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By L. A. Roe, E. A. Elevatorski

Wollastonite, named after William H. Wollaston, an English chemist, is a calcium metasilicate, CaSiO3; CaO: 48.30%, SiO2: 51.70%. It has a short history as an industrial mineral. The earliest production of wollastonite is reported to be from a deposit near Code Siding, located north of Randsburg, CA. At this locality small tonnages of wollastonite were quarried during 1933-34 and 1938-41, and processed into mineral wool. This operation was largely experimental and virtually no United States production was again reported until the 1950s when a large deposit near Willsboro, NY, was developed by the Cabot Corp. A processing plant was placed onstream in 1953, with nearly continuous production to date. It is currently operated by NYCO, a division of Processed Minerals, Inc. Since 1958, wollastonite deposits in the Little and Big Maria Mountains of Riverside County, and in the Panamint Range of Inyo County, both in California, have operated intermittently for production of both ornamental and commercial wollastonite. During 1980, the United States was the major producing country, furnishing about 75% of the world's output. Current production comes from Finland, Mexico, India, and Kenya. Small amounts have been shipped intermittently from the USSR, New Zealand, Republic of the Sudan, Republic of South Africa, and Namibia (South-West Africa). The principal use of wollastonite is in the manufacture of plastics. Other uses are for paints, ceramics, adhesives, fluxes, glazes, thermal insulation board, and refractory products. Mineralogy Pure wollastonite, CaSiO3, has the composition of 48.3% CaO and 51.7% SiO2. However, it is seldom found in the pure state due to the ease with which it takes into solution the metasilicates of manganese, magnesium, iron, and strontium. Predominantly, wollastonite occurs as a contact metamorphic deposit forming between limestones and igneous rocks. Commonly associated minerals are garnet, diopside, epidote, calcite, and quartz. It has a specific gravity of 2.8 to 3.0, and hardness of 4.5 to 5 on Mohs' scale. When pure, it has a brilliant white color, but with impurities it may be grayish or brownish. Luster is vitreous to pearly. Melting point of wollastonite is about 1540ºC. Wollastonite occurs in coarse-bladed masses, rarely showing good crystal form. It is usually acicular or fibrous, even in the smallest of particles. The most unique property of crushed and ground wollastonite is its cleavage. Fragments of crushed wollastonite tend to be needle-shaped, imparting a high strength, and this property is the basis for many of its uses. The fiber lengths are commonly in the ratio of 7 or 8 to 1, length to diameter. The average diameter of wollastonite is 3.5 µm. Some crystals of wollastonite fluoresce under short-wave or longwave ultraviolet light, or both, with colors ranging from yellow-orange to pink-orange. Specimens may also show phosphorescence. The acicularity of wollastonite is a property of considerable importance to the marketplace. The plastics industry makes utilization of high aspect ratio grades of wollastonite (20:1) for reinforcing thermoplastics and thermoset polymer compounds. The naturally high pH of 9.9 (10% water slurry) is a prime property to the coatings industry. The coatings industry uses milled grades of wollastonite as a pH stabilizer in interior and exterior PVA and acrylic latex systems. Processed wollastonite can have a G.E. brightness of 90 to 93. Chemically, wollastonite is inert and this property makes it useful as a filler and reinforcing agent. There are two polymorphs of calcium silicates: wollastonite, a low temperature form, and pseudowollastonite, a high temperature

Jan 1, 1983

By A. M. Childs, R. F. Mather, K. R. Rawling

"The challenges encountered in the design and construction of mines and their process facilities today are becoming more intense and the engineering more competitive. The need to incorporate new techno1ogy to compensate for ever rising costs is always present, but its application in the harsh environment of Northern Canada increasingly requires the inclusion of new proven methods and innovative approaches to arrive at economically attractive projects.This paper deals with the development of the process design for the Cullaton Lake Gold Mine in the Northwest Territories. Particular emphasis is given to the interaction of the imposed construction and testwork schedules, and their effect on certain process decisions.The challenge that faced the project team may be defined by the following factors:1. A schedule which required that metallurgical testing, engineering, and procurement and delivery of all equipment and construction supplies should be complete within a period of ten months.2. Transportation of all personnel, equipment and supplies to the site by airlift, as no road was available or affordable.3. A six week period when transportation to the site was impossible.4. The extremes of temperature beyond the tree line in the Northwest Territories.5. A complete lack of infrastructure in the area."

Jan 1, 1983

By Paul C. Hyndman

Three properties in the Tuolumne River RARE II area, the Eagle Bluff Mine (lode) and the Indian Creek Bar and Bossy Bar Prospects (placer), have identified subeconomic gold resources (table 1). Nineteen other properties have potential for gold resources. Adjacent to the study area, five properties have identified mineral resources, and nine others have potential for resources. Properties having high-grade zones (shoots), but licking enough tonnage to be classified as resources, are listed in table 2. Gold, in lode and placer deposits, is the principal mineral commodity in the Toluene River study area. Ten properties within the RARE II boundary have gold-rich zones or shoots; they range in size from 12 to 2,500 tons and in average grade from 0.09 to 0.97 oz gold per ton.

Jan 1, 1983

By Robert B. Fulton

Staurolite, an iron aluminum silicate mineral, is used industrially as a high value-in-use sand-blasting agent, as a premium grade foundry sand, and as the source of aluminum in portland cement manufacture in areas where the aluminum constituent is not economically available from shale or argillaceous limestone. It is produced by E. I. du Pont de Nemours & Co. as a coproduct in titanium mineral production in Florida where it was first recovered on a commercial scale in June 1952 from the Pleistocene sand deposit known as Trail Ridge. In the Trail Ridge deposit it comprises about one-fifth of the heavy minerals, the principal other heavy mineral constituents being ilmenite, leucoxene, rutile, zircon, kyanite, sillimanite, and tourmaline. Staurolite and the other silicate nonconductive heavy minerals are separated from the conductive titanium minerals on high-tension separators. The silicates are then separated from one another magnetically, the staurolite being relatively magnetic. In the total processing, 200 tons of raw sand yield 7 tons of heavy mineral concentrate from which about one ton of staurolite is recovered. This process yields staurolite concentrates of the characteristics given in Table 1. These concentrates are sold as three products with the size distribution of subrounded particles shown in Table 2. All three grades are used in sand-blasting for cleaning metal, for paint removal, and for cleaning buildings. Staurolite compares favorably with lower unit cost abrasives, such as boiler slags and mineral aggregates, in applications where the abrasive is used only one time and is not recovered. Because it is hard, fine, clean, and dense it can reduce blasting time, with less material reportedly being required [ ]

Jan 1, 1983

By N. J. Themelis

The basic chemical, thermal and transport principles that underlie sulfide smelting of. copper, nickel and lead are reviewed. Two basic types of modern smelting processes are distinguished?: flash-smelting, where the predominant reactions occur between oxygen-bearing gas and concentrate particles dispersed therein; and bath-smelting where the concentrate is enveloped and reacted in a turbulent bath of matte, slag and gas. The controlling heat and mass transfer phenomena are discussed, and appropriate correlations are proposed.

Jan 1, 1983

By H. William Zeller

The Bureau of Mines is conducting research to determine whether the use of chemical surfactants improves respirable coal dust control and is evaluating laboratory test criteria for selecting effective surfactants. This publication presents the results from wetting effectiveness tests with emphasis on the capillary rise test. The test variables investigated included coal particle size, type of surfactant, surfactant concentration, test duration, and mineral con-tent of the water. In addition to the rise test, measurements of con-tact angle, zeta potential, and sink time for various coal and surfactant combinations were conducted. No significant correlations among the four wetting tests were observed, a surprising result which implies that each test type measures specific aspects of the wetting phenomenon and also that each test type should only be used to select surfactants for specific applications. For example, the rise test shows solution penetration into porous materials, and the sink test discriminates among surfactants for dispersing finely ground materials into suspension. Another important conclusion is that combinations of agents retain their individual wetting properties, allowing mixtures to be for-mulated to perform well in both rise and sink tests.

Jan 1, 1983

By H. Craig Boyle, Craig H. B. Leitch

"The Trout Lake stockwork molybdenum deposit is located in the Selkirk Mountains of British Columbia, 50 km southeast of Revelstoke. The property is being explored by a joint venture between Newmont Exploration of Canada and Esso Minerals Canada.The deposit is associated with a small granodiorite stock of Upper Cretaceous age (76 Ma) which has variably altered the surrounding schists, argillites and marbles of the lower Paleozoic Lardeau Group to hornjelsic biotite schists and skarn. The intrusive is composed of a small stock and an intersecting network of northeast- and northwest-trending dykes at surface that coalesce downward into a larger stock. There are two main phases of intrusion, with an earlier quartz porphyritic granodiorite cut by an intra-mineral ""quartz diorite"" porphyry. A strong sub-vertical north-trending fault controls the distribution of the mineralized stock work and displays post-mineral movement.Molybdenite, accompanied by pyrite and pyrrhotite, is mainly present along the margins of veins in a well-developed quartz stock work, but occasionally is strongly disseminated in microfractured intrusives. The stock work is strongest in and around the contacts of the intrusive and its apophyses, and occurs over a vertical range of more than 1,000 m. As defined by the 0.10% MoS] contour, the main mineralized zone is up to 300 m long by 200m wide. Preliminary drill-indicated reserves, currently being revised, are approximately 50 million tonnes of 0.23% MoS2, within which are several zones of higher-grade material. Hydrothermal alteration, as defined by quantitative X-ray diffraction studies on composite core sections, is composed of a central quartz/K-feldspar/albite/minor biotite zone coincident with molybdenum mineralization, which is overlapped by a slightly later, antipathetic quartz/ sericite/pyrite zone. Ankeritic carbonate is also a common alteration mineral, but only traces of fluorite, and no topaz or sulfosalts, have been observed. Analysis for trace elements such as Sn, W, Bi, Sb, As, Hg, U, Ag, Au, Mn, Cu, Pb, Zn and F has been limited except for Sn and W, which appear to be zoned inside and outside the Mo zone respectively; the other elements do not show detectable patterns thus far."

Jan 1, 1983

By R. F. Tylecote

"The closure of the iron and steel making plant at Consett in Durham in 1980 marked the end of an era-a long era in the world's iron and steel making history. Iron had been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century.The paper describes sites in the area that first worked the bloomery process and then, in the 16th century, as did most of Europe, graduated to the blast furnace process. The main emphasis is on the early introduction of coal to iron making at the end of the 18th century and the use of the steam engine to render integrated sites possible.IntroductionIron has been smelted in the Tyne-Wear area of the United Kingdom since before the Roman period, but apart from clear evidence of smithing in the Roman period, the historical evidence for iron production on a large scale dates from the 14th century. Like many other countries, the United Kingdom benefitted from the visits of foreign observers, such as Jars, Svedenstierna, de la Houliere and Dufrenoy, who left detailed records. In modern times, information gained from excavations of iron and steel making sites has supplemented the historical record.Natural ResourcesUp to the end of the 19th century, the industry was wholly dependent on its own resources. Iron ore, limestone, wood, coal and water power were all found a short distance away from the main valleys of the Tyne and Wear. The main sources of iron ore were the coal measures, with rider ores from the lead vein s in Alston and Weardale, and carbonate ores from shale horizons in the Carboniferous limestone. Good coking coal was available from West Durham and reasonable coal from the Tyne valley and Northumberland limestone. Limestone was plentiful."

Jan 1, 1983

By Harry E. Holzschuh

The two Agrico Chemical Company self unloading Phosphate Rock barges put into service in 1976 operate at over their design carrying capacity. Each barge now carries 26,000 short ton instead of the planned 25,000 short ton at 32 foot of draft. They are in service between Agrico's Tampa, Florida Terminal and the Donaldsonville, Louisiana Fertilizer Complex, moving a total of 2,500,000 short tons each year. This was the first use of the Parascrew design for a marine application. The barges, with their 3,000 STPH unloading and matching loading rate is the vital link in this total transportation and handling system. Rock is moved from the Pierce, Florida Mines through the Tampa Big Bend Terminal, across the Gulf of Mexico, and up the Mississippi to the Agrico Faustina Phosphoric Acid Plant 30 miles below Bacon Rouge, Louisiana. The trip from the terminal to the plant is 600 miles and the turnaround time is just about six days. Seven years operating experience has proved that the system works. Fittingly, the two barges are named the "Faustina" and the "Pierce". They have a beam of 85-feet and are 495 feet long. folded depth is 43 feet, with a ballasted light draft of 19 feet and a typical loaded draft of 32 feet. There are four separated holds with the machinery room located forward of 101 hold. Each hold is 51 feet wide at the coamings with an 18 foot straight section on the side, and a 24 foot long, 600 slope sheet for a 23 foot clear reclaim width at the bottom. The Parascrew in each of the holds is 37 feet long between the bearings and is supported on a 14 inch diameter hollow shaft. The screw pitch varies and the diameter of the flights step up from l'-9" diameter to 2'-6" diameter on the discharge end. By sloping the centerline, a minimum four inch bottom clearance is maintained across the hold. Some bending of the tube does take place.

Jan 1, 1983

By Jaime Tumialán

El presente texto describe el diseño y ejecución del sistema con winchas de fricción" Koepe" del pique central de Casapalca, dado que será uno de los más modernos del Perú y su aplicación se realizará en minas con características semejantes. Existen dos sistemas básicos de izaje: el de izaje con wincbas de tambora, donde el cable es enrrollado o desenrrollado en la tambora durante el izaje, y el de izaje con wincbas de fricción ("Koepe"), en el cual el cable pasa sobre la polea o tambora de fricción durante el izaje. Cada sistema tiene sus ventajas y desventajas y solo debe usarse en una correcta aplicación. Las principales ventajas de las winchas de fricción sobre las de tambora son: menor consumo de energía para igual capacidad, menores dimensiones de las partes mecánicas, menor costo de capital y operación, mayor seguridad debido a que se usan varios cables y una mayor capacidad a grandes profundidades.

Jan 1, 1983

By Robert H. Robinson, Levent Ozdemir, Russell J. Miller

The paper summarizes an investigation into the applicability of mechanical excavation to oil shale mining; identifies available machine types that are best suited to various aspects of the mining operation; presents preliminary comments on the configuration of an "IDEAL" oil shale mining machine; and establishes the background information necessary for conceptualizing and evaluating new mining methods using mechanical excavation equipment. Conclusions are also presented as to the best currently available systems, as well as potential future systems.

Jan 1, 1983

By P. M. Prasad

The last two decades have witnessed the emergence of numerous hydrometallurgical and direct processing techniques for the extraction of some metals from pocketed/lean/complex sulfide ore deposits. A new approach with some inherent technological merits, investigated in recent years, is the lime-enhanced reduction of metal sulfides. Thermodynamic aspects relevant to the lime-enhanced reduction of metal sulfides by H2,C0 and C are discussed. A survey of the researches on the basic features of and factors influencing the lime-scavenged reduction of selected sulfides and sulfide concentrates reveals that lime tremendously enhances the sulfide reduction rates (up to 100 times) and drastically reduces the sulfur emission into off-gas to negligible levels. Further successful practice of lime-enhanced reduction requires only a moderate temperature of reduction (characteristic of each sul¬fide) and, in the case of gaseous reduction, relatively low gas flow rates. Relevant kinetic aspects of the concerned reactions that have a bearing on process development and its understanding are also briefly discussed. A conceptual scheme of general applicability for the processing of sulfide concentrates by the lime-enhanced reduction technique consists of three main steps: (0 lime-enhanced reduction by a suitable reagent (e,g., H,2, CO, gasified coal, water gas), (ii) separation of the product metal from the dry slag (CaS + unused CO) by mechanical separation, magnetic/gravity concentration or flotation and (iii) melting and refining by standard procedures. This novel approach, which is patently less complex, is expected to employ basically simpler flow sheets at comparatively lower operational temperatures and aid in pollution abatement. Potential for developing such a route for the small scale extraction of metals like copper, molybdenum and antimony is indicated. Possibility of utilizing this technique for the production of fibers/ filaments of some metals is also outlined.

Jan 1, 1983

Joint ventures exist as a means of sharing risks and obeying regulations. An unincorporated joint venture allows a company to take a share only of a project yet allows that company to treat such share as though it were an integral part of the company. The nature of the risks inherent in many ventures is described and comparisons made with alternative corporate vehicles. Different procedures for managing joint ventures are also reviewed and the types of problem encountered in establishing and operating joint ventures are discussed. The basic characteristics of successful joint ventures, in Australia, are listed and a conclusion reached that, despite its difficulties, the joint venture will continue to proliferate as a corporate vehicle for project development.

Jan 1, 1983

By Howard J. Handewith

Long used in mine development in England, Europe and Russia, roadheaders are growing in size, features, productivity and application. Beginning with the basics, this paper covers the economic and the technical aspects of the new roadheaders in both mine production and development. The author explains how to choose and integrate roadheaders into ongoing operations as another step in the inexorable march from labor to capital intensive mining. Innovations now on the drawing boards are covered that are the challenge of the future.

Jan 1, 1983

By R. M. Schuster, F. M. Benavides

Samuel G. Bonasso The article by Benavides and Schuster provides an in-depth study of three transportation alternatives for a four-mine complex in western Kentucky. The examination of aerial tramways was not undertaken as an alternative solution. We feel this is an oversight since industrial ropeways are competitive with both belt conveyance and overland truck hauling. In fact, there are aerial tramway systems, operational today, which are 100 years old and operating with some original components. Maybe unfortunately, there are no fixed rules or guidelines whereby the most cost-effective means of transporting and handling material for a given situation may be selected. Each situation must be evaluated so the variables that influence the selection of the desired alternative can be clearly defined. However, there are in-place industrial ropeway systems that have proven economically feasible over a range of 1.6-50 km (1-31 miles). The more difficult the terrain, the greater the cost efficiency.

Jan 1, 1983

By Thomas J. Peters

The U.S. Bureau of Mines and the U.S. Geological Survey are responsible for the evaluation of the mineral resources and potential of further planning areas included in the U.S. Forest Service Roadless Area Review and Evaluation (RARE II) program. The Bureau of Mines primarily evaluates mineral deposits and prospects within the areas. The Geological Survey naps the area's geology and conducts geochemical sampling. Evaluations are in conformance with the Forest and Rangeland Renewable Resources Planning Act of 1974 as amended by the National Forest Management Act of 1976. The Hauser RARE II area, which consists of 7,600 acres (3,100 ha) within the Cleveland National Forest, is in southern San Diego County, California. The area, which forms the north slope of Hauser Canyon, ranges between 1,600 and 3,919 ft (490 m) in elevation. It is sparsely to densely covered with desert shrubs. The area is underlain by granitic rocks of the Peninsular Ranges batholith.

Jan 1, 1983

By D. Geoffry Minnes, Ray Blair, Stanley J. LeFond

Nepheline syenite is a silica deficient crystal-line rock consisting of albite and microcline feldspars and nepheline, together with varying but small amounts of mafic silicates and other accessory minerals. Nepheline-bearing rocks are widely distributed around the world but only in Canada, Norway, the Union of Soviet Socialist Republics, and the United States are deposits worked commercially, Because of its low melting point and fluxing ability, nepheline syenite was investigated in the early 1900s by many students of glass and ceramics. Although the nepheline syenite deposits in Methuen Township, Ont., Canada, were discovered as early as 1897 it wasn't until 1935 that the first mill was erected to produce nepheline syenite products. In Canada, nepheline syenite deposits are worked by Indusmin Ltd. and International Minerals and Chemical Corp. (Canada) Ltd. who have combined production capacity in excess of 1800 stpd. Between 1935 and 1972 seven million tons valued at $78 million were produced from the Methuen Township deposits. In Norway, the Norsk Nefelin Div. of Elkem Spigerverket has produced nepheline syenite from a deposit on Stjernöy Island in western Finland since early 1960. Production has increased from 8 kt in 1961 to over 200 kt in 1980. Nepheline syenite has been under investigation in the Union of Soviet Socialist Republics (USSR) since at least 1928. In 1951 the first commercial alumina works was brought on stream at Volkhov, near Leningrad, utilizing nepheline concentrates from the Kola peninsula as mill feed. Since then two others have been completed and more are planned. Large quantities of portland cement, sodium carbonate, and potassium carbonate are produced in conjunction with the alumina. A material called nepheline syenite, but actually a pulaskite, is produced in Pulaski County, Arkansas, by the McGeorge Construction Co. for construction aggregates and by the 3M Co. for roofing granules. The Dome Fill Co. purchases the fines and uses them in the preparation of enclosed construction fill. Production is over 2,000,000 stpy. Chap. 16 on "Feldspar, Nepheline Syenite, and Aplite" in the 3rd ed. of Industrial Minerals and Rocks (Castle and Gillson, 1960) and Nepheline Syenite Deposits of Southern Ontario (Hewitt, 1960) contain excellent accounts of earlier commercial development of nepheline syenite as a glass and ceramic material. As in the 4th ed., this chapter deals mostly with the period since 1960 and with matters not previously reported in detail. An English monograph on Nepheline-Syenite and Phonolite (Allen et al., 1968) is a complete survey, at the time, of nepheline syenite which, with its very complete list of references, is an excellent source book. End Uses Nepheline syenite from the Canadian and Norwegian producers finds use primarily in the manufacture of glass and ceramics. One producer also makes several grades of nephellne syenite that are useful as extender pigments and fillers in paint, plastics, and rubber. In the Soviet Union nepheline is used in increasing quantities in the manufacture of alumina, alkali carbonates, and portland cement and to a lesser degree it is used in the manufacture of colored container glass.

Jan 1, 1983

There are serious problems in forecast- ing accurately and achieving this goal depends on good quality information, correct assumpt- ions and sound analysis. planner. The forecaster must focus attention on a number of key areas of interest. These areas include major economic trends and changing GNP structure, consumption time series, end-use consumption patterns and substitution potential, accurately updating data bases (up to 5 years ahead), random factor estimation and examination of both long term and secondary mine potential. While metal price forecasting has suffered due to recent uncertainties, with increased importance on planning tools and cost analyses, it is still a necessary function. Forecasting is subject to the real world and the metal industry is made up of imperfect markets in a dynamic state. The real world provides the challenge to improve the accuracy of forecasting.

Jan 1, 1983

By Dyne GD

From experience in the design and operation of power station combustion facilities in most mainland Australian States, involving a wide range of black coals and lignites, and in the specification and procurement of coal supplies for power station use, techniques for the optimisation of coal resource development and power generation utilisation have been developed to ensure compatibility between characteristics of the selected coals and power station design. These techniques include computer data bases for resource data handling and computer simulation of coal-fired boilers for determining coal property cost effects. Data Base Systems allow results of coal analyses to be efficiently handled, to assist in the review of the relevance of resource data to the coal sections proposed to be mined and the coal fractions proposed to be marketed. Data Base Systems also facilitate the marshalling of coal quality data into basic utilisation format to enable a proper utilisation review and analysis of the certainty and scatter of coal properties. Computer simulation of the effects of different coal properties on the capital and operating cost of power stations is achieved by establishing conceptual design parameters of the major items of plant to relate the variations in coal specification to equipment size and type. Variations in power station budget costs can then be determined using the computer model for variations in coal specification.

Jan 1, 1983

Few, if any, reliable thermodynamic data are available for the activity of tin oxide in slags. In this work, the activity of the oxide in silica saturated iron silicate slags has been measured at 1573 K using the equilibrium Sn (alloy) + Y2O2-SnO (slag).Slag and a Ag-Sn alloy were sealed in a zirconium oxide crucible to prevent the escape of volatile tin oxide, and the oxygen pressure at equilibrium measured in situ using the zirconium oxide as a solid electrolyte. Activity of tin was calculated from known data for the Ag-Sn system and activity of tin oxide calculated from free energy data. The results have been extrapolated to predict the industrially important distribution of tin and iron between Fe-Sn alloy and iron silicate based slags.

Jan 1, 1983