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By Arthur V. Petty

The Bureau of Mines has researched the utilization of mining and pro-cessing wastes as raw materials for the production of glass-ceramic pipe. Characterization of various wastes as to occurrence and chemical composition is reported. A computer program was developed and used to identify waste materials and mixes that would result in glass melts from which glass-ceramics could be produced after cooling and subsequent heat treatments. The production of abrasion-resistant pipe from inexpensive and readily available domestic resources could offer an economical substitute for high-alloy steels containing the critical and strategic materials cobalt and chromium.

Jan 1, 1984

By John B. Wright

This paper describes laboratory techniques and subsequent results of Bureau of Mines research to produce chlorination-grade feedstock from an abundant, low-grade, domestic, rock ilmenite ore. The research is part of the Bureau-effort to devise technology that may help decrease U.S. dependence on imported raw materials. A rock ilmenite containing about 46 wt pct Ti02 was smelted in an electric arc furnace with coke, woodchips, and Na2C03 to separate most of the iron as pig iron and to form a low-iron, titanium-enriched slag. The slag was ground, pelletized, oxidized, and then sulfated with mixtures of SO2 and air in a continuous 4.5- to 9.1- kg/h apparatus at 1023 to 1223 K. The sulfated slag, containing 60 to 65 pct TiO2, was reground and leached in water at ambient temperature to decrease the combined levels of the troublesome Ca, Mg, and Mn impurities from 7.0 to 1.7 wt pct. At levels of more than 3 wt pct, these impurities contribute to operating and disposal problems, The final product was upgraded to about 84 wt pct TiO2. This material potentially is suitable for chlorination in a fluidized-bed reactor. The most favorable results were achieved with leached slag sulfated at a feedrate of 4.5 kg/h and at temperatures of 1073 to 1123 K.

Jan 1, 1984

By A. K. Gangopadhyay

This paper discusses the effect of grinding media composition, mineral type and slurry environment on the wear rate of various grinding media (balls). Sufficient wear data have been obtained and correlated with the modes of wear determined from examination of the ball surfaces using scanning electron microscopy. Five modes of wear have been identified to be operative under certain slurry conditions for the various ball compositions studied.

Jan 1, 1984

By Dae S. Young

A new probabilistic approach is introduced for slope stability analysis including adverse impact of blasting vibrations. The material strength within a slope area is randomized in this bi-variate joint probability analysis. To be a completely general engineering method, the new probabilistic approach employs the random variable transformation technique: the Hermite model of the Gaussian transformation function, which transforms the experimental histogram of strength values to the standard Gaussian variables. Because bi- normal joint probability is analyzed on the true probability region projected on the Gaussian transformed variable plane, it is an exact solution of slope stability based on the available sample data. Details of the probabilistic approach are given through a case study on an iron ore mine. The case study demonstrated that the probabilistic approach is effective and simple enough to be a routine engineering practice for slope analysis.

Jan 1, 1984

By J. D. Miller, A. Cortez, J. Hupka

The separation efficiency of the hot water digestion-flotation technique used for bitumen recovery from various domestic tar sands was evaluated. Bitumen viscosity was found to be the most important tar sand property in determining the success of the bitumen separation. Bitumen viscosity of the tar sand war controlled by changes in digestion temperature and/or changes in diluent (kerosene) addition. Complete and uniform dilution of the bitumen phase was achieved by providing a sufficient presoaking, or penetration time, for a given tar sand type. For all the tar sand samples tested, an excellent correlation was obtained between the coefficient of separation and the bitumen viscosity. To achieve a satisfactory coefficient of separation, it was found that the bitumen viscosity must be reduced below 1.5 Pa.s (16 P) at the temperature of digestion. This was the case regardless of the tar sand type, grade, or origin.

Jan 1, 1984

By Hun-Joon Sohn

Chemical metathesis and electrochemical reductive conversion of chalcopyrite in the presence of cupric ions were studied in sulfuric acid solutions for temperatures up to 90°C. The process results in the displacement of iron in the chalcopyrite lattice by copper ions with rejection of ferrous ions to the aqueous phase. The rate of reaction was found to be very slow, requiring subsieve-sized particles for extensive reaction to occur. The reaction was insensitive to copper ion concentration. Stirred ball milling of chalcopyrite introduces lattice strain. The reaction rate with strained particles was markedly higher than with annealed chalcopyrite. The reaction rate was found to be diffusion-limited, showing two distinct reaction stages corresponding to the formation of CuS (covellite) followed by Cu1.8S (digenite). The experimental activation energy for the first stage was 102 J (24.4 kcal) and the second stage 123 3 (29.4 -kcal) per mole. The rate-controlling process is diffusion of lattice ions, probably iron. The enhanced rate after milling is attributed to a recrystallization process which provides new paths for diffusion along dislocations and grain boundaries.

Jan 1, 1984

By Muhammad I. Kabir

The streamline method of recovery prediction reduces a two-dimensional problem to a bundle of one-dimensional ones. This paper presents the development and application of a novel scaling technique which, when used with a streamline model, causes s bundle of one-dimensional problems to further reduce to a single one-dimensional calculation. The one-dimensional calculation accounts for chemical-rock interactions and the streamline model for areal sweep. The scaling technique significantly reduces computation time, is readily modified to desk-top calculations, and can be applied to both absorbing and reacting species. The work was sponsored by the Interior Department's Bureau of Mines.

Jan 1, 1984

Exploration for uranium in Australia commenced only during the 1940s, but in this short period has been very successful as one third of the world's low cost uranium reserves have been discovered in Australia. Total uranium exploration expenditure in Australia up to the end of 1983 was $A(1983) 554 million; this discovered 20 potentially economic deposits and official reserves of 560 000 tonnes of uranium oxide at an average cost of $1 per kg of U 0 . An exponential 8 eserves indicates distribution of uranium r that there could be 54 undiscovered uranium deposits in Australia, each with reserves of 20 000 tonnes U308 or more, in addition to smaller deposits. Using a constant uranium price of $A(1983) 79 per kg, no deposit is economic at a grade below 0.12 per cent U 08 or with reserves of less than 3 000 tonnes. Selecting deposits with reserves of 5 000 tonnes U 0g or more as prime exploration targets, only 39 per cent of discoveries will yield a real internal rate of return (IRR) of 10 per cent or more. After committing a minimum exploration budget of $10 million to this search, an explorer has one chance between 7 and 12 of discovering a deposit that will repay the exploration investment.

Jan 1, 1984

By Allan R. Ide

It is a great pleasure for me to speak-before such a prestigious group as the American Institute of Mining, Metallurgical and Petroleum Engineers. The substance of my talk today is the handling of coal and petroleum coke: their characteristics and environmental problems, and how we were able to correct the problems, prescribe the cure and enjoy the benefits. When coke first became a by-product derived from the oil refineries everyone would have been very happy if someone had offered to take this pro- duct off their hands. Unfortunately, there was no market at that time, and no one seemed interested. Soon thereafter, it became a sellable product and began to be shipped to many countries in the world. This was when all of the pollution problems began. I will be talking briefly about some of these problems and showing a short film on this subject afterwards.

Jan 1, 1984

By John Durkin

Electromagnetic narrow-band signals were transmitted through the earth at 27 coal mines located throughout the United States. From those Bureau of Mines tests, apparent earth conductivity values were derived based upon a homogeneous half-space model of the earth. The derived conductivity values were found to be inversely proportional to the transmitted frequency and mine depth. A linear regression model relating the logarithm of the conductivity to the mine depth was formulated, and the results indicate that the mine depth can be an adequate predictor of the apparent earth conductivity above coal mines. Apparent earth conductivity was found to decrease with mine depth.

Jan 1, 1984

By Jonq-Keh Lee

This paper deals with the effects of air leakage from intake to return airways through a series of stoppings on the analysis of coal mine ventilation. The mathematical model which assumes continuous leakage along adjoining intake and return airways is reviewed, and a new mathematical approach is presented based upon the concentrated leakage through individual stoppings. The procedure incorporating the new method in the analysis of coal mine ventilation networks is also discussed.

Jan 1, 1984

By K. P. Chong

Fracture toughness of oil shale is an essential property in fragmentation to optimize particle sizes and permeability distributions in in-situ processes. Fracture mechanics of oil shale has been based on conventional fracture mechanics using notched samples and assuming the material to be isotropic and elastic. Oil shale is a layered material more accurately characterized as transversely isotropic. The senior author proposes to use a semi- circular core specimen with a center crack subjected to three point bending. Singular crack tip elements with isoparametric elements are used. The precracked semi-circular disk is modeled under displacement loading. The effect of crack length on the non-dimensionalized stress intensity factor is investigated by strain energy method, ellipse method, and stress method. Very close agreements are found. The fracture toughness is obtained by compressing the specimen in to failure. Parameters such as oil yield are investigated.

Jan 1, 1984

By Jones IO

Although small units have been in use formany years, particularly in opal mining at shallow depths, there has been little effort in the past to explore the potential of the vacuum lift system in other more demanding applications. Recent developments in Western Australia by a small number of mining companies, contractors and manufacturers have seen the design and construction of several larger, more powerful units for use in winzing, shaft sinking, hoisting and spillage removal. Some of these units have proved very successful and suggest that they could be developed for a wider range of applications and duties in future.

Jan 1, 1984

By P. R. Thomas

This paper addresses the relative long-term cost and resource position of new and existing ferrochromium production in selected Market Economy Countries (MEC'S). The market impact of new ferrochromium production in nations such as India and the Philippines and the continuing change in international trading patterns are also evaluated. This paper draws upon the data and analyses of a recent Bureau of Mines, Department of Interior, Minerals Availability Program appraisal that evaluated the cost and availability of chromite and ferrochromium production from the demonstrated resources of 80 producing or potential mining operations in 10 market economy countries.

Jan 1, 1984

By G. K. Derby

The Bureau of Mines investigated methods for removing dragline bucket wire rope terminations with the objective of finding efficient methods that are safer than the method most commonly used at U.S. surface mines, which is to use the explosive impact of a projectile fired from a cannon to remove the rope termination. Removal of a wire rope termination for repair or replacement requires separation of the wedge and socket that lock together to secure the rope end. The Bureau investigated currently used methods and improved upon and tested two safer alternate methods for removing wire rope terminations. A cannon test program was conducted, using 40-and 50-gr primer (detonating) cord, to establish the possible force produced with a 4-in-bore cannon and a 55-lb projectile. Wedge and socket units supplied from cooperating mines were separated under controlled conditions to establish data on separation force requirements. The two alternate methods investigated were use of the force generated by (1) a pendulum ram and by (2) a portable hydraulic pusher. Both methods are capable of providing sufficient force to effect wedge and socket separations on draglines with up to 78-yd3 buckets under normal conditions.

Jan 1, 1984

By Michael A. Werner

"A Yieldable Structure for Use in Areas of High Rock Stress & Deformation." Rock stress of up to 9000 psi have been recorded in the mines of the Coeur d'Alene Mining district. Associated with these large stresses are rock fractures and deformation. In order to maintain openings required for mining, large wood preparation structures are constructed to provide access to the work areas for men and materials. These wood raise preparation structures are costly to construct and maintain. Therefore a steel-foam concrete structure was designed and proposed for testing which would be less costly to construct, require no maintainence and maintain its structural integrity while allowing up to 53 inches of wall rock deformation.

Jan 1, 1984

By Howes PM

In the iron and steelmaking processes, dusts are generated and treated by wet dedust- ing methods to form slurries which are high in iron content, but also contain certain impuri- ties. For many years these slurries have been processed and the wet cake, which is produced, has been dumped because of the high zinc and alkali chloride contents. Sintering is an appropriate process for recycling of these materials, provided the deleterious impurities can be kept under control. Zinc is a deleterious element in blast furnaces because it promotes the formation of accretions on the upper walls of the furnace. This results in irregular furnace performance. Alkali chlorides effect the emissions from the sinter plant waste gas due to the high resis- tivity of these components, resulting in decreased efficiency of the electrostatic precipitator. Experimental work indicated a concentra- tion of zinc in the -11 pmt particle size frac- tion. A cyclone plant was installed producing a "coarse" usable product and a "fine" waste Product.

Jan 1, 1984

By W. C. Bagby

The Dee disseminated gold deposit is the northernmost mine in the Carlin gold belt. We analyzed soil samples £ran undisturbed areas overlying the deposit to determine the usefulness of soil geochemistry in identifying ore zones. The depth of sampling ranged from 12 to 14 inches, depending on soil development. The -80 mesh fraction was analyzed by atomic absorption for Au, As, Sb, Hg, and T1 and by semiquantitative spectrographic analysis for Ag. Highly anomalous Au, Kg, As, Ag, and Sb are most closely associated with ore zones whereas T1 is more broadly dispersed. Hg is the only element that identifies deep ore.

Jan 1, 1984

By Peter G. Chamberlain

The surge in gold and silver prices during the 1970's attracted many new mining operators and has rekindled interest among experienced ones. With its low capital investment requirements and fast payout, leaching has attracted many operators--particularly those with small or low- grade deposits. Although in certain situations leaching offers many advantages over conventional mining methods, many operators are uncertain how these relatively new techniques should be implemented. Consequently the Bureau of Mines has prepared this circular to disseminate information on gold and silver leaching practices, techniques, and problem. Engineering data gathered from 26 operations indicate that most ores are leached in heaps following crushing and distribution on pads. Metal values are recovered from cyanide leach solutions using either zinc precipitation or charcoal adsorption. Potential problems that my hamper on block development of a leaching operation are poor percolation characteristics of the ore, calcium salt buildup, low temperatures, and solution losses. An extensive bibliography on gold and silver leaching is appended.

Jan 1, 1984

By Norman J. Tienkaivip, Christopher J. Preston

"This paper describes the use of electronics for physical measurement and computer analysis in both open-pit and underground mining operations for the ultimate purpose of optimizing production blasts. Techniques in monitoring single borehole blasts using both pressure and vibration sensors to establish in-situ dynamic rock properties are outlined, including characterization of multiple borehole production blasts with regard to stress generation.Once field derived measurements are computer analyzed, they are channelled as input parallel to other data, such as the explosives thermochemical performance properties generated by a sophisticated computer program called ""HT-65"" into BLASPA . BLASPA, a blast simulation computer program, then couples these input with a mathematical model which defines the blasting processes. Aspects such as the blast geometry, explosive loads and distribution, hook-up, and costs are studied. The final output table gives specific blast performance or quality factors for each blast procedure. These results are then easily compared and rapidly optimized to achieve maximum performance at lowest blasting and drilling cost."

Jan 1, 1984