical roof fall warning system. Based on the results and experience obtained during field testing, a commercial prototype microseismic roof fall warning system was designed and constructed. Although it was the intent of the program to field test the commercial prototype system, delays in equipment fabrication and contract time limitations did not permit field testing.

Jan 1, 1980

By K. T. Menzies

This report documents laboratory and in-mine analyses of diesel exhaust pollutants carried out to assess the fate of potentially reactive species in the mine environment. Specifically, the concentration of stable compounds including carbon monoxide and carbon dioxide, and potentially reactive compounds including nitric oxide, nitrogen dioxide, sulfur dioxide, aldehydes, formaldehyde, acrolein, formic acid, odorants, particulates, soluble sulfates, and polynuclear aromatic hydrocarbons were determined. The concentration and mass emission rates of these compounds were measured in the laboratory under three engine speed and load conditions and with three exhaust control conditions, i.e., none, catalyst, water conditioner. Once calibrated, the engine was installed in the Bureau of Mines Safety Research Coal Mine and the concentration of exhaust pollutants measured at several distances downstream (inby) of the engine. Laboratory results confirm the relatively small effect of exhaust control devices on most pollutants under engine conditions of low speed and load. At higher engine speed and load, the catalyst is more effective in controlling many pollutants. The in-mine data indicates that during residence times, which are typical for miner/exhaust contact, most diesel exhaust pollutants do not decrease in concentration. The obvious exceptions are nitrogen dioxide, sulfur dioxide and formaldehyde. The concentration of these pollutants is reduced by up to 75 percent in five minutes. The lack of increase in levels of obvious reaction products indicates that surface loss may be a major sink for these pollutants.

Jan 1, 1980

By J. J. de Barbadillo

This report describes a process for recovering chromium and other metals from superalloy scrap. Part I contains the results of laboratory scale experiments which were conducted to test a complex flowsheet utilizing a wide range of extractive metallurgical operations. The novel basis for the process is the formation of a sulfide matte in which chromium is concentrated in a discrete chromium sulfide phase. Mineral processing and hydrometallugical procedures are used to separate chromium sulfide from the other matte constituents. The products of the process are a chromium-nickel alloy suitable for reuse in the superalloy industry, electrolytic nickel, electrolytic cobalt, and an iron-molybdenum residue. Recovery of the principal elements contained in the scrap are chromium(Cr)-93 percent, nickel(Ni)-99 percent, cobalt(Co)-96 percent, molybdenum(Mo)-92 percent. Part II encompasses a preliminary engineering design of a pilot plant capable of treating 100 pounds(lb) of superalloy scrap per hour. Also included is an economic analysis of the operation of the pilot plant.

Jan 1, 1980

By Grant R. Brown

The report provides guidance for determining those environmental impacts associated with the surface mining of steeply pitching coal seams. In addition to the environmental impacts, four additional issues are addressed, namely (1) Time and motion studies of those coal mining systems employed in mining seams which pitch in excess of 250, (2) Assessment of those mining techniques, (3) Development of rationale for the mining methods employed, (4) Identification of the reclamation practices and determine whether these practices were in compliance with appropriate Federal and State regulations. Five surface mines located in three geologically distinct basins of the United States were analyzed during the period of August through November 1979. The three basins include the Hanna Basin of Wyoming, the North Park Basin of Colorado and the Southern Anthracite Field of Pennsylvania.

Jan 1, 1980

By W. A. Young

To initiate this project a critical evaluation of the pre-sent phosphate mining industry in the Western phosphate field was conducted. Mines were visited, mine operators were interviewed and pertinent literature studied. Three phosphate mining enterprises were reviewed and mining cost estimates prepared. The report discusses the present state of phosphate processing, rock alteration and location. New ideas and concepts are proposed to improve the recovery of phosphate rock from the Phosphoria formation. The report evaluates two variations to the present phosphate open pit mining methods, which were developed to improve the economics of mining phosphate and to better accomplish necessary reclamation and accelerate the time for environmental recovery. A material handling system using conveyor haulage will eliminate the need for trucks. Terrace haulback utilizes safety benches to haul and dispose of waste in the mined out pit. Ore will be removed from the pit via an inclined, cable-supported mobile conveyor.

Jan 1, 1980

By R. S. Nutter

The results of designing, constructing, and laboratory testing of a modular, distributed, microprocessor-based mine monitoring and control system are presented. A standard computer communications protocol (DDCMP) was utilized throughout the system. Tests were performed on the utilization of a high-level language for programming mine monitoring and control systems. Laboratory tests were run on a combined air velocity/methane sensor.

Jan 1, 1980

By Kenneth Wardell

Criteria have been fully developed for determining the optimum size of oil and gas well blocks. The criteria lead to the formation of well barrier pillars which are, of themselves, inherently stable and take account of variable mine roof and floor conditions. The criteria ensure, through considerations of ground movement, that strains transmitted to well casings, are within tolerable limits of casing specifications. The criteria cater for well barrier pillars in multi-seam mining situations and where previous old mining has taken place. The criteria maintain flexibility in being adaptable to local mine design situations. The criteria are applicable to proposed extraction thicknesses up to 15 feet at depths up to 2,400 feet. The criteria are related to producing wells and to abandoned wells. In the latter connection, various states of well abandonment are recognised.

Jan 1, 1980

By Philip K. Hopke

A systematic study of the mechanism of interaction of 218Po(RaA) armed by the decay of 222Rn with airborne particulate matter has been made. The rate of attachment of RaA to particles in the diameter range of 0.1 µm to 10.0 µm has been measured as a function of particle size, concentration, and composition, radon concentration, time of interaction, relative humidity and temperature. It was found that under the conditions in these experiments the attachment rate was proportional to the square of the particle diameter and varied with temperature and relative humidity. The composition of the particles apparently has no effect on the attachment. The variation in attachment rate was related to a sticking probability coefficient of approximately 0.02 that varies systematically with temperature and humidity. In addition, the rate of deposition of RaA on the wall of the attachment kinetics system was measured and also found to change with temperature and relative humidity.

Jan 1, 1980

By Virgil Marple

In the summer of 1979 the University of Minnesota Mobile Laboratory (UMML), designed for the analysis of airborne particles and gases was used to study fugitive dust from an open pit coal mine. The analysis consisted of determining the particle size distribution and concentration of dust from various mining operations, such as blasting, draglines, loading, roadways and bottom scrapers. For some operations the particles size distribution and concentrations were determined at varying distrances. Details of the dust concentration within the plumes as the plume passed the UMML were measured with an optical particle counter. For line sources, such as roadways this enabled the calculation of the particle flux at the sampling location. In addition to the standard instruments associated with the UMML, the applicability of some new instruments were investigated. These included a uniform deposit cascade impactor and a flux meter. Finally, a technique in identifying plume origins which utilized elemental X-ray flourescence analysis of filter samples was shown to be effective.

Jan 1, 1980

By David E. Siskind

The Bureau of Mines studied airblast from surface mining to assess its damage and annoyance potential, and to determine safe levels and appropriate measurement techniques. Research results obtained from direct measurements of airblast-produced structure responses, damage, and analysis of instrument characteristics were combined with studies of sonic booms and human response to transient overpressures. Safe levels of airblast were found to be 134 dBL (0.1 Hz), 133 dBL (2 Hz), 129 dBL (6 Hz), and 105 dB C-slow. These four air-blast levels and measurement methods are equivalent in terms of structure response, and anyone could be used as a safe-level criterion. Of the four methods, only the 0.1-Hz high-pass linear method accurately measures the total airblast energy present; however, the other three were found to adequately quantify the structure response and also represent techniques that are readily available to industry. Where a single airblast measuring system must he used, the 2-Hz linear peak response is the best overall compromise. The human response and annoyance problem from airblast is probably caused primarily by wall rattling and the resulting secondary noises. Although these will not entirely be precluded by the recommended levels, they are low enough to preclude damage to residential structures and any possible human injury over the long term.

Jan 1, 1980

By J. A. Kost

The objective of Contract J0295041 was to determine if the addition of a surfactant (wetting agent) to the water used for dust control in underground coal mines results in the reduction of airborne dust. Laboratory wettability tests, including the capillary rise test, a coal dust sinking test and zeta potential measurements, were used to select a coal seam/surfactant combination for in-mine testing. Four surfactants were selected for underground testing: Surfynol 465, Aerosol MA-80, DC-13, and Dustallay. The underground tests in the Lower Kittanning seam, Indiana County, PA, involved a Wilcox Mark 20 auger mining system, equipped with spray nozzles located on the cutting augers, Conflow venturi sprays, and a spray manifold. Respirable dust samples were provided by MSA Model G personal samplers and Simslin II instantaneous dust monitor; total airborne dust samples were provided by MSA Model G samplers with UNICO filter cassettes. Based on data obtained from 24 test periods surfactants, as compared to plain water, reduced the airborne respirable dust an average of 27 percent and total airborne dust an average of 36 percent.

Jan 1, 1980

This Bureau of Mines report reviews the information presented at the Sixth Mineral Waste Utilization Symposium cosponsored by the Bureau of Mines, U.S. Department of the Interior, and the IIT Research Institute. Environmental scientists and engineers from nine countries participated in the symposium, which was held May 2-3, 1978, at the Chicago campus of IIT Research Institute. The 56 papers presented on the reclamation and recycling of mining and mineral wastes, municipal solid waste, industrial wastes, and scrap metal are summarized herein.

Jan 1, 1980

By R. W. Watson

In January 1980, the Bureau of Mines initiated an experimental program to examine the fire and explosion hazards of one-hour self-contained self rescuers (SSRs). This action was prompted by a growing concern on the part of government and industrial safety officials over the potential hazards of these devices when deployed on a large scale in underground coal mines. Prior evaluation of the safety of these devices had been at best sporadic and usually limited to experimental models. The recent availability of preproduction models of a l-hour SSR fabricated by the Mine Safety Appliance Company* and a production model manufactured by Dragerwerk Ag Lubeck of the Federal Republic of Germany allowed for a more comprehensive and meaningful evaluation of their safety in underground coal mines. This report summarizes the results of a 5-month study of the potential hazards of these two items. During the course of the work, periodic progress reports were presented to officials of the Mine Safety and Health Administration and various mining organizations including the American Mining Congress, Bituminous Coal Operators of America. National Independent Coal Operators Association, and the United Mine Workers of America. The free exchange of ideas that occurred during these meetings had a significant impact on the direction of this study and a serious attempt was made to address all of the issues that were raised at these meetings. The authors are extremely grateful to the individuals that participated in defining the specific problems that could arise as a result of deploying the self-contained self rescuers in an underground coal mine environment.

Jan 1, 1980

By R. L. Rankin

The program objective was to conduct surveys of respirable dust concentrations in coal mining operations at locations outby the working face. The results of these surveys were directed toward 1. identifying outby dust sources, 2. evaluating the severity of the major dust sources, 3. establishing dust sampling frequency, 4. establishing dust sampler locations, and 5. assessing the? areas of influence of the dust sources. The study included dust sampling of only nonhigh risk personnel and areas at six dif-ferent mines. Thirteen continuous mining, four longwall and two conventional mining sections were sampled. The severity of outby respirable dust sources such as load points, runways, dump points, beltways, transfer points and main haulage operations were characterized and areas within the mine were ranked according to severity. Information on engineering controls was also acquired. Guidelines for implementing a dust sampling program are presented and include sampler locations, ventilation surveys, dust surveys, effects of shift-to-shift variations, and sampling frequency.

Jan 1, 1980

By Jose P. T. Agapito

Several underground coal mines currently operating in the Beckley District of West Virginia are experiencing serious roof and floor problems. A significant portion of the estimated two billion tons of coal resources may be lost as a result of these ground control problems. Preliminary studies by the Bureau of Mines indicated that these problems are due in part to a high horizontal stress field. During this contract study, a field program was conducted to quantify the horizontal in situ stress. A total of 14 overcoring sites (using the Bureau of Mines strain-relief overcoring technique) in five mines were drilled producing 53 data sets. Analysis of the data was done to provide in situ horizontal stresses for each of the five mine, and for the district as a whole. Stress data indicate horizontal stresses far in excess of that predicted by theory and in some cases, up to six times the estimated vertical stress. In addition to the field testing, a detailed computer modeling study was conducted using finite element and boundary integral (displacement discontinuity) methods. Verification of in situ stresses was obtained by the models and analysis of various development geometries, mining methods and remedial techniques were conducted. Recommendations for reducing ground control problems and future studies are presented.

Jan 1, 1980

By John H. Johnson

Diesel tailpipe CO, C02, NO, and N02 concentrations by the Emissions Measurement Apparatus (EMA) were found to compare satisfactorily with simultaneous concentrations by instruments in the MSHA engine certification laboratory in Bruceton, Pa. The EMA was then applied to the measurement of LHD vehicle diesel tailpipe gases and smoke opacity in the White Pine and Brushy Creek Mines. A general experimental approach was developed by which instruments could be compared for the measurement of diesel exhaust pollutant concentrations in the 1/2 to 5TLV range. The concentrations are changed by varying engine speed, dynamometer load, and the portion of the exhaust which enters the dilution tunnel. Dräger detector tube diluted exhaust CO, CO2, NO, and NO2 measurements were compared with simultaneously taken portable instrument measurements. Diesel exhaust interference inaccuracies were separated from inaccuracies due to detector tube calibration by comparing the instrument readings with both actual detector tube readings and detector tube readings corrected by recalibration of the detector tubes alongside NBS traceable calibration gases. The detector tubes' accuracy was found to be only slightly affected by diesel exhaust interferences and it was concluded that most measure within certification limits established by the National Institute for Occupational Safety and Health. The effects of 2 exhaust system configurations on the pollutant concentrations in a dead-end heading were studied. Both of the configurations exhausted the gases near the roof, directing them toward the crosscut, and both improved the stratification of the air in the heading, due to the bouyancy of the hot exhaust gases. One of the configurations was a pair of Fume Diluters which diluted the exhaust with air by a 10:1 ratio, and the second system was simply a pair of exhaust pipes, bent to direct the exhaust similarly to the fume dilutors. By redirecting the exhaust, the concentration of C02 measured on the LHD vehicle was reduced by as much as 507, in dead-end headings up to 200 ft long. The Fume Diluters showed no improvement over the simple redesign of the exhaust system.

Jan 1, 1980

By Wils L. Cooley

The report covers several aspects of mine safety ground systems, primarily for underground coal mines. The design of a combined ground fault-ground check monitoring system is presented. An analysis is made of grounding systems for dc shuttle cars. Complete resistance data and results of physical inspections of self-salting ground rods are presented. A detailed resistance and economic analysis is presented for the use of composite materials for building inexpensive and effective ground beds in high-resistivity areas. The desireability of penetrating the coal seam with a borehole safety ground is investigated. A report is made of a Mine Substation Grounding and Bonding Workshop.

Jan 1, 1980

By David Bendersky

This report covers a technical and economic investigation of old electrical power systems, equipment and practices being used in the metal/non-metal raining industry. The principal sources of information were the MSHA District offices, visits to representa¬tive mines and mills, equipment manufacturers and the literature. A list of 85 mines and mills, submitted by the MSHA Districts as candidates for this study, is given and their characteristics are analysed. The electrical power systems and practices at the 10 mines and 9 mills which were visited are described. The principal areas which do not conform to standard electrical practices are discussed with emphasis on the safety aspects of these practices. The costs to update electrical power systems and practices in metal/non-metal mines and mills are given. The principal findings of the study are summarized and recommendations are submitted.

Jan 1, 1980