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By L. O. Filipov, N. E. Menad, A. Geneyton

"Zeta potential of synthetic monazites presenting various compositions were measured to investigate the effect of the main lanthanides substitutions on electrophoretic mobility and resulting IEP. The measurements are performed in a CO2 depleted and enriched solutions showing both reduced influence of monazite chemistry and strong influence of ions resulting from the solubilization and dissociation of CO2. The influence of oleic acid on the electrophoretic mobility of those monazites was also investigated. The influence of pH on oleate adsorption was studied using a bubble/particle adhesion system. Adhesion strength measurements were performed on pure synthetic monazite-(Ce) and monazite-(La). An extensive thermodynamic model of monazite in water was developed to highlight correlations between lanthanides hydroxides/carbonates species concentrations in the bulk solution and oleate adsorption. Based on electrophoretic measurements, advanced thermodynamic consideration and adhesion measurements, further details of the oleate adsorption model on monazite surface were proposed.INTRODUCTION Electrophoretic and potentiometric data on monazite and, a fortiori, other rare earth semi-soluble salts such as bastnaesite are extremely erratic (Chelgani et al. 2015). The isoelectric points measured with electrophoretic mobility methods range from 4.7 to 6.5 although sporadic data indicates an IEP (isoelectric point) far from that range. Different explanations are proposed in the literature to explain the IEP variability notably the numerous chemical substitutions that frequently occurred within monazite crystal lattice (Chelgani et al. 2015). Based on lanthanides speciation diagram, several authors highlighted the influence of specific lanthanide species on the flotation performance of rare earth semi-soluble salts when carboxylate or hydroxamate collectors are used. Although lanthanides ions have a great affinity for carbonates groups (Kragten et Decnop-Weever 1987), lanthanide (hydrogen) carbonates were not implemented in speciation diagrams. In this work, an advanced thermodynamic model is proposed to highlight correlation between flotation performance and lanthanide species predominance but also concentrations. Qualitative measurement of the monazite surface hydrophobicity are performed through tests of adhesion of coarse monazite particles onto bubbles. Since flotation and microflotation technics are highly influenced by hydrodynamic parameters, this method was investigated to obtain a sharp contrast between appropriate and inappropriate pH conditions. This paper is to investigate 1) the effect of lanthanides substitution on monazite surface properties through zeta potential measurements, 2) the mechanism of adsorption of carboxylates on monazite surfaces and 3) the effect of CO2 on monazite surface properties and carboxylates adsorption."

Jan 1, 2018

By G. B. Abaka-Wood

"The versatility of froth flotation has made it vital in the beneficiation of rare earth elements (REE) minerals from either high or low grade ores of complex mineralogy. There has been a significant increase in the tonnage of rich iron oxide tailings obtained from extraction of primary commodities such as copper and gold in Australia, which have been identified to have very low grade rare earth oxides (REO) (= 1%). There is a vast knowledge gap in the upgrade of REO from such tailings. The aim of this research is to investigate the feasibility of the use of fatty acids for the upgrading of REO from selected iron-oxide rich tailings. Two forms of fatty acid collectors (oleic acid and sodium oleate) were employed in this investigation. Bench scale flotation tests were carried out using a Denver D-12 cell.The effects of pulp pH, fatty acid dosage, particle size distribution (-150 +75 µm, -75 +38 µm and -38 µm) and conventional depressants (sodium silicate and starch) dosage on flotation recovery of REO were investigated. A comparison of the flotation results indicated that sodium oleate was the more efficient fatty acid for REO flotation at all the pulp pH investigated. The flotation performance is demonstrated to be particle size-dependent. The results on the effect of depressants dosage indicated that both sodium silicate and starch were unselective in reducing the recovery of hematite (Fe2O3) and quartz (SiO2) with corresponding decrease in REO recovery. Generally, Fe2O3 and SiO2 formed substantial contents of the flotation concentrates obtained, both in the absence and presence of depressants, which indicates liberation is a major challenge in achieving selective REO upgrade and recovery.The flotation tests carried out on the iron-oxide rich tailings suggest the possibility of REO upgrade using fatty acids, although particle size distribution and minerals liberation are key limiting factors in achieving selective REO upgrade and recovery."

Jan 1, 2018

By T. R. Kostecki

"Instrumented rock bolts are effective tools for assessing the reinforcement and condition of immediate roofs; however, instrumentation can have relatively high costs, which can be justified by high reliability and repeatable and representative data measurements. The instrument’s durability and operational life are of great importance, along with accuracy, applicability, and usefulness. This paper develops reliability models for three instrumentation technologies used in slotted rebar, drawing data from studies at five underground coal mines. Three case studies demonstrate instrument applicability and usefulness. Finally, two types of instrumented rock bolts are used to determine the direction of bend and maximum bending strain. RÉSUMÉ Les boulons d’ancrage instrumentés sont des outils performants qui permettent d’évaluer la consolidation et la condition des toits immédiats. L’instrumentation peut cependant se révéler très onéreuse, des coûts qui se justifient par sa fiabilité élevée ainsi que par des mesures de données reproductibles et représentatives. La durabilité de l’instrument et sa durée de vie opérationnelle sont très importantes, de même que son exactitude, son applicabilité et son utilité. En s’appuyant sur des données issues d’études menées dans cinq mines de charbon souterraines, cet article développe des modèles de fiabilité pour trois technologies d’instrumentation utilisées pour des barres d’armature nervurées. Trois études de cas démontrent l’applicabilité de l’instrument et son utilité. Enfin, deux types de boulons d’ancrage instrumentés sont utilisés pour déterminer la direction de la flexion et la contrainte de flexion maximale.INTRODUCTION Using instrumented rock bolts to monitor strain changes in a rock bolt array allows engineers to understand the per-formance and effectiveness of the rock reinforcement system and the response of the rock mass to such support; however, instrumentation remains a niche solution for solving complex ground-control problems—particularly for underground coal mines, which is where they are needed most. From 2000 to 2016, fall-of-ground fatalities still accounted for an average of approximately 30% of the total annual underground coal mine fatalities in the United States alone (United States Department of Labor, 2018). These tools would also be useful for deep hard-rock mining conditions. The main reasons for the lack of widespread use are not only cost but also accuracy, applicability, implementation procedures, intrinsic permissibility, and reliability (Peng, 2015). As a result, measurements of coal mine roof behaviour using instrumented rock bolts are quite scarce, not widely published, or inadequately presented to provide a seamless understanding of a roof’s response to support."

Jan 1, 2018

By S. Tafazoli, D. Cooper, I. Bell, S. Nouranian, B. Sameti, M. Ramezani

"Image-based rock fragmentation sensing in mines and quarries includes an important rock boundary delineation step, commonly referred to as rock segmentation. This paper presents an artificial intelligence-based solution to this challenge. The proposed technique encodes prior knowledge of previously analyzed images into mathematical/statistical models. Human-labeled images are used as inputs to train neural networks through an optimization process. The networks can then be used in real time for rock delineation. To build the models, special deep artificial neural networks are used as a pixel classifier. The proposed classifier labels each pixel (edge, rock or fine) by analyzing a plurality of pixels within the image. Advances in machine learning allow the network to contain many parameters. The increased number of parameters is a strong factor in the classifier’s ability to correctly classify each pixel. Deep learning-based segmentation, combined with 3D imaging followed by post processing, provides a unified fragmentation sensing solution. Results from automatic segmentation are compared to human labeled segmentation using the percentage passing curves for 64 rock images. INTRODUCTION Mines and quarries can see significant productivity and performance benefits by controlling material sizes (McKee, Chitmobo, & Morrell, 1995; Sellers & Gumede, 2012). During the past decade, image-based fragmentation analysis has been applied to estimate rock size distributions in order to optimize procedures in mines and quarries. Using a roving camera and operator assisted analysis Maerz, Franklin, and Coursen (1987) measured the size distribution of the blasted rock and eliminated the need for manual sieve analysis. Since then, many others have introduced automated and manual methods for fragmentation analysis and improved upon existing approaches (Girdner, Kemeny, Srikant, & McGill, 1996; Smith & Kemeny, 1993; Palangio, Palangio, & Maerz, 2005; Tafazoli & Ziraknejad, 2009; Raina, 2013). In image-based fragmentation, rock boundaries are identified in the image, and an image scaling is applied to transform rock pixel sizes into real world dimensions. Usually geometric references, such as regularly shaped objects (discs and basketballs) (Siddigui, Ali Shah, & Behan, 2009), or the known size of an excavator bucket (Zeng, Chow, Baumann, & Tafazoli, 2012), are used to determine the proper scaling factor. In recent years, 3D imaging and sensing have also been incorporated to improve rock delineation. Specific methods include using camera-laser combinations and stereo imaging to measure rock fragmentation on conveyor belts (Noy, 2013; Thurley, 2013; Dislaire, Illing, Laurent, & Pirard, 2013) as well as portable fragmentation analysis devices with 3D imaging sensors (Sameti, et al., 2014)."

Jan 1, 2018

By M. Unesi, S. Haj Mohammadi, M. R. Abdoli, M. R. Garmsiri

"Hydrocyclone-thickener circuit is a promising solution to enhance the dewatering efficiency in mineral industries. The challenges in the circuit is reducing particle size in the thickener feed and the good feature is a rise in the retention time of sediments in the thickener. In this work, the effect of particle size, bed depth and residence time on the thickener performance were investigated. In this order, pilot scale columns were employed at Sarcheshmeh and Shahrebabak copper complexes. Furthermore, the influence of residence time was differentiated due to the variations in the bed depth and settling flux. Moreover, a new approach was introduced to estimate solids residence time in the thickener. results indicated that with smaller particles that are introduced to the column, the bed density as well as thickener discharge solids concentration dropped significantly. It was found that thickener discharge solids concentration fell from 59.6 to 33.8 % with reducing particle size from 130 to 22 µm in the settling flux of 20 t/m2/day. Additionally, it was found that longer residence time and deeper bed resulted in an increase in the thickener performance while the bed depth has a stronger effect. It was proved that employing a hydrocyclone prior to the thickener resuted in an increase in the dewatering efficiency.INTRODUCTION Thickeners are widely employed in mineral industries to recycle tailings and concentrate water content. A limited fraction of suspension water content is recycled using a thickener. For instance, about 50 percent of tailings water content could be recycled using a shallow bed thickener during copper processing. Since the scarcity of global water resources became more serious, the demand for improving dewatering efficiency in mineral industries became more significant [1]. A number of solutions were recommended to enhance dewatering efficiency of thickeners including optimization of current thickeners, employing deep bed thickeners and utilizing thickener-filter or hydrocyclone-thickener circuits. Optimization of existing thickeners is essential, however, it does not meet the significant demand for recycled water. The application of deep bed thickeners (known as paste thickeners) has been rising in the mineral industries [2] due to a higher dewatering efficiency while its costs is remarkable."

Jan 1, 2018

By H. R. Manouchehri

"In all electrical beneficiation methods, the difference in electro-physical properties of the contributed mineral particles, essentially frictional charge, electrical conductivity and dielectric constant properties are exploited to achieve separation. The composition of the raw material determines what kind of either corona charging, conductive induction, or triboelectric separation method should be employed. The process is versatile and is influenced by different parameters related to mineral characteristics, surrounding ambient conditions and electrical and mechanical attributions of the separating device. Electrical separation is surface based beneficiation method which is mainly affected by the surface and surface changes of the minerals. Therefore, it is essential to understand how the electrophysical properties of the minerals can be changed/modified. During electrical/electrostatic separation process, both charge magnitude and its polarity that developed on the particles and therefore, their electrical beneficiation potential is essentially defined by surface phenomena. Therefore, it is essential to understand how the main electro-physical parameters can be changed/modified with applied surface treatment/pretreatment methods to promote separation. Surface treatment of minerals is carried out by different means, including chemical conditioning, irradiation, thermal treatment, etc. This paper discusses and analyze the electrical separation process, electrophysical properties of the minerals with special focus on the effect of surface pretreatment/treatment methods to affect electrical beneficiation potential of the minerals. The surface treatment methods vary in a wide range from simple surface cleaning to more complicated chemical conditioning and doping. The knowledge of the solid-state physics and chemistry leads to improve the beneficiation potential of different mineral systems by choosing suitable treatment method(s). Despite the complexity and multiplicity of the charging mechanisms, difficulties in separating fines it seems to be beneficial make our attempts to further investigate and develop the process as dry, low cost beneficiation process, especially nowadays when environmental concerns, as well as energy and water consumptions are main concerns for mining industry."

Jan 1, 2018

By Wayne Rogers, Kell Monro, Arthur Pacunana

The Phu Kham Copper-Gold Operation (PKM) is a large-scale open pit mine located in northern Laos. It was developed and is operated by Phu Bia Mining Limited (PBM) a Lao-registered subsidiary company of Australian incorporated, PanAust Limited. Production commenced at Phu Kham in 2008. Since the second half of 2016, there has been a significant increase in ore hardness and this has negatively impacted the PKM concentrator and resulted in lower SAG mill throughput rates. Over the remaining life of mine, the changing ore body and increase in ore hardness is forecast to continue as the pit deepens and the availability of softer blending ores reduce. To manage this risk, PKM initiated a Hard Ores Management Program to determine the most effective way to improve the mill throughput of harder ores. This involved conducting a number of innovative and process control driven blasting trials to optimize run-of-mine (ROM) fragmentation and other blasting outcomes. From 2016 to 2017, the performance of high powder factor blasting, electronic detonators and fast timing, high velocity of detonation (VOD) explosives, double-priming, and deck blasting, were individually and systematically assessed. The success of each blasting trial was then based on a ‘value for money’ criteria. This criteria is a cost / benefit analysis that weighed-up the additional cost to implement the trial against the measured improvement in mill throughput. Electronic and high VOD 90:10 emulsion:ANFO blasts were determined to have the best value for money, achieving an increase in mill throughput of 54% compared to baseline. This paper discusses how the implementation of an innovative and process control driven blasting trial methodology was able to successfully manage the hard ore challenges at PKM. In addition, this success was achieved without any major cost implications, safety incidents or process plant set-backs.

Jan 1, 2018

By S. Cagirici, Z. Öztürk, A. Hassanzadeh

Many flotation kinetics models have been studied in the literature. Their applicability was extensively investigated and argued in detail. However, model selection criteria were not adequately discussed from the statistical points of view. In this investigation, the kinetic behavior of a complex copper sulfide ore was studied in a mechanical Denver flotation cell focusing on flotation kinetics of chalcopyrite, pyrite and molybdenite. Different flotation kinetics models including nine common empirical models and four mathematical models namely Hill, Chapman (Sigmodial function), single rectangular (Hyperbola equation) and exponential were applied to the experimental data. In addition to assessment of the goodness of fit criterion for each model, a factor of model complexity was considered using information criteria (IC) (i.e. Bayesian information (BIC), low of iterated logarithm (LILC) and Akaike information (AIC) indices). The obtained results showed that the IC indices could simply manifest the best-fitted model to the experimental data. Whereas, the coefficient of determination values (R2) were relatively same for all models. By taking the R2 and model complexity criteria into account, the exponential model was chosen as the best representative mathematical model to demonstrate chalcopyrite kinetic behavior. However, Chapman model was selected as the best one for the flotation of pyrite and molybdenite. In case of the common first-order flotation kinetics models, fast and slow flotation kinetic model (Kelsall) was reasonably fitted the best to the given data of chalcopyrite. However, the gas/solid kinetics adsorption model was chosen as the best-fitted one for pyrite and molybdenite. Furthermore, it was found that mathematical models represent better results in association with flotation kinetic behavior of chalcopyrite, pyrite and molybdenite due to the consideration of more parameters in modeling. Finally, it was concluded that the IC indices must be applied to the process of model selection due to consideration of goodness of fit, complexity of a model and model consistency.

Jan 1, 2018

By Dianyin Liang, Hongxiang Ran, Xiaoming Wang, Xiaoou Xia

"This paper presents a new magnetic separator, which can be applied to increase the grade of fine magnetite ore feeding of ball mill. This innovative equipment possesses a rotating magnetic system and has a magnetic field of rapid polarity change which can strengthen the destruction of magnetic agglomerations and the dispersion of minerals to improve the quality of separation. Now this type separators have been successfully applied in several large concentrating plants such as Shuichang Iron Mine under Shouang Mining Company in China. Finally, this paper outlines practical results focused on feed grade and tailing yield, the results are showing that the quality of feeding can be improve tremendously. Hence, a new generator of rotating magnetic field has been paved. INTRODUCTION Jidong region in China is the important origin of iron ore, the characteristics of the iron ore in this region is low grade and complex, the iron mine discharges fine powder tailings reaches tens of millions of tons each year, in the wind action easy to form sand, this poses a threat to the atmosphere environment of Beijing. In order to reduce the mixing of large amount of useless ore and reduce the energy consumption of mill operation, a high efficiency pregrinding equipment is needed. Rotating magnetic field separator (RMS) is an advanced equipment, the main advantage of RMS is the significant reduction in particle entrapment and can easily break magnetic agglomeration. This reduction is so significant that RMS is capable of operating very close to theoritical limit for separator precision and can increace efficiency in selection process.Some expenrimental work on dry rotating magnetic field separation has been carried out in July 1998 in the company Ka Pty Ltd, then in 2008 BGRIMM developed industrial separation XCTG0816 in Shandong province . The wet RMS was researched in1960s in Former Soviet Union and the first industrial equipment was developed by BGRIMM in 1970s,then in 1990s wet RMS was applied in Ansteel group corporation. In 2017,6 units large wet RMS (SXCT1230)which were the largest RMS was applied in Sichuan province. No matter wet RMS and dry RMS, although they are used in differenct applications, they have some common research.in addition ,they all have good use effect."

Jan 1, 2018

By Baogui Yang, Jie Yang, Anthony Iannacchione

"The cemented coal gangue-fly ash backfill technique (CGFB) has commonly been used to control subsidence damage caused by underground coal mining. This paper discusses the CGFB backfilling process used at the Xin-Yang coal mine, Shanxi Province, China. A general description of the components of the CGFB are provided. The reaction of the strata to the backfilling process is simulated with a scaled physical model based on the Xin-Yang conditions and verified with subsidence points on the surface. With the help of the cemented filling materials, the CGFB produces only a slight bend to the overburden roof strata over the longwall panel. Physical models were constructed at the China University of Mining and Technology, Beijing, to simulate actual conditions. The modeling results show minor fracture distribution in the overlying strata and lower abutment pressure development within the backfilling area. The effectiveness of the CGFB technique is verified by a reduction in the vertical surface subsidence measured above the backfilled area.INTRODUCTIONUnderground longwall mining is the most efficient underground means to recover coal resources and is used widely in China, the US, Australia, and Europe. However, this type of mining has introduced some serious environmental impacts. Perhaps the most significant environmental issues are the surface and groundwater impacts associated with the formation of the subsidence basin (Bell and Donnelly, 2006). Backfill technology has been used for years to mitigate subsidence impact. Simply speaking, the backfilling technique places filling materials into the void left from the extraction of coal. When this material is placed within the gob, it is capable of partially supporting the overburden until a new equilibrium is reached. Essentially, the backfill material inhibits crack development and expansion caused by the strata movement and mitigates damaging ground deformations.The cemented gangue-fly ash backfill (CGFB) is one type of novel backfill technology, consisting of cement, coal gangue, fly ash, water, and additives in varying concentrations. The CGFB is mixed on the surface, pumped underground through a pipeline as a slurry, and placed in the void behind the longwall shield under the protection of specially designed hydraulic supports."

Jan 1, 2018

By D. R. Willmer, E. J. Haas

"DISCLAIMER The findings and conclusions in this paper are those of the authors and do not necessarily represent the views of the National Institute for Occupational Safety and Health. Reference to specific brand names does not imply endorsement by the National Institute for Occupational Safety and Health. ABSTRACT This study analyzed the publicly available health and safety policies of 26 mining companies to determine the quantity of health and safety (H&S) practices that mining companies encourage in relation to the Plan-Do-Check-Act cycle. A thematic content analysis of the policies identified elements and practices within the text. On average, companies communicated information on about 7 elements (range 1–14, standard deviation = 3.49) and discussed 15 practices (range 2–34, standard deviation = 9.13). The elements in which companies highlighted the most practices were risk management, emergency management, leadership development, and occupational health. A discussion of the policy trends shows areas that mine sites can improve upon within their Plan-Do-Check-Act cycle, in addition to encouraging the use of both leading and lagging indicators to manage health and safety performance. INTRODUCTION Mining companies and their employees are expected to identify and manage risks at their worksites to ensure the health and safety (H&S) of everyone at the site. The primary mechanism in place to control these risks is a company’s health and safety management system (HSMS) (Boyle, 2012). Broadly, an HSMS is a set of standard, interrelated, and interacting elements used to promote and achieve occupational H&S goals (ANSI/AIHA Z-10, 2012; BS OHSAS 18001, 2007). The practices conveyed within an HSMS are expected to minimize incidents, injuries, illnesses, and even save worker lives (Alsop and LeCouteur, 1999; Arocena and Núñez, 2010). In the United States, both the Occupational Safety and Health Administration (OSHA) and Mine Safety and Health Administration (MSHA) regulate and encourage aspects of an HSMS (US Federal Register, 2011, 2010). Many HSMS documents (i.e., Chemical Industries Association, 1995; Health and Safety Executive [HSE], 1995; International Labour Office [ILO], 2001) attribute the source of their basic management system to Deming’s Plan-Do-Check-Act (PDCA) model of continuous quality improvement and organize their practices within this cycle (Johnson, 2002). The PDCA cycle is a well-adopted approach in health and safety management and promotes continuous learning and adaptability (Robson et al., 2007)."

Jan 1, 2018

By Mike Cammack, Logan Huppert, Gustavo Azpilcueta

During the summer of 2015, Unisea Inc. sought proposals for the G1 Dock Replacement Project in Dutch Harbor, Alaska. It would be a one year project and construction was scheduled to begin in the spring of 2016. One aspect of the project was the requirement for a layer of armor stone to protect part of the dock. An estimated 30,500 tonnes (37,670 t) of armor stone were needed for the project. The source of rock was the Unisea Quarry due to its proximity to the project and the quality of the stone meeting all the required technical standards.

Jan 1, 2018

By U. Dmitrakova, G. Sedelnikova, D. Kim, E. Savari

"The paper presents the results of research on the development of gold and silver extraction technology from refractory gold sulphide flotation concentrate of one deposits of Nord-East of Russia. The concentrate is due to the complex mineral composition. Gold and silver are finely disseminated in sulphide minerals (arsenopyrite and pyrite partially oxidized by 7-11%). These are characterized by high content of silver 219 g/t and sulphide sulfur 32%, the presence of poorly soluble silver minerals (silver sulfosalts, fahlore, finely dispersed hypergenic acanthite in iron hydroxides and jarosite, etc.), and impurity minerals capable of interacting with cyanide (pyrrhotite, marcasite, nonferrous sulphides) and causing higher than normal cyanide consumption. Pretreatment of refractory sulphide concentrate by biooxidation using a mixed association of mesophilic and moderately thermophilic bacteria at a temperature of 36-40 °C for 120 hours oxidized arsenopyrite by 97.5%, pyrite by 93.5%, unlocked refractory gold, and generally oxidized the minerals absorbing cyanide and oxygen before cyanidation. Further oxidation of these minerals-absorbents was facilitated by the aeration in calcareous medium of the solid biooxidation residues of the concentrate. Sorption cyanidation of the solid biooxidation residues with addition of lead (II) of recovered 91.2% of gold and 82.9% silver from biooxidation residue, compared with 80.1% and 46.6%, respectively, for sorption cyanidation without the preceding biooxidation step. Biooxidation of the concentrate prior to cyanidation improves the recovery of precious metals, especially silver, and significantly reduces cyanide consumption from 18.7 kg/t to 3-5 kg/t of concentrate. INTRODUCTION Biooxidation of gold sulphide concentrates using acidophilic microorganisms has been successfully applied worldwide (van Aswegen et al., 2007; Gericke et al., 2009; Sovmen et al., 2007; Sovmen et al., 2009). At least 15 full-scale plants for tank biooxidation of sulphide concentrates are presently in operation, and the construction of new ones is planned (Bulaev et al, 2015)."

Jan 1, 2018

By K. Awuah-Offei, A. U. Rehman

"Information diffusion potential of a social media user affects how quickly information about a mineral project can diffuse through that user. If management can use social media and network analysis, in community engagement program, to understand how fast and how far information will diffuse to communities and followers of particular social media users, it can selectively focus on the most influential users. This paper proposes a method to examine the information diffusion potential of social media accounts. The work uses Gephi, an open source software, to extract and analyze data from different Twitter handles to predict their information diffusion potential. The work uses case studies of real Twitter users (e.g. mining news organizations and bloggers) associated with mining to illustrate the approach. The case study results show that there are significant disparities in information diffusion potential that will demand selective attention. This research will help mines develop effective social media engagement strategies. INTRODUCTION The mineral industry provides raw material for industrial activity to support our society (Martens and Rattmann, 2001). Mines have changed conventional mining practices to sustainable ones because of the negative impacts of mining and increased public awareness (Wang et al 2016). The concept of sustainable mining is getting mature as stakeholders (e.g., governments, investors and host communities) are getting involved in mining projects (World Economic Forum, 2014). The failure of mining companies to address the demands of these stakeholders might result in failure to acquire social license to operate (Thomson and Boutilier, 2011). The social license to operate (SLO), if granted, is mutually beneficial to all stakeholders. Mines prefer being granted SLO and keeping it to avoid any kind of social unrest due to their operation (Prno, 2013; Moffat and Zhang, 2014). Mining communities can grant different levels of SLO; ranging from withholding SLO to psychologically identifying with the project (Joyce and Thomson, 2000; Thomsan and Boutilier, 2011). Most of the previous work to understand community perceptions and SLO in mining is generally qualitative (ICMM, 2012a; Thomson and Boutilier, 2011; Prno, 2013; Moffat and Zhang, 2014; IFC, 2014). In particular, there is limited work on how community perceptions change over time due to information diffusion (Boateng and Awuah-Offei, 2017). However, SLO changes with respect to time (Yates and Horvath, 2013), which can result in risks that are not easy to predict. Mine managers and engineers have a desire to understand these changes so as to mitigate these risks (Que and Awuah-Offei, 2014; Que et al., 2015)."

Jan 1, 2018

By K. Amano, K. Haga, Y. Watanabe, A. Shibayama, A. Batnasan, A. Battsengel

"Apatite is an important host mineral in igneous and metamorphic rocks for production of phosphate fertilizers and phosphoric acid, and a potential source of rare earth elements (REE) production. For dissolution of REEs, sulfuric acid is better leaching reagent to develop the economical viable process for recovering of rare earth elements from apatite ore. However, the efficiency of rare earth elements dissolution in H2SO4 is about 30 % due to the formation of calcium phosphate or calcium sulfate as precipitate. On the other hands, phosphorus is mainly produced from phosphate ore. However, when treating rare earth elements containing phosphate ore, rare earth elements were discharged. Hence, development of novel apatite ore treatment process is required for effective utilization of natural resources. In this study, apatite deposit associated with REE was treated with sulfuric acid leaching and two stage precipitation by oxalic acid (C2H2O4) and magnesium chloride (MgCl2) for recovering REE and phosphorus, individually. Results showed that it can be seen the vast majority of La (87.5%), Ce (87.3 %), Pr (86.1 %), Nd (85.2 %) and Y (90.9 %) were dissolved in 1 mol/L diluted H2SO4 solution from the apatite ore. As average leaching rate of REE, over 85% of REE were leached by the condition. In the first stage precipitation using the obtained pregnant leach solution from leaching, over 90% of REE was precipitated by oxalic acid addition after controlling pH to 1 by NH4OH solution. After pH changed to 8.5, over 90% of phosphorus was recovered as precipitate by magnesium chloride addition in second stage precipitation"

Jan 1, 2018

By Fedotov. K. V., A. Y. Senchenko, V. A. Chanturiya

"The paper describes an efficient process to treat the ore from the largest in Russia copper deposit – Udokan. The recommended process is universally applicable to Udokan ores different in composition and allows reaching high copper recoveries during production of high-grade cathode copper and sulphide concentrate with 45% copper content. There are several promising trends for the process optimization and in the case they are implemented, economics of the whole project could improve significantly. One of the most important optimization options implies reduction of specific energy consumption in the course of comminution operations. Another possible option to optimize the already selected process flowsheet is production of cathode copper from sulphide concentrate directly at a mining and metallurgical plant without sending the latter to other metallurgical works.INTRODUCTIONUdokan copper deposit with resources of more than 20 million tons of copper is the largest in Russia and one of the largest copper deposits in the world. The deposit is located in Kalar District of the Trans-Baikal Territory, 30 km away from Novaya Chara railway station of the Baikal-Amur Mainline.Scientists and engineers from various research institutions have studied Udokan copper ores for years. Along the way, some conceptual process flowsheets have been proposed and each of them has its own pros and cons. The key requirement to the processes being developed was their universal application for processing of all the ore types using a single flowsheet. Due to the hard mining and geological conditions and because of complex material composition of Udokan ores it is of great difficulty to design a process which would provide for maximum economic benefits. That is why the process optimization has been ongoing until now.According to the Russian standards, the main input document for design of a metallurgical plant is referred to as a Process Design Report that covers the following key data sections: analysis of metallurgical testing results, validation of the process, design criteria, process flow diagrams, the mass and metallurgical balances, process description, equipment list and other information necessary for the subsequent design."

Jan 1, 2018

By Sun Chuanyao, Cao Fei, Sun Desi, Zhou Dezhi

"The research applies the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Density functional theory (DFT) was applied to investigate the electronic properties of O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) and O-isopropyl-N-ethyl thionocarbamate (Z-200). The calculation results show that both the energy of highest occupied molecular orbital (EHOMO) and the lowest unoccupied molecular orbital (ELUMO) of IP-BIAN are smaller than that of Z-200, electronegativity of IP-BIAN is higher than that of Z-200. According to the Klopman’s generalized perturbation theory, the collecting power of the two compounds is predicted to be Z-200 > IP-BIAN, the selectivity of IP-BIAN is better than that of Z-200. Then the thionocarbamate molecular is synthesized, and the compounds are characterized by nuclear magnetic resonance (NMR). It turns out that the test result identifies the prediction after the flotation verified test of pure mineral and actual mineral. The results demonstrate that the EHOMO and ELUMO are smaller in the thionocarbamate after a nitrogen atom is bound to benzyl, the thionocarbamate has strong selectivity and low collecting power. The lower the LUMO energy of thionocarbamate is, the stronger the back donation covalent p-bond between collectors and chalcopyrite is, thus improving flotation power for chalcopyrite and selectivity against pyrite. The result proves the feasibility of design and synthesis of the novel thionocarbamate through the frontier orbital properties of the collectors.1. INTRODUCTION Thiocarbamate is a kind of nonionic polar collector and is now widely used as flotation collector for copper-sulphur separation. The flotation power of thiocarbamate to chalcopyrite is stronger than pyrite, so it has high selectivity against pyrite. The frontier orbital theory and density functional theory (DFT) has been widely applied to study the structure-activity relationship of flotation collectors [1-6]. The flotation test results can be interpreted by using the reaction energy criteria and quantum-chemical parameters, such as the energy of the highest occupied molecular orbital (EHOMO) and the energy of the lowest unoccupied molecular orbital (ELUMO) of collector [7-11]. In turn, there are rarely reports about screening the novel flotation collector, by the frontier orbital properties such as HOMO and LUMO of flotation collectors. In this thesis, we apply the density functional theory and molecule design technology to design and synthesize the novel flotation collectors for copper-sulphur separation. Based on the previous findings of the structure-activity relationship of xanthogen formats [12], it has stronger collecting ability to chalcopyrite while the xanthogen formats after a nitrogen atom is bound to benzyl. Thus, in this study, a novel thionocarbamate molecule O-isopropyl-N-benzyl thionocarbamate (IP-BIAN) will be constructed, when the group structure connected with N atom in the known collector O-isopropyl-N-ethyl thionocarbamate (Z-200) is replaced with ethyl by propyl. The collectors (IP-BIAN and Z-200) have been calculated by DFT methods in quantum chemistry. By analyzing the reaction energy criteria and the frontier orbital properties (HOMO and LUMO), this research predicts flotation performance of novel collectors (IP-BIAN), then the synthetic experiments and flotation verified tests are conducted. The research provides a new theory reference for screening out the high-effective flotation collectors of copper-sulphur separation. This technology adoption will contribute to the sustainable development of mineral resources as it shortens the research cycle of new collector molecules and reduces the investment."

Jan 1, 2018

By A. Y. Senchenko, Y. V. Kulikov

"The most common technique for selection of grinding equipment is the Bond method implying determination of a ball mill work index (BWi). The method is perfect for greenfield projects where a ball mill must be sized to grind an ore to 80% passing 75-100 µm. Finer grinding will require application of specific correction factors to a standard equation since initially the method was not designated for sizing of fine (minus 75 µm) grinding mills. Significant issues are related to selection of grinding equipment for treatment of originally fine materials when the standard procedure is not applicable. In 1984, Levin published his special technique titled as “A proposed test for the determination of the grindability of fine materials”, where he offered to use the standard Bond ball mill for determination of a specific grinding energy. However, this method did not meet with wide recognition. In 2017, Institute TOMS under guidance of JKMRC’s specialists performed a testwork aimed at verification of a new universal technique for determination of grindability of initially fine materials. An object was to test three aged tailings samples for the subsequent modelling of comminution circuit and evaluation of potential throughput of the existing ball mills with final grind size of ?80 passing 53 µm. In parallel with development of the universal approach, TOMS’ specialists carried out tests according to the Levin method in order to compare the data resulted from two methods. The results from lab ball mill testing on three products following the alternative test methods are presented in this paper along with the testing methodology and results analysis. Specific energy was calculated for regrinding of the materials to the required size. Difference of the examined methods and assessment of their applicability for sizing of full-scale equipment are explored."

Jan 1, 2018

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, Keiko Sasaki

"Hydrogen peroxide (H2O2) is frequently used as an oxidizing agent in various applications. It has also been reported to reduce the recovery of sulfide minerals. Moreover, the previous work applied H2O2 aqueous solution in selective flotation of chalcopyrite and molybdenite. However, the oxidation method suffered in pilot scale test due to too long conditioning time. Furthermore, the excessive reagent consumption increased the reagent cost, causing the method not economically feasible. Consequently, further improvement is required to reduce the conditioning time and the reagent consumption. The oxidation performance of H2O2 can be improved by using ferrous iron as catalyst, producing a Fenton’s reagent which is more powerful oxidizer than the H2O2 itself. Therefore, the effect of Fenton’s reagent on the floatability of chalcopyrite and molybdenite was investigated in this study. The flotation test results show that selective flotation of chalcopyrite and molybdenite might be possible at low concentration of H2O2 aqueous solution by adding ferrous iron. Moreover, the conditioning time could be shortened by this improvement. To understand the phenomenon, surface characterization using atomic force microscopy (AFM) along with x-ray photoelectron spectroscopy (XPS) analysis were carried out. The AFM images show that the surface of chalcopyrite was readily covered with mountainous features which alters its hydrophobicity after the oxidation treatment. Meanwhile, the molybdenite surface remained clean and relatively hydrophobic. The XPS results indicate that the mountainous features are various oxidation products (i.e., FeOOH, Fe2(SO4)3, CuO, Cu(OH)2). Possible mechanisms of this phenomenon were proposed in this work.INTRODUCTIONConventionally, copper and molybdenum ores are separated in selective flotation circuits by using copper depressants (i.e., sodium hydrosulfide (NaHS), sodium sulfide (Na2S), and Nokes reagent (P2S5+NaOH)). However, these depressants are usually toxic or hazardous. Therefore, various methods have been developed to replace these toxic and hazardous depressants, for example, by synthesizing new non-toxic or low-toxic depressants or by using various oxidation methods such as sodium hypochlorite in an alkaline medium, manganese dioxide, oxygen, ozone, and plasma pre-treatment (Arbiter and Young 1951; Barzyk et al. 1981; Curtis 1941; Hirajima et al. 2014, 2017). Recent study by Chimonyo et al. (2016) reported the effect of H2O2 on reducing the recoveries of sulfide minerals. Moreover, Hirajima et al. (2017) demonstrated that H2O2 depressed the floatability of chalcopyrite and could deliver a selective separation on copper and molybdenum (Cu-Mo) bulk concentrate in flotation process. However, they reported that this method required a higher concentration of H2O2 and a longer treatment time (4.5 h) to get a comparable result to that of using NaHS as copper depressant. Therefore, further improvements are necessary to reduce the conditioning time and reagent consumption."

Jan 1, 2018

By B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, J. Taguta

The adsorption of heterocyclic collectors such 2-mercaptobenzothiazole (MBT), 2-mercaptobenzoxazole (MBO), 2-mercaptobenzimidazole (MBI) and their derivatives on pyrite form a basis in understanding the flotation reactivity that may be applicable in a wide range of sulphide minerals. This study uses a computational and experimental approach to determine the heat of adsorption of MBT, MBO, MBI and modified MBT collectors onto pyrite surfaces. Computational calculations found that the adsorption energies were in the order: MBO > MBI > MBT. The heterocyclic collectors were adsorbed in their thiolate form on the surface. In the case of the pyrite (100) surface, the MBT adsorbed through the exocyclic sulphur atom, while MBO and MBI adsorbed through the exocyclic sulphur and N atoms onto the 5-coordinated Fe atom. The (111) surface was found to be more reactive and different adsorption mechanisms were predicted, where the MBT exocyclic sulphur atom bridged on the 5- coordinated Fe and surface 2-coordinated sulphur atoms, while the N atom adsorbed on the 5-coordinated Fe atom. In the case of MBO and MBI, dissociation of the exocyclic sulphur atom from the collector occurred with subsequent interaction with the surface 5-cordinated Fe and 2-coordinated S atoms. This resulted in the collector carbon atom adsorbing on the surface 2-coordinated S atom, while the N atom adsorbed on the 5-coordinated Fe atom. The adsorption of the modified MBT was found to be more exothermic than the MBT, which showed that introduction of a –CS2 group on the exocyclic sulphur atom improved the affinity of MBT on the surface, and was thus a better flotation collector. The computational results were supported by experimental enthalpy of adsorption measurements and microflotation tests. The chemistry of the heterocyclic thioamides is complicated by the fact that they can exist in a number of tautomeric and ionic forms at different pH’s. This is discussed in relation to the flotation and calorimetric data.

Jan 1, 2018